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Articles 1351 - 1380 of 16676

Full-Text Articles in Engineering

Microstructural, Oxidation, And Mechanical Behavior Of Nbti-Based Refractory Alloys With 5 To 10 Pct Co, Cr, And Ni Additions, Tae Kyong John Kim, Jennifer Carter Feb 2025

Microstructural, Oxidation, And Mechanical Behavior Of Nbti-Based Refractory Alloys With 5 To 10 Pct Co, Cr, And Ni Additions, Tae Kyong John Kim, Jennifer Carter

Faculty Scholarship

NbTi-based refractory alloys with additions of Co, Cr, and Ni represent an interesting medium-entropy alloy system with potential for protective oxide film formation, high strength, and ductility. This study investigates the microstructural evolution, oxidation behavior, and mechanical properties of NbTi-based alloys containing 5 to 10 at. pct Co, Cr, and Ni. CALPHAD predictions suggest that this composition range can be heat treated to obtain a predominantly body-centered cubic matrix phase. Mechanical properties, including microhardness, yield strength, maximum strength, and specific strength are evaluated through isothermal compression tests conducted between room temperature and 800 °C. The oxidation kinetics of these alloys …

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Research Of Horse Oil Based Shampoo For Fine Hair Involving Local Oils And Enzyms Transesterification, Sherzod Y. Rakhmanov, Madina O. Khaydarova, Bonu G. Аrislonboyeva, Nilufar A. Khaydarova, Dilshod P. Rakhimov Feb 2025

Research Of Horse Oil Based Shampoo For Fine Hair Involving Local Oils And Enzyms Transesterification, Sherzod Y. Rakhmanov, Madina O. Khaydarova, Bonu G. Аrislonboyeva, Nilufar A. Khaydarova, Dilshod P. Rakhimov

CHEMISTRY AND CHEMICAL ENGINEERING

Currently, there are many shampoos, balms and various hair masks. Shampoo-tonics have also been introduced into production, providing temporary coloring without damaging the hair structure. In this research work, we set ourselves the task of conducting a study of a shampoo for soft hair that provides durability, granularity and shine to hair by transesterifying horse oil with the enzyme lipase and the surfactant sodium lauryl sulfate. Depending on the type of shampoo, we conducted a scientific study using the following experimental method. To add horse oil to the shampoo formula, we re-esterified mixtures of horse oil and sunflower oil in …

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Effect Of Desorption On Photocatalytic Decomposition Of Methylene Blue Using Materials From Solid Wastes Of Production Of Molybdenum Oxides (Vi) And Titanium Dioxide, Dilshoda R. Tursunova, Shahlo Sh. Daminova, Rafael A. Nusretov, Ayipbergen Shiknazarov, Zuhra Ch. Kadirova Feb 2025

Effect Of Desorption On Photocatalytic Decomposition Of Methylene Blue Using Materials From Solid Wastes Of Production Of Molybdenum Oxides (Vi) And Titanium Dioxide, Dilshoda R. Tursunova, Shahlo Sh. Daminova, Rafael A. Nusretov, Ayipbergen Shiknazarov, Zuhra Ch. Kadirova

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the work is to obtain and characterize a composite photocatalyst based on the spent catalyst of the Shurtan Mining and Chemical Combine based on titanium dioxide and molybdenum-containing waste of the Almalyk Mining and Metallurgical Combine and to identify factors influencing the process of photocatalytic decomposition of methylene blue in solution under the action of UV light. In this work, we studied the kinetics of photocatalytic decomposition of methylene blue on the surface of materials obtained from technogenic solid waste, which were thermally activated at a temperature of 600 ° C. It was found that desorption plays …

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X-Ray Photoelectron Spectroscopy Investigation Of Surface Changes In Chalcocite And Enargite Minerals Following Oxidation Treatment, Berdakh T. Daniyarov, Miki Hajime, Baxtigul Y. Ruzieva, Shahlo Sh. Daminova Feb 2025

X-Ray Photoelectron Spectroscopy Investigation Of Surface Changes In Chalcocite And Enargite Minerals Following Oxidation Treatment, Berdakh T. Daniyarov, Miki Hajime, Baxtigul Y. Ruzieva, Shahlo Sh. Daminova

