Engineering Commons^™

Integration Of Large Pv Power Plants And Batteries In The Electric Power System, Oluwaseun M. Akeyo

Theses and Dissertations--Electrical and Computer Engineering

The declining cost of renewables, the need for cleaner sources of energy, and environmental protection policies have led to the growing penetration of inverter-based resources such as solar photovoltaics (PV), wind, and battery energy storage systems (BESS) into the electric power system. The intermittent nature of these resources poses multiple challenges to the power grid and substantial changes in the conventional generation and electrical power delivery practices will be required to accommodate the large penetration of these renewable power plants. The impact of large solar PV penetration on both generation and transmission systems, and the use of BESS to mitigate …

Quantifying Nitrogen Fate In Karst Agroecosystem Streams Of Central Kentucky: Development And Application Of Numerical Modeling And Insight From High-Resolution Sensors, Nolan Lewis Bunnell

Theses and Dissertations--Biosystems and Agricultural Engineering

In-stream fate of nutrients in karst agroecosystems remains poorly understood, despite the known impact of karst on water resources at local to global scales. In the Inner-Bluegrass region of central Kentucky, heterogeneity of karst maturity, flow pathways, and nutrient sources adds to the complexity of quantifying nutrient dynamics, thus requiring novel monitoring and modeling approaches. The significance of these streams is recognized given spring/surface water confluences have been identified as hotspots for biogeochemical transformations. In slow-moving streams high in dissolved inorganic nutrients (particularly dissolved inorganic nitrogen (DIN) and dissolved reactive phosphorus (DRP)), benthic and floating aquatic macrophytes are recognized to …

An Assessment Of 2d And 3d Spatial Accuracy Of Photogrammetry For Livestock Health Monitoring, Luis Felipe Pampolini

Theses and Dissertations--Biosystems and Agricultural Engineering

The overall objective of this study was to evaluate the use of consumer-grade unmanned aircraft systems for image-based remote sensing in agriculture with application towards livestock health monitoring. A two-dimensional spatial error experiment was conducted to quantify the spatial accuracy of georeferenced orthomosaic imagery collected using a drone and processed with photogrammetry software. Treatment variables included altitude above ground level and image data type (visible and multispectral). The results from the ANOVA test indicated that there were significant differences between data types, but no significant differences between altitudes. The experiment was then expanded to a three-dimensional study where two life-size …

Fourier Transform Infrared Spectroscopy (As A Rapid Method) Coupled With Machine Learning Approaches For Detection And Quantification Of Gluten Contaminations In Grain-Based Foods, Abuchi Godswill Okeke

Theses and Dissertations--Biosystems and Agricultural Engineering

Cross-contamination between food grains during harvesting, transportation, and/or food processing is still a major issue in the food industry. Due to cross-contact with gluten-rich grains (wheat, barley, and rye grains), gluten can get into food that’s naturally free from gluten and thus may not be safe for consumption for people susceptible to gluten-related disorders such as celiac disease, wheat allergy, gluten intolerance or sensitivity. The conventional method of gluten detection is cumbersome, time-consuming, and requires well-trained personnel. Therefore, there is a need for a rapid and equally effective technique to authenticate gluten contamination in foods. This research work explored the …

Characterization And Enzyme Engineering Of Laccases Towards Lignin Valorization In Aqueous Ionic Liquids, Joseph Stevens

Theses and Dissertations--Biosystems and Agricultural Engineering

Lignin is one of the most abundant polymers found in nature, making up 15 – 40% of the weight of terrestrial biomass. Due to the structural and monomeric heterogeneity of lignin, it is recalcitrant thermochemical and biological valorization methods. Converting lignin to value-added products via sustainable and cost-effective pathways will reduce waste and add value to future cellulosic biorefineries. Biological methods for lignin valorization (e.g. lignin degrading enzymes or microbes) is limited by low lignin solubility in biocompatible solvents, resulting in low product yield. Recent reports on biocatalysts for lignin valorization have focused on the lignolytic multicopper oxidase laccase, …

