Engineering Science and Materials Commons^™

Fuel Cell Performance Of Non-Precious Metal Based Electrocatalysts, Yan-Feng Zhang, Fei Xiao, Guang-Yu Chen, Min-Hua Shao

Journal of Electrochemistry

The commercialization of proton exchange membrane fuel cells (PEMFCs) is hindered by high cost and low durability of Pt based electrocatalysts. Developing efficient and durable non-precious metal catalysts is a promising approach to addressing these conundrums. Among them, transition metals dispersed in a nitrogen (N)-doped carbon support (M-N-C) show good oxygen reduction reaction activity. This article reviews recent progress in M-N-C catalysts development, focusing on the catalysts design, membrane electrode assembly fabrication, fuel cell performance, and durability testing. Template-assisted approach is an efficient way to synthesize M-N-C materials with homogeneously dispersed single atom active site and reduced metal particles, carbides …

A Framework For Using Fused Image Data In Statistical Process Control, Shengfeng Chen

Dissertations

The use of image data in manufacturing quality control systems has grown rapidly over the years. Technological advancements in imaging devices (e.g., digital cameras, x-ray scanners, infrared cameras) have provided convenient and cost-effective ways to obtain images. These images contain important quality features (e.g., textures and product dimensions) that can be used to monitor, diagnose, predict, and control manufacturing processes. A key tool for monitoring images is statistical process control charts. Integrating images of parts to detect process shifts can significantly improve a quality systems efficiency. Unfortunately, appropriate techniques that take full advantage of data-rich images for control charting are …

Performance Of Pld Grown Zno Thin Film As A Thin Film Transistor, Shahidul Asif

Graduate Theses/Dissertations

The performance of ZnO thin film (grown in different parameters) as a thin film transistor (TFT) is the focus of this study. ZnO is renowned for being n-type semiconductor naturally which was utilized in fabricating a thin film transistor here. This thesis is compared the performance of ZnO thin film transistor by growing the thin film using pulsed laser deposition (PLD) on two slightly different substrates at different temperatures in an optimal 0.1 milli bar oxygen pressure which was later analyzed using other material characterization methods. The substrates were both Si (100) but had different resistivity due to different amount …

Hardness Evaluation On Ss 316l Joined With Gas Tungsten Arc Welding Under Constant Heat Treatment, Duwi Leksono, Imam Sudjono

Journal of Mechanical Engineering Science and Technology (JMEST)

The purpose of this study is to show the hardness of the GTAW welding results on SS 316L metal with surface heating during the welding process. Observations in this study used SS 316L material with heat temperature regulation on the metal surface of the welding process using heating variations of 100 ℃, 120 ℃ and 140 ℃. The welding process of SS 316L material used a welding joint model uses single V-type welding joint with an angle of 60°, a spacing of 2 mm, a root surface of 1 mm and a thickness of 5 mm. Vickers hardness test was …

The Effect Of Solution Treatment Temperature And Quenching Media Variation In Heat Treatment Process Cu-Zn-Al Shape Memory Alloys On Shape Memory Effect And Microstructures, Wikan Jatimurti, Monica Gayatri K, Mavindra Ramadhani, Rochman Rochiem

Journal of Mechanical Engineering Science and Technology (JMEST)

Shape memory alloys (SMAs) are metal alloys with a reversible ability to recover their shape at a certain temperature after being deformed. This ability referred to as Shape Memory Effect (SME). The application of SMAs such as Ni-Ti and Cu-Zn-Al alloys usually used on automotive, biomedical, etc. The commonly used SMA is Ni-Ti because of its superior SME properties than Cu-Zn-Al, even though the price is quite higher. The SME of Cu-Zn-Al might be improved by increasing the presence of the martensite phase in its microstructure by heat treatment. The heat treatment process given to Cu-21Zn-5Al alloy is a homogenizing, …

Performance Enhancement Of Shell And Tube Heat Exchanger On Parallel Flow With Single Segmental Baffle, Avita Ayu Permanasari, Poppy Puspitasari, Sukarni Sukarni, Retno Wulandari

