Synthesis And Characterization Of Hybrid Shell Microcapsules For Anti-Corrosion Ni-Co Coating,
2022
Chulalongkorn University
Synthesis And Characterization Of Hybrid Shell Microcapsules For Anti-Corrosion Ni-Co Coating, Hamed Sadabadi, Saeed Reza Allahkaram, Omid Ghader, Pradeep K. Rohatgi
Journal of Metals, Materials and Minerals
This paper presents the results of the study of microcapsules synthesized using a novel hybrid shell of polyureaformaldehyde/SiO2 (PUF/SiO2) and a core of linseed oil. The synthesis was accomplished by facial polymerization combined with sol-gel of TEOS, and urea-formaldehyde resin to form the hybrid shell under optimal process parameters. The microcapsules were embedded in a metal coating using the electrodeposition method. Microcapsules were characterized by scanning electron microscope (SEM, FE-SEM), energy-dispersive spectroscopy (EDS), particle size analyzer (PSA), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The experimental results indicated that the average size of capsules synthesized umder the optimum processing …
Dyeing Of Curcumin And Durable Press Finishing With Citric Acid On Cotton Fabric Using One Step Process,
2022
Chulalongkorn University
Dyeing Of Curcumin And Durable Press Finishing With Citric Acid On Cotton Fabric Using One Step Process, Supannee Boonroeng, Piyaporn Kampeerapappun
Journal of Metals, Materials and Minerals
Cotton is an affordable and durable option for clothing. However, cotton garments tend to wrinkle easily. Therefore, cotton fabrics were studied to improve their wrinkle resistance properties. In this work, curcumin was mixed in an aqueous solution of citric acid and its catalyst and applied to cotton fabric using pad-dry-cure process for both the dyeing and finishing properties. Aloe vera extract and chitosan were used to compare for the reaction of their functional groups with carboxyl groups of citric acid on cotton fabrics. The mixture of curcumin and citric acid solution showed anti-wrinkle properties on the treated cotton. There were …
Mineralogical Studies And Optimization Of Tabling Parameters Of Low Grade Chromite Ore By Box Behnken Design Of Experiments,
2022
Chulalongkorn University
Mineralogical Studies And Optimization Of Tabling Parameters Of Low Grade Chromite Ore By Box Behnken Design Of Experiments, Amit Kumar Bhandary, Siddhartha Mukherjee, Rajib Dey, Mahua Ghosh Chaudhuri
Journal of Metals, Materials and Minerals
Chromite ore is geologically associated with gangue materials which have lower density compared to pure chromite (FeO.Cr2O3). Gravity separation techniques are very suitable for beneficiation of low grade chromite ore. In the present study mineralogical analysis of the sample has been carried out by using Wavelength dispersive x-ray fluorescence (WDXRF), X-ray powder diffraction (XRD), Scanning electron microscopy (SEM) and Energy dispersive X-ray (EDX). The beneficiation of low grade (Cr2O3% 26.88) chromite ore has been investigated using wilfley table. Optimization has been carried out using box-behnken statistical design (BBD). The experimental parameters selected are: tilt angle, water flow rate and pre-heat …
Magnetic Nanoparticles Coated With Zwitterionic Copolymer As An Advanced Material For Rapid And Instrument-Free Biomolecular Detection In Human Serum,
2022
Chulalongkorn University
Magnetic Nanoparticles Coated With Zwitterionic Copolymer As An Advanced Material For Rapid And Instrument-Free Biomolecular Detection In Human Serum, Supannika Boonjamnian, Varunee Sadsri, Voravee P. Hoven, Piyaporn Na Nongkhai
Journal of Metals, Materials and Minerals
The traditional agglutination assays especially those based on polystyrene beads have been recognized as convenient tools for disease diagnosis despite their limited detection range and low sensitivity. Unlike other particles namely polystyrene beads, SiO2 and gold nanoparticles having insignificant magnetic properties, magnetic nanoparticles (MNPs) offer unique advantages as their magnetic properties for agglutination methods. In the presence of magnet, not only can they be used to enrich the samples, but also their aggregation can also be induced, providing sensitive and rapid measurements. This work aims to develop MNPs for aggregation-based biomolecular detection. The MNPs were surface-modified with PMAMPC via an …
