Short Review On Electrochemical Energy Storage,
2015
Institute of physics, Chinese Academy of Science, Beijing 100190, China;
Short Review On Electrochemical Energy Storage, Hong Li, Ying-Chun Lyu
Journal of Electrochemistry
Energy storage is a critical supporting technology in many fields such as energy, information, transportation, and healthcare, aerospace, advanced manufacture, advanced equipment, national security. Electrochemical energy storage technique has been widely applied and is developing continuously. In this article, the energy storage mechanism, technical indicators and technology ready level in electrochemical energy storage are summarized. Mainly based on lithium ion batteries, untraditional electrochemical issues in electrochemical energy storage devices are described from the perspective of fundamental science. These issues deal mainly with thermodynamics, kinetics, size effect, asymmetric system, asymmetric reaction path, surface phenomenon, hybrid ion transportation, and solid state battery. …
Sulfonated-Graphene/Nafion Composite Membrane For All Vanadium Redox Flow Batteries,
2015
Huai An Kerun Film Material Co., Ltd, Huai'an 211600, Jiangsu, China;
Sulfonated-Graphene/Nafion Composite Membrane For All Vanadium Redox Flow Batteries, Da-Wei Yang, Yan-Qing Dong, Jing-Min Fan, Ming-Sen Zheng, Quan-Feng Dong
Journal of Electrochemistry
Nafion membrane has been widely used in fuel cells due to its good proton conductivity, chemical and mechanical stabilities. However, the well-developed water channels in Nafion membrane have restricted its application in all vanadium redox flow batteries owing to the high permeation of vanadium ions and the cost. In this work, the water adsorption rate, resistivity and transference number of vanadium ions of sulfonated-graphene/Nafion composite membrane were investigated and compared with those of Nafion membrane in an effort to overcome the abovementioned drawbacks. It was found that the area resistivity and permeation rate of sulfonated-graphene/Nafion composite membrane were significantly reduced …
Research Progress Of Secondary Sodium-Air Batteries,
2015
CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China; Graduate School of Chinese Academy of Sciences, Beijing 100039, China
Research Progress Of Secondary Sodium-Air Batteries, San-Pei Zhang, Zhao-Yin Wen, Jun Jin, Xiang-Wei Wu, Ying-Ying Hu, Mei-Fen Wu
Journal of Electrochemistry
Rechargeable sodium-air batteries have been the focus in the fields of batteries and energy storage recently, owing to their high specific energy density (1600 Wh·kg-1), an equilibrium discharge potential of 2.3 V and earth-abundant sodium element However, research on sodium-air cells is still in an infant age and presents many scientific issues. Based on recently reported work and our own experience on sodium-based batteries, this review summarizes the research progress related to the critical scientific is sues of secondary sodium-air batteries and the application prospect of sodium-air battery.
Characterization Of The Separator With Thermal-Shutdown Layer For Use In Lithium Batteries,
2015
China Aviation Lithium Battery Co., Ltd., Luoyang 471003, Henan, China;
Characterization Of The Separator With Thermal-Shutdown Layer For Use In Lithium Batteries, Li Bai, Yong-Jian Huai, Xin-Ping Ai, Hai Jia
Journal of Electrochemistry
In this paper, the lithium ion battery coated with the thermal-shutdown functional layer has been introduced. The shutdown temperature of the separator could be decreased by using the melting point of thermal-shutdown functional layer. When the internal battery environment reached a critical temperature, the functional layer melted and coated the anode/separator with a non-conductive barrier, halting Li-ion transport and shutting down the cell permanently. The results showed that the functional layer did not affect the resistance, rate performance and cycle life. It was found the functional layer can significantly improve the safety of the battery when misused.