CHEMISTRY AND CHEMICAL ENGINEERING

Copper sulfide minerals, such as chalcocite (Cu₂S) and enargite (Cu₃AsS₄), are important sources of copper, which has wide applications in electronics, energy, and other industries. These minerals are traditionally processed using flotation methods, which are one of the most effective ways to extract copper from sulfide ores. However, the success of flotation of copper sulfides, such as chalcocite and enargite, strongly depends on changes in their surface properties, such as hydrophobicity or hydrophilicity, which can be modified by various chemical reagents. To further understand the impact of these chemical reagents on chalcocite and enargite minerals, X-ray photoelectron spectroscopy (XPS) was …

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Synthesis And Study Of Complex Compounds With 1,3,4-Oxadiazole Derivatives Based On Ammonium Vanadate, Mehribon A. Pirimova, Shaxnoza A. Kadirova, Abduhakim A. Ziyayev Feb 2025

Synthesis And Study Of Complex Compounds With 1,3,4-Oxadiazole Derivatives Based On Ammonium Vanadate, Mehribon A. Pirimova, Shaxnoza A. Kadirova, Abduhakim A. Ziyayev

CHEMISTRY AND CHEMICAL ENGINEERING

This research work examines the synthesis, structure and properties of ammonium vanadate complex compounds based on 1,3,4-oxadiazole derivatives. Competing donor centers in coordination, electronic and geometric structures of the ligand molecule were studied based on quantum chemical calculations using the Gaussian09 LanL2DZ software package. Among the ligands, 2-carboxymethylthio-5-phenyl-1,3,4-oxadiazole ligand has been shown to have more competitive donor atoms than other ligands.

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Structural Features And Morphology Of Biodegradable Composites Based On Polylactide And Corn Starch, Eygeniy N. Poddenezhny, Andrei A. Boiko, Ekaterina E. Trusova, Viktor M. Shapovalov Feb 2025

Structural Features And Morphology Of Biodegradable Composites Based On Polylactide And Corn Starch, Eygeniy N. Poddenezhny, Andrei A. Boiko, Ekaterina E. Trusova, Viktor M. Shapovalov

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the work was to study the morphology and structural features of biodegradable composites based on polylactide, filled with corn starch formed by extrusion method. The characteristics of the obtained materials were investigated by scanning electron microscopy, X-ray diffraction, IR spectroscopy. It was established that the presence of polyethylene glycol PEG–4000 as a plasticizer and surfactant – glycerin monostearate in the initial mixture leads to the formation of a nonporous heterogeneous system, in which starch particles are statistically distributed in the matrix. The starch concentration in the composite varied from 20 to 55 wt. %. When the starch …

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Influence Of Thermal Cycling On The Resistance Of Bismuth Cuprates Synthesized Using Solar Energy, Dilbara Dj. Gulamova, Sirojiddin Z. Mirzaev, Sirojiddin Kh. Bobokulov, Elyor B. Eshonkulov, Grigor I. Mamniashvili Feb 2025

Influence Of Thermal Cycling On The Resistance Of Bismuth Cuprates Synthesized Using Solar Energy, Dilbara Dj. Gulamova, Sirojiddin Z. Mirzaev, Sirojiddin Kh. Bobokulov, Elyor B. Eshonkulov, Grigor I. Mamniashvili

CHEMISTRY AND CHEMICAL ENGINEERING

A bulk superconducting ceramic synthesized using solar technology exhibits a sharp increase in resistance from zero to approximately 160Ω at 250 K. Four thermal cycling tests in the range of 79-360 K revealed a tendency for the temperature transition interval to narrow and a comparatively sharp jump at 290 K, suggesting a superconducting transition. The effect of stress concentration at grain boundaries during four cycles leads to an increase in the superconducting transition temperature due to the cumulative rise in stress and pinning force. The assumption that these effects are caused by superconducting homologous phases is based on the manifestation …

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The Effect Of B2o3 On The Structure And Properties Of The Glasses Of The Na2o–Cao–Mgo–Sio2–P2o5 System, Mihail V. Dyadenko, Ivan A. Levitskiy, Irina I. Kurilo, Alexander S. Glinskii Feb 2025

The Effect Of B2o3 On The Structure And Properties Of The Glasses Of The Na2o–Cao–Mgo–Sio2–P2o5 System, Mihail V. Dyadenko, Ivan A. Levitskiy, Irina I. Kurilo, Alexander S. Glinskii