Mechanical Property Evaluation Of Additively Manufactured Materials Across A Wide Temperature Range,
2022
South Dakota State University
Mechanical Property Evaluation Of Additively Manufactured Materials Across A Wide Temperature Range, Sanket Vinayak Hirve
Electronic Theses and Dissertations
Additive manufacturing (also called 3d printing) has transitioned from a prototyping-only technology to a technology that is able to create usable parts with complex geometries. 3D printed parts are beginning to be used across all areas of engineering, such as biomedical, aerospace, automobile and many more. Typically, the term “3D printing” refers to layer by layer deposition of polymer materials, while the term “additive manufacturing” refers to layer by layer metal deposition. Conventional manufacturing, or substrative manufacturing, has several main problems that additive manufacturing can help overcome, such as high cost for low volume production, inability to create very complex …
Nb₃Sn Coating Of A 2.6 Ghz Srf Cavity By Sputter Deposition Technique,
2022
Old Dominion University
Nb₃Sn Coating Of A 2.6 Ghz Srf Cavity By Sputter Deposition Technique, M. S. Shakel, Wei Cao, H. Elsayed-Ali, G. V. Eremeev, U. Pudasaini, A. M. Valente-Feliciano
Electrical & Computer Engineering Faculty Publications
Nb₃Sn is of interest as a coating for SRF cavities due to its higher transition temperature Tc ~18.3 K and superheating field Hsh ~400 mT, both are twice that of Nb. Nb₃Sn coated cavities can achieve high-quality factors at 4 K and can replace the bulk Nb cavities operated at 2 K. A cylindrical magnetron sputtering system was built, commissioned, and used to deposit Nb₃Sn on the inner surface of a 2.6 GHz single-cell Nb cavity. With two identical cylindrical magnetrons, this system can coat a cavity with high symmetry and uniform thickness. Using Nb-Sn multilayer sequential sputtering followed by …
Cyclic Voltammetric Simulations On Batteries With Porous Electrodes,
2021
Materials Genome Institute, Shanghai University, Shanghai 200444, China;
Cyclic Voltammetric Simulations On Batteries With Porous Electrodes, Xue-Fan Cai, Sheng Sun
Journal of Electrochemistry
Lithium-ion batteries (LIBs) are among the most widely used energy storage devices. Whole-cell modeling and simulations of LIBs can optimize the design of batteries with lower costs and higher speeds. The Pseudo-Two-Dimensional (P2D) electrochemical model is among the most famous whole-cell models and widely applied in LIB simulations. P2D model consists of a series of kinetic equations to model Li+/Li diffusion in working/counter electrodes and electrolytes, which are filled in the porous electrodes and separator, and reactions at the interface of electrolyte and active particles. The traditional applications of P2D model, however, are limited to the cases where …
Effect Of Aluminum Alloy Surface Modification On Adhesion Of The Modified Polyurethane Coating And Its Corrosion Protective Performance,
2021
1. State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen 361005, Fujian, China;
Effect Of Aluminum Alloy Surface Modification On Adhesion Of The Modified Polyurethane Coating And Its Corrosion Protective Performance, Xian-Yin Kuang, Shao-Qiang Jin, Yan-Hui Cao, Yan-Mei Zhang, Shi-Gang Dong, Long-Hui Zhu, Li-Wen Lin, Chang-Jian Lin
Journal of Electrochemistry
The ordinary organic coatings on aluminum alloy usually encounter a problem of low adhesion to the substrate, which results in destruction and failure of the long-term protective performance of the anticorrosion systems. The surface modification of aluminum alloy is able to enhance the adhesion of organic coating on aluminum alloys, and to improve their protective performance. In this work, a combined surface modification of anodic oxidation and mussel adhesion protein/CeO2/3-aminopropyltriethoxysilane composite film (MCA) was developed on the aluminum alloy. The adhesion of modified polyurethane coated on the treated aluminum alloy and its corrosion protective performance were evaluated comprehensively …