Effects Of Microstructures Of Active Material On Performance Of Vrla Battery,
2015
Shenzhen Center Power Tech. Co., LTD, Shenzhen 518120, Guangdong, China;
Effects Of Microstructures Of Active Material On Performance Of Vrla Battery, Lei Jiang, Shou-Zhong Yi
Journal of Electrochemistry
The structure, morphology and content of the as-prepared and the processed samples were characterized by the means of SEM and XRD. The discharge capacities and cycle life performances of the as-prepared and the processed samples were tested by electrochemical measurements with different rates. The results indicated that the 4BS technology which can affect the plate design, deep cycle capability and cycle life is a basic technology for the VRLA batteries. It was also confirmed that the contents and structures of α-PbO2 and β-PbO2 formed with different processing conditions can affect the performance of the VRLA batteries, suggesting that …
Development Of Proton Conduction Membranes In Application Of Vanadium Flow Battery,
2015
State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China;
Development Of Proton Conduction Membranes In Application Of Vanadium Flow Battery, Le-Tu Qingge, Wei-Nan Guo, Ping Liu, Bao-Guo Wang
Journal of Electrochemistry
The polymeric hydrophilic/hydrophobic interactions into membrane formation were introduced. A general and straightforward strategy for preparing membranes with nanometer-scale pores was suggested by utilization of hydrophilic/hydrophobic interactions to generate phase separation and removal of polyion aggregates through water immersion. Poly(vinylidene fluoride) (PVDF) and sodium allyl sulfonate (SAS) serve as the membrane material and pore-generator, respectively, resulting in chemically stable and oxidation-resistant membranes with various potential applications. Following the same procedure invented to produce the laboratory-scale membranes, the scale-up process to manufacture large-area membranes was completed. The obtained membrane exhibited the conductivity of 3.5×10-2 S•cm-1, thickness of 100 …
Preparations And Properties Of Polybenzimidazole/Polyvinylbenzyl Crosslinked Composite Membranes For High Temperature Proton Exchange Membrane Fuel Cells,
2015
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;University of Chinese Academy of Sciences, Beijing 100039, China;
Preparations And Properties Of Polybenzimidazole/Polyvinylbenzyl Crosslinked Composite Membranes For High Temperature Proton Exchange Membrane Fuel Cells, Jin-Kai Hao, Yong-Yi Jiang, Zhen Wang, Xiao-Jin Li, Zhi-Gang Shao, Bao-Lian Yi
Journal of Electrochemistry
In order to increase the chemical stability of polybenzimidazole (PBl) membrane, a highly stable polymer, poly vinyl. benzyl chloride (PVBC), was chosen as the macromolecular crosslinker, and 1H-1,2,4-triazol was adopted to prepare the crosslinked PBI-based membranes. The influence of the PVBC amount on membrane characteristic was investigated in detail. The results indi. cated that the crosslinked structure of the membrane effectively improved the chemical stability, and at the same time, the mem. brane presented good mechanical property and proton conductivity. The fuel cell performance for the membrane was tested with hy. drogen and oxygen single cell without humidification at 150 …
Impact Of Water Content On The Performance Of Lifepo4 Based Lithium-Ion Battery,
2015
Shanghai Electrochemical Energy Devices Research Center, Department of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China;
Impact Of Water Content On The Performance Of Lifepo4 Based Lithium-Ion Battery, Jun-Ting Niu, Lin Sun, Shu-Wen Kang, Zhen-Wei Zhao, Zi-Feng Ma
Journal of Electrochemistry
Through different dry conditions and measuring by moisture test instrument, cathode pole pieces with different water contents of 0.3‰ ~ 0.7‰ were obtained to prepare lithium-ion batteries. Cycling performance and high rate performance at 1C ~ 5C discharge rates were tested. Moreover, ASR performances of LiFePO4 base lithium-ion batteries after 200 cycles with different water contents were investigated by EIS. The results showed that the cycle performance and rate performance were closely related to the water content of the electrode. When the water content went up to 0.6‰ the cycle stability and rate performance fell. Meanwhile, the internal resistance and …
Latest Progresses In Vanadium Flow Battery Technologies And Applications,
2015
Dalian Rongke Power Co. Ltd., Dalian 116025, Liaoning, China;
Latest Progresses In Vanadium Flow Battery Technologies And Applications, Xiao-Li Wang, Yu Zhang, Hua-Min Zhang
Journal of Electrochemistry
With virtues of high safety, long cycle life, friend environment and state of charge easy monitoring, vanadium flow battery has become an effective technique for large scale energy storage. United States, Japan, Europe and other developed countries are actively promoting the developments of vanadium flow battery technology and related equipments. In this paper, the performance of containerized vanadium flow battery, which was newly developed by Rongke Power (RKP) and Dalian Institute of Chemical Physics, was introduced. The operation data of 5 MW/10 MWh vanadium flow battery energy storage station was displayed. Finally, it is pointed out that reducing the cost, …
Review For Applications Of "Lead Carbon" Batteries In Energy Storage System,
2015
Harbin Institute of Technology, Harbin 150001, Heilongjiang, China; Chilwee Power Co., Ltd., Changxing 313100, Zhejiang, China;
Review For Applications Of "Lead Carbon" Batteries In Energy Storage System, Yong-Quan Ma, Ke Ke, Da-Ming Gu
Journal of Electrochemistry
Three types of “lead carbon” batteries are introduced by comparing their advantages and disadvantages. Then their applications in energy storage system (ESS), especially in the field of renewable energy power generation, are discussed. The prospects and potential applications of “lead carbon” batteries in EES for electric power supply system are analyzed by combining the state-of-the-art techniques in this field.
