Engineering Science and Materials Commons^™

Visible Light Crosslinkable Human Hair Keratin Hydrogels, Kan Yue, Yanhui Liu, Batzaya Byambaa, Vaishali Singh, Wanjun Liu, Xiuyu Li, Yunxia Sun, Yu Shrike Zhang, Ali Tamayol, Peihua Zhang, Kee Woei Ng, Nasim Annabi, Ali Khademhosseini

Department of Mechanical and Materials Engineering: Faculty Publications

Keratins extracted from human hair have emerged as a promising biomaterial for various biomedical applications, partly due to their wide availability, low cost, minimal immune response, and the potential to engineer autologous tissue constructs. However, the fabrication of keratin-based scaffolds typically relies on limited crosslinking mechanisms, such as via physical interactions or disulfide bond formation, which are time-consuming and result in relatively poor mechanical strength and stability. Here, we report the preparation of photocrosslinkable keratin-polyethylene glycol (PEG) hydrogels via the thiol-norbornene “click” reaction, which can be formed within one minute upon irradiation of visible light. The resulting keratin-PEG hydrogels showed …

Characterization Of 3d Printed Polylactic Acid/ Polycaprolactone/Titanium Dioxide Composites For Bone Replacement And Grafting, Sandra Elena Najera Beltran

Open Access Theses & Dissertations

A material that mimics the properties of bones was developed by optimizing the ratio of polymer composites of polylactic acid (PLA) and poly-ε-caprolactone (PCL), containing small amounts of titanium oxide (TiO2). Although titanium-based alloys have commonly been used for bone replacement procedures due to their biocompatibility with the human body and their mechanical properties, stress shielding continues to be a problem. The structure of a bone has a porosity which permits the flow of nutrients, blood, oxygen and minerals, and is an issue at the time of creating bone replacements using conventional methods. PLA and PCL have been used in …

Development And Characterization Of Novel Materials For The Advancement Of Additive Manufacturing By Material Extrusion 3d Printing, Jose Gilberto Siqueiros

Open Access Theses & Dissertations

The development of additive manufacturing technologies has been under the spotlight from the past decade due to its enormous potential to disrupt current manufacturing processes. Material extrusion 3D printing (ME3DP) is the most common type of additive manufacturing technology as it experienced an exponential growth after the expiration of the fused deposition modeling patent filed in 1989 by Scott Crump. The large interest behind this technology is generated from the capacity to create complex shapes, rapid prototyping, relatively ease of use, low cost, and high accessibility. The gradual evolution of material extrusion 3D printing calls to become a technology ordinarily …

Optimization Of Microfluidic Particle Separator Geometry Using Computational Fluid Dynamics, Joseph Petersen

Electronic Theses and Dissertations

Computational fluid dynamics software was used to simulate the motion of circulating tumor cells in a variety of microfluidic cell isolation devices. Design of several novel microfluidic cell isolation devices was aided by viewing streamlines of fluid in devices in simulation. Devices that performed best in simulation used 5-micrometer wide guiding channels to guide cells to the capture location in the device. While these devices performed better than other devices in simulation and captured all particles regardless of position along inlet, experimental results differ from simulation.

Simulation Of Gas Dynamic Cold Spray Process, Sai Rajkumar Vadla

Electronic Theses and Dissertations

The utilization of computational fluid dynamics (CFD) as a study tool in the aerodynamics and turbomachinery industry reinforces efficiency in the design of aircraft or for understanding the flow through pipes. CFD offer tools to model different geometries and perform a more extensive study of the flow phenomena. This gives the opportunity to model a variety of geometries and analyze their behavior under different operating conditions. A similar approach can be applied to coating technologies. Coating technologies play an essential role in the manufacturing industry. Their ability to form layers of specific materials onto engineering components to enhance mechanical and …

Methods, Systems, And Devices Relating To Force Control Surgical Systems, Shane M. Farritor, Thomas Frederick, Kearney Lackas, Joe Bartels, Jacob Greenburg

Department of Mechanical and Materials Engineering: Faculty Publications

The various embodiments herein relate to robotic surgical systems and devices that use force and/or torque sensors to measure forces applied at various components of the system or device. Certain implementations include robotic surgical devices having one or more force/torque sensors that detect or measure one or more forces applied at or on one or more arms. Other embodiments relate to systems having a robotic surgical device that has one or more sensors and an external controller that has one or more motors such that the sensors transmit information that is used at the controller to actuate the motors to …