Functional Sulfate Electrolytes Enable The Enhanced Cycling Stability Of Nati2(Po4)3/C Anode Material For Aqueous Sodium-Ion Batteries,
2021
College of Chemistry & Chemical Engineering and Resource Utilization, Northeast Forestry University, Harbin 150040, Heilongjiang, China;
Functional Sulfate Electrolytes Enable The Enhanced Cycling Stability Of Nati2(Po4)3/C Anode Material For Aqueous Sodium-Ion Batteries, Shu-Jin Li, Zhi-Kang Cao, Wen-Kai Wang, Xiao-Han Zhang, Xing-De Xiang
Journal of Electrochemistry
Aqueous sodium-ion batteries show promising application in fields of large-scale storage of intermittent renewable energies owing to the earth-abundant sodium resources and incombustible aqueous electrolytes. Primary factors determining whether they can be commercially utilized are low cost and long lifetime. Among current electrode materials, NASICON-type NaTi2(PO4)3 arouses wide interests as an anode material for aqueous sodium-ion batteries as it offers a high specific capacity, fast Na-transport ability and reasonable working potential, however, suffering from insufficient cycling performance caused by severe dissolution of active materials in traditional aqueous electrolytes. In this work, a functional sulfate electrolyte …
Influence Of Heat Treatment Time On Cathode Material Cr8O21 For Lithium Battery,
2021
1. Guizhou Meiling Power Sources Co. Ltd, State Key Laboratory of Advanced Chemical Power Sources,Zunyi 563003, Guizhou, China;
Influence Of Heat Treatment Time On Cathode Material Cr8O21 For Lithium Battery, Jiu-Kang Teng, Qing-Jie Wang, Liang Zhang, Hong-Mei Zhang, Xiao-Tao Chen, Peng Zhang, Jin-Bao Zhao
Journal of Electrochemistry
Chromium oxide (Cr8O21) cathode material for lithium batteries was synthesized by thermal decomposition of chromium trioxide (CrO3) at high temperature. The electrochemical properties of chromium oxide depended on the time and temperature during the heat treatment. Pure phase chromium oxide was prepared, and the effects of heat treatment time on the structures and electrochemical properties of Cr8O21 were systematically studied. The first discharge mechanism of chromium oxide in lithium batteries was explored, and the results were similar to that in lithium-sulfur batteries. The crystal phases and electrochemical properties of the prepared …
Effect Of Glycol Based Coolant Pollution On Pem Fuel Cells Stack And Recovery Measures,
2021
Shanghai Shenli Technology Co., Ltd., Shanghai 201401, China;
Effect Of Glycol Based Coolant Pollution On Pem Fuel Cells Stack And Recovery Measures, Cong-Yi Zhu, Xiao-Hui Li, Quan-Quan Gan
Journal of Electrochemistry
As the heat conduction medium of fuel cell cooling system, coolant is very important for the thermal management of fuel cell stack. In practical application, coolant leakage into the stack often occurs. Due to the randomness of fault location of components, the location of coolant leakage is uncertain, which may occur on the cathode side or anode side of some or all single cells. The main effects of coolant pollution on fuel cell stack are as follows: the output of open circuit voltage decreases sharply, the consistency of single cells voltage decreases and so on, which seriously affects the normal …
Formation And Morphological Evolution Of Nanoporous Anodized Iron Oxide Films,
2021
School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China;
Formation And Morphological Evolution Of Nanoporous Anodized Iron Oxide Films, Jin-Wei Cao, Nan Gao, Zhao-Qing Gao, Chen Wang, Sheng-Yan Shang, Yun-Peng Wang, Hai-Tao Ma
Journal of Electrochemistry