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this work was to study the effect of boron oxide on the physico-chemical and technological properties of glasses of the Na2O–CaO–MgO–SiO2–P2O5 system. The study of crystallization ability, density, the temperature of the onset of softening, as well as the chemical stability of experimental glasses modified with boron oxide, made it possible to indirectly assess their ability to dissolve in aqueous solutions and show bioactive properties. The article presents the results of the influence of B2O3 on the viscosity of the studied glasses and the value of their …

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Research Of The Decomposition Process Of Unenriched Phosphate Raw Materials Of Central Kyzylkum With Nitric And Sulfuric Acids, Husan A. Zikirov, Ruslan Ch. Yorbobaev, Kholtura Ch. Mirzakulov Feb 2025

Research Of The Decomposition Process Of Unenriched Phosphate Raw Materials Of Central Kyzylkum With Nitric And Sulfuric Acids, Husan A. Zikirov, Ruslan Ch. Yorbobaev, Kholtura Ch. Mirzakulov

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the research is to establish the optimal technological parameters of the process of decomposition of unenriched phosphate raw materials of the Central Kyzylkum nitric and sulfuric acid for processing complex nitrogen-phosphorus fertilizers, to study the chemical composition, rheological properties. The coefficient of decomposition of unenriched phosphate raw materials, pH of acid pulp depending on various ratios and the total rate of nitric-sulfuric acid, as well as S:L of the environment are determined. The chemical and mineralogical composition of nitrosulphophosphate fertilizers formed after drying the ammoniated pulp are established.

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Biobased Acrylate Composites With Enhanced Strength For Additive Manufacturing, Nicole Wagner, Joseph Mcwherter Feb 2025

Biobased Acrylate Composites With Enhanced Strength For Additive Manufacturing, Nicole Wagner, Joseph Mcwherter

Engineering Faculty Articles and Research

With the expanding use of polymers in additive manufacturing, sustainable resins for use in vat photopolymerization are required to reduce their environmental impact. One promising approach to achieve this is to incorporate biobased fillers that replace the acrylates in photopolymer resins as ‘green’ alternatives. In this study, photopolymer composites consisting of a methacrylate resin with varying calcium carbonate powder content between 0 and 50 wt.% were investigated. A digital light processing technique was used to fabricate tensile test specimens for mechanical testing. Good printability, dimensional accuracy, and good interlayer adhesion were observed for composite resin formulations that incorporated calcium carbonate …

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Selective Leaching Of Rare Earth Elements From Complex Rare Earth Ore Using Deep Eutectic Solvents, Frank Agyemang, Mehran Saddat, Zainab Nasrullah, Richard Ladouceur Feb 2025

Selective Leaching Of Rare Earth Elements From Complex Rare Earth Ore Using Deep Eutectic Solvents, Frank Agyemang, Mehran Saddat, Zainab Nasrullah, Richard Ladouceur

Metallurgical & Materials Engineering

Rare earth elements (REEs) are valuable for various modern technological applications, including metallurgy, machine building, radio electronics, instrument engineering, nuclear engineering, and manufacturing. The extraction and separation of rare earth elements (REEs) from their complex ores is challenging due to their distinct physical and chemical properties, contributing to their market scarcity. At present, REE recovery utilizes traditional pyro- or hydrometallurgical processes. The overall process in the recovery and separation of individual elements from complex REE systems suffers from high energy demands and the use of many hazardous chemicals that negatively impact the environment. With the growing trend toward a circular …

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Process Intensification By Resonant Vibratory Mixing For The Recyclable Samarium - Cobalt Magnets After Chemical Leaching With Deep Eutectic Solvents, Zainab Nasrullah, Frank Agyemang, Mehran Saddat, Richard Ladouceur Feb 2025

Process Intensification By Resonant Vibratory Mixing For The Recyclable Samarium - Cobalt Magnets After Chemical Leaching With Deep Eutectic Solvents, Zainab Nasrullah, Frank Agyemang, Mehran Saddat, Richard Ladouceur

