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Design And Development Of Transition Metal-Based Electrocatalysts For Environmentally Friendly And Efficient Hydrogen Evolution Reactions (Her), Navid Attarzadeh 2023 University of Texas at El Paso

Design And Development Of Transition Metal-Based Electrocatalysts For Environmentally Friendly And Efficient Hydrogen Evolution Reactions (Her), Navid Attarzadeh

Open Access Theses & Dissertations

Hydrogen fuel is a clean energy source primarily because it emits no carbon dioxide (CO2). Sustainable energy alternatives have attracted the scientific community and policymakers as concerns over global warming and depletion of fossil fuels have increased significantly. Substituting H2 gas as a primary source for our daily energy consumption under the guideline of the hydrogen economy concept has not progressed as anticipated because of inadequate efficiency associated with the generation (electrolyzer) and utilization (fuel cell) devices. However, there are challenges associated with hydrogen that must be overcome for it to become a truly sustainable and widespread energy source. The …


Studies On Atomic And Molecular Properties Using Locally Scaled And Perdew-Zunger Self-Interaction Corrected Density Functional Approximations, Philip Adeniyi Oyedele 2023 University of Texas at El Paso

Studies On Atomic And Molecular Properties Using Locally Scaled And Perdew-Zunger Self-Interaction Corrected Density Functional Approximations, Philip Adeniyi Oyedele

Open Access Theses & Dissertations

This thesis examines some properties of atoms and molecules using one-electron self-interaction-correction (SIC) methods such as the Perdew-Zunger SIC (PZSIC) and the locally scaled SIC method of Zope and coworkers within the Fermi-Lowdin SIC formal- ism. The accuracy of electron density is examined by comparing moments of the den- sity, ⟨r^n⟩ = ∫ ρ(r)rndτ = ∫ ∞ 0 4πr2ρ(r)rndr (n = −2, −1, 0, 1, 2, 3) with the corresponding available values from the Coupled cluster (CC) singles, doubles, and perturbative triples (CCSD(T)) method. Three test sets are considered: boron through neon neutral atoms, two and four electron cations, and …


Double Cantilever Beam Mode-I Testing Validation In Large-Scale Additive Manufacturing Carbon Composite, Luis Alfonso Camacho 2023 University of Texas at El Paso

Double Cantilever Beam Mode-I Testing Validation In Large-Scale Additive Manufacturing Carbon Composite, Luis Alfonso Camacho

Open Access Theses & Dissertations

Testing for mechanical properties for additive manufacturing has been based on already existing standards for traditional manufacturing methods. For composites in large scale additive manufacturing there is a research gap in bond strength and fracture toughness for a single layer interface. By using Double cantilever beam Mode I, this thesis manuscript validates testing parameters and protocols to describe the intricacies of ABS matrix 20 wt.% carbon filled composite, specifically on the layer-to-layer interface. Studies suggest that fracture toughness is sensitive to process parameters, like deflection speed and sharpened crack tip at the layer interface of BAAM 3D printed part and …


Electrochemical Approaches To Life-Support Resources In Space Missions And Nuclear Technologies: Hydrogen Peroxide And Uranium Films, Armando Manuel Pena-Duarte 2023 University of Texas at El Paso

Electrochemical Approaches To Life-Support Resources In Space Missions And Nuclear Technologies: Hydrogen Peroxide And Uranium Films, Armando Manuel Pena-Duarte

Open Access Theses & Dissertations

Space race has developed several technological advances that have achieved and continue to achieve the success of space missions in the aerospace timeline. Currently, the number of space technical and scientific innovations is still growing––demanding new materials and developments for extreme performing applications of fuel cells, batteries, supercapacitors, and systems of nuclear energy. Space missions require life-support solutions, auto-sustainable closed-loop living environments, cleaning and sanitizing solutions against pathogens, and safe nuclear-based resources of energy––with fissile materials with well-controlled dimensions within the core fuel elements. Likewise, to guarantee safety conditions, reduce costs, and facilitate operational logistics, space missions must reduce their …


Characterization Of Mechanically Recycled Polylactic Acid (Pla) Filament For 3d-Printing By Evaluating Mechanical, Thermal, And Chemical Properties And Process Performance, Mahsa Shabani Samghabady 2023 Clemson University

