Engineering Science and Materials Commons^™

Intrinsic Kinetic Properties Of Ternary Material For Lithium Ion Batteries Assessed By Single Particle Microelectrode, Yi-Min Wei

Journal of Electrochemistry

Electrochemical performances such as capacity, rate, cycle and thermal stability of the nickel (Ni), cobalt (Co) and manganese (Mn) ternary cathode material, LiNi_xCo_yMn_zO₂ (x + y + z = 1), are significantly influenced by the proportion of Ni, Co, and Mn elements. To obtain higher specific capacity, LiNi_0.6Co_0.2Mn _0.2O₂ (NCM622) and LiNi_0.8Co_0.1Mn_0.1O₂ (NCM811) with high amounts of Ni element were employed for the lithium ion batteries. By now, many studies have been focusing on the thermal and cycling stabilities of …

Preparation And Electrocatalytic Activity Of Nitrogen-Doping Tungsten Carbide Catalyst, Pian-Pian Yang, Li-Zhen Huang, Ying-Ying Li, Mei-Qin Shi, Chun-An Ma

Journal of Electrochemistry

Tungsten carbide (WC) is a promising electrocatalyst, however, its electrocatalytic activity is far inferior to Pt and Pt-group metal. In this work, nitrogen-doping tungsten carbide (WN|WC) catalysts with a nanoplate morphology were prepared via the tungsten nitride (WN) as the precursor and sodium tungstate as the tungsten source. The SEM and TEM results indicated that carbon atoms entered into the WN lattice to form the hexagonal close packed WC phase. In this way, an atomic scale heterostructure involving the closely linked interfaces between WN and WC was created . The XRD data confirmed that the cubic crystal structure of WN …

Deposition Mechanism And Coating Characterization For The Trivalent Chromium Electrodeposition In Sulphate Electrolyte, Hui Yan, Shuai-Shuai Huang, Fang-Zu Yang, Zhong-Qun Tian, Shao-Min Zhou

Journal of Electrochemistry

Linear sweep voltammetry (LSV) and cyclic voltammetry (CV) were used to study the electrodeposition mechanism of trivalent chromium on a copper electrode in the novel sulphate electrolyte for thick trivalent chromium plating. The thickness, morphology, composition, microhardness, and structure, as well as the corrosion resistance in 3.5wt% NaCl solution of the trivalent chromium coatings were investigated by X-ray fluorescence gage, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), microhardness tester, X-ray diffraction (XRD) and Tafel curve measurements. The results showed that the electrodeposition of trivalent chromium involved two consecutive one electron reduction steps. The first step, Cr³⁺ + e …

Applications Of Electrospinning In Lithium-Air Batteries, Yue Fu, Jin Wang, Hai-Yang Yu, Jing-Hua Tian, Rui-Zhi Yang

Journal of Electrochemistry

Lithium-air batteries have received increasing attention as the “ultimate batteries” due to their extremely high theoretical capacity and environment friendly. However, there are still many obstacles hindering the wide applications of the lithium-air batteries owing to the limitations of large charge-discharge over-potentials, poor Columbic efficiency and cycling performance. Exploring of high-efficiency, low-cost and eco-friendly catalysts is one of the vital issues for lithium-air batteries. Meanwhile, electrospinning techniques have been under substantial developments due to its simple fabrication process, high efficiency and production. This paper reviews the recent progresses in fabrications of various novel catalysts for lithium-air batteries with electrospinning techniques, …

Numerical Simulation Of Energy Localization In Dynamic Materials, Arkadi Berezovski, Mihhail Berezovski

Publications

Dynamic materials are artificially constructed in such a way that they may vary their characteristic properties in space or in time, or both, by an appropriate arrangement or control. These controlled changes in time can be provided by the application of an external (non-mechanical) field, or through a phase transition. In principle, all materials change their properties with time, but very slowly and smoothly. Changes in properties of dynamic materials should be realized in a short or quasi-nil time lapse and over a sufficiently large material region. Wave propagation is a characteristic feature for dynamic materials because it is also …

An Electrochemical Investigation In The Anticorrosive Properties Of Silver Nanoparticles For The Acidic Corrosion Of Aluminium, H. A. Fetouh, B. A. Abd-El-Nabey, Y. M. Goher, M. S. Karam

Journal of Electrochemistry

The mass loss, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques were used for the determinations of the corrosion rates for aluminium in 1.0 mol·L^-1 hydrochloric acid (HCl) solutions both in the absence and presence of silver nanoparticles (SNPs) at 30 ℃. The protection efficiency was evaluated to be 96.4% for 0.014 g·L^-1 of the SNPs. It has been found that the capacity of the electrical double layer at the aluminium/solution interface was decreased with increasing the concentration of the SNPs, indicating that the SNPs were adsorbed at the aluminium surface. The Langmuir adsorption isotherm and the kinetic-thermodynamic …

Screening Algorithm Based On The Color Halftone Fluorescent Printing And Its Application In Packaging Design, Hu Yaojian, Liu Juan, Wang Ruojing, Zhong Yunfei