Metallurgical & Materials Engineering

To sustain the circular economy, defense applications, and other renewable technologies, recycling rare earth elements (REEs) and other critical elements from their secondary resources is important. This cause has resulted in rigorous research and development for viable extraction and separation of REEs. Previously, Sm-Co recycling has been done with technologies, which fall under the categories of pyrometallurgy, physical separation, and hydrometallurgy. All these methods have limitations associated with energy, cost, and environment. Reportedly, the chemical leaching technology has successfully recovered and separated Sm-Co. Still, it has limitations associated with slow mass transfer and leaching kinetics, and there is a need …

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Simulation-Based Models For Postearthquake Response: A Survey And Research Directions, Abhijit Gosavi, Lauryn A. Spearing, Lesley H. Sneed Feb 2025

Simulation-Based Models For Postearthquake Response: A Survey And Research Directions, Abhijit Gosavi, Lauryn A. Spearing, Lesley H. Sneed

Engineering Management and Systems Engineering Faculty Research & Creative Works

Computer simulation is increasingly being used by emergency planners as a tool to improve disaster response given that it can model real-world scenarios, such as earthquakes. Although there has been an increase in simulation research focused on disaster response, much of this literature is from disparate fields and across disaster scenarios. To bridge this gap, this paper surveys simulation-based models for post-earthquake response from the year 2000 onward. Advantages of simulation over closed-form statistical models are discussed. Three main subproblems in post-earthquake response models are explored: (1) service distribution (e.g., food, water), (2) infrastructure restoration (at the building and transportation …

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Rheology And Early-Age Structure Development In Binary And Ternary Blends Modified With Novel Graphene Types, Sahil Surehali, Collin Gustafson, Sayee Srikarah Volaity, Ranjith Divigalpitiya, Aditya Kumar, Narayanan Neithalath Feb 2025

Rheology And Early-Age Structure Development In Binary And Ternary Blends Modified With Novel Graphene Types, Sahil Surehali, Collin Gustafson, Sayee Srikarah Volaity, Ranjith Divigalpitiya, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

Interest in the use of graphene to enhance the properties of cementitious materials is growing, but major impediments in implementation are the cost of graphene and changes in binder rheology attributable to these nanomaterials. This study explores the influence of novel, cost-effective, environment-friendly, and mass-producible graphene on the rheology and early-age structure development of cementitious binders. Two novel graphene types—fractal graphene (FG) and reactive graphene (RG)—are used in plain cement mixtures as well as those containing 30 % (by mass) of fly ash and/or limestone powder, at low dosages of ≤0.02 % by mass of binder. The early- and later-age …

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Effect Of Shrinkage-Mitigating Materials, Fiber Type, And Repair Thickness On Flexural Behavior Of Beams Repaired With Fiber-Reinforced Self-Consolidating Concrete, Jingjie Wei, Kamal H. Khayat Feb 2025

Effect Of Shrinkage-Mitigating Materials, Fiber Type, And Repair Thickness On Flexural Behavior Of Beams Repaired With Fiber-Reinforced Self-Consolidating Concrete, Jingjie Wei, Kamal H. Khayat

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

While self-consolidating concrete (SCC) has emerged as a highly effective approach for the repair of concrete structures, there have been few investigations regarding the effect of the combination of different fiber and shrinkage-mitigating material types (shrinkage-reducing admixture, SRA; superabsorbent polymer, SAP; and expansive agent, EA) on the flexural behavior of repaired structures. This study aims to explore the influence of three different shrinkage-mitigating materials (1.25%–2.5 % SRA, 4%–8% EA, and 0.2%–0.4 % SAP), four fiber types (two macro synthetic fibers, MSFA and MSFB; 5D hooked steel fibers, 5D; a combination of 80 % 3D hooked steel +20 % short steel …

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Thermally Stimulated Stiffening And Fly Ash's Alkaline Activation By Ca(Oh)2 Addition Facilitates 3d-Printing, Xiaodi Dai, Sharu Bhagavathi Kandy, Narayanan Neithalath, Aditya Kumar, Mathieu Bauchy, Edward Garboczi, Torben Gaedt, Samanvaya Srivastava, Gaurav Sant Feb 2025

Thermally Stimulated Stiffening And Fly Ash's Alkaline Activation By Ca(Oh)2 Addition Facilitates 3d-Printing, Xiaodi Dai, Sharu Bhagavathi Kandy, Narayanan Neithalath, Aditya Kumar, Mathieu Bauchy, Edward Garboczi, Torben Gaedt, Samanvaya Srivastava, Gaurav Sant