Frequency Dependent Deformation Reversibility During Cyclic Loading, Shuai Shao, Michael M. Khonsari, Jian Wang, Nima Shamsaei, Nan Li

Department of Mechanical and Materials Engineering: Faculty Publications

High-frequency testing (HFT) is useful for accelerated fatigue testing of conventional materials that typically serve under low-frequency loading conditions, as well as for the assessment of the robustness of microelectromechanical systems which typically experience high-frequency service conditions. Using discrete dislocation dynamics, we attempt to elucidate the effect of loading frequency on the reversibility of cyclic deformation. We demonstrate that the HFT induces a higher fraction of reversible cyclic deformation because of a larger portion of elastic/anelastic deformation due to limited dislocation mobility, and a higher degree of reversibility in plastic deformation owing to the less occurrence of cross-slip.

Neuroprotective And Anti-Inflammatory Effects Of Rhus Coriaria Extract In A Mouse Model Of Ischemic Optic Neuropathy, Saba Khalilpour, Ghazaleh Behnammanesh, Fouad Suede, Mohammed O. Ezzat, Jayadhisan Muniandy, Yasser Tabana, Mohamed B. K. Ahamed, Ali Tamayol, Amin Malik Shah Majid, Enrico Sangiovanni, Mario Dell'agli, Aman Shah Majid

Department of Mechanical and Materials Engineering: Faculty Publications

Modulating oxidative stresses and inflammation can potentially prevent or alleviate the pathological conditions of diseases associated with the nervous system, including ischemic optic neuropathy. In this study we evaluated the anti-neuroinflammatory and neuroprotective activities of Rhus coriaria (R. coriaria) extract in vivo. The half maximal inhibitory concentration (IC₅₀) for DPPH, ABTS and B-carotene were 6.79 ± 0.009 µg/mL, 10.94 ± 0.09 µg/mL, and 6.25 ± 0.06 µg/mL, respectively. Retinal ischemia was induced by optic nerve crush injury in albino Balb/c mice. The anti-inflammatory activity of ethanolic extract of R. coriaria (ERC) and linoleic acid (LA) on …

Molecular Doping Enabled Scalable Blading Of Efficient Hole-Transport-Layer-Free Perovskite Solar Cells, Wu-Qiang Wu, Qi Wang, Yanjun Fang, Yuchuan Shao, Shi Tang, Yehao Deng, Haidong Lu, Ye Liu, Tao Li, Zhibin Yang, Alexei Gruverman, Jinsong Huang

Department of Mechanical and Materials Engineering: Faculty Publications

The efficiencies of perovskite solar cells (PSCs) are now reaching such consistently high levels that scalable manufacturing at low cost is becoming critical. However, this remains challenging due to the expensive hole-transporting materials usually employed, and difficulties associated with the scalable deposition of other functional layers. By simplifying the device architecture, hole-transport-layer-free PSCs with improved photovoltaic performance are fabricated via a scalable doctor-blading process. Molecular doping of halide perovskite films improved the conductivity of the films and their electronic contact with the conductive substrate, resulting in a reduced series resistance. It facilitates the extraction of photoexcited holes from perovskite directly …

Manufacturing A Composite Wheel Prototype Using 3d Printed Molds, Steven Thuening

All Graduate Theses, Dissertations, and Other Capstone Projects

Throughout the evolution of high performance racing, a large emphasis has been on reducing the weight of the vehicle in order to improve its performance. Over the years, new designs and materials have been introduced reducing weight in a variety of different locations. Comparing weight reduced in different areas has shown that some areas are more valuable to reduce than others are. Perhaps one of the most beneficial locations are the wheels. This is because the mass of the wheel is considered unsprung and rotational. Because of this, large improvements towards the reduction of wheel mass have been developed in …

Additive Manufacturing With High Density Polyethylene: Mechanical Properties Evaluation, Calvin Wampol

Electronic Theses and Dissertations

High-density polyethylene is a common recyclable plastic that has a large potential as an additive manufacturing material due its economic and environmental benefits. However, high-density polyethylene has undesirable thermal properties that cause the material to shirk and not adhere to the printing bed during an additive manufacturing processes. Researchers have attempted to combat these thermal properties but have only created novel filaments of high-density polyethylene without being able to create 3D printed specimens for mechanical property testing. This paper presents several methods to create 3D printed specimens with pure high-density polyethylene filament on a fused filament fabrication type 3D printer. …

