Engineering Commons^™

On The Mechanical Properties Of Al/Cu-Grid/Al Intermetallic Composite, Hamza Essoussi, Said Ettaqi

Journal of Metals, Materials and Minerals

The present paper deals with the experimental investigation of new process combining static compression with high temperature as a simple way to prepare new Al/Cu-grid/Al metallic composite (MC) that consists of Aluminum matrix and Copper grid acting as ductile reinforcement stacked between the Al sheets. At the stage of composite fabrication, two different thermal cycles were tested to highlight the effect of processing temperature on the layers’ adherence and the mechanical properties of the prepared composites. Consequently, the microstructural and mechanical results revealed that the compression at 630℃ for 30 min, then furnace cooled to 450℃ followed by air cooling …

Thermal Behavior Of Solid Acids In The Rb3h(So4)2-Rbhso4 System Under Ambient Atmosphere, Chatr Panithipongwut Kowalski, Permpoon Chaijaroen, Farook Kaewniyom

Journal of Metals, Materials and Minerals

The thermal behavior of solid acids in the Rb3H(SO4)2-RbHSO4 system under ambient atmosphere has been studied in comparison to the previously reported high-temperature behavior of the same system under humidified atmosphere. The findings showed that, under this level of humidity, the transition of RbHSO4, the transition of Rb5H3(SO4)4, and the disproportionation of Rb3H(SO4)2, occurred at the same temperatures as those under humidified atmosphere. However, the results from differential scanning calorimetry did not reveal the reaction temperature between Rb3H(SO4)2 and RbHSO4 due to the slow process. The dehydration temperatures of Rb5H3(SO4)4 were surprisingly similar between the systems under low and high …

Graphene Enhanced Linear Low-Density Polyethylene Nanocomposites By Premixing And Melt Compounding, Wan Nazri Wan Busu, Ruey Shan Chen, Muhammad Jefri Mohd Yusof, Sahrim Ahmad

Journal of Metals, Materials and Minerals

In this study, linear low-density polyethylene/graphene nanoplatelets (LLDPE/GNPs) nanocomposites were prepared from conventional melt-mixing method and our new approach; two-step premix mixing technique. Indirect mixing technique (IDT) was employed to fabricate a premix of LLDPE/ GNPs in the ratio of 80:20 wt%. The effects of GNPs loadings and the processing method of nanocomposites on the mechanical strength, decomposition temperature, crystallinity, electrical impedance and morphology were investigated. Irrespective of processing methods, the prepared nanocomposites exhibited crystalline structure due to the presence of GNPs whilst the degradation temperature was recorded to be increased with GNPs loadings that signified improved thermal stability. The …

Preparation Of Transparent Alumina Thin Films Deposited By Rf Magnetron Sputtering, Busarin Noikaew Noikaew, Laksana Wangmooklang, Saisamorn Niyomsoan, Siriporn Larpkiattaworn

Journal of Metals, Materials and Minerals

Alumina (Al2O3) thin films were prepared by RF magnetron sputtering technique using Al2O3 ceramic target. Effects of sputtering powers and oxygen gas mixtures were investigated and the optimized coating condition was applied on semi-precious gemstones. RF sputtering powers were varied to optimize the transparency of the films. Besides, the oxygen gas mixtures were also studied at the optimized sputtering power with a constant sputtering pressure. Optical and physical properties of the thin films were investigated using UV-Vis Spectrophotometer, FESEM, XRF, GIXRD, XRR including a microscratch tester. The Al2O3 films were highly transparent in the visible region in form of an …

Extraction Of Cellulose Nanofibers From Empty Palm Fruit Bunches Via Mechanical Defibrillation, Zi-Qian Tan, Takaomi Kobayashi, Duangdao Aht-Ong