Materials Science and Engineering Faculty Research & Creative Works

3D-printing could offer substantial benefits to the construction industry including the fabrication of customized/bespoke components, eliminating formwork, and reducing material waste. Despite these advantages, control of the pumpability, extrudability, and buildability of 3D-printed concrete (3DPC) remains challenging. This study demonstrates how the use of fly ash (FA) enables enhanced thermal stiffening, and rapid alkali-activation in the presence of portlandite (Ca(OH)2, CH). In general, blends of CH and FA exhibit less structural build-up at low temperatures, but upon reaching a trigger temperature of 75 °C, these blends achieve rapid stiffening, at rates of ∼800 Pa/s. The rapid stiffening arises from the …

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Influence Of Temperature, Oxygen Partial Pressure, And Microstructure On The High-Temperature Oxidation Behavior Of The Sic Layer Of Triso Particles, Visharad Jalan, Adam Bratten, Meng Shi, Tyler Gerczak, Haiyan Zhao, Jonathan D. Poplawsky, Xiaoqing He, Grant Helmreich, Haiming Wen Feb 2025

Influence Of Temperature, Oxygen Partial Pressure, And Microstructure On The High-Temperature Oxidation Behavior Of The Sic Layer Of Triso Particles, Visharad Jalan, Adam Bratten, Meng Shi, Tyler Gerczak, Haiyan Zhao, Jonathan D. Poplawsky, Xiaoqing He, Grant Helmreich, Haiming Wen

Materials Science and Engineering Faculty Research & Creative Works

Tri structural isotropic (TRISO)-coated fuel particles are designed for use in high-temperature gas-cooled nuclear reactors, featuring a structural SiC layer that may be exposed to oxygen-rich environments over 1000 °C. Surrogate TRISO particles were tested in 0.2–20 kPa O2 atmospheres to observe the differences in oxidation behavior. Oxide growth mechanisms remained consistent from 1200–1600 °C for each PO2, with activation energies of 228 ± 7 kJ/mol for 20 kPa O2 and 188 ± 8 kJ/mol for 0.2 kPa O2. At 1600 °C, kinetic analysis revealed a change in oxide growth mechanisms between 0.2 and 6 kPa O2. In 0.2 kPa …

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Impurity Behavior In Cast Copper Anodes: Implications For Electrorefining In A Circular Economy, Agustin Morales-Aragon, Daniel Sánchez-Rodas, Guillermo Ríos, Michael S. Moats Feb 2025

Impurity Behavior In Cast Copper Anodes: Implications For Electrorefining In A Circular Economy, Agustin Morales-Aragon, Daniel Sánchez-Rodas, Guillermo Ríos, Michael S. Moats

Materials Science and Engineering Faculty Research & Creative Works

The behavior of impurities in cast copper was investigated to simulate production with increased utilization of secondary sources within the framework of a circular economy. The incorporation of impurities, particularly Ni, Sn, and Sb, from recycled Cu may significantly impact the electrorefining process. In this study, commercial anodes were doped with Ni, Sn, and Sb concentrations of 2500–6500 g/t, 300–900 g/t, and 450–950 g/t, respectively. Anode concentrations of Pb and Bi were maintained at 1000 g/t and 350 g/t, respectively. As concentrations were examined at two levels, 860 or 1700 g/t, depending on the commercial anode used to create the …

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Elevated Temperature Performance: Arc-Jet Testing Of Carbon Fiber Reinforced Zrb2 Bars Up To 2200 °C For Strength Retention Assessment, D. Sciti, A. Vinci, L. Zoli, P. Galizia, M. Mor, W. Fahrenholtz, S. Mungiguerra, R. Savino, A. M. Caporale, A. Airoldi Feb 2025

Elevated Temperature Performance: Arc-Jet Testing Of Carbon Fiber Reinforced Zrb2 Bars Up To 2200 °C For Strength Retention Assessment, D. Sciti, A. Vinci, L. Zoli, P. Galizia, M. Mor, W. Fahrenholtz, S. Mungiguerra, R. Savino, A. M. Caporale, A. Airoldi