Influence Of Substrate Stage Temperature And Rotation Rate On The Magneto-Optical Quality Of Rf-Sputtered Bi2.1dy0.9fe3.9ga1.1o12 Garnet Thin Films, Mohammad E. Alam, Mikhail Vasiliev, Kamal Alameh

Research outputs 2014 to 2021

Highly bismuth-substituted iron garnet thin films are prepared on quartz substrates by using a radio frequency (RF) magnetron sputtering technique. We study the factors (process parameters associated with the RF magnetron sputter deposition technique) affecting the magneto-optical (MO) properties of ferrite garnet films of composition Bi2.1Dy0.9Fe3.9Ga1.1O12. All films show high MO response across the visible range of wavelengths after being annealed. In particular, the effects of substrate stage temperature and rotation rate on the various properties of films are studied. Experimental results reveal that the characteristics of garnet films of this type can be tuned and optimized for use in …

Spectrally-Selective Energy-Harvesting Solar Windows For Public Infrastructure Applications, Mikhail Vasiliev, Kamal Alameh, Mohammad Alam

Research outputs 2014 to 2021

A study of photovoltaic solar window technologies is reported and it focuses on their structural features, functional materials, system development, and suitability for use in practical field applications including public infrastructures and agricultural installations. Energy generation performance characteristics are summarized and compared to theory-limit predictions. Working examples of pilot-trial solar window-based installations are described. We also report on achieving electric power outputs of about 25 Wp/m2 from clear and transparent large-area glass-based solar windows.

Design And Analysis Of A 3d-Printed, Thermoplastic Elastomer (Tpe) Spring Element For Use In Corrective Hand Orthotics, Kevin Thomas Richardson

Theses and Dissertations--Mechanical and Aerospace Engineering

This thesis proposes an algorithm that determine the geometry of 3D-printed, custom-designed spring element bands made of thermoplastic elastomer (TPE) for use in a wearable orthotic device to aid in the physical therapy of a human hand exhibiting spasticity after stroke. Each finger of the hand is modeled as a mechanical system consisting of a triple-rod pendulum with nonlinear stiffness at each joint and forces applied at the attachment point of each flexor muscle. The system is assumed quasi-static, which leads to a torque balance between the flexor tendons in the hand, joint stiffness and the design force applied to …

Structural And Optical Investigations Of Rbxcs1-Xh2po4, Alex D. Price

Open Access Theses & Dissertations

Proton conductor solid acid electrolytes RbxCs1-xH2PO4 (0≤x≤1) have been investigated using second harmonic generation and powder x-ray diffraction. Second harmonic generation is an optical technique which can be used to study the structural properties of materials. Microscopes of this nature have the ability to image objects with a variable penetration depth in a non-destructive manner, allowing for great potential to be used for in situ observations of the electrolyte’s structure when in a fuel cell under operating conditions.

X-ray powder diffraction was carried out on the series of samples and found for values of 0≤x≤0.5 the structure of the material …

Magnetron Sputtering Of Nb3Sn For Srf Cavities, Md. N. Sayeed, H. Elsayed-Ali, G. V. Eremeev, M. J. Kelley, U. Pudasaini, C. E. Reece

Electrical & Computer Engineering Faculty Publications

Nb₃Sn is a potential candidate for surface material of SRF cavities since it can enable the cavity to operate at higher temperatures with high quality factor and at an increased accelerating gradient. Nb-Sn films were deposited using magnetron sputtering of individual Nb and Sn targets onto Nb and sapphire substrates. The as-deposited films were annealed at 1200 °C for 3 hours. The films were characterized for their structure by X-ray Diffraction (XRD), morphology by Field Emission Scanning Electron Microscopy (FESEM), and composition by Energy Dispersive X-ray Spectroscopy (EDS) and Time of Flight Secondary Ion Mass Spectrometry (ToF-SIMS). The …

การประมาณค่าในช่วงเชิงพหุนามลากรานจ์ร่วมกับตัวประกอบถ่วงน้ำหนักนอกช่วงแบบใหม่เพื่อแก้ปัญหาการไหลภายในช่องว่างสี่เหลี่ยมผืนผ้า, อุทัย ประสพชิงชนะ

Chulalongkorn University Theses and Dissertations (Chula ETD)