Journal of Mechanical Engineering Science and Technology (JMEST)

The shell and tube heat exchanger was a tool to exchange the heat energy between fluids with different temperatures that occurred through direct or indirect contact. The energy exchange in fluids could be occurred with the same phase (liquid to liquid or gas to gas) or two fluids with different phase. To date, the process of heat transfer in the industrial field was crucial in machine work. Therefore, there were studies directed to optimize and develop the function and thermal performance of a heat exchanger by adding Baffles to the side of the shell. Vortex flow that occurs with the …

Physical Behavior Of Thermally Affected Bronze And Brass, Samiul Kaiser, Mohammad Salim Kaiser

Journal of Mechanical Engineering Science and Technology (JMEST)

The physical behavior of thermally affected cast copper, aluminum bronze and brass has been studied by subjecting to heating isochronally for one hour at a range of 600°C. It shows that solid-solution hardening takes place into the Al added bronze and Zn added brass metal. Due to heating Al forms hard and brittle intermetallic of copper aluminates into the bronze metal which responses some age-hardening effects. The electrical conductivity of the metals increases initially through heat treatment due to stress relieving and finally decreases due to formation of intermetallic precipitates. The color of the heated samples are also studied through …

The Influence Of The Reference Area Of Aileron On The N2xx Aircraft Using Computational Fluid Dynamics, Siti Nur Rahmah, Gaguk Jatisukamto, Hary Sutjahjono

Journal of Mechanical Engineering Science and Technology (JMEST)

Aileron is a control surface that functions as a regulator of roll motion. The movements of the ailerons are opposite to the left and right sides. Previous studies have shown that graphs of hinge moment coefficient (Chm) values increases with increasing angle of attack. This study is to determine the aerodynamic characteristics of aileron by combining the surface area of the vane into the aileron by varying the aileron’s deflection. The calculation is performed using a numerical method in two dimensions (2D) commercial CFD simulation software. The results of the study concluded that the hinge moment coefficient for modified airfoil …

The Effect Of Heat Treatment To The Erosion Rate Of Brass Composite, Aminnudin Aminnudin, Solichin Solichin

Journal of Mechanical Engineering Science and Technology (JMEST)

Brass composites can be improved their mechanical properties by the heat treatment process. The improvement of the mechanical properties of this technique is expected to increase the resistance of the composite to erosion that occurs in the environment of flow water. Brass composites used are compositeswith fly ash 5, 10, 15, and 20%. The heat treatment process was carried out using electric furnace withoutprotective gas. Composite heat up to 350°C and 400°C for 30 min. and quenching with water. Before and after the erosion test, the weight of the test specimen was weighed with analytical scales. The treatment process affects …

Interaction Of Optomechanical Cavities With Acoustic Waves And Oscillators, Ke Huang

Optical Science and Engineering ETDs

Resonators and oscillators are key elements in a wide variety of natural and manmade systems. As such understanding and exploiting their dynamics both as isolated devices and members of coupled systems has been the subject of intensive investigation for more than a century. The advent of optomechanical resonators (OMRs) that support strong coupling between optical and mechanical modes resulting in self-sustained optomechanical oscillations, has created new opportunities for device development and implementation of coupled oscillatory systems. One aspect of this thesis is focused on exploring some of the unique features of OMRs and optomechanical oscillators (OMOs) that can be exploited …

Comparison Of Plantar Pressure Profile Of Young Adults During Training On Elliptical Devices And Overground Walking: A Pilot Study, Guilherme Manna Cesar, Thad W. Buster, Judith M. Burnfield

Department of Mechanical and Materials Engineering: Faculty Publications

Background: Elliptical training may offer advantages over other cardiorespiratory exercises for those requiring podiatric care, since its constant double-limb support diminishes recurring high-impact plantar forces while allowing exercise in a functional, upright posture. Unknown is the impact of distinct elliptical models, that can alter user’s body mechanics, on potential variations in plantar pressure patterns.

Purpose: To compare plantar pressure variables while exercising on four ellipticals and walking.