Materials Science and Engineering Faculty Research & Creative Works

For the first time, ultra-high temperature ceramic matrix composite bars were tested inside an arc-jet facility to investigate the impact of oxidation damage on strength retention. The composite bars, which were based on a ZrB2 / SiC matrix reinforced with 45 vol% carbon fibers, were produced by slurry impregnation and sintering. The first batch was tested under 3-point (pt) bending, and two additional batches were exposed to plasma of dissociated air up to a temperature of 2200 °C for 2 min or 2.2 min and then subjected to 3-pt bending. More than 75% of the initial strength was retained even …

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Effects Of Gypsum And Limestone On Early-Age Hydration And Strength Optimization In Belite Calcium Sulfoaluminate Cement, Sai Akshay Ponduru, Bryan K. Aylas-Paredes, Taihao Han, Advaith Neithalath, Narayanan Neithalath, Gaurav Sant, Aditya Kumar Feb 2025

Effects Of Gypsum And Limestone On Early-Age Hydration And Strength Optimization In Belite Calcium Sulfoaluminate Cement, Sai Akshay Ponduru, Bryan K. Aylas-Paredes, Taihao Han, Advaith Neithalath, Narayanan Neithalath, Gaurav Sant, Aditya Kumar

Materials Science and Engineering Faculty Research & Creative Works

Belite calcium sulfoaluminate cement (CSAB), an alternative to Portland cement, exhibits excellent strength at both early and later ages. However, due to its high belite content, the carbon reduction from this type of cement is not sufficient when compared to other alternative cements. To further enhance CSAB's sustainability, this study investigates the performance of CSAB when partially replaced by low-carbon mineral additives (i.e., limestone and gypsum). The primary objective is to identify the optimal mixture design by incorporating gypsum and limestone to formulate a sustainable binder that maintains high compressive strength. The CSAB is replaced (with both additives) by up …

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Predicting The High Temperature Deformation Behavior Of Haynes282 By A Dislocation-Density Based Crystal Plasticity Model, Tianju Chen, Huadong Fu, Shujing Dong, Yue Zhou, Yijia Gu, Caizhi Zhou, Ridwan Sakidja Feb 2025

Predicting The High Temperature Deformation Behavior Of Haynes282 By A Dislocation-Density Based Crystal Plasticity Model, Tianju Chen, Huadong Fu, Shujing Dong, Yue Zhou, Yijia Gu, Caizhi Zhou, Ridwan Sakidja

Materials Science and Engineering Faculty Research & Creative Works

Mechanical behavior of Haynes282 is heavily dependent upon the microstructure state, calling for mesoscale model to study the relationship between the underlying microstructure and macroscopic performance. In this work, we employ crystal plasticity finite element method (CPFEM) to explore the deformation mechanisms of Hanyes282 subjected to tensile (short-term) and creep (long-term) tests. Haynes282 is a newly developed Ni-based superalloy, containing relatively low volume fraction (≤20%) of spherical γ′ precipitate phase. A dislocation-density based model is developed to describe the tensile and the creep behavior, where a dimension reduction algorithm is proposed to obtain more accurate inter-particle spacing. Furthermore, dislocation-particle interaction …

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Spark Plasma Sintering Of (Zr,Nb)C Ceramics, Jacob Stacy, Greg Hilmas, Jeremy Watts, Brian Taylor, Jhonathan Rosales Jan 2025

Spark Plasma Sintering Of (Zr,Nb)C Ceramics, Jacob Stacy, Greg Hilmas, Jeremy Watts, Brian Taylor, Jhonathan Rosales

Materials Science and Engineering Faculty Research & Creative Works

A range of (Zr,Nb)C ceramics containing 20–50 vol% NbC were spark plasma sintered at 2000°C. The ceramics had relative densities greater than 97 %, and all compositions formed a complete solid solution. The average grain size was ∼7.1 µm over all compositions. Elastic moduli values ranged from 436 to 445 GPa, and the fracture toughness ranged from 0.8 to 2.8 MPa·m1/2 over the compositional range, both increasing with increasing NbC content. The hardnesses of the (Zr,Nb)C ceramics ranged from 19.1 to 20.2 GPa at a load of 9.81 N. The flexural strength increased from 352 to 395 MPa as the …

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New Insights Into Controlling The Functional Properties Of Tin Oxide-Based Materials, Alexandra Kuriganova, Nina Smirnova Jan 2025

New Insights Into Controlling The Functional Properties Of Tin Oxide-Based Materials, Alexandra Kuriganova, Nina Smirnova