งานวิจัยนี้มีวัตถุประสงค์เพื่อนำเสนอแผนแบบใหม่ที่มีชื่อว่าแผนแบบ LIP (Lagrange Interpolating Polynomial scheme) และการประมาณค่านอกช่วงแบบใหม่ที่มีชื่อว่าการประมาณค่านอกช่วงแบบ WF-LIP (Weighting Factors with Lagrange Interpolating Polynomial extrapolation) โดยแผนแบบ LIP ถูกใช้สำหรับการประมาณค่าของตัวแปรและอนุพันธ์ของตัวแปรทั้งเทียบกับระยะและเวลาในระเบียบวิธีไฟไนต์วอลู่ม ข้อดีของแผนแบบ LIP คือ เป็นแผนที่มีความแม่นยำลำดับสี่ เป็นแผนที่ง่ายต่อการพัฒนาโปรแกรมที่ใช้การแก้ปัญหาด้วยเม็สซ์ที่ไม่สม่ำเสมอ และเป็นทั้งแผนทางระยะและแผนทางเวลา สำหรับการประมาณค่านอกช่วงแบบ WF-LIP ถูกนำมาใช้ในการหาค่าคาดเดาเริ่มต้นของตัวแปรในแต่ละช่วงเวลาย่อยของปัญหาที่สภาวะไม่คงตัว ซึ่งใช้วิธีการหาคำตอบของแต่ละช่วงเวลาย่อยด้วยวิธีการทำซ้ำ จากผลการตรวจสอบความถูกต้องของคำตอบที่คำนวณจากแผนแบบ LIP และการทดสอบประสิทธิภาพของการประมาณค่านอกช่วงแบบ WF-LIP พบว่า คำตอบที่คำนวณจากแผนแบบ LIP มีความถูกต้องและมีความสอดคล้องกับคำตอบที่นำมาใช้ในการเปรียบเทียบความถูกต้อง ขณะที่การประมาณค่านอกช่วงแบบ WF-LIP สามารถช่วยลดระยะเวลาที่ใช้ในการคำนวณเพื่อหาคำตอบของปัญหาได้สูงสุดถึงร้อยละ 49.69 เมื่อเทียบกับกรณีที่การคำนวณหาคำตอบ โดยไม่ได้ใช้การประมาณค่านอกช่วงแบบ WF-LIP

Microstructural Characterization Of LensTm Ti-6al-4v: Investigating The Effects Of Process Variables Across Multiple Deposit Geometries, Laura Christine Davidson

Browse all Theses and Dissertations

Laser based additive manufacturing of Ti-6Al-4V components is under consideration for aerospace applications. The mechanical properties of the finished components depend on their microstructure. Process mapping compares process variables such as heat source power, heat source travel speed, material feed rate, part preheat temperature and feature geometry to process outcomes such as microstructure, melt pool geometry and residual stresses. In this work, the microstructure of two-dimensional pads, multilayer pads, thin walls, and structural components at the steady state location was observed. A method for measuring β grain widths that allows for the calculation of standard deviations, confidence intervals, and variances …

Galvanic And Pitting Corrosion Of A Fastener Assembly, Julie Shallman

Williams Honors College, Honors Research Projects

This research focuses on coupled galvanic/pitting corrosion of AA7075 when combined with stainless steel in a fastener assembly. A one-dimensional mathematical model of a well-mixed thin film electrolyte is developed to predict the damage profile of the AA7075 surface when its protective coating is damaged. The damage exposes the galvanic couple. A time dependent system of partial differential equations for potential, chloride concentration, aluminum ion concentration, and damage is developed and solved numerically. Two approaches to calculate the current density within aluminum pits are discussed. The first is a current balance between the cathodic, anodic and passive portions of the …

Defect Engineering: Novel Strengthening Mechanism For Low- Dimensional Zinc Oxide Nanostructures, Seyed Emad Rezaei

Browse all Theses and Dissertations

The advent of nanomaterials has opened a new avenue for designing and fabricating materials with unique properties, e.g., superior mechanical properties. Based on a common notion, the perfect structures are assumed to exhibit better mechanical properties, such as higher yield strength and Young's modulus. Therefore, researchers have devoted an extensive amount of time to decrease defect concentration by fabricating materials with the micro/nanoscale, e.g., nanowires (NWs) and nanobelts (NBs), to enhance the mechanical characteristics of the system. However, defects are a part of the fabrication process and precise control over synthesizing procedure is needed to eliminate them from the material. …