The preparation of iron oxide films with nanoporous structure by anodization has attracted much attention for its potential applications. However, the formation mechanism of porous structure during anodization is still unclear. In this paper, the composition of anodic current during the formation of nanoporous anodized iron oxide film was analyzed in combination with the current density-potential response (I-V curve) and the derivation of Faraday’s law. The results showed that the anodic current consisted of an ionic current (leading to the migration of ions to form oxide) and an electronic current (leading to the oxygen evolution), and the …
Copper Nanoparticles In-Situ Anchored On Nitrogen-Doped Carbon For High-Efficiency Oxygen Reduction Reaction Electrocatalyst,
2021
1. Key Laboratory of Green Chemical Process of Xinjiang Corps, College of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, Xinjiang, China;
Copper Nanoparticles In-Situ Anchored On Nitrogen-Doped Carbon For High-Efficiency Oxygen Reduction Reaction Electrocatalyst, Hui-Fang Yuan, Yue Zhang, Xing-Wu Zhai, Li-Bing Hu, Gui-Xian Ge, Gang Wang, Feng Yu, Bin Dai
Journal of Electrochemistry
Compared with noble metal platinum (Pt)-based catalysts, inexpensive non-noble metal electrocatalysts have attracted extensive attention for oxygen reduction reaction (ORR). Herein, chitosan as a kind of biomass resource rich in nitrogen and carbon was used to prepare nitrogen-doped carbon (N-C) and N-C in-situ anchored by copper nanoparticles (Cu/N-C). The as-obtained N-C and Cu/N-C nanoparticles were successfully used as non-noble eletrocatalysts tested for ORR. Compared with the N-C, the Cu/N-C showed the high surface area of 607.3 m 2·g-1 with the mean pore size of 2.5 nm and the pore volume of 0.40 cm3·g-1 …
Nitrogen-Sulfur Co-Doped Porous Carbon Preparation And Its Application In Lithium-Sulfur Batteries,
2021
1. School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, Gansu, China;
Nitrogen-Sulfur Co-Doped Porous Carbon Preparation And Its Application In Lithium-Sulfur Batteries, Gui-Xiang Zhao, Wail Hafiz Zaki Ahmed, Fu-Liang Zhu
Journal of Electrochemistry
In recent years, lithium-sulfur (Li-S) batteries have been considered as a promising candidate for the next generation of energy storage system due to their ultrahigh theoretical capacity (1675 mAh·g-1) and energy density (2600 Wh·kg-1). However, the practical application of Li-S batteries is seriously limited by their insulating nature of sulfur, the shuttle effect of polysulfides (LiPSs), and volume expansion during charging and discharging. To overcome those disadvantages, one of the commonly methods is to infiltrate sulfur into porous conductive carbon framework, such as porous carbon, hollow carbon spheres, graphene, carbon nanotubes and some composites of the …
Photoelectrochemical Sensing Based On Zr-Mofs For Homocysteine Detection,
2021
1. School of Chemistry and Chemical Engineering, Jinzhong University, Jinzhong, 030600, Shanxi, China;2. Institute of Environmental Science and School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, Shanxi, China;
Photoelectrochemical Sensing Based On Zr-Mofs For Homocysteine Detection, Wen-Xia Dong, Guang-Ming Wen, Bin Liu, Zhong-Ping Li
Journal of Electrochemistry
Due to the independent form of the light source and detection system, photoelectrochemical (PEC) sensor has the advantages of low background, high sensitivity and simple operation. So far, PEC systems have been widely used in the fields including the actual detection of metal ions, biological antibodies or antigens in environmental pollutants. When the photosensitive material is irradiated by a light source with an energy being equal to or greater than its band gap, electrons (e-) transition occurs from the valence band to the conduction band, leaving a hole (h+), at the same time, the generated electron-hole …
Structure Analysis Of Pemfc Cathode Catalyst Layer,
2021
Fuel Cell Institute, School of Mechanical and Power Engineering, Shanghai Jiaotong University, Shanghai 200240, China;
Structure Analysis Of Pemfc Cathode Catalyst Layer, Rui-Qing Wang, Sheng Sui
Journal of Electrochemistry