Characterization Of Mechanically Recycled Polylactic Acid (Pla) Filament For 3d-Printing By Evaluating Mechanical, Thermal, And Chemical Properties And Process Performance, Mahsa Shabani Samghabady

All Theses

Polylactic acid (PLA) is a biopolymer made from renewable resources such as sugar and corn. PLA filament is a popular material used in Fused Deposition Modeling (FDM) 3D-printing. While this material has many advantages, all the failed parts, support structures, rafts, nozzle tests, and the many prototype iterations during the 3D-printing process contribute to the plastic pollution and release of greenhouse gases. Although PLA is biodegradable, it can take years to degrade in landfills. Instead of throwing away PLA waste and buying new filaments, PLA can be recycled. Amongst the different recycling technologies, mechanical recycling is the most environmentally friendly. …


Twin-Solute, Twin-Dislocation And Twin-Twin Interactions In Magnesium, Materials Yue, Jian Wang, Jian-Feng Nie 2023 Monash University

Twin-Solute, Twin-Dislocation And Twin-Twin Interactions In Magnesium, Materials Yue, Jian Wang, Jian-Feng Nie

Department of Mechanical and Materials Engineering: Faculty Publications

Magnesium alloys have received considerable research interest due to their lightweight, high specific strength and excellent castability. However, their plastic deformation is more complicated compared to cubic materials, primarily because their low-symmetry hexagonal closepacked (hcp) crystal structure. Deformation twinning is a crucial plastic deformation mechanism in magnesium, and twins can affect the evolution of microstructure by interacting with other lattice defects, thereby affecting the mechanical properties. This paper provides a review of the interactions between deformation twins and lattice defects, such as solute atoms, dislocations and twins, in magnesium and its alloys. This review starts with interactions between twin boundaries …


Atomistic Simulations Of Twin Facets Associated With Three-Dimensional { []011 } Twins In Magnesium, Qiyu Zeng, Mingyu Gong, Houyu Ma, Yao Shen, Jian-feng Nie, Jian Wang, Yue Liu 2023 Shanghai Jiao Tong University

Atomistic Simulations Of Twin Facets Associated With Three-Dimensional { []011 } Twins In Magnesium, Qiyu Zeng, Mingyu Gong, Houyu Ma, Yao Shen, Jian-Feng Nie, Jian Wang, Yue Liu

Department of Mechanical and Materials Engineering: Faculty Publications

Twinning is a deformation mechanism that creates three-dimensional (3D) twin domains through the migration of twin facets. This occurs via the nucleation and glide of twinning disconnections (TDs), which can pile up to create twin facets. A comprehensive under- standing of twin facets associated with 3D twins, including their atomic structures and energies, is crucial for understanding deformation twinning. In this study, we propose a molecular statics/dynamics (MS/MD) approach to determine characteristic twin facets enclosing 3D non-equilibrium/equilibrium { [] 011 } twin domains, which has been much less studied than the counterpart { [] 012 } twin domains. The stability …


The Essential Work Of Fracture In Peridynamics, Christer Stenström, Kjell Eriksson, Florin Bobaru, Stefan Golling, Pär Jonsén 2023 Luleå University of Technology, Luossavaara-Kiirunavaara Aktiebolag

The Essential Work Of Fracture In Peridynamics, Christer Stenström, Kjell Eriksson, Florin Bobaru, Stefan Golling, Pär Jonsén

Department of Mechanical and Materials Engineering: Faculty Publications

In this work, the essential work of fracture (EWF) method is introduced for a peridynamic (PD) material model to characterize fracture toughness of ductile materials. First, an analytical derivation for the path-independence of the PD J -integral is provided. Thereafter, the classical J -integral and PD J-integral are computed on a number of analytical crack problems, for subsequent investigation on how it performs under large scale yielding of thin sheets. To represent a highly nonlinear elastic behavior, a new adaptive bond stiffness calibration and a modified bonddamage model with gradual softening are proposed. The model is employed for two …


Mesoporous Particle Embedded Nanofibrous Scaffolds Sustain Biological Factors For Tendon Tissue Engineering, Chiara Rinoldi, Ewa Kijeńska-Gawrońska, Marcin Heljak, Jakub Jaroszewicz, Artur Kamiński, Ali Khademhosseini, Ali Tamayol, Wojciech Swieszkowski 2023 Warsaw University of Technology

