Engineering Science and Materials Commons^™

Perovskite Catalysts For Fuel Reforming In Sofc:A Review And Perspective, Tong Wei, Jian Li, Li-Chao Jia, Bo Chi, Jian Pu

Journal of Electrochemistry

Solid oxide fuel cell (SOFC) is a generating device by electrochemical reaction to transfer the chemical energy of fossil fuels (coal, oil and gas, etc.), the biomass fuel or other hydrocarbon fuels directly into electricity with higher energy conversion efficiency and lower pollution, which is recognized to be efficient green energy technology in the 21st century. However, when hydrocarbons are directly used as fuel, carbon deposition is easy to occur in nickel-based anode, thus, losing electrochemical catalytic activity. Fuel pre-reforming on the outside of the anode is an effective solution, which strongly relies on highly efficient and stable reforming catalysts. …

Construction And Electrochemical Performance Of Garnet-Type Solid Electrolyte/Al-Li Alloy Interface, Jia-Lin Ma, Hong-Chun Wang, Zheng-Liang Gong, Yong Yang

Journal of Electrochemistry

Garnet-type solid electrolyte is a newly developed Li ion conductor and promising in the application of all-solid-state batteries. However, Garnet is incompatible with Li anode, which restricts the application of Garnet-type solid batteries. In order to improve the contact between Garnet-type solid electrolyte and Li electrode, a composite anode which contains Al-Li alloy (Al₄Li₉) was prepared as an electrode. Al-Li alloy has many advantages such as easy preparation, low cost, simple post-treatment and high capacity. Garnet-type Li_6.5La₃Zr_1.75W_0.25O₁₂ (LLZWO) was synthesized via solid-state reaction. Garnet solid electrolyte has …

Direct Carbon Solid Oxide Fuel Cells, Jiang Liu, Xiao-Min Yan

Journal of Electrochemistry

Carbon is richly reserved in coal, biomasses, and many other nature resources. It is usually used as an energy source through oxygen oxidation reaction. The oxidation is generally realized through combustion which causes serious air pollution. Besides, the conversion efficiency of generating electricity through the combustion process is limited by Carnot efficiency. A direct carbon solid oxide fuel cell (DC-SOFC) is a solid oxide fuel cell (SOFC) directly operated with solid carbon as the fuel. It can convert the chemical energy of carbon into electricity with high efficiency. The concentration of produced CO₂ from a DC-SOFC is so high …

Research Progress In Ethane Dehydrogenation To Cogenerate Power And Value-Added Chemicals In Solid Oxide Fuel Cells, Yun Fan, Qi Wang, Jun Li, Jing-Li Luo, Xian-Zhu Fu

Journal of Electrochemistry

Increasing supplies of methane/shale gas have promoted global development of higher value chemicals such as ethylene production by ethane, which dramatically changes the markets of petrochemical industry. Clean and efficient transformation of ethane into higher value chemicals has far-reaching significance. Ethylene production through ethane steam cracking is a relatively matured technology for industrial production. However, the process consumes large amounts of energy and the presence of carbon deposition becomes a serious problem which is difficult to be solved. The cogenerated energy-chemicals solid oxide fuel cells have been widely studied because fuel gas can be converted into high-value chemicals via spontaneous …

Development Status And Prospects Of Hydrogen Production By High Temperature Solid Oxide Electrolysis, Wen-Qiang Zhang, Bo Yu

Journal of Electrochemistry

Solid oxide electrolysis cell is an advanced energy conversion device with high efficiency, simplicity, flexibility, and environmental friendliness. It is currently a research hotspot in the international energy field. This paper introduces and analyzes the basic principles, key materials, system components and developments of solid oxidation electrolysis cells. Furthermore, the recent research progresses, challenges and future development directions in solid oxidation electrolysis cells in the field of high-efficiency hydrogen production are summarized and outlined.

Materials, Micro-Stacks And Related Applications Of Single-Chamber Solid Oxide Fuel Cells, Zhe Lv, Bo Wei, Zhi-Hong Wang, Yan-Ting Tian

Journal of Electrochemistry

Single-chamber solid oxide fuel cell (SC-SOFC) is a special type of fuel cells, in which both an anode and a cathode are placed in one chamber. Its working principle relies on the selective catalytic activity of the electrodes towards fuel and oxidant in a gas mixture, leading to the generation of an electromotive force. Because of its unique principle and structure, SC-SOFC has many advantages such as sealing-free, easy stacking, quick start-up and no carbon deposition, thus, it possesses large potential in application. Herein, the principles and characteristics of SC-SOFC are introduced. Furthermore, the SC-SOFC materials, micro-stack design, degeneration mechanisms …

Recent Advances Of Co2 Electrochemical Reduction In Solid Oxide Electrolysis Cells, Yi-Hang Li, Chang-Rong Xia

Journal of Electrochemistry

Solid oxide electrolysis cells (SOECs) have stimulated wide interests for their promising application in the reduction of CO₂ emissions and the storage of renewable energy. Here, the advances made in the development of cathode materials including cermets and perovskite oxides in our research group, are summarized, along with the design of cell configurations. The electrochemical kinetics and performances of cathodes and cells are discussed and analyzed. It is expected that this brief review offers critical insights and useful guidelines for developing superior electrodes and SOECs in the future.

