Engineering Commons^™

Synthesis Of Acetylene Diols In The Catalytic System Of Cu(Otf)2/Thf/Tbabr, Abduvakhаb Ikramov, Lochinbek Q. Ablakulov, Odiljon E. Ziyadullayev, Sardor M. Rakhmatov, Mirjalol E. Ziyadullayev

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the work was the synthesis of acetylenediols in the Cu(OTf)₂/THF/TBABr catalytic system. The synthesis of acetylenic diols based on the alkynylation process of aliphatic and heterocyclic ketones containing two carbonyl groups in their molecules in the presence of alkyne hydrocarbons was studied for the first time using the Cu(OTf)₂/THF/TBABr catalytic system. The effects of temperature, reaction time, nature of solvent and catalyst, and molar amount of starting materials on the synthesis of acetylenic alcohols in the selected system were studied, and based on the results obtained, alternative conditions for the process were found.

Synthesis And Study Of New Complex Compounds Of Copper(Ii) And (5-Methyl-1,3,4-Thiadiazole-2-Ylsulfanil)-Acetic Acid, Ekaterina V. Kinshakova, Aziz K. Atashov, Batirbay S. Torambetov, Shakhnoza A. Kadirova

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this study is to synthesize new copper (II) coordination compounds with a heterocyclic polydentate ligand (5-methyl-1,3,4-thiadiazole-2-ylsulfanyl) -acetic acid and to study their structure. The structure of the complexes was established by the method of X-ray diffraction analysis (XRD) of single crystals, it was shown that the complexes have a polymer structure and a coordination polyhedron of the square pyramid type, however, one of them is mono-nuclear composition (C₁₀H₁₄CuN₄O₆S₄*2H₂O)_n, and the second is bi-nuclear composition of cluster type (C₂₀H₂₀Cu_{2 …}

Synthesis Of Acetylene-Based Hetarene Derivatives In The Presence Of Catalysts, Abdulla T. Umrzokov, Abduvaxаb Ikramov, Khusnitdin M. Vapoev, Yusuf K. Zhumanov, Sardor M. Kodirov

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the study is to synthesize hetaren derivatives of acetylene amination reactions using local natural raw materials as catalyst carriers. Various grades of Oltintag and Angren kaolins, various grades of Navbakhor bentonite, as well as the opaque rock of the Karmaninsky deposit were used as catalyst carriers. Thermal, acidic and hydrothermal treatment was carried out on the appropriate sorbents, with the production of catalysts of various modifications from sorbents and active components. The processes of catalytic condensation of acetylene with ammonia were studied using modified catalysts. The effect of the reaction temperature, the active components of the catalyst, …

Bismuth Cuprates Produced By Solar Energy Showing Anomalous Resistance, Dilbara Dj. Gulamova, Sirojiddin Z. Mirzaev, Sirojiddin Kh. Bobokulov, Timur I. Gulamov

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the study is to obtain bismuth superconducting cuprates with higher superconducting properties. The advantages of superconducting materials in power engineering, disadvantages of synthesis based on solid-phase and melt principles, and the prospect of using nontrivial methods to obtain high critical parameters are presented. The advantages of synthesis under the influence of concentrated solar energy are shown. In order to obtain a superconductor with high critical properties, a massive, long-term stable bismuth cuprate was synthesized using solar technology. It pushes out an external magnetic field and has a nanostructured layered microstructure with caverns containing submicron-sized particles. The phase …

Predicting Battery Efficiency: A Theoretical Approach, Haiti Schafers

SACAD: Scholarly Activities

The Kansas ElectroRally Races continuously demand faster electric vehicles (EV). When designing a vehicle one of the most important components is the battery. This study was designed to find the following; What is the optimal throttle percentage to run a 36V 20Ah (768Wh) LiFePO4 Rechargeable Battery Pack[1].

The optimal throttle percentage was found with methods detailed in a different section. Based on the performance of the older cars this study choose to focus on 50% and 70%, while obtaining other relevant data to further that inference.