Mesoporous Particle Embedded Nanofibrous Scaffolds Sustain Biological Factors For Tendon Tissue Engineering, Chiara Rinoldi, Ewa KijeńSka-GawrońSka, Marcin Heljak, Jakub Jaroszewicz, Artur KamińSki, Ali Khademhosseini, Ali Tamayol, Wojciech Swieszkowski

Department of Mechanical and Materials Engineering: Faculty Publications

In recent years, fiber-based systems have been explored in the frame of tissue engineering due to their robustness in recapitulating the architecture and mechanical properties of native tissues. Such scaffolds offer anisotropic architecture capable of reproducing the native collagen fibers’ orientation and distribution. Moreover, fibrous constructs might provide a biomimetic environment for cell encapsulation and proliferation as well as influence their orientation and distribution. In this work, we combine two fiber fabrication techniques, such as electrospinning and wet-spinning, in order to obtain novel cell-laden 3D fibrous layered scaffolds which can simultaneously provide: (i) mechanical support; (ii) suitable microenvironment for 3D …


A Strong And Ductile Cobalt-Free Solid-Solution Fe30ni30mn30cr10 Multi-Principal Element Alloy From Hot Rolling, Hans Pommerenke, Jiaqi Duan, Nathan Curtis, Victor DeLibera, Adam Bratten, Andrew Hoffman, Mario Buchely, Ronald O'Malley, Haiming Wen 2023 Missouri University of Science and Technology

A Strong And Ductile Cobalt-Free Solid-Solution Fe30ni30mn30cr10 Multi-Principal Element Alloy From Hot Rolling, Hans Pommerenke, Jiaqi Duan, Nathan Curtis, Victor Delibera, Adam Bratten, Andrew Hoffman, Mario Buchely, Ronald O'Malley, Haiming Wen

Materials Science and Engineering Faculty Research & Creative Works

Most of the face-centered cubic (FCC) multi-principal element alloys (MPEAs) developed thus far contain cobalt. for many applications, it is either required or beneficial to avoid cobalt, since cobalt has long-term activation issue (for nuclear applications), is expensive, and is considered a critical material. in addition, FCC structured solid-solution MPEAs tend to have relatively low strength. an FCC solid-solution Fe30Ni30Mn30Cr10 (at %) MPEA was fabricated via arc melting, followed by homogenization at 1100 °C for 12 h. the alloy was hot rolled at 1100 °C with a total reduction of up to 97 %. the microstructure was characterized, and mechanical …


Nitric Oxide: Physiological Functions, Delivery, And Biomedical Applications, Syed Muntazir Andrabi, Navatha Shree Sharma, Anik Karan, S. M. Shatil Shahriar, Brent Cordon, Bing Ma, Jingwei Xie 2023 University of Nebraska Medical Center

Nitric Oxide: Physiological Functions, Delivery, And Biomedical Applications, Syed Muntazir Andrabi, Navatha Shree Sharma, Anik Karan, S. M. Shatil Shahriar, Brent Cordon, Bing Ma, Jingwei Xie

Department of Mechanical and Materials Engineering: Faculty Publications

Nitric oxide (NO) is a gaseous molecule that has a central role in signaling pathways involved in numerous physiological processes (e.g., vasodilation, neurotransmission, inflammation, apoptosis, and tumor growth). Due to its gaseous form, NO has a short half-life, and its physiology role is concentration dependent, often restricting its function to a target site. Providing NO from an external source is beneficial in promoting cellular functions and treatment of different pathological conditions. Hence, the multifaceted role of NO in physiology and pathology has garnered massive interest in developing strategies to deliver exogenous NO for the treatment of various regenerative and biomedical …


Design And Development Of Ultrabroadband, High-Gain, And High-Isolation Thz Mimo Antenna With A Complementary Split-Ring Resonator Metamaterial, Ammar Armghan, Khaled Aliqab, Meshari Alsharari, Osamah Alsalman, Juveriya Parmar, Shobhit K. Patel 2023 Jouf University

Design And Development Of Ultrabroadband, High-Gain, And High-Isolation Thz Mimo Antenna With A Complementary Split-Ring Resonator Metamaterial, Ammar Armghan, Khaled Aliqab, Meshari Alsharari, Osamah Alsalman, Juveriya Parmar, Shobhit K. Patel

