Engineering Commons^™

The Characterization And Nanomechanical Properties Of Microstructurally Complex Systems, Kerry Ann Baker

Theses and Dissertations--Chemical and Materials Engineering

Since the dawn of civilization, the use of metals has played an integral role in the evolution of human society. Over the years, and with the introduction of new engineering and science, we have learned how to combine metals to create new metallic systems. We have expanded our understanding of dealloying and chemical reactions, and, in doing so, we created nanoporous metals. Our use of metals has evolved from basic alloys such as bronze and steel to more complex alloys such as multi-principal element alloys. Nanoporous gold is an advanced metallic system that can be created through the dealloying process. …

Thermomechanical Process Simulation And Quantification Of Nanoscale Precipitation Influencing Ductility And Strength During Alloy Processing, Alyssa Stubbers

Theses and Dissertations--Chemical and Materials Engineering

Experimental process simulation and quantification of microstructure development during processing are challenging due to limitations with machinery temperature capability, inadequate resolution and sampling volume of currently available characterization techniques, and difficulty characterizing material microstructures as close to processing-relevant conditions as possible. This dissertation addresses how process simulation can be performed using Gleeble thermomechanical technologies and how microstructure development during these processing simulations can be quantified both in-situ and ex-situ.

The first portion of this dissertation demonstrates how Gleeble technologies can be applied to simulate complex material processing conditions in order to produce process-property profiles that can be used to inform …

Application Of Multi-Scale Computational Techniques To Complex Materials Systems, Mujan N. Seif

Theses and Dissertations--Chemical and Materials Engineering

The applications of computational materials science are ever-increasing, connecting fields far beyond traditional subfields in materials science. This dissertation demonstrates the broad scope of multi-scale computational techniques by investigating multiple unrelated complex material systems, namely scandate thermionic cathodes and the metallic foam component of micrometeoroid and orbital debris (MMOD) shielding. Sc-containing "scandate" cathodes have been widely reported to exhibit superior properties compared to previous thermionic cathodes; however, knowledge of their precise operating mechanism remains elusive. Here, quantum mechanical calculations were utilized to map the phase space of stable, highly-faceted and chemically-complex W nanoparticles, accounting for both finite temperature and chemical …

Surface Properties, Work Function, And Thermionic Electron Emission Characterization Of Materials For Next-Generation Dispenser Cathodes, Antonio Mantica

Theses and Dissertations--Chemical and Materials Engineering

A dispenser cathode’s ability to thermionically emit electrons is highly dependent on its material properties, especially those of the surface. Understanding the relationship between surface properties and electron emission, therefore, is vital to reach the next generation of the many vacuum electron devices (VEDs) that rely on the physics of electron emission. In the past century, many techniques have been developed to characterize material surfaces and quantify thermionic emission. These techniques are based on a wide range of different physical phenomena, including measuring photoemission via the photoelectric effect, measuring the electrostatic potential between metals in electrical contact, and current collection …

Drop Wetting And Sliding On Soft, Swollen Elastomers, Zhuoyun Cai

Theses and Dissertations--Chemical and Materials Engineering

Soft, slippery surfaces have gained increasing attention due to their wide range of potential applications, for example in self-cleaning, anti-fouling, liquid collection, and more. One design approach in creating slippery surfaces is using a swollen elastomer, which is a polymer network swollen with a lubricant. This type of surface may be beneficial for longer-term use than standard lubricant-infused surfaces, and provides a versatile surface with tunable mechanical properties. Hence, understanding the physics of soft surface interactions is important for fundamental soft matter physics, biomaterials, adhesives, and coatings. This research experimentally investigates wetting on soft infused networks, with the aim of …

Effects Of Confinement On Ionic Liquids And Deep Eutectic Solvents For The Design Of Catalytic Systems, Electrochemical Devices, And Separations, Andrew Drake

Theses and Dissertations--Chemical and Materials Engineering

Confinement of ionic liquids (ILs) and deep eutectic solvents (DESs) within mesoporous materials such as silica helps to control the local environment within the pores for applications such as catalysis, electrochemistry, and absorption. Silica thin films with 2.5 and 8 nm pores and micron-sized silica particles with pore diameters of 5.4 and 9 nm were synthesized to study the effect of nanoconfinement on ILs 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF₆]), 1-butyl-3-methylimidazolium chloride ([BMIM][Cl]), and DESs reline and ethaline (choline chloride and urea or ethylene glycol). Silica thin films with vertically aligned, well ordered, and accessible pores were synthesized via the evaporation-induced …

Advanced Microstructural Characterization Of Functionally Graded Dental Ceramic Material For Materials-Informed Finishing, Angani Vigneswaran

Theses and Dissertations--Manufacturing Systems Engineering

Yttria-stabilized tetragonal zirconia polycrystal (Y-TZP) has gained popularity as the choice of material for dental prosthetics. Ivoclar Vivadent’s IPS e.max ZirCAD Prime dental ceramic incorporates a unique gradient technology that varies the yttria content over the thickness of the material. The top layer is composed of 5Y-TZP which is desired for its optical properties while the bottom layer is composed of a much stronger 3Y-TZP. In between the two layers, 5Y-TZP and 3Y-TZP are mixed to form a transition layer. Varying the amount of yttria allows for more esthetically pleasing translucency in the visible areas of the restoration without compromising …

Removal Of Selenium And Heavy Metals From Coal Combustion Residuals Wastewater Using Surface Modified Iron Based Media, Madan Tandukar, Alex Korff, Andrew Vincent, Chris Hardin

World of Coal Ash Proceedings

No abstract provided.