The Role Of Chitosan In Increasing The Mechanical And Antibacterial Properties Of Paper, Khurshid Khamidulla Ugli Khaydullaev, Jaloliddin Faxriddin Ugli Ungarov, Munavvar Umar Kizi Iskandarova, Yorqinjon Tulqin Ugli Ergashev, Guzal Yusupovna Akmalova, Elmurod Abduqodirovich Egamberdiev

Technical science and innovation

Chitosan is also widely used in the paper industry to improve paper production and paper properties. Indeed, the molecular structure of chitosan is similar to cellulose, which contributes to the formation of a strong compound. Due to the presence of chitin (-NHCOCH₃) functional groups in chitosan (-NH₂), these groups are insoluble in water, but soluble in a solution of chitosan acid with deacetylation levels above 60%. On the contrary, chitin does not dissolve. Chitin and chitosan are insoluble in alkaline and organic solutions under normal conditions. In general, a high percentage of the amine (NH_{2 …}

Design Features Of Ion Exchange Plant For Wastewater Treatment, Tatyana Vladimirovna Drabkova, Sadritdin Makhamatdinovich Turabdzhanov, Fayzulla Nigmatullaevich Rakhmatullaev, Ulughukha Nusratullaevich Rakhmatov, Aziza Alimdzhanovna Shokhakimova

Technical science and innovation

This study presents an ion exchange unit designed for selective and comprehensive wastewater treatment. The unit includes all technological processes: solution filtration, ion exchanger loosening, sorbent regeneration and washing, which is a significant advantage of the proposed technology and eliminates the need for additional devices. This significantly increases the overall efficiency of the cleaning process, reducing costs and simplifying the operation of the system. Experimental studies have confirmed the high efficiency and feasibility of using ion exchange units in modern operating conditions, which makes them universal in application for various industries, including metallurgy and chemistry. The main idea of the …

Approach Formula To Increase Energy Efficiency Of Internal Combustion Engines In The “Green Economy” And Impact On The Natural Ecosystem, Zakirjon Ergashevich Musabekov, Hilola Zokir Qizi Uralova, Sayyodbek Ilxomjon O‘G‘Li Abdullajonov

Technical science and innovation

This article discusses, analyzes, and proposes solutions for the role of internal combustion engines in forming a "green economy", as well as ways to replace or modernize them. The relationship between internal combustion engines and the "green economy," as well as their energy efficiency and impact on natural ecosystems, is a crucial and urgent issue. These engines primarily generate energy through the combustion of petroleum-based fuels such as gasoline and diesel. However, this process releases harmful gases into the atmosphere, contributing to environmental degradation. The green economy is an economic model designed to protect the environment, ensure the efficient management …

Practical Experiments Conducted On Determining The Air Velocity At The Inlet And Outlet Of The Intensive Separator And Processing Of The Obtained Results, Ilxom Zapirovich Abbazov, Kudrat Sherzadovich Khodjayev, Bobir Nabijon Ugli Sharopov, Rashid Kaldybaev

Technical science and innovation

In the primary processing of cotton raw materials, the means of storing cotton, transporting it from the gins to the departments, and transferring the product between departments are pneumatic conveying devices. Separators are devices for separating cotton from the air and cotton mixture in such pneumatic conveying devices. Separators are used in two types of conditions, namely, in a mobile or stationary state. The device for separating cotton from air consists of three main working parts: they are the parts for feeding cotton into the working chamber, separating it from the air flow, and removing cotton and air. These parts, …

Effective Cleaning Of Cotton In A Saw Gin, Rustam Shennikovich Sulaymonov, Amirqulovich Begzod Irgashev, Zarshid Omonov Jumanazar O'G'Li

Technical science and innovation

In order to improve the efficiency of the cotton cleaning process and improve the quality of the fiber, the Gin feeder was improved with a colosnik grid. This constructive change serves to more effectively separate cotton raw materials from impurities and reduce the likelihood of fiber damage. Studies have found that the cleaning efficiency of the feeder in cleaning Cotton of varieties I and III has increased by an average of 2.4 (abs)% compared to the current system. Fiber quality also improved by 0.46% (abs) for Type I cotton and 0.22% (abs) for Type III cotton. Experimental results showed that …