Department of Mechanical and Materials Engineering: Faculty Publications

The need for high-speed communication has created a way to design THz antennas that operate at high frequencies, speeds, and data rates. In this manuscript, a THz MIMO antenna is designed using a metamaterial. The two-port antenna design proposed uses a complementary splitring resonator patch. The design results are also compared with a simple patch antenna to show the improvement. The design shows a better isolation of 50 dB. A broadband width of 8.3 THz is achieved using this complementary split-ring resonator design. The percentage bandwidth is 90%, showing an ultrabroadband response. The highest gain of 10.34 dB is achieved …


Restoration Of Normal Blood Flow In Atherosclerotic Arteries Promotes Plaque Stabilization, Morgan A. Schake, Ian McCue, Evan T. Curtis, Thomas J. Ripperda Jr., Samuel Harvey, Bryan T. Hackfort, Anna Fitzwater, Yiannis S. Chatzizisis, Forrest Kievit, Ryan M. Pedrigi 2023 University of Nebraska- Lincoln

Restoration Of Normal Blood Flow In Atherosclerotic Arteries Promotes Plaque Stabilization, Morgan A. Schake, Ian Mccue, Evan T. Curtis, Thomas J. Ripperda Jr., Samuel Harvey, Bryan T. Hackfort, Anna Fitzwater, Yiannis S. Chatzizisis, Forrest Kievit, Ryan M. Pedrigi

Department of Mechanical and Materials Engineering: Faculty Publications

Blood flow is a key regulator of atherosclerosis. Disturbed blood flow promotes atherosclerotic plaque development, whereas normal blood flow protects against plaque development. We hypothesized that normal blood flow is also therapeutic, if it were able to be restored within atherosclerotic arteries. Apolipoprotein E-deficient (ApoE-/-) mice were initially instrumented with a blood flow-modifying cuff to induce plaque development and then five weeks later the cuffwas removed to allowrestoration of normal blood flow. Plaques in decuffed mice exhibited compositional changes that indicated increased stability compared to plaques in mice with the cuff maintained. The therapeutic benefit of decuffingwas comparable …


The Center For Centering Dome, Olek Piechaczek, Ryan M. Scharf 2023 California Polytechnic State University, San Luis Obispo

The Center For Centering Dome, Olek Piechaczek, Ryan M. Scharf

Architectural Engineering

The Center for Centering seeks to create a large-scale healing center, conducive to individual centering of the mind and body. This mobile installation provides a relaxing, enclosed space while still maintaining a connection to the outdoors. The clients liked the idea of having a pop-up installation that could be easily set up as a touring display. With a deadline for installation looming in June 2022, a team of students had five months to design and manufacture the structure.

In winter 2022, the students developed custom geometry to minimize the number of individual parts and built a ¼ scale model of …


Exploring The Intersection Of Biology And Design For Product Innovations, Ajay P. Malshe, Salil Bapat, Kamlakar Rajurkar, Ang Ang, Jean-Marc Linares 2023 Purdue University

Exploring The Intersection Of Biology And Design For Product Innovations, Ajay P. Malshe, Salil Bapat, Kamlakar Rajurkar, Ang Ang, Jean-Marc Linares

Department of Mechanical and Materials Engineering: Faculty Publications

Design, development, productization, and applications of advanced product concepts are pressing for higher multifunctionality, resilience, and maximization of available resources equitably to meet the growing and continuing demands of global customers. These demands have further accelerated during the recent COVID- 19 pandemic and are continuing to be a challenge. Engineering designs are one of the most effective ways to endow products with functions, resilience, and sustainability. Biology, through millions of years of evolution, has met these acute requirements under severe resource and environmental constraints. As the manufacturing of products is reaching the fundamental limits of raw materials, labor, and resource …


Self-Assembly Of Exfoliated Graphene Flakes As Anticorrosive Coatings For Additive Manufactured Steels, Kaleb Hood, Wen Qian, Yi Xia, Savannah Krupa, Annie Dao, Sarah Ahmed, Samuel Olson, Nam Nguyen, Joseph A. Turner, Jun Jiao 2023 Portland State University

Self-Assembly Of Exfoliated Graphene Flakes As Anticorrosive Coatings For Additive Manufactured Steels, Kaleb Hood, Wen Qian, Yi Xia, Savannah Krupa, Annie Dao, Sarah Ahmed, Samuel Olson, Nam Nguyen, Joseph A. Turner, Jun Jiao