Effects Of Watershed Disturbances And River-Tributary Confluences On Sedimentation Dynamics In The Upper Ohio River Basin, Ciara Pickering

Theses and Dissertations--Biosystems and Agricultural Engineering

Harmful algal blooms (HABs) are of increasing concern in the Ohio River Basin. Fine sediment dynamics in riverine environments are increasingly recognized to play important roles in proliferation and toxicity of Microcystis blooms. Further, the fate of sediment at confluences of tributaries and the main river system are important zones for sediment retention and transient storage. The objective of this study was to improve understanding of watershed sediment loading dynamics and backwater inundation influencing sedimentation within confluence watersheds. The study site is the Fourpole Creek watershed in Huntington, WV which is a disturbed forested watershed impacted by a backwater confluence …

Physicochemical Characterization, Structural Determination, And Molecular Dynamic Modeling Of Proso Millet Proteins For Enhanced Food Functionality, Felix Akharume

Theses and Dissertations--Biosystems and Agricultural Engineering

More than one-third of Americans today incorporate plant-based protein into their diet and about 40% believed that plant-based protein is healthier than animal protein, especially Millennials. The increasing global demand for plant-based proteins driven by the high cost of animal proteins, consumers’ desire for lean protein, vegetarianism, and the need for more sustainable green protein products have necessitated research into alternate emerging and underutilized sources of protein to complement or supplement the major plant protein in the market- soy, pea, and gluten. Therefore, this dissertation is focused on the valorization of the proteins in proso millet. Specifically, this work focused …

Numerical Approximation Of The Ground Reaction And Support Reaction Curves For Underground Limestone Mines, Jesus Castillo Gomez

Theses and Dissertations--Mining Engineering

Pillar stability has been a matter of study for the last 70 years. The determination of pillar strength had taken different solutions and approaches over that time. This research has led to numerous empirical formulations that have reduced the number of pillar failures worldwide. However, new numerical approaches are being studied. In the last 20 years, the Ground Reaction Curve concept has been examined as a way of understanding the convergence of the rock-mass. Although the Ground Reaction Curve was first introduced in the civil tunneling industry, several authors have introduced the Ground Reaction Curve concept as an approach for …

Knee Joint Loading Following Anterior Cruciate Ligament Reconstruction: Link To Patient Reported Outcomes And A Novel Method To Monitor With Wearable Sensors, Alex Spencer

Theses and Dissertations--Kinesiology and Health Promotion

Recovery from anterior cruciate ligament reconstruction (ACLR) commonly results in undesirable physical and patient-reported outcomes (PROs). Identification of modifiable factors such as knee contact force (KCF) early in rehabilitation that can improve these outcomes is important due to the rapid decrease in function, quality of life, and joint health in this population. Additionally, if noninvasive measurement of KCFs outside of a traditional laboratory were possible, clinicians could optimize patient treatment with personalized care. Therefore, there are two primary aims to this thesis: 1) quantify the link between KCF and PROs which measure pain, ability to perform activities of daily living, …

End-To-End Prediction Of Weld Penetration In Real Time Based On Deep Learning, Wenhua Jiao

Theses and Dissertations--Electrical and Computer Engineering

Welding is an important joining technique that has been automated/robotized. In automated/robotic welding applications, however, the parameters are preset and are not adaptively adjusted to overcome unpredicted disturbances, which cause these applications to not be able to meet the standards from welding/manufacturing industry in terms of quality, efficiency, and individuality. Combining information sensing and processing with traditional welding techniques is a significant step toward revolutionizing the welding industry. In practical welding, the weld penetration as measured by the back-side bead width is a critical factor when determining the integrity of the weld produced. However, the back-side bead width is difficult …