Mechanical Cleaning Of Industrial Exhaust Gases By Wet Method., A. A. Turgunov, E. A. Egamberdiev, R. F. Rashidov, A. A. Kholmurodov, D. J. Ergash

Technical science and innovation

Environmental protection is a priority area of human development. This paper presents the materials of scientific research of the creative group of the Tashkent State Technical University named after Islam Karimov, aimed at mineralization of the load on the environment, in particular on the atmospheric air of industrial enterprises. One of the more accessible solutions to this problem is the use of modern, more efficient devices for capturing and neutralizing exhaust gas emissions into the atmosphere from industry. Today, the use of mechanical methods for capturing pollutants is relevant due to the simplicity of design and operation. Wet methods for …

Adaptive Control System Of Nonlinear Dynamic Object On The Basis Of Neuro-Fuzzy Networks, Isomiddin Xakimovich Siddikov, Dilnoza Maxamadjanovna Umurzakova

Technical science and innovation

The presented paper is devoted to the development of an adaptive control system for a nonlinear dynamic object using neuro-fuzzy networks. The authors note that in real conditions dynamic objects function under conditions of uncertainty, which are characterised by complex and poorly understood relationships between technological variables, the presence of perturbing and random disturbances, as well as nonlinear elements. This makes it difficult to apply traditional linear adaptive control algorithms. The use of self-organising adaptive control is proposed, in which the mathematical model of the controlled system is formed by operational identification during system operation. It is shown that linear …

Development Of Analytical Dependencies For Determining Kinematic Parameters Of The Drive Of The Working Engine Of The Mixing Machine, N. A. Maksudova

Technical science and innovation

The requirement of any technological process of product preparation is intensive mixing. This ensures uniform distribution of components. At the initial stage of designing planetary mechanisms, special attention is paid to determining the kinematic parameters. The dimensions, weight and design of the mechanism depend on the value of these parameters. The main criterion for assessing the scheme of the planetary mechanism is the kinematic parameters of the gear wheels of the mechanism. The article presents a kinematic scheme of the planetary mechanism of the kneading machine. The principle of rotation of the gear wheels of the planetary mechanism of the …

Modern Ir-Spectroscopic Methods For The Analysis Of Hydroxybenzene-Methanal Resin Obtained On The Basis Of 2,5-Furandion, Sherali Anvarovich Umarov, Ravshan Israilovich Ismailov Ismailov

Technical science and innovation

The chemical changes occurring during the synthesis of hydroxybenzene-methanal resins obtained on the basis of 2,5-furandion under various ratios and temperature conditions were investigated using the IR spectroscopic method. Analysis of the compositional changes in the resin during the production of the thermoreactive resin revealed that the content of hydroxyl groups (~3300–3500 cm⁻¹) decreased, while the aldehyde groups (~1700–1750 cm⁻¹) increased; moreover, the presence of ether groups (~1050–1150 cm⁻¹) indicated that the process was successful. The synthesis of resins based on thermoreactive hydroxybenzene-methanal resins was carried out at high temperatures (70°C, 80°C, 95°C). During the identification of the functional groups …

Development And Analysis Of The Kinematic-Dynamic Model Of The Rehabilitation Exoskeleton System, Umidjon Abdumutalipovich Takabaev, Zafar Botirovich Juraev

Technical science and innovation

Designing modern rehabilitation exoskeleton systems requires a comprehensive study of human-machine interactions. In this process, creating kinematic and dynamic mathematical models of the system is extremely important. In this paper, we develop mathematical models that describe rehabilitation exoskeleton systems' kinematic and dynamic properties. Based on the Denavit-Hartenberg method we construct kinematic model of the exoskeleton system. The method gave us to determine the coordinate system for each joint. Furthermore, we also study the motion range of joints of the exoskeleton. Modeling the dynamic properties of the system performed with the second-order Lagrange equation. The exoskeleton construction consisting of knee, thigh, …

Theoretical Analysis Of The Fiber Flow Movement Under The Influence Of Columns, Avazbek Azamatovich Obidov, Rashid Gulomjonovich Rakhimov