Journal of Applied Packaging Research

Abstract：This paper analyzed the characteristics of colorless fluorescent ink and the existing color separation theory, so that colored additive method should be used in printing color pattern with colorless fluorescent ink as well as three-color screening separation type (red, green and blue). Considering the exhibition of the tone, this paper selected dot parallel screening method. At the same time, through comparing the properties of different dots, this paper adopted a special method of AM screening, using regular triangle as the basic dot model to a threshold matrix of AM screening. Finally, designing a screening algorithm which best suit the …

Ureteral Tunnel Length Versus Ureteral Orifice Configuration In The Determination Of Ureterovesical Junction Competence: A Computer Simulation Model, Carlos A. Villanueva, J. Tong, Carl A. Nelson, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

Introduction The long-held belief that a ureteral re-implant tunnel should be five times the diameter of the ureter, as proposed by Paquin in 1959, ignores the effect of the orifice on the occurrence of reflux. In 1969, Lyon proposed that the shape of the ureteral orifice (UO) is more important than the intravesical tunnel. However, both theories missed quantitative evidence from principles of physics. The goal of the current study was to test Lyon’s theory through numerical models (i.e. to quantify the sensitivity of ureterovesical junction (UVJ) competence to intravesical tunnel length and to the UO).

Materials and methods The …

Beauchemin Residence, Hannah E. Rogers

Architectural Engineering

The following report details the structural engineering completed on the Beauchemin Residence, as well as the associated drawings, details, and special considerations. The Beauchemin Residence is an existing single story wood frame building on raised wood floor, located in the city of San Clemente. The scope of work includes calculations for a new roof, new walls (gravity & lateral), retrofit of the existing foundation, new foundation, and providing calculations. The process and progression of the structural design is documented, and correlated to the final product in the Appendix A & B.

Eigenstrain As A Mechanical Set-Point Of Cells, Shengmao Lin, Marsha C. Lampi, Cynthia A. Reinhart-King, Gary C.P. Tsui, Jian Wang, Carl A. Nelson, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

Cell contraction regulates how cells sense their mechanical environment. We sought to identify the set-point of cell contraction, also referred to as tensional homeostasis. In this work, bovine aortic endothelial cells (BAECs), cultured on substrates with different stiffness, were characterized using traction force microscopy (TFM). Numerical models were developed to provide insights into the mechanics of cell–substrate interactions. Cell contraction was modeled as eigenstrain which could induce isometric cell contraction without external forces. The predicted traction stresses matched well with TFM measurements. Furthermore, our numerical model provided cell stress and displacement maps for inspecting the fundamental regulating mechanism of cell …

Spot-R By Triax, Purdue Ect Team

ECT Fact Sheets Archive

Triax’s Spot-r system was developed to tackle the construction industry’s unique safety and productivity challenges, stemming from a demonstrated lack of total jobsite visibility and automatically collected, easily accessible field data. Spot-r by Triax combines a proprietary mesh network with sensor technology to record and transmit previously unattainable workforce and equipment location, activity and safety data within a defined area – all in real-time.

The Spot-r network is installed around the site and operates in a 900 MHz network, with a subset using a cellular connection to forward Spot-r sensor data to Triax’s custom, cloud dashboard. In the hazardous construction …

Purdue’S Biowall, Purdue Ect Team

ECT Fact Sheets Archive

Mechanical ventilation, energy recovery ventilation, and infiltration (air that leaks into a building) are commonly used to introduce fresh air. These are all valid approaches, but a living plant-based filter is an innovative complement to these traditional technologies. A Biowall has the potential to improve indoor air quality while reducing the quantity of air needed for ventilation, creating the potential for energy savings. Figure 1 shows a Biowall prototype being evaluated in the ReNEWW House, a research home located near the Purdue University campus (http://www.renewwhouse.com/).

Mdp (Machine Drive Power) Intelligent Compaction Technology, Purdue Ect Team

ECT Fact Sheets Archive

Caterpillar developed MDP (Machine Drive Power) technology to fill this gap. Rather than an accelerometer and vibratory drum, it uses the principle of rolling resistance to provide indications of soil stiffness. This allows it to perform more reliably on cohesive and granular soils with less variability than accelerometer systems. It also means that the technology can be used on both vibratory and static drum compactors, which are often used on larger sites. While the technology is quite useful on its own, it is even better as a complementary technology to the existing accelerometer-based systems. Contractors who use vibratory soil compactors …

Automating The Crowd-Mapping Workflow With Deep Learning, Lasith Niroshan

Theses

Maintaining updated maps in an ever-changing built environment is important for supporting modern society in many ways. The usage of online crowdsourced maps in particular has gained importance in a wide range of recent location-based applications (route planning/navigation, urban planning, real estate, tourism, etc). However, both traditional map production methods and updating today’s online maps suffer from early obsolescence due to their largely manual map production/update workflows. Significant research efforts have focused on refining techniques to identify changes in raster satellite images, aiming to improve and streamline map production processes. Concurrently, the surge in Internet usage has led to a …