Journal of Metals, Materials and Minerals

In recent years, there has been an increasing interest in finding alternative material to replace fossil-oil based product due to the environmental concern. Lignocellulosic biomass has emerged as the promising candidate due to its low-cost and sustainability. The objective of this work was to prepare cellulose nanofibers (CNFs) from empty palm fruit bunches (EPFB), which are the waste originating from palm oil industry. Cellulose fibers were first extracted from EPFB by chemical treatment, followed by mechanical disintegration using high-pressure homogenization. Fiber concentration and defibrillation time during mechanical treatment were studied to investigate their effects on the properties of produced nanofibers. …

The Effect Of Phosphogypsum On Stabilizing Clay Soil And Improving Its Properties For Use As Foundation Soil, Mai Yahya Maaitah, Mus'ab Ziad Banat

Journal of Metals, Materials and Minerals

Expansive soil covers large areas in a variety of regions in Jordan which is insufficient to meet the engineering specifications in construction. Phosphogypsum is considered to be the main by-product material which comes from phosphate rock deposits that is available in Jordan. The main purpose of this research is to study the effects of stabilization by phosphogypsum on expansive soil properties. Three Jordanian regions were chosen to represent the expansive soils, Irbid, Madaba, and Abu-Nusire city. Soils were mixed with phosphogypsum at different percentages by dry weight of soil. Some of the representative laboratory tests for swell properties were conducted: …

The Effect Of Artificial Defects On The Fatigue Characteristics Of Aisi 4340 Steel, Yakov B. Unigovski, Dmitry Fishman, Liat Fishman, Liron Shichman, Ofir Moshe, Roni Shneck, Emmanuel Gutman

Journal of Metals, Materials and Minerals

This study examined the fatigue life (Nf) and fatigue limit (FL) of AISI 4340 steel in relation to surface roughness, artificial defects and shot peening. Artificial surface defects on fatigue specimens were obtained by electrical discharge machining (EDM) or by pre-corrosion in 3.5% NaCl and perchloric acid solutions, followed by a fatigue test. The presence of artificial defects of various sizes, taken into account by the area  parameter, led to a significant decrease in fatigue characteristics, while shot peening contributed to their noticeable improvement. Defects resulting from electrochemical corrosion had a much greater negative effect on fatigue …

The Enhancement Of Ethanol Gas Sensors Response Based On Calcium And Zinc Co-Doped Lafeo3/Fe2o3 Thick Film Ceramics Utilizing Yarosite Minerals Extraction As Fe2o3 Precursor, Endi Suhendi, Zeany Luckyta Amanda, Muhamad Taufik Ulhakim, Andhy Setiawan, Dani Gustaman Syarif

Journal of Metals, Materials and Minerals

A gas sensor is a renewed interest of research which has been developed to make a device that can be detected the harmful gases and applied in the several fields of industries. In this paper, we report the modified of gas sensor based thick film ceramic LaFeO3/Fe2O3 by added calcium and zinc co-doping prepared by screen-printed technique. In this work, yarosite mineral was utilized as Fe2O3 precursor. It aims to take the advantages of abundance natural resources in Indonesia to save a cost in gas sensor fabrication. Then, x-ray diffraction (XRD), scanning electron microscopy (SEM) and electrical properties characterization were …

Wollastonite And Talc Reinforced Polypropylene Hybrid Composites: Mechanical, Morphological And Thermal Properties, Naruedee Putfak, Amnouy Larpkasemsuk

Journal of Metals, Materials and Minerals

This study focused on evaluating the mechanical, thermal, and morphological properties of polypropylene (PP) hybrid composites containing two different inorganic mineral fillers, namely wollastonite (WO) and talc. The composites were prepared by melt mixing process using a twin screw extruder and an injection molding machine. All composites contained a constant filler loading at 20 wt% with varying WO/talc weight ratios (20/0, 15/5, 10/10, 5/15, and 0/20). Melt flow index (MFI), mechanical properties (impact strength and tensile properties), heat distortion temperature (HDT) fractured surface morphology, and thermal behaviors of the resulting composites were investigated. The results revealed an enhancement in the …