Nanostructured Device Designs For Enhanced Performance In Cds/Cu2S Heterojunction Solar Cells, Benjamin Wells

Theses and Dissertations--Electrical and Computer Engineering

Nanostructured CdS/Cu2S devices have been simulated using SCAPS-1D to demonstrate enhanced performance over traditional planar device structures. Two designs were examined: a nanowire CdS/planar Cu2S device and a nanowire CdS/nanowire Cu2S device. The addition of nanowires to a device had been previously demonstrated to improve device performance in a nanowire CdS/planar CdTe device by decreasing the amount of light absorbed by the CdS window layer, thus allowing more light to reach the absorber layer. Additionally, the total number of interface states can be greatly reduced due to the decreased total surface area between the window and absorber layers. The nanowire …

Investigation Of Host Nanotube Parameters For Enhancing The Performance Of Nanostructured Cds-Cdte Solar Cells, Deepak Kumar

Theses and Dissertations--Electrical and Computer Engineering

Numerical simulations are performed to investigate the effects of host nanotube parameters (pore diameter and pitch for different CdS coverages) and CdTe doping density on device performance in nanowire CdS/ CdTe solar cells using SCAPS-1D. This research finds the optimum values for these parameters in order to achieve the highest efficiency. Experimentally the effect of anodization voltage and fluoride ion concentration on the pore diameter and the pitch are studied for the Titania nanotubes host. It is observed that in the range of 0.3 mL to 2 mL of ammonium fluoride content, pore diameter and the pitch of the Titania …

Ecosystem Of Bagged Grain Stored Under Naturally Ventilated Warehouse: Analysis And Modelling, Michael Ayodele Omodara

Theses and Dissertations--Biosystems and Agricultural Engineering

Grain in Africa and indeed most developing parts of the world are stored in polypropylene or jute bags arranged in stacks of varied dimensions in naturally ventilated warehouses. This practice is, however, associated with high postharvest losses due to poor temperature and moisture management during storage. This constitutes a major economic and food security challenge in these countries. Therefore, this study characterizes changes in moisture content and temperature occurring in a stack of bagged corn by determining the permeability of bag materials that influence moisture transfer and developing a mathematical model of heat and mass transfer which incorporates the unique …

Investigation Into Mine Pillar Design And Global Stability Using The Ground Reaction Curve Concept, Ravi Chandan Ray

Theses and Dissertations--Mining Engineering

Pillars form an important support structure in any underground mine. A bulk of the overburden load is borne by the mine pillars. Thus, the strength of pillars has been a subject of detailed research over more than 6 decades. This work has led to the development of largely empirical pillar design formulations that have reduced the risk of pillar failures and mine collapse. Current research, however, has drawn attention to the fact that some of the assumptions used in the development of conventional pillar design methodologies are not always valid. Conventional pillar design methodology assumes that the pillars carry the …

Tolerance Intervals For Time Series Models And Specifying Trimming/Winsorizing Cutoffs, Kedai Cheng

Theses and Dissertations--Statistics

Confidence intervals are used to capture a parameter of interest, usually a mean or a quantile, at a specified confidence level. Prediction intervals are another practical interval that aim at making sound predictions of future values with some confidence. Although these are useful inference tools, neither of them gives people a plausible range of the sampled population. Tolerance intervals are such an inference tool that captures a specified proportion of the sampled population at a predetermined confidence level. In this dissertation, tolerance intervals for an autoregressive process with order p are constructed. In addition, a method of utilizing tolerance interval …

Interfaces In Lead-Free Tin Perovskite Photovoltaics: An Investigation Of Energetics, Ion Mobility, Surface Modification, And Performance, Alex Boehm