Journal of Electrochemistry

Development of methodologies for fabrications of nanostructured materials that provide control over their microstructural features and compositions represents a fundamental step in the advancement of technologies for productions of materials with well-defined functional properties. Pulse electrolysis, a top-down electrochemical approach, has been demonstrated to be a viable method for producing nanostructured materials with a particular efficacy in the synthesis of tin oxides. This method allows for significant control over the composition and shape of the resulting tin oxides particles by modifying the anionic composition of the aqueous electrolyte, obviating the need for additional capping agents in the synthesis process and …

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A Cnt Intercalated Co Porphyrin-Based Metal Organic Framework Catalyst For Oxygen Reduction Reaction, Pei-Pei He, Jin-Hua Shi, Xiao-Yu Li, Ming-Jie Liu, Zhou Fang, Jing He, Zhong-Jian Li, Xin-Sheng Peng, Qing-Gang He Jan 2025

A Cnt Intercalated Co Porphyrin-Based Metal Organic Framework Catalyst For Oxygen Reduction Reaction, Pei-Pei He, Jin-Hua Shi, Xiao-Yu Li, Ming-Jie Liu, Zhou Fang, Jing He, Zhong-Jian Li, Xin-Sheng Peng, Qing-Gang He

Journal of Electrochemistry

The poor electronic conductivity of metal-organic framework (MOF) materials hinders their direct application in the field of electrocatalysis in fuel cells. Herein, we proposed a strategy of embedding carbon nanotubes (CNTs) during the growth process of MOF crystals, synthesizing a metalloporphyrin-based MOF catalyst TCPPCo-MOF-CNT with a unique CNT-intercalated MOF structure. Physical characterization revealed that the CNTs enhance the overall conductivity while retaining the original characteristics of the MOF and metalloporphyrin. Simultaneously, the insertion of CNTs generated adequate mesopores and created a hierarchical porous structure that enhances mass transfer efficiency. X-ray photoelectron spectroscopic analysis confirmed that the C atom in CNT …

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Nanostructured Graphitic Carbon Nitride For Photocatalytic And Electrochemical Applications, Muhammad Abdul Qadeer, Iqra Fareed, Asif Hussaine, Muhammad Asim Farid, Sadia Nazir, Faheem K. Butt, Ji-Jun Zou, Muhammad Tahir, Shang-Feng Du Jan 2025

Nanostructured Graphitic Carbon Nitride For Photocatalytic And Electrochemical Applications, Muhammad Abdul Qadeer, Iqra Fareed, Asif Hussaine, Muhammad Asim Farid, Sadia Nazir, Faheem K. Butt, Ji-Jun Zou, Muhammad Tahir, Shang-Feng Du

Journal of Electrochemistry

Graphitic carbon nitride (g-C3N4) exhibits great mechanical as well as thermal characteristics, making it a valuable material for use in photoelectric conversion devices, an accelerator for synthesis of organic compounds, an electrolyte for fuel cell applications or power sources, and a hydrogen storage substance and a fluorescence detector. It is fabricated using different methods, and there is a variety of morphologies and nanostructures such as zero to three dimensions that have been designed for different purposes. There are many reports about g-C3N4 in recent years, but a comprehensive review which covers nanostructure dimensions …

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Novel Approach For The Micro Cracks Detection Of Solar Wafers And Cells, Mohd Israil, Arvind Kumar Sharma, Ekta Gupta Jan 2025

Novel Approach For The Micro Cracks Detection Of Solar Wafers And Cells, Mohd Israil, Arvind Kumar Sharma, Ekta Gupta

Al-Bahir

This paper deals with the review of various existing technique for the microcracks detection in silicon solar cell and wafer. In addition to this, we proposed a novel approach for the machine learning technique for the inspection of the cracks those are existed in the solar cell and wafer and not able to detect by the naked eyes. There are many techniques have been developed by the various researchers around the world to inspect solar cells for defect. All the techniques discussed in this article having some features and some weakness too. This paper present here gives the two-fold solution …

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A Comparison Of Energy Dispersive Spectroscopy In Transmission Scanning Electron Microscopy With Scanning Transmission Electron Microscopy, Jennifer Carter, Tugce Karakulak, Jeffrey Pigott Jan 2025