Effect Of Nitrocarburizing And Argon Admixing On Low Carbon Steel For Component Facility In Radiometallurgical Installation, Erwan Hermawan, Suprapto Suprapto, Usman Sudjadi, Siti Shaleha, Maman Kartaman Ajiriyanto

Journal of Metals, Materials and Minerals

Steel is an important component in the industrialized world with rising growth in world consumption. Steel has wide applications due to its high strength, durability, and cost-effectiveness. This has applications in the nuclear power plant. In Indonesian nuclear industry, low carbon steel is used not only for the fabrication of reactor components but also for the radiometallurgical facilities. However, to avoid the risk of premature failure and enhance the longevity of the components in the service condition, surface modification for the improvement of hardness has been realized. Amongst several methods, surface hardening by following nitrocarburizing has been found to be …

Structural, Magnetic And Transport Properties Of Ca And Sr Doped Lanthanum Manganites, Sunita Keshri, Shailendra Rajput, Sonali Biswas, Leena Joshi, Wojciech Suski, Piotr Wiśniewski

Journal of Metals, Materials and Minerals

This article presents a comparative study for the effect of average A-site cation size on the structural, transport and magnetic properties of Lanthanum manganites. Three polycrystalline colossal magneto-resistive compounds were synthesized using standard solid state reaction method. The electrical resistivity data were analyzed employing standard two-phase model to understand the conduction mechanism. The resistance of polycrystalline ceramic depends on the intragrain resistance (intrinsic resistance) and the intergrain or grain-boundary resistance (extrinsic resistance). The substitution of Sr ions at La-site provides higher magnetic and metal-insulator transitions as compared to Ca ions. The combined substitution of Ca and Sr ions at La-site …

Formation Of Nano-Crystalline Chromium-Zirconium Nitride (Cr-Zr-N) Film Coating By Dc Unbalanced Magnetron Sputtering, Kumpon Leelaruedee, Kattareeya Taweesup, Patama Visuttipitukul

Journal of Metals, Materials and Minerals

This research aimed to improve the properties of chromium nitride (CrN) film coatings by addition of zirconium (Zr) as the third element to form Cr-Zr-N ternary nitride. DC unbalanced magnetron sputtering method was used to form Cr-Zr-N film with various Zr/Zr + Cr atomic ratios.  Mechanical properties, surface morphology and crystal structure of the film were investigated. In the research, Cr-Zr-N film were categorised into 3 types with different Zr amount: low zirconium, (Zr/Zr + Cr = 0.29), medium zirconium (Zr/Zr + Cr = 0.44), and high zirconium (Zr/Zr + Cr = 0.74). All Cr-Zr-N films exhibited nano-crystalline structures with …

Controlled Plasma Tuning Of Mos2 Based Photodetector: From Visible To Ultraviolet Photo Response, Huda Musa Mutlaq, Ali Jabbar Fraih

Journal of Metals, Materials and Minerals

Among diverse family of two-dimensional materials, molybdenum disulfide (MoS2) is one of the most promising materials for optical applications thanks to its tunable optical energy bandgap. In this work, a MoS2 based photodetector is fabricated and its optical properties is investigated. With the help of controlled oxygen plasma bombardment, its photoresponse is tuned from visible to ultraviolet region. The photodetector was subjected to three bombardment times of 60 s, 120 s, and 180 s, and it was observed that 180 s irradiation resulted in a change in the optical response range of the photodetector from visible to ultraviolet. In fact, …

Retaining The High-Temperature Phases Of Rb3h(So4)2 And Rb5h3(So4)4 At Room Temperature, Chatr Panithipongwut Kowalski