Theses and Dissertations--Chemistry

Halide perovskites have generated tremendous interest as low-cost semiconductors for optoelectronics, such as photovoltaics, lasers, and light emitting diodes due to their extraordinary optical and transport properties. Perovskite photovoltaics in particular have demonstrated a meteoric rise in power conversion efficiencies and drawn considerable interest as a next-generation solar energy technology. The rapid development has centered around lead-based derivatives, and concerns regarding the toxicity of lead has sparked interest in low toxicity and more environmentally friendly perovskite derivatives. In this regime tin (Sn) is regarded as a prominent alternative owing to the ideal bandgap and reduced toxicity exhibited by Sn-halide perovskites. …

Correlating The Physicochemical Properties Of Magnesium Stearate With Tablet Dissolution And Lubrication, Julie L. Calahan

Theses and Dissertations--Pharmacy

Magnesium stearate (MgSt) is the most commonly used pharmaceutical excipient and is present in over half the tablet formulations on the market. In spite of its popularity as an effective lubricant, it has been repeatedly recognized that there is significant variability between MgSt samples, which can cause inconsistent lubrication between batches of MgSt. The hypothesis of this research is that the batch-to-batch variability in tablet lubrication and dissolution observed in tablet formulations containing different MgSt samples can be correlated with differences in MgSt physicochemical properties (fatty acid salt composition, crystal hydrate form, particle size and surface area). Developing correlations between …

Holistic Resilience Quantification Framework Of Rural Communities, Amanda Melendez

Theses and Dissertations--Civil Engineering

Communities need to prepare for anticipated hazards, adapt to varying conditions, and resist and recover rapidly from disturbances. Protecting the built environment from natural and man-made hazards and understanding the impact of these hazards helps allocate resources efficiently. Recently, an indicator-based and time-dependent approach was developed for defining and measuring the functionality and disaster resilience continuously at the community level. This computational method uses seven dimensions that find qualitative characteristics and transforms them into quantitative measures. The proposed framework is used to study the resilience of rural communities’ subject to severe flooding events. Harlan County in the Appalachian region is …

Adaptive Tracking Controller For Real-Time Hybrid Simulation, Alejandro Palacio-Betancur

Theses and Dissertations--Civil Engineering

Real-time hybrid simulation (RTHS) is a versatile and cost-effective testing method for studying the performance of structures subjected to dynamic loading. RTHS decomposes a structure into partitioned physical and numerical sub-structures that are coupled together through actuation systems. The sub-structuring approach is particularly attractive for studying large-scale problems since it allows for setting up large-scale structures with thousands of degrees of freedom in numerical simulations while specific components can be studied experimentally.The actuator dynamics generate an inevitable time delay in the overall system that affects the accuracy and stability of the simulation. Therefore, developing robust tracking control methodologies are necessary …

Variance Decomposition Of Forecasted Water Budget And Sediment Processes Under Changing Climate In Fluvial And Fluviokarst Systems, Nabil Al Aamery

Theses and Dissertations--Civil Engineering

Variance decomposition is the partitioning of different factors affecting the variance structure of a response variable. The present research focuses on future streamflow and sediment transport processes projections as the response variables. The authors propose using numerous climate factors and hydrological modeling factors that can cause any response variable to vary from historic to future conditions in any given watershed system. The climate modeling factors include global climate model, downscaling method, emission scenario, project phase, bias correction. The hydrological modeling factor includes hydrological model parametrization, and meteorological variable inclusion in the analysis. This research uses a wide spectrum of data, …

Applications Of Drones In Atmospheric Chemistry, Travis J. Schuyler

Theses and Dissertations--Chemistry

The emission of greenhouse gases (GHGs) has changed the composition of the atmosphere during the Anthropocene. A major technical and scientific challenge is quantifying the resulting fugitive trace gas fluxes under variable meteorological conditions. Accurately documenting the sources and magnitude of GHGs emission is an important undertaking for discriminating contributions of different processes to radiative forcing. Therefore, the adverse environmental and health effects of undetected gas leaks motivates new methods of detecting, characterizing, and quantifying plumes of fugitive trace gases. Currently, there is no mobile platform able to quantify trace gases at altitudes(UASs), or drones, can be deployed on-site in …

Fabrication, Characterization And Applications Of Highly Conductive Wet-Spun Pedot:Pss Fibers, Ruben Sarabia Riquelme

Theses and Dissertations--Chemical and Materials Engineering

Smart electronic textiles cross conventional uses to include functionalities such as light emission, health monitoring, climate control, sensing, storage and conversion of energy, etc. New fibers and yarns that are electrically conductive and mechanically robust are needed as fundamental building blocks for these next generation textiles.