Nio@Rgo Supported Palladium And Silver Nanoparticles As Electrocatalysts For Oxygen Reduction Reaction, Shuo Yao, Tai-Zhong Huang, Rizwan Haider, Heng-Yi Fang, Jie-Mei Yu, Zhan-Kun Jiang, Dong Liang, Yue Sun, Xian-Xia Yuan

Journal of Electrochemistry

For pervasive applications of fuel cells, highly efficient and economical materials are required to replace Pt-based catalysts for oxygen reduction reaction (ORR). In this study, the NiO@rGO, Pd-NiO@rGO and Ag-NiO@rGO nanoparticles were synthesized, and their catalytic performances toward ORR were investigated. The results revealed that all the three materials were capable of catalyzing ORR, but both the Pd-NiO@rGO and Ag-NiO@rGO showed the better performances compared with the NiO@rGO in terms of the reaction pathway being 4-electron process, the increases of the onset potential and the intermediate yielding rate, as well as the extended stability. Moreover, the effect of Pd modification …

Designing An Adjustable And Transportable Staircase, Allison Currey

Undergraduate Honors Thesis Projects

People climb stairs every day, whether it is at work, a store, or at home; however, there are populations such as people who are elderly, with pathologies, with Parkinson’s disease, or have suffered from a stroke that see climbing the stairs as a challenging task and it decreases their mobility and quality of life. Factors such as muscle weakness, strategy, and balance have been previously investigated in these populations during stair climbing. However, few studies have researched how stair climb ability, balance, and perception of difficulty are influenced by step height. The objective of this thesis is to design a …

Stationary Exercise Classification Using Imus And Deep Learning, Andrew M. Heroy, Zackary Gill, Samantha Sprague, David Stroud, John Santerre

SMU Data Science Review

In the current market, successful fitness tracking devices utilize heart rate and GPS to determine performance. These devices are useful, but don't extensively classify stationary exercise. This paper proposes a modern approach for tuning and investigating optimal neural network types on stationary exercises using Inertial Measurement Units (IMUs). Using three IMUs located on the ankle, waist, and wrist, data is collected to map the body as it moves during the stationary physical activity. A novel five-stage deep learning tuning system was written and deployed to classify user movement as one of three classes: air squats, jumping jacks, and kettlebell swings. …

Subsurface Analytics: Contribution Of Artificial Intelligence And Machine Learning To Reservoir Engineering, Reservoir Modeling, And Reservoir Management, Shahab D. Mohaghegh

Faculty & Staff Scholarship

Subsurface Analytics is a new technology that changes the way reservoir simulation and modeling is performed. Instead of starting with the construction of mathematical equations to model the physics of the fluid flow through porous media and then modification of the geological models in order to achieve history match, Subsurface Analytics that is a completely AI-based reservoir simulation and modeling technology takes a completely different approach. In AI-based reservoir modeling, field measurements form the foundation of the reservoir model. Using data-driven, pattern recognition technologies; the physics of the fluid flow through porous media is modeled through discovering the best, most …

Morphology And Structure Of Pb Thin Films Grown On Si (111) By Pulsed Laser Deposition, Bektur Abdisatarov

Masters Theses & Specialist Projects

Pulsed laser deposition (PLD) is a versatile thin film deposition technique in which high powered laser beam interacts with a target material inside an ultrahigh vacuum chamber. Highly energetic particles such as electrons, atoms, protons, and ions generate a plasma plume that directed towards a substrate material where recondenses form a thin film. PLD is an effective and reliable method to create varieties of thin films such as metal, polymer, and ceramic for many technologically essential applications.

In this study, thin Pb films were grown by pulsed laser deposition on Si (111) at various laser fluences, pulse wavelengths, deposition times, …

Stability Analysis, Dynamic Modeling, And Kinematic Analysis Of Hydraulically Amplified Dielectric Elastomer Actuators And Robot Manipulators, Amir Hosein Zamanian

Mechanical Engineering Research Theses and Dissertations

In this dissertation, we have proposed a new dielectric elastomer actuator design and model that couples electrostatics, fluid mechanics, linear and nonlinear elastic deformations. The internal hydraulic pressure can amplify the structural deformation generated by induced electrostatic forces (Maxwell pressure), given the name of this class of actuators, hydraulically amplified dielectric elastomer actuators (HADEAs).