Journal of Metals, Materials and Minerals

The attempts to maintain the higher-temperature phases of Rb3H(SO4)2 and Rb5H3(SO4)4 were demonstrated in this work for the first time. The goal was to explore the possibility to utilize solid acids at lower temperatures while keeping the high-temperature phases which connects to the desirable conductivities. Enabling to do so will allow the ease of handling and thermal cycling, and the energy saving in fuel cell applications, and will allow researchers to study the high-temperature properties of solid acids at lower temperatures without the expenses for the in-situ measurements and the accessibility limitations. The four relatively simple methods, which were the …

Poly(Vinyl)Alcohol Film Composited With Carbon Dots From Water Hyacinth Stalks Based On Gamma Irradiation For The Uv Blocking Film, Tanagorn Kwamman, Threeraphat Chutimasakul, Panida Sangangam, Nattamon Puengposop, Kanokorn Wechakorn

Journal of Metals, Materials and Minerals

UV-radiation in the range of 200 nm to 400 nm from sunlight can inhibit the photosynthesis process in plants, while visible light in the range of 400 nm to 700 nm promotes photosynthesis and plant growth. In this work, poly(vinyl)alcohol-carbon dots composite film (PVA-CDs film) was developed as a UV-blocking film due to the excellent optical properties of carbon dots and the film-forming properties of PVA. For the synthesis of carbon dots using gamma irradiation, water hyacinth stalk, an invasive aquatic plant, was used as a carbon source. The result showed that PVA-CDs composite film exhibited excellent UV absorption (200 …

Luminescent Properties Of Polyaniline Capped Mn Doped Zns Quantum Dots, Anju Bala, Rajeev Sehrawat, Anil Kumar Sharma, Pardeep Soni

Journal of Metals, Materials and Minerals

Synthesis of polyaniline capped and Mn doped quantum dots are performed with co-precipitation tech. while structural, optical and morphological properties have been carried out by using Fourier Transform Infrared Spectroscopy (FTIR), X-Ray Diffraction (XRD) study, photoluminescent (PL), absorption spectroscopy and High-Resolution Transmission Electron Microscopy (HR-TEM). Particles size is nearly 2 nm calculated using XRD analysis and nearly 2.5 nm as estimated from HR-TEM study. FTIR spectra confirm that ZnS and polyaniline interact through S-H vibrations. The absorption spectra analysis reflects the occurrence of blue shift at the peak of absorption along with the enhanced band gap of polyaniline capped ZnS(Mn) …

Generation Of Excited Species In A Streamer Discharge, Shirshak K. Dhali

Electrical & Computer Engineering Faculty Publications

At or near atmospheric pressure, most transient discharges, particularly in molecular gases or gas mixture containing molecular gases, result in a space charge dominated transport called a streamer discharge. The excited species generation in such discharges forms the basis for plasma chemistry in most technological applications. In this paper, we simulate the propagation of streamers in atmospheric pressure N₂ to understand the energy partitioning in the formation of various excited species and compare the results to a uniform Townsend discharge. The model is fully two-dimensional with azimuthal symmetry. The results show a significantly larger fraction of the energy goes …

Charge Transport, Conductivity And Seebeck Coefficient In Pristine And Tcnq Loaded Preferentially Grown Metal Organic Frameworks, Xin Chen, Kai Zhang, Zeinab Mohammed Hassan, Engelbert Redel, Helmut Baumgart

Electrical & Computer Engineering Faculty Publications

This investigation on Metal-Organic Framework (MOF) HUKUST-1 films focuses on comparing the undoped pristine state and with the case of doping by TCNQ infiltration of the MOF pore structure. We have determined the temperature dependent charge transport and p-type conductivity for HKUST-1 films. Furthermore, the electrical conductivity and the current-voltage characteristics have been characterized in detail. Because the most common forms of MOFs, bulk MOF powders, do not lend themselves easily to electrical characterization investigations, here in this study the electrical measurements were performed on dense, compact surface-anchored metal-organic framework (SURMOF) films. These monolithic, well-defined, and (001) preferentially oriented MOF …