Conjugated polymers are promising candidates in the field of electronic textiles because they are made of earth-abundant, inexpensive elements, have good mechanical properties and flexibility, and can be processed using low-cost large-scale solution processing methods. Currently, the main method to fabricate electrically conductive fibers or yarns from conjugated polymers is the deposition of the …

Nanostructured Metal Thin Films As Components Of Composite Membranes For Separations And Catalysis, Michael J. Detisch

Theses and Dissertations--Chemical and Materials Engineering

Novel metallic thin film composite membranes are synthesized and evaluated in this work for improved separations and catalysis capabilities. Advances in technology that allow for improved membrane performance in solvent separations are desirable for low molecular weight organic separation applications such as those in pharmaceutical industries. Additionally, the introduction of catalytic materials into membrane systems allow for optimization of complex processes in a single step. By adding a nanostructured metallic thin film to its surface, a polymer membrane may be modified to exhibit these improved properties. Using magnetron sputtering, thin metal films may be deposited on commercially available membranes to …

Ab Initio Investigation On The Surface Chemistry Of Functionalized Titania Membranes, Evan Hyde

Theses and Dissertations--Chemical and Materials Engineering

Titania (titanium dioxide) is a metal oxide which has recently been investigated as a photocatalyst, most commonly for use in hydrolysis, which absorbs mostly in the UV range. However, the range of absorption can be shifted to fall within the visible light range either by doping or by functionalizing the surface with atomic or molecular adsorbates. Over the course of this research, a series of Density Functional Theory (DFT) calculations are performed to ascertain the effects of these different methods on the photocatalytic performance of titania. While the effects of nitrogen doping and oxygen vacancies are well known, more recent …

A Thermodynamic And Feasibility Study Of Green Solvents For The Fabrication Of Water Treatment Membranes, Xiaobo Dong

Theses and Dissertations--Chemical and Materials Engineering

Nonsolvent induced phase separation (NIPS) has been widely used to fabricate polymeric membranes. In NIPS, a polymer is dissolved in a solvent to form a dope solution, which is then cast on a substrate and immersed in a nonsolvent bath, where phase inversion occurs. Petroleum-derived organic solvents, such as N-Methyl-2-Pyrrolidone (NMP) and Dimethylacetamide (DMAc), have been traditionally used to fabricate polymeric membranes via NIPS. However, these solvents may have negative impacts on environmental and human health; therefore, using greener and less toxic solvents, preferably derived from biomass, is of great interest to make membrane fabrication sustainable. In this dissertation, two …

Understanding And Mitigating The Electrochemical-Mechanical Degradation Of High Capacity Battery Electrodes, Dingying Dang

Theses and Dissertations--Chemical and Materials Engineering

Lithium-ion batteries (LIBs) with high energy density and cycling stability play a critical role in developing electric vehicle (EV) and grid energy storage techniques. The electrochemical performance of LIBs can be improved by using high capacity positive (e.g., LiNi_1/3Mn_1/3Co_1/3O₂, i.e., NMC111) and negative (e.g., silicon) electrodes; both, however, experience severe electrochemical-mechanical degradation caused by the lithiation/delithiation induced volume changes. Understanding mechanical degradation mechanisms and their relationships with the capacity fading of electrodes is important for improving the cycling stability of electrodes as well as optimizing the design of electrodes with high capacity …