First, we developed novel lumped-parameter models (LPMs) using linear and hyper-elastic material models and second compared the LPM results with finite element analysis in quasi-static simulations. We analytically expressed the conditions for the snap-through instability in the HADEA, which appears after exceeding a certain voltage applied …

Dynamic And Control Of Air-Bearing Spacecraft Simulator, Jacob Joseph Korczyk

Doctoral Dissertations and Master's Theses

An air bearing is being designed as a spacecraft rotational motion simulator, featuring the Sawyer Robot and its control box. The objective is to maneuver the robot as desired, performing operations specific to on-orbit servicing operations while maintaining stability of the system. Before the control can be designed, the dynamics of the platform and the robot must be modeled. The dynamics of the robot can be derived utilizing a Newton-Euler recursive approach. By beginning with a simple pendulum, then adding links (degrees of freedom) to more closely resemble the Sawyer arm, the equations of motion for the robot can be …

Fatigue Damage Assessment Of Reinforced Concrete Slabs Using Integrated Dynamic Testing And Simulation, Jamadin Adiza

Student Works (2020-2029)

Assessment of existing fatigued structures is an important aspect of civil engineering infrastructure. This is critical in most loaded civil engineering structures such as bridges that are constantly subjected to dynamic loading, causing fatigue in the materials over time. Bridge deck slabs are one of the most structural elements susceptible to different cyclic loads, requiring regular checks for damage to fatigue. In order to understand the deterioration, fatigue carrying capacity and residual strength, the serviceability of the slab under the fatigue loads was not fully explored. Therefore, this research is designed to use vibration-based techniques to investigate the integrity of …

Hybrid Non-Destructive Assessment For Flow Induced Vibration Piping Systems Using Coupled Fluid-Structure Interaction, Keen Kuan Kong

Student Works (2020-2029)

Pipelines and piping systems are of great importance in many industries such as water supply, petroleum and petrochemicals and nuclear power generation. They provide transport for high-velocity pressurized fluids operating under time-varying conditions. They are required to operate non-stop for a schedule of 24 hours a day, 7 days a week. Piping vibration failures have been one of the major causes of downtime, fires and explosions in industrial plant over the past 30 years. Failure of piping systems can have disastrous effects, leading to injuries and fatalities as well as to substantial cost to industry and the environment. Flow-induced vibration …

Modeling Nonlinear Heat Transfer For A Pin-On-Disc Sliding System, Brian A. Boardman

Theses and Dissertations

The objective of this research is to develop a numerical method to characterize heat transfer and wear rates for samples of Vascomax® 300, or Maraging 300, steel. A pin-on-disc experiment was conducted in which samples were exposed to a high-pressure, high-speed, sliding contact environment. This sliding contact generates frictional heating that influences the temperature distribution and wear characteristics of the test samples. A two-dimensional nonlinear heat transfer equation is discretized and solved via a second-order explicit finite difference scheme to predict the transient temperature distribution of the pin. This schematic is used to predict the removal of material from the …

Focused Beam System Biaxial Material Characterization, Nicholas A. O'Gorman

Theses and Dissertations

Electromagnetic material characterization is the process of determining the constitutive parameters (complex permittivity and permeability) of given a sample. Due to the large number of unknowns involved, multiple unique measurements are required for material property extraction. Many measurement methods, such as waveguides and striplines, possess a rigid internal structure that the sample being measured must adhere to. This rigidity limits these methods to samples that fit within the device and inhibits oblique sample orientations, limiting the number of independent measurements that can be obtained. A focus beam system, due to being an open system with greater freedom in sample size …

A Wirelessly Controlled Smart Bandage With 3d-Printed Miniaturized Needle Arrays, Hossein Derakhshandeh, Fariba Aghabaglou, Alec Mccarthy, Azadeh Mostafavi, Chris Wiseman, Zack Bonick, Ian Ghanavati, Seth Harris, Craig Kreikemeier-Bower, Seyed Masoud Moosavi Basri, Jordan Rosenbohm, Ruiguo Yang, Pooria Mostafalu, Dennis Orgill, Ali Tamayol

Department of Mechanical and Materials Engineering: Faculty Publications

PUBLIC ACCESS

Results Of Improvement Of The Technological Process Of Sorting Of Draged Seeds, R.K. Djamolov, E.T. Maksudov, K. Djamolov

Irrigation and Melioration

The article presents the results of experiments conducted to justify the parameters of the seed selection unit to improve the process of sorting seeds. The experiments were carried out by changing the angle of inclination of the seed tray to the horizontal plane from α = 390 to α = 540 and the radius of the lower part of the tray in the aisle R = 140-180 mm. The experimental results show that the bottom of the tray, made in the form of a semicircle, allows the seeds to move up the pipe when the seeds fall from the tray …