Me-Em 2017-18 Annual Report, Department Of Mechanical Engineering-Engineering Mechanics, Michigan Technological University

Department of Mechanical and Aerospace Engineering Annual Reports

Table of Contents

• Curriculum Revision
• The Result: MEP I-IV
• ME-EM Research
• Alumni Features
• Enrollment & Degrees
• Graduates
• Faculty & Staff
• Alumni
• Donors
• Contracts & Grants
• Patents & Publications

Electronic And Crystalline Characteristics Of Mixed Metal Halide Perovskite Semiconductor Films, Patrick Joseph Cleaver

Browse all Theses and Dissertations

Solar technology has a long history of incremental improvements in cost, reliability and efficiency. However, solar cells based on lead halide perovskite films have made more rapid leaps forward in the past 10 years, making it the fastest growing solar technology in terms of efficiency. Leaders in academia and industry continue to find success in overcoming manufacturability and stability issues, but have not yet discovered a high-efficiency perovskite film without the use of toxic lead. Probing less toxic analogs to the highly efficient lead halide, a series of thin films with perovskite structures, i.e. A2BB’X6 where A = Cs or …

An Integrated Microstructural-Nanomechanical-Chemical Approach To Examine Material-Specific Characteristics Of Cementitious Interphase Regions, Mahdieh Khedmati, Yong-Rak Kim, Joseph A. Turner, Hani Alanazi, Charles Nguyen

Department of Mechanical and Materials Engineering: Faculty Publications

Effective properties and structural performance of cementitious mixtures are substantially governed by the quality of the interphase region because it acts as a bridge transferring forces between aggregates and a binding matrix and is generally susceptible to damage. As alternative binding agents like alkali-activated precursors have obtained substantial attention in recent years, there is a growing need for fundamental knowledge to uncover interphase formation mechanisms. In this paper, two different types of binding materials, i.e., fly ash-based geopolymer and ordinary portland cement, were mixed with limestone aggregate to examine and compare the microstructures and nanomechanical properties of interphase region. To …

Methods, Systems, And Devices For Surgical Access And Procedures, Shane M. Farritor, Mark Rentschler, Amy Lehman, Stephen R. Platt, Jeff Hawks

Department of Mechanical and Materials Engineering: Faculty Publications

The embodiments disclosed herein relate to various medical device components, including components that can be incorporated into robotic and/or in vivo medical devices. Certain embodiments include various actuation system embodiments, including fluid actuation systems, drive train actuation systems, and motorless actuation systems. Additional embodiments include a reversibly lockable tube that can provide access for a medical device to a patient's cavity and further provides a reversible rigidity or stability during operation of the device. Further embodiments include various operational components for medical devices, including medical device arm mechanisms that have both axial and rotational movement while maintaining a relatively compact …

Excess Charge-Carrier Induced Instability Of Hybrid Perovskites, Yuze Lin, Bo Chen, Yanjun Fang, Jingjing Zhao, Chunxiong Bao, Zhenhua Yu, Yehao Deng, Peter N. Rudd, Yanfa Yan, Yongbo Yuan, Jinsong Huang

Department of Mechanical and Materials Engineering: Faculty Publications

Identifying the origin of intrinsic instability for organic–inorganic halide perovskites (OIHPs) is crucial for their application in electronic devices, including solar cells, photodetectors, radiation detectors, and light-emitting diodes, as their efficiencies or sensitivities have already been demonstrated to be competitive with commercial available devices. Here we show that free charges in OIHPs, whether generated by incident light or by current-injection from electrodes, can reduce their stability, while efficient charge extraction effectively stabilizes the perovskite materials. The excess of both holes and electrons reduce the activation energy for ion migration within OIHPs, accelerating the degradation of OIHPs, while the excess holes …

Visible Light Crosslinkable Human Hair Keratin Hydrogels, Kan Yue, Yanhui Liu, Batzaya Byambaa, Vaishali Singh, Wanjun Liu, Xiuyu Li, Yunxia Sun, Yu Shrike Zhang, Ali Tamayol, Peihua Zhang, Kee Woei Ng, Nasim Annabi, Ali Khademhosseini

Department of Mechanical and Materials Engineering: Faculty Publications

Keratins extracted from human hair have emerged as a promising biomaterial for various biomedical applications, partly due to their wide availability, low cost, minimal immune response, and the potential to engineer autologous tissue constructs. However, the fabrication of keratin-based scaffolds typically relies on limited crosslinking mechanisms, such as via physical interactions or disulfide bond formation, which are time-consuming and result in relatively poor mechanical strength and stability. Here, we report the preparation of photocrosslinkable keratin-polyethylene glycol (PEG) hydrogels via the thiol-norbornene “click” reaction, which can be formed within one minute upon irradiation of visible light. The resulting keratin-PEG hydrogels showed …