Analysis Of Post-Deposition Recrystallization Processing Via Indium Bromide Of Cu(In,Ga)Se2 Thin Films, Deewakar Poudel, Benjamin Belfore, Tasnuva Ashrafee, Shankar Karki, Grace Rajan, Angus Rockett, Sylvain Marsillac

Applied Research Center Publications

Cu(In,Ga)Se₂ (CIGS) thin films were deposited at low temperature (350 °C) and high rate (10 µm/h) by a single stage process. The effect of post-deposition treatments at 400 °C and 500 °C by indium bromide vapor were studied and compared to the effect of a simple annealing under selenium. Structural, electrical, and chemical analyses demonstrate that there is a drastic difference between the different types of annealing, with the ones under indium bromide leading to much larger grains and higher conductivity. These properties are associated with a modification of the elemental profiles, specifically for gallium and sodium.

Biomass-Derived Electrode Materials And Sustainable Processes For Supercapacitors, Katelyn M. Shell

Theses and Dissertations

Biomass is one of the most abundant natural resources and has been used as a source of energy for thousands of years. Biomass as a precursor for energy storage materials is still relatively novel and faces several obstacles before becoming commonly used in today’s electrical devices. Currently, energy storage devices, such as batteries, capacitors, and supercapacitors, utilize petroleum-derived graphitic carbons for anodes, generating a need for more sustainable materials. Biomass, as a carbon-rich source for electrode materials, presents a viable and economically feasible alternative due to the prevalent lignocellulosic compounds: lignin, cellulose, and hemicellulose. Preliminary studies on the solid residues …

Determination Of Hydrogel Degradation By Passive Mechanical Testing, Avery Rosh-Gorsky

Honors Theses

This paper details a new technique to measure the mechanical properties of ETTMP PEGDA hydrogels using Hertz Contact Theory and simultaneously analyze both the model drug release and gel erosion in situ. This method involves curing a drug loaded hydrogel in a standard cuvette and placing a glass bead and phosphate buffer solution (PBS). Over time, the cross-linked network of the hydrogel breaks down, and, as a result, the ball sinks into the hydrogel. This method provides a macroscopic and inexpensive way to continuously and passively measure properties of the hydrogel as the hydrogel degrades. By plotting both the …

Incorporation Of Perlite And Recycled Aggregates For Internal Concrete Curing, Yosra El Maghraby, Mohamed Nagib Abou-Zeid Prof., Mohamed Abdel-Raouf Dr.

Civil Engineering

No abstract provided.

Potential Advantages Of Basalt Frp Bars Compared To Carbon Frp Bars & Conventional Steel, Yosra El Maghraby, Mohamed Nagib Abou-Zeid Prof., Ezzeldeen Yazeed El Sayed Ahmed Prof

Civil Engineering

No abstract provided.

The Effects Of Rigid Polyurethane Foam As A Confinement Material On Breaching Charge Detonations, Nathan Franz Paerschke-O'Brien

Masters Theses

"The effects of a rigid polyurethane foam used as a confinement material on four types of breaching explosives were tested, focusing on the changes in shockwave peak pressures, detonation load compression forces, and brisance cratering abilities. The Plate Dent testing procedure was modified to incorporate a load cell force sensor, and two air overpressure sensors were included adjacent to the blast to quantify each test result. The testing variables focused on the polyurethane foam cure times and thickness volumes around the breaching explosives to determine the breaching charges' optimal energy output capabilities when confined by the foam material. The rigid …

Dry Reforming Of Methane Using Microwave Irradiated Metal Oxide/Coal Char Catalysts, Anthony Carter

Graduate Theses, Dissertations, and Problem Reports (ETD)