Department of Mechanical and Materials Engineering: Faculty Publications

This study demonstrates the feasibility of using liquid exfoliation of expandable graphite into multilayer exfoliated graphene flakes (EGFs) to form a self-assembled thin film on an air–water interface. The film can coat the surface of additive manufactured (AM) steel substrates to enhance surface properties, specifically AM 316 stainless-steel (AM316), AM 8620 steel (AM8620), and samples of the same alloys made by conventional manufacturing (CM) processes. Liquid exfoliation offers a high yield route for an EGF coating that can cover up to 95% of the sample surface with a single application. The thin, flexible EGFs can coat a rough AM metal …


Exploring Methods For Recycling Filament Waste In 3d Printing, Max Rios Carballo 2023 CUNY, New York City College of Technology

Exploring Methods For Recycling Filament Waste In 3d Printing, Max Rios Carballo

Publications and Research

The goal of the current study is to investigate cutting-edge techniques for recycling filament waste from 3D printing procedures. Appropriate waste management techniques are required to reduce this trash's harmful environmental consequences. The goal of the project is to look at new methods for recycling filament waste in order to minimize disposal and encourage reuse. To acquire data from pertinent papers and research, a thorough literature review methodology was used. The findings show that this issue may be resolved utilizing a variety of recycling techniques, including shredding, melting, and re-extrusion. The type of filament waste and the intended goal will …


Machinability Of High Mn Steel Using Tool Life Criteria, Dika Handayani, Victor F. Okhuysen, Nicole Wagner 2023 California State Polytechnic University - Pomona

Machinability Of High Mn Steel Using Tool Life Criteria, Dika Handayani, Victor F. Okhuysen, Nicole Wagner

Engineering Faculty Articles and Research

High Mn steel alloys have shown to provide both high strength and ductility. However, current literature offers limited guidance on the machinability of these steel alloys. Therefore, this work provides turning recommendations for high Mn steel that is based on tool life data. Several indexable carbide inserts with various rake angles were used to machine cast billets of high Mn steel. Turning characteristics from various feed rates, cutting speeds, and depths of cut were analyzed. Through a design of experiments, it was determined that the feed rate was the most significant factor affecting tool life and that a tool with …


Enhancing Compatibility And Mechanical Properties Of Natural Rubber Composites, Krisma Yessi Sianturi, Adam Febriyanto Nugraha, Belle kristaura, Mochamad Chalid 2023 University of Indonesia

Enhancing Compatibility And Mechanical Properties Of Natural Rubber Composites, Krisma Yessi Sianturi, Adam Febriyanto Nugraha, Belle Kristaura, Mochamad Chalid

Journal of Materials Exploration and Findings

Pure natural rubber (NR) exhibits low mechanical properties, necessitating the incorporation of additives like vulcanizing agents and fillers. Carbon black and silica, conventional fillers, are relatively expensive and not environmentally friendly. This study explores using Oil Palm Empty Fruit Bunch (OPEFB) fiber as an affordable, abundant, and biodegradable alternative filler for NR. However, compatibility issues arise between the nonpolar NR and the polar OPEFB fiber. A latex-starch hybrid coupling agent (CA (NR-St)) was added to the composite formulation to address this. NR, OPEFB fiber, and the coupling agent were mixed using an open roll mill with a 10 phr OPEFB …


Characterization Of Novel Self-Healing Polymer Blends For Additive Manufacturing, Truman James Word 2023 University of Texas at El Paso

Characterization Of Novel Self-Healing Polymer Blends For Additive Manufacturing, Truman James Word

Open Access Theses & Dissertations

This dissertation begins with an overview of novel polymer systems which have been developed by the Polymer Extrusion Lab at the University of Texas at El Paso. Many composite polymer systems have been created using many different polymers as well as ceramics and metals primarily in the form of powders added to the bulk polymer. The bulk of this work entails a study that was conducted to develop and characterize the mechanical, shape memory and self-healing properties of three polymer blends: polylactic acid (PLA) combined with maleated styrene-ethylene-butylene-styrene (SEBS-g-MA), acrylonitrile butadiene styrene (ABS) combined with maleated styrene-ethylene-butylene-styrene (SEBS-g-MA), and polylactic …


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