Technical science and innovation

During the study, the optimal design for testing the improved fiber cleaning device was initially selected, and a process flow diagram of the fiber cleaning chamber was created for theoretical studies. According to this process flow diagram, based on theoretical studies, the behavior of fibers in the grate of the fiber cleaning device was studied, and the effect of changing the geometric parameters of the grates on the cleaning efficiency was determined. Using the developed mathematical model, graphs were constructed for the dependence of the fiber flow rate on the angle of coverage at different values of the angular speeds …

Sorption-Spectroscopic Method For Determining Mn Ions In Wastewater, Zulayho Asanalievna Smanova, Zukhra Ziyatovna Yakshieva, Nazira Kuchkarbayevna Madusmanova, Gulyorkhon Otkir Qizi Miradkhamova

Technical science and innovation

In this article, the processes of metal complex synthesis are studied in detail. Zinc OEDF+NTF complexation reactions were carried out in the presence of polyhydric alcohols, ethylene glycol, glycerol, and citric acid. For the first time, the synergistic efficiency of a mixture of zinc OEDF+NTF complexes with methyldiethanolamine, used as an inhibitor of mineral salt accumulation, was studied. It was found that when selecting the components in equivalent amounts, the inhibition efficiency of the composition is at least 90%. The high efficiency of inhibiting mineral salt accumulation in the composition is due to the presence of methyldiethanolamine, alkylimidazoline, and their …

The Influence Of Dispersed Fillers On The Mechanical Properties Of Sulfur Polymer Heterocomposites, Erkin Abdukhafizovich Rakhmatov, Durdiymurad Gurbanovich Gadamov, Umida Alijonovna Ziyamukhamedova, Jasurbek Himmat Ugli Nafasov, Elbek Tukhtanazar Ugli Turgunaliev, Shokhjakhon Uktam Ugli Abdurakhimov

Technical science and innovation

This article discusses improving the physical, mechanical, and operational properties of composite materials modified with sulfur-containing plasticizers used in the modern construction industry. Furthermore, based on an in-depth analysis of the literature, the types and sizes of fillers and the significance of their mixing technology in the formation of a structure with low porosity of a composite material with a sulfur binder have been studied. The article thoroughly describes a method for obtaining a composite material with a stable sulfur-containing binder, the processes of preparing a solid filler, impregnating the filler with an organic modifier, humidifying and heating the filler …

Some Results Of Studying The Connection Between Geodynamic Processes And Observed Anomalous Electromagnetic Phenomena, Botir Khamidovich Khaydarov, Umar Abdullaevich Najmiddinov

Technical science and innovation

This article provides information about various cases of anomalous changes in electromagnetic fields recorded in real field conditions in seismically active areas in connection with the occurrence of earthquakes and various assessments and interpretations of the noted anomalies are carried. The main attention was focused on the consideration of the concept of changes in the conditions of waveguide propagation of atmospherics and the model of surface emitters. There is considered сevery reason to believe that both mechanisms can manifest themselves separately or together depending on the nature of the process, the rheology of the medium and other geophysical conditions, just …

Installation Of Self-Controlled Floating Bars At Water Intake Pipelines Of Pumping Stations, Oleg Yakovlevich Glovatsky, Rustam Khujakulov, Fakhriddin Jaylovovich Nasirov, Ilhom Islamov, Jorabek Abdurahman Uralov, Shakhboz Amirov

Technical science and innovation

In modern conditions, to maintain a favorable hydraulic regime on mechanical water lifting systems, it is rational to use protective structures on watercourses that use the energy of the water flow in the form of a floating tank. Based on the obtained theoretical principles, fundamentally new self-controlled floating structures were created and the hydrodynamic characteristics of the movement of an unsteady three-dimensional flow for the parameters of the wing profile were refined. The theory of unsteady three-dimensional movement of a multiphase flow with its artificial stratification and protection from selected phases in depth is used by floating guide systems at …