This research focuses on the synthesis of both shaped and amorphous powder materials, the combination of these materials with dried Powder River Basin (PRB) coal char, and their reactionary properties with methane and carbon dioxide gasses with conventional and microwave (MW) heating. The first goal of this project was to synthesize shaped micro and nano sized particles with ideal dielectric properties for converting electromagnetic energy into heat and proven capabilities of activating methane. These particles were synthesized via solvothermal, hydrothermal, and co-preceptory treatments alone and onto the surface of dried PRB coal char. PRB is a sub-bituminous, low-ranking coal (LRC) …

Multi-Level Analysis Of Atomic Layer Deposition Barrier Coatings On Additively Manufactured Plastics For High Vacuum Applications, Nupur Bihari

Dissertations, Master's Theses and Master's Reports

While hardware innovations in micro/nano electronics and photonics are heavily patented, the rise of the open-source movement has significantly shifted focus to the importance of obtaining low-cost, functional and easily modifiable research equipment. This thesis provides a foundation of open source development of equipment to aid in the micro/nano electronics and photonics fields.

First, the massive acceptance of the open source Arduino microcontroller has aided in the development of control systems with a wide variety of uses. Here it is used for the development of an open-source dual axis gimbal system. This system is used to characterize optoelectronic properties of …

The Effects Of Molybdenum, Chromium, And Niobium On Gray Iron For Brake Rotor Applications, Matthew Hasbrouck

Dissertations, Master's Theses and Master's Reports

Brake rotor composition and microstructure must be optimized for thermal and mechanical performance to avoid thermal-mechanical cracking, excessive wear, and to reduce noise. Niobium is an element that increases the strength and wear resistance of gray iron; however, the interaction of niobium with other common alloying elements (chromium and molybdenum) is not well understood. Thirteen gray cast iron alloys were produced with varying levels of carbon equivalent (CE), Cr, Mo, and Nb. Bars with four different diameters (8, 14, 22, and 30 mm) were cast from each alloy and microstructural and physical properties such as graphite flake morphology, pearlite spacing, …

Establishing Independent Tunability Of The Mechanical And Transport Properties Of Polymer Gels, Lucas Rankin

Master’s Theses

Polymer gels can be used in the fabrication of materials for filtering liquid and gaseous media, solid-state electrolytes, and transdermal medical patches. This diverse range of applications primarily relies on the transport and mechanical properties of polymer gels. Both sets of properties have shown excellent tunability, but typically in a coupled fashion. Establishing the independent tunability of the transport and mechanical properties of polymer gels (using simple, cost-effective methods) is paramount if polymer gels are to be used to their full potential. Specifically, block copolymer gels self-assemble into organized nanoscale networks within the gel solvent, which allows for facile control …

Atmospheric Corrosion Of Galvanically Coupled Aluminum Alloys And Carbon Steel, Mitchell Felde

Williams Honors College, Honors Research Projects

Aluminum alloys are a steadily growing material being commonly used in lieu of typical steels. Additional alloying, heat treatment, and other property enhancing processes are expanding the use of these alloys. However, with this expansion, galvanic corrosion is becoming more of an issue in the design stage due to the combination of these alloys with steels. The automotive industry is one industry where the use of aluminum alloys is becoming common practice. Aluminum alloys provide a lightweight aspect over the conventional carbon steel that was used previously. As a result of this transition towards more lightweight materials, galvanic coupling is …

Testing The Effectiveness Of Various Fabrics For Use In Protective Face Coverings, Isaac Daley

Williams Honors College, Honors Research Projects

Facemask requirements have been heavily implemented as a result of the COVID-19 pandemic. The purpose of this study was to test various fabrics that could be used in face coverings and determine which materials are best for reducing virus transmission rates. Of the seven fabrics tested, five were conventional home-use fabrics and the other two were surfaces modified with hydrophobic organosilanes. Wettability and droplet adherence tests were performed on each material. The materials that performed the best were decyltrichlorosilane (DTS) modified cotton, perfluorotrichlorosilane (FTS) modified cotton, and polyester. Contact angles for water droplets on these fabrics were 106°, 93°, and …