A Comparison Of Energy Dispersive Spectroscopy In Transmission Scanning Electron Microscopy With Scanning Transmission Electron Microscopy, Jennifer Carter, Tugce Karakulak, Jeffrey Pigott

Faculty Scholarship

The objective of this work was to explore the capabilities of a field emission gun scanning electron microscope (FEG-SEM) equipped with a transmission scanning electron detector (TSEM) and energy dispersive spectroscopy (EDS) to identify nanoscale chemical heterogeneities in a gas atomization reaction synthesis (GARS) steel sample. The results of this analysis were compared to the same study conducted with scanning transmission electron microscopy (STEM) with EDS mapping. TSEM-EDS was performed using the standard spectral analysis approach, i.e., pixel-by-pixel identification of elements from the spectra, and a new principal component analysis approach to detect regions of similar spectra before identifying elemental …

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Identifying The Effect Of Architecture Morphology On Wind Fields And Pm2.5 Dispersion At The Urban Block Scale Via A Combined Scheme, Bin Guo, Lu Li, Xiaowei Zhu, Zheng Wang, Miaoyi Chen, Lin Pei, Tengyue Guo Jan 2025

Identifying The Effect Of Architecture Morphology On Wind Fields And Pm2.5 Dispersion At The Urban Block Scale Via A Combined Scheme, Bin Guo, Lu Li, Xiaowei Zhu, Zheng Wang, Miaoyi Chen, Lin Pei, Tengyue Guo

Mechanical and Materials Engineering Faculty Publications and Presentations

This study explores the potential of architecture morphology to mitigate PM2.5 pollution through enhanced urban ventilation. Despite the recognized influence of building designs on wind and air pollution distribution at the urban block scale, specific mechanisms remain poorly understood. To address this gap, we have developed an integrative approach combining in-situ observations, Geographic Information System (GIS), Remote Sensing (RS), Computational Fluid Dynamics (CFD), and statistical modeling. Here, CFD simulates the flow field and PM2.5 dispersion, using in-situ observations for turbulence model selection. GIS quantify architecture morphology parameters to establish accurate CFD boundary conditions, ensuring simulations reflect real-world conditions and precise …

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Effect Of Displacement Rate On Delamination Growth Rate In Unidirectional Glass Fiber Composites In Both Bridging And Non-Bridging Scenarios, Wafaa Ahmed Shaker, Taher H. Awad, Mostafa M. Elhadary Jan 2025

Effect Of Displacement Rate On Delamination Growth Rate In Unidirectional Glass Fiber Composites In Both Bridging And Non-Bridging Scenarios, Wafaa Ahmed Shaker, Taher H. Awad, Mostafa M. Elhadary

Mansoura Engineering Journal

Experimentally, the mode I delamination behavior of unidirectional glass/epoxy composites at quasi-static displacement rates of 1, 3, and 5 is explored. When comparing the variation between fracture toughness GIC values at 1 mm/min and GIC at 3 mm/min, the average variation is 30% increasing. However, the average variance in GIC between 3 mm/min and 5 mm/min is increasing by 11%. As a result, the crack propagation velocity has a noticeable effect on the value of GIC at lower speeds and a limited effect at higher speeds. The same comparison is made with bridging specimens for 1 and 3 mm/min displacement …

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Optimizing And Validation Of Sustainable Uhpc With Waste Glass Powder Utilizing Modified Particle Packing Approach And Response Surface Methodology, Mohamed Taman, Elsaid Maaty, Alaa Mehrez, Ahmed Kamal Isaac Jan 2025

Optimizing And Validation Of Sustainable Uhpc With Waste Glass Powder Utilizing Modified Particle Packing Approach And Response Surface Methodology, Mohamed Taman, Elsaid Maaty, Alaa Mehrez, Ahmed Kamal Isaac

Journal of Engineering Research

The current study explores the potential of utilizing Waste glass powder (WGP) as an alternative to cement in the development of sustainable eco-friendly Ultra-high-performance concrete (UHPC). UHPC mixtures underwent optimization through the application of a Modified Andreasen and Andersen (MAA) particle packing model, resulting in a reduction of cement content from 900 to 800 kg/m3. Six mixes were cast, with varying levels of cement replacement ratios with WGP up to 50%. The evaluation focuses on the flowability, dry density, and mechanical properties of UHPC at different ages using normal curing. A statistical model utilizing response surface methodology (RSM) …

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