Methods: For this cross-sectional pilot study, plantar pressure data were recorded from ten young adults while exercising on four ellipticals (True, Octane, Life Fitness, SportsArt) and walking overground. One-way repeated measures ANOVA identified …

Towards A Sociotechnical Reconfiguration Of Engineering And An Education For Ethics : A Critical Realist Investigation Into The Patterns Of Education And Accreditation Of Ethics In Engineering Programmes In Ireland, Diana Adela Martin

Doctoral

The focus of this thesis is on the provision and evaluation of ethics in engineeringprogrammes in Ireland, by placing this examinationin the wider cultural context of engineering education.The study benefitted from the support of the national accrediting body Engineers Ireland, and included 23 engineering programmes from 2 institutes of technology and 4 universities in Ireland which underwent accreditation between 2017-2019.By using a Critical Realistframe, the study undertakes a multi-layeredinvestigation of the engineering education system that takes into consideration theindividual level of single agents such as instructors and evaluators, the institutional level comprised of engineering programmes, as well as the policy …

The Use And Explanation Of The Phase Angle In Forced Vibration Testing, Nicholas R. Slavin, Ryan D. Thornton

Architectural Engineering

Forced vibration testing is a tool used to characterize a structure’s dynamic properties. When subjecting a structure to a forced harmonic load, the results help define the structure’s fundamental frequencies and dominant mode shapes. However, when conducting testing, it is difficult to determine the contributions of each mode to the response at a given location in the structure. The recorded response from a forced vibration test is a combination of unknown modal constituents. Excitation may not result in the pure, single mode response that the experimenter desires, but may instead result in a combination of modal responses that obscure the …

Magnetically Induced Carrier Distribution In A Composite Rod Of Piezoelectric Semiconductors And Piezomagnetics, Guolin Wang, Jinxi Liu, Wenjie Feng, Jiashi Yang

Department of Mechanical and Materials Engineering: Faculty Publications

In this work, we study the behavior of a composite rod consisting of a piezoelectric semiconductor layer and two piezomagnetic layers under an applied axial magnetic field. Based on the phenomenological theories of piezoelectric semiconductors and piezomagnetics, a one-dimensional model is developed from which an analytical solution is obtained. The explicit expressions of the coupled fields and the numerical results show that an axially applied magnetic field produces extensional deformation through piezomagnetic coupling, the extension then produces polarization through piezoelectric coupling, and the polarization then causes the redistribution of mobile charges. Thus, the composite rod exhibits a coupling between the …

Dynamics Of Discontinuities In Elastic Solids, Arkadi Berezovski, Mihhail Berezovski

Publications

The paper is devoted to evolving discontinuities in elastic solids. A discontinuity is represented as a singular set of material points. Evolution of a discontinuity is driven by the configurational force acting at such a set. The main attention is paid to the determination of the velocity of a propagating discontinuity. Martensitic phase transition fronts and brittle cracks are considered as representative examples.

Development Of High-Density Propulsion System Technologies For Interplanetary Small Satellites And Cubesats, Morgan Andrew Roddy

Graduate Theses and Dissertations

The goal of this research was to support the development of a novel propulsion system for small satellites (<180 kg) and CubeSats. This was pursued by conducting a collection of studies that were designed to provide engineering data that would be critical in designing a functional prototype. The novel propulsion system was conceived by the author to provide best-in-class performance for the small satellite and CubeSat families of spacecraft. This context presents specific design requirements that the presented technology attempts to satisfy. The most critical among these is high density; the propellant was designed to be stored with high density and the thruster was designed to be as compact as possible. The propulsion system is composed of two primary elements, a propellant generator and a thruster. The propellant generator works by sublimating a solid crystal into vapor and then using this vapor to etch a dense metal. The resulting gaseous byproducts of this reaction are the propellant. This dissertation used xenon difluoride (XeF2) vapor to etch tungsten (W) which react to form xenon gas (Xe) and tungsten hexafluoride (WF6). This approach gave a theoretical propellant storage density 5.40 g/cm3; and 5.17 g/cm3 was demonstrated. The sublimation dynamics of the XeF2 were studied as a function of surface area and temperature and it was found to be suitable for the intended application due to its high effluence rate; that is, it sublimates fast enough to be useful. The sublimation rates are on the order of 10’s of µg/s. The etch rate of XeF2 on W was also studied and found to be suitably fast to provide useful amounts of reactants for use as a propellant, again on the order of 1’s of µg/s. The thruster is an electrostatic radio frequency (RF) ion thruster design and is manufactured with Low Temperature Co-Fired Ceramic (LTCC) materials system and manufacturing technology. Manufacturing samples of the thruster were built at the University of Arkansas in July 2015 and tested at NASA’s Marshall Space Flight Center in May 2018. Testing validated the viability of the LTCC thruster and provided valuable information on how to improve the thruster’s design.