Correlation Of Socioeconomic Characteristics And Maintenance Level Of Houses In Mass Housing Scheme In Ilorin, Nigeria, Oladimeji Samuel Bolaji, Abubakar-Kamar Tayo Aishat, Adeyemi Olabanji Lukman, Arosanyin Mofeoluwa Victor

Architecture and Planning Journal (APJ)

It is a common belief that certain behaviors are influenced by a person's social level. This claim is taken to apply to housing maintenance in any society, whether it is owned or rented. The aim of this study is to identify the socioeconomic indicators that are most predictive of the maintenance level of houses in mass housing schemes in the metropolis of Ilorin, Nigeria. Both primary and secondary data were used in this investigation. Qualitative and quantitative data through structured questionnaires administered on 1125 household heads constituting 27% of the sample frame were collected from sixteen (16) mass housing schemes …

Occupational Safety Culture In Modern Aviation Maintenance, Sang-A Lee

Journal of Aviation Technology and Engineering

Aviation maintenance is paramount to the safety and efficiency of global air travel. Disturbingly, 2022 data revealed an unprecedented surge in severe injuries among aircraft maintenance technicians in the United States, prompting renewed scrutiny of the aviation maintenance occupational safety culture. In light of these developments, a systematic literature review was conducted to discern the influential factors shaping this safety culture, especially considering the industry’s rapid technological advancements. The review process involved meticulous key word searches, stringent article selection criteria, and qualitative data analysis software to interpret findings. From the synthesis of 35 peerreviewed articles, nine pivotal constructs emerged: (1) …

Recent Advances In Non-Enzymatic Electrochemical Sensors For Theophylline Detection, Gustria Ernis, Yulia M T A Putri, Muhammad Iqbal Syauqi, Prastika Krisma Jiwanti, Yeni Wahyuni Hartati, Takeshi Kondo, Qonita Kurnia Anjani, Jarnuzi Gunlazuardi

Journal of Electrochemistry

Detection of target analytes at low concentrations is significant in various fields, including pharmaceuticals, healthcare, and environmental protection. Theophylline (TP), a natural alkaloid used as a bronchodilator to treat respiratory disorders such as asthma, bronchitis, and emphysema, has a narrow therapeutic window with a safe plasma concentration ranging from 55.5–111.0 μmol·L^–1 in adults. Accurate monitoring of TP levels is essential because too low or too high can cause serious side effects. In this regard, non-enzymatic electrochemical sensors offer a practical solution with rapidity, portability, and high sensitivity. This article aims to provide a comprehensive review of the recent developments …

Study On Dopamine Electrochemical Sensing Based On Au@Mos2, Ning An, Ni Su, Xin-Ran Li, Jian-Yu Liu, Qi-Yan Wang

Journal of Electrochemistry

Dopamine (DA) is a vital neurotransmitter, and accurate detection of its concentration is critical for both clinical diagnostics and neuroscience research. Due to its electrochemical activity, DA is commonly detected using electrochemical methods, which are favored for their simplicity, fast response time, and suitability for in vivo analysis. In this work, a highly sensitive DA electrochemical sensor was developed using an Au@MoS₂ composite, created by modifying molybdenum disulfide (MoS₂) nanosheets with gold nanoparticles through HAuCl₄ reduction, and it was aimed at enhancing DA adsorption and improving detection performance. Scanning Electron Microscopy (SEM), transmission electron microscopy (TEM), …

In-Situ Electrodeposition Of Feco-Mof On Au Ultramicroelectrode For Highly Sensitive Detection Of Epinephrine, Yan Chen, Shang Jian, Si-Yu Wan, Xiao-Tong Cui, Zhong-Gang Liu, Zheng Guo

Journal of Electrochemistry

Metal-organic framework (MOF) nanostructures have emerged as a prominent class of materials in the advancement of electrochemical sensors. The rational design of bimetallic MOF-functionalized microelectrode is of importance for improving the electrochemical performance but still in great challenge. In this work, the bimetallic FeCo-MOF nanostructures were assembled onto a gold disk ultramicroelectrode (Au UME, 5.2 μm in diameter) via an in-situ electrodeposition method, which enhanced the sensitive detection of epinephrine (EP). The in-situ electrodeposited FeCo-MOF exhibited a characteristic nanoflower-like morphology and was uniformly dispersed on the Au UME. The FeCo-MOF/Au UME demonstrated excellent electrochemical performance on the detection of EP …