Preparation And Performance Of Lithium-Rich Manganese Layered Materialsâ 0.6li[Li1/3Mn2/3]O2·0.4liniXMnYCo1-X-YO2(X < 0.6, Y > 0),
2015
Beijing General Research Institute of Mining and Metallurgy, Beijing 100160, China;Beijing Easpring Material Technology Co. Ltd., Beijing 100160, China;
Preparation And Performance Of Lithium-Rich Manganese Layered Materialsâ 0.6li[Li1/3Mn2/3]O2·0.4liniXMnYCo1-X-YO2(X < 0.6, Y > 0), Hai-Lan Feng, Ya-Fei Liu, Yan-Bin Chen
Journal of Electrochemistry
Lithium-rich manganese based cathode materials 0.6Li[Li1/3Mn2/3]O2⋅0.4LiNixMnyCo1-x-yO2 (x < 0.6, y > 0) were synthesized by carbonate co-precipitation and high temperature solid-state reaction. The structures and morphologies of the as-prepared materials were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM). The results of high temperature in-situ XRD test show that the lattice parameters change significantly with increasing temperature and Ni content. The cation mixing gets serious and the spinel phase appears in the high Ni content samples when the temperature is up to 800 oC. Under voltages ranging from 2.0 to …
Application Of Pd/Graphene Modified Electrode In The Detection Of 4-Chlorophenol,
2015
College of Environmental Science and Engineering, Beijing Forestry University, Beijing 100083, China;
Application Of Pd/Graphene Modified Electrode In The Detection Of 4-Chlorophenol, Peng Shi, Bo-Xuan Wang, Quan-Lin Song, Hui Wang, Xin Liu, Zhao-Yong Bian
Journal of Electrochemistry
The Pd/graphene composites were synthesized by a modified Hummers method and NaBH4 reduction process, and then were characterized using XRD, SEM, XPS, and TEM. The Pd/graphene modified glassy carbon electrode (Pd/graphene/GCE) was prepared based on this method. Cyclic voltammetry was used to study the optimum operation conditions for the 4-chlorophenol detection. It was shown that the surface of the graphene was smooth and Pd nanoparticles were uniformly dispersed on graphene. The average particle size was calculated to be 6.5 ± 0.05 nm. These nanoparticles exhibited high catalytic activity and sensitivity toward chlorophenols. PBS with a concentration of 0.1 mol·L-1 …
Pre-Construction Rock Treatment And Soil Modification Program Using Low Mobility Grout To Mitigate Future Sinkhole Development In A 2,787.1 Square Meter (30,000 Sf) Maintenance Facility,
2015
US Army Corps of Engineers
Pre-Construction Rock Treatment And Soil Modification Program Using Low Mobility Grout To Mitigate Future Sinkhole Development In A 2,787.1 Square Meter (30,000 Sf) Maintenance Facility, Steven W. Shifflett
Sinkhole Conference 2015
The US Army required construction of a 2,787.1 square meters (30,000 sf) maintenance facility supported on shallow foundations at the Fort Campbell Military Installation. During the subsurface investigation a seven foot air-filled void was encountered in the bedrock within the building footprint. Electrical Resistivity Imaging (ERI) was conducted in an attempt to determine the lateral extent of the encountered void and to establish the general prevalence of karst features at the site. Due to uncertainty in the subsurface conditions, a rock treatment and soil modification program was developed which consisted of a series of targeted exploratory grout holes advanced in …
An Approach For The Development Of Complex Systems Archetypes,
2015
Old Dominion University
An Approach For The Development Of Complex Systems Archetypes, Walter Lee Akers
Engineering Management & Systems Engineering Theses & Dissertations
The purpose of this research is to explore the principles and concepts of systems theory in pursuit of a collection of complex systems archetypes that can be used for system exploration and diagnostics. The study begins with an examination of the archetypes and classification systems that already exist in the domain of systems theory. This review includes a critique of their purpose, structure, and general applicability. The research then develops and employs a new approach to grounded theory, using a visual coding model to explore the origins, relationships, and meanings of the principles of systems theory. The goal of the …
Pattern Formation Of Elastic Waves And Energy Localization Due To Elastic Gratings,
2015
Tallinn University of Technology
Pattern Formation Of Elastic Waves And Energy Localization Due To Elastic Gratings, A. Berezovski, J. Engelbrecht, Mihhail Berezovski
Publications
Elastic wave propagation through diffraction gratings is studied numerically in the plane strain setting. The interaction of the waves with periodically ordered elastic inclusions leads to a self-imaging Talbot effect for the wavelength equal or close to the grating size. The energy localization is observed at the vicinity of inclusions in the case of elastic gratings. Such a localization is absent in the case of rigid gratings.