The sluggish oxygen reduction reaction (ORR) on the cathode of the proton exchange membrane fuel cell (PEMFC) has always been one of the key factors limiting its commercialization. The optimization of the cathode catalytic layer structure plays an important role in improving fuel cell performance and reducing production costs. In this paper, two different catalysts (platinum nanoparticles (Pt-NPs) and platinum nanowires (Pt-NWs)) were prepared by using catalyst coated substrate (CCS) method. By constructing a double-layer catalytic layer structure, we analyzed the effect of different catalytic layer structures by performing a single cell test. The results showed that the dense platinum …
Mathematical Model Of The Efficiency Of Investments Aimed In The Implementation Of Water-Saving Technologies,
2021
Ministry of Higher and Secondary Specialized Education of the Republic of Uzbekistan
Mathematical Model Of The Efficiency Of Investments Aimed In The Implementation Of Water-Saving Technologies
Irrigation and Melioration
In Uzbekistan, research work is being carried out aimed at improving the economic mechanisms for the introduction of water-saving technologies for irrigating agricultural crops. At the same time, the issues related to the analysis of the effectiveness of the use of water-saving technologies when irrigating cotton, the development of mathematical methods for assessing the effectiveness of investments, as well as their introduction into practice have not been sufficiently studied. This article provides a mathematical model of the efficiency of investments aimed at introducing water-saving technologies. The results of a numerical experiment of a mathematical model show that the introduction of …
Efficient Use Of Water Resources In The Basins Of Small Rivers,
2021
TIIAME
Efficient Use Of Water Resources In The Basins Of Small Rivers, F. Gapparov, M.F. Gafforova
Irrigation and Melioration
The article provides a recommendation for the efficient use of water resources in the basins of small foothill rivers. The research was carried out on the example of the Govasay river basin located in the northern part of the Fergana Valley. The efficiency factor of the canal has been determined and a technical assessment has been given for the management of water resources in the river basin; the efficiency of the canal is 65-75%. A program for the operational management of water resources in The Govasay river basin and a GIS map of water consumers in the Govasay river basin …
Model Of Groundwater Level Control Using Horizontal Drainage,
2021
TIIAME
Model Of Groundwater Level Control Using Horizontal Drainage, A. Arifjanov, M. Otaxonov, Z. Abdulkhaev
Irrigation and Melioration
The article describes the main factors affecting the rise in the level of groundwater in the city of Fergana and ways to eliminate them. Currently, in order to reduce the negative impact of rising groundwater levels on the environment, crops, buildings and structures, as well as underground utilities, it is proposed to design horizontal drainage in urban areas and a mathematical model has been developed for changing the groundwater level. For this, long-term data from observation wells were analyzed and the hydraulic parameters of horizontal drainage were selected taking into account the hydrogeology of the area. Taking into account the …
Results Of Proximate Analysis Of Energy Use Of Municipal Solid Waste,
2021
TIIAME
Results Of Proximate Analysis Of Energy Use Of Municipal Solid Waste, N.N. Abduganiev
Irrigation and Melioration
In the modern industrialized world, various raw materials are processed and used for human consumption. While some of the raw materials are converted into the desired product, the rest is thrown into the environment as waste. It is known that solid waste is a type of biomass that is formed in the course of human life. The article presents the results of a preliminary analysis of studies on the use of solid waste energy in the Urta-Chirchik district of the Tashkent region. Sorting results showed that the total volume of municipal solid waste in the district consists mainly of wood …