Web Application For Simulation Of An Agent-Based Model In Netlogo3d, Chris Davis Perumal, Abraham Nofal, Benedict J. Kolber, Rachael Miller Neilan

Spora: A Journal of Biomathematics

Agent-based models (ABMs) are computer simulation models for studying systems of autonomous agents. Modelers often use specialized software like NetLogo to develop ABMs, but this software poses barriers to researchers in other disciplines with no prior programming experience. To address this issue, we developed a web application that allows users to simulate our ABM via a web browser, eliminating the need for the user to download and use specialized software. While presented in the context of a specific ABM, our approach can be applied to other ABMs to enhance accessibility. The ABM presented here was developed in NetLogo3D. The model …

Retracted: Image Denoising: Smooth Total Variation Minimization For 5g Enhanced Mobile Broadband Transmission System, Shehab Ahmed Ibrahem, Walled Khalid Khalid Abdulwahab, Moceheb Lazam Lazam Shuwandy

Iraqi Journal for Computer Science and Mathematics

Image denoising is an important area of computer vision. Rudin-Osher-Fatemi model based on a gradient is one of the simplest models used in image denoising to solve the problem of restoring the clear image. The challenge in solving this model is the non-differentiability of Total Variation function (TV-function) minimization. Image transmission is widespread over wireless systems, including the fifth generation (5G) cellular network. Transmission impairment can affect transmitted images, including noise, attenuation, and distortion. This study proposed a new smoothing technique to make the TV-function differentiable and smooth. The new smoothed function was used for de-noising images with the help …

War Strategy Algorithm- Based Hybrid Optimization For Accurate And Rapid Speech Recognition, Shahad Thamear Abd Al-Latief, Salman Yussof, Azhana Ahmad, Saif Mohanad Khadim, Ahmed Alkhayyat

Iraqi Journal for Computer Science and Mathematics

Speech recognition-based applications increased and developed as a result of artificial intelligence's rapid growth, particularly Machine Learning, which play a crucial role in many aspects of daily life, such as applications related to human-computer interaction, and natural language processing. The complexity and diversity of speech signals provides challenges in maximizing the rate of accuracy and efficiency of speech recognition systems. Hyperparameter tuning is a crucial step in machine learning that has a significant role in optimizing the performance and generalization by determining the optimal values for the model's hyperparameters. This paper employed the recently developed WAR Strategy optimization algorithm for …

Hybrid Methods For Detecting Face Morphing Attacks, Essa M. Namis, Khalid Shaker, Sufyan Al-Janabi

Iraqi Journal for Computer Science and Mathematics

The face morphing process blends two or more facial images to produce a singular morphed facial image that shows the vulnerabilities of Face Recognition Systems (FRS). The widespread use of facial recognition algorithms, especially in Automatic Border Control (ABC) systems, has elicited concerns about potential attacks, as modified passports pose a significant risk to national security. This research presents a hybrid approach for feature extraction from facial images. The suggested approach involves three stages: The initial phase involves preprocessing the image through resizing and face identification, using the Viola-Jones algorithm to detect and locate the human face in the image, …

Finding General Mathematical Formulas For Extraction The Minimal Path Sets Of Complex Parallel-Series Networks, Mariem Hassan Lafta, Zahir Abdul Haddi Hassan

Iraqi Journal for Computer Science and Mathematics

Most real-world technological systems are highly complex, making it challenging to examine their reliability. Many systems can be represented as Complex Parallel-Series Networks (CPSN). The large number of components and subnetworks, along with their intricate connection, complicates the identification, evaluation, and potential failure of the CPSN. A minimal path set is a minimal set of components whose proper functioning (success) guarantees the success (operability) of the system. The set is minimal in the sense that removing any component from it means it no longer guarantees system success. The primary research problem is to identify these minimal path sets, both for …