Long-Term Durability Of Solar Photovoltaic Modules, Chibuisi Chinasaokwu Okorieimoh, Brian Norton

Conference papers

Solar photovoltaic (PV) panels experience long-term performance degradation resulting in lower like-per-like efficiencies and performance ratios when compared with their initial performance. Manufacturers of solar photovoltaic modules usually guarantee the life span for more than 20 years. It is therefore necessary to track and mitigate degradation of PV modules over this period to satisfy such guarantees and beyond this period to identify maintenance and repair requirements. Degradation of solar PV modules makes them less efficient, less reliable and, ultimately, inoperative. This paper reviews relevant literature to discuss:

• Causes of efficiency reductions in photovoltaic cells

• Ways to achieve long-term durability of …

Preparations Of Nano-MnoX/Ti Electrocatalytic Membrane Electrode For Catalytic Oxidation Of Cyclohexane Using Intermittent Electrodeposition, Xue Zhou, Hong Wang, Zhen Yin, Yu-Jun Zhang, Jian-Xin Li

Journal of Electrochemistry

Cyclohexanone and cyclohexanol (KA oil) obtained from highly selective oxidation of cyclohexane (CHA) show important industrial value and application prospects. In this work, the intermittent electrodeposition was developed to prepare nano-MnO_x catalyst loading porous tubular titanium membrane electrode (MnO_x/Ti), which was employed to constitute an electro-catalytic membrane reactor (ECMR) for the oxidation of cyclohexane to produce cyclohexanol and cyclohexanone. The surface morphology, crystal structure and electrochemical property of the catalysts were characterized by FESEM, XRD and electrochemical workstation, respectively. The results show that the catalyst prepared by the intermittent electrodeposition displayed nano-flower-like γ-MnO₂. Compared with …

Preparation Of Α-Hydroxylated Acetal From 2-Butanone By Indirect Electrooxidation, Hai-Qing Huang, Ye Miao, Xin-Sheng Zhang

Journal of Electrochemistry

Acetoin (3-hydroxy-2-butanone) is an important food spice. As a platform compound, it is widely used in medicine, tobacco, cosmetics, chemical material and other industries. In this paper, α-hydroxylated acetal, an intermediate of acetoin, was prepared from 2-butanone by indirect electrooxidation in the plate and frame electrolytic cell, in which graphite plates were used as both an anode and a cathode, while KOH as an electrolyte and KI as a catalyst. Acetoin could be prepared by hydrolysis in acidic aqueous solution from acetoin intermediate. The effects of current density, electrolyte flow rate between the plates, 2-butanone concentration and electrolysis temperature …

Electrochemical Response Of A Single Wire-Electrode Ac Probe In 3.5wt.% Nacl, Zhen-Wen Zou, Da-Jiang Zheng, Zi-Ming Wang, Guang-Ling Song

Journal of Electrochemistry

In this paper, a recently developed single wire-electrode AC probe technology which does not need a reference or counter electrode was employed to investigate the electrochemical corrosion and sacrificial anode protection behaviors of steel and zinc in 3.5wt.% NaCl. With this simple, fast, reliable and stable probe, the instantaneous corrosion rate and accumulated corrosion loss of carbon steel in 3.5wt.% NaCl were measured, and the results revealed that both were greater than those of zinc. Furthermore, the observed different corrosion behaviors between carbon steel and zinc during the immersion could be caused by their different surface films. With the galvanic …