Epri Research On Groundwater-Surface Water Interactions Near Coal Combustion Product Sites, Bruce Hensel, Jeff Thomas, Tim Towey, Anthony Aufdenkampe

World of Coal Ash Proceedings

No abstract provided.

Cqa - A Common Sense Approach At Becoming The Mvp On Your Next Project, James Price, Michael Fisher, John Metcalf

World of Coal Ash Proceedings

No abstract provided.

Challenges & Pragmatic Solutions For The Design And Construction Of A 300-Acre Ccr Landfill Located In The Southwestern Us - A Case Study, Andy Lucas, Jason Pokorny

World of Coal Ash Proceedings

No abstract provided.

State Of The Practice For Compaction Quality Of Dry Stack Ccr Storage Facilities, Bruce Cunningham, Pavana Vennapusa, David J. White, Robert Eric Hageman

World of Coal Ash Proceedings

No abstract provided.

Hybrid Closure Approach: Constructing Bidding Lessons Learned, Brian Harthun, P.E.

World of Coal Ash Proceedings

No abstract provided.

Groundwater Compliance & Strategy Insights For Ccr Rule Stakeholders, Sheryl Smith, Mark Johnson

World of Coal Ash Proceedings

No abstract provided.

Ecological Risk Assessment For Coal Combustion Residuals And Herrington Lake Adjacent To The Kentucky Utilities E.W. Brown Generating Station, Mary Sorensen, Alex Smith, Mark Nielsen

World of Coal Ash Proceedings

No abstract provided.

Geochemical Explanations For Strong Natural Attenuation Of Molybdenum, Selenium, And Lithium In A Groundwater Plume, Jacob Chu, J. P. Brandenburg

World of Coal Ash Proceedings

No abstract provided.

Ccr Landfill Construction & Operation Under Subtitle D, Thomas R. Gredell

World of Coal Ash Proceedings

No abstract provided.

Use Of A Net Environmental Benefit Analysis To Evaluate Remedial Options To Address Coal Ash – Case Studies, Joseph Nicolette, Michael Rockel

World of Coal Ash Proceedings

No abstract provided.

Monitoring Well Integrity And Performance Part Ii - Seeing The Benefits, Bryan R. Hansen, Jacob G. Gruzalski, Thomas S. Dicken, Rock J. Vitale

World of Coal Ash Proceedings

No abstract provided.

Hybrid Closure Approach: Design Investigation Review, Brian Sperrazza, P.E., P.G.

World of Coal Ash Proceedings

No abstract provided.

Use Of Tritium-Helium Isotopes For Vertical Delineation Of Ccr Constituents In Groundwater, Lane Dorman, Lauren Fitzgerald, Ryan Fimmen, Robert Trey Singleton

World of Coal Ash Proceedings

No abstract provided.

Construction Risk Management Considerations For Ccr Surface Impoundment Closures, John P. Seymour, Chris Robb

World of Coal Ash Proceedings

No abstract provided.

Ccr Beneficial Use Data Capture And Reporting, Joe Ploetz, Kevin Foody

World of Coal Ash Proceedings

No abstract provided.

The Intersection Of The Ccr Rule, Superfund, And Irrigation On The Great Plains, Shane D. Mcdonald, Jillian Troyer, Robert Kleinmann, Marty Stange

World of Coal Ash Proceedings

No abstract provided.

Using Shear Wave Velocity Measurements To Identify Cemented Ccr, Andrew Fuggle, Longde Jin, Haley Roberts

World of Coal Ash Proceedings

No abstract provided.

Wind Performance Evaluation Of Engineered Turf Final Cover And Exposed Geomembrane, Ming Zhu, Bryan Scholl

World of Coal Ash Proceedings

No abstract provided.

Attenuation And Source Zone Depletion Of Boron From Coal Combustion Residuals In Groundwater, J.P. Brandenburg, Dave Hagen

World of Coal Ash Proceedings

No abstract provided.

Building Defensibility For Mna Remedy Selection, Michael Healey, Jeff Roberts, Sarah Cronk, Andrzej Przepiora

World of Coal Ash Proceedings

No abstract provided.

Hybrid Closure Approach: Project Summary, Glenn Leo, P.E.

World of Coal Ash Proceedings

No abstract provided.

Whole Effluent Toxicity (Wet) Assessments And Experimental Considerations For Evaluating Coagulation Agents And Polymers For Wastewater Treatment Of Coal Combustion Products, Konrad J. Kulacki, William L. Goodfellow Jr., Margaret L. Fleming, Alexandra N. Steele

World of Coal Ash Proceedings

No abstract provided.