Biomechanical Characerization And Evaluation Of Conservative Clubfoot Correction,
2015
Marquette University
Biomechanical Characerization And Evaluation Of Conservative Clubfoot Correction, Tamara Loren Cohen
Dissertations (1934 -)
Congential talipes equinovarus, or clubfoot, affects approximately 200,000 newborns worldwide each year and presents with equinovarus of the hindfoot, as well as cavus and adduction of the midfoot. In addition to bone malformation and displacement, soft tissue contractures encapsulate the medial and posterior aspects of the affected foot. The Ponseti method is a conservative treatment that progressively repositions the clubfoot through weekly casting, followed by bracing. Concerns exist regarding the variability in outcomes, resistance to treatment, and risk of relapse, which occur in approximately 10% of the population. Potential factors contributing to variability and resistant clubfoot include cast material performance, …
Elevated Test Pressure Significantly Reduces Dynamic Accumulation Oxygen Transmission Rate (Astm F3136) Measurement Time For Barrier Packaging Films,
2015
University of Florida
Elevated Test Pressure Significantly Reduces Dynamic Accumulation Oxygen Transmission Rate (Astm F3136) Measurement Time For Barrier Packaging Films, Bruce A. Welt
Journal of Applied Packaging Research
Measurement of gas transmission rates of materials is important for successful package design. The dynamic accumulation (DA) method (ASTM F3136) is becoming increasingly popular for measuring oxygen transmission rate (OTR) due to its simplicity and low cost. However, measurement time increases with barrier properties of materials, limiting measurement throughput. A dynamic accumulation measurement prototype capable of operating up to 1,000 psig was developed in order to accelerate gas transfer by boosting concentration gradients via elevated absolute pressures. Results show that measurement results were independent of test pressure while measurement times were substantially reduced. These results also suggest that gas transmission …
A Nonequilibrium Finite-Rate Carbon Ablation Model For Radiating Earth Re-Entry Flows,
2015
Air Force Institute of Technology
A Nonequilibrium Finite-Rate Carbon Ablation Model For Radiating Earth Re-Entry Flows, Christopher R. Alba
Theses and Dissertations
Vehicles entering planetary atmospheres at high speed require an ablative heat shield in order to withstand the high thermal energy flux to the body. The interaction between the ablative products and the flow field is not well characterized. Numerical simulations were conducted to investigate the influence of carbon ablation on shock layer radiation. Data collected from experiments performed in the X-2 expansion tunnel at the University of Queensland was used to compare to the simulations. The model was a short half-cylinder made of isomolded graphite and was tested in 8.6 km/s Earth entry flow. The model surface was heated within …
Me-Em Enewsbrief, September 2015,
2015
Michigan Technological University
Me-Em Enewsbrief, September 2015, Department Of Mechanical Engineering-Engineering Mechanics, Michigan Technological University
Department of Mechanical and Aerospace Engineering eNewsBrief
No abstract provided.
Synthesis, Structure And Electrochemical Performance Of Na2Mnsio4/C Cathode Material For Na-Ion Batteries,
2015
State Key Lab of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China;
Synthesis, Structure And Electrochemical Performance Of Na2Mnsio4/C Cathode Material For Na-Ion Batteries, Shou-Ding Li, Jiang-Huai Guo, Yong Xie, Jin-Xiao Mi, Yong Yang
Journal of Electrochemistry
As a promising cathode material for sodium ion batteries, pure phase Na2MnSiO4/C nanocomposite was successfully synthesized by a sol-gel method with a citric acid as a complex agent. The as prepared material was characterized by XRD, FTIR, SEM and TEM techniques. XRD and Rietveld refinement results indicated that the sample was indexed as monoclinic structure with space group of Pn. It was observed by SEM and TEM that the obtained product consisted of micro-scaled secondary particles, which were composed of NaMnSiO4 nanocrystallites and amorphous carbon network. More importantly, the uniform carbon network in the …
