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Growth And Analysis Of Micro And Nano Cdte Arrays For Solar Cell Applications, Brandon Adrian Aguirre 2014 University of Texas at El Paso

Growth And Analysis Of Micro And Nano Cdte Arrays For Solar Cell Applications, Brandon Adrian Aguirre

Open Access Theses & Dissertations

CdTe is an excellent material for infrared detectors and photovoltaic applications. The efficiency of CdTe/CdS solar cells has increased very rapidly in the last 3 years to ~20% but is still below the maximum theoretical value of 30%. Although the short-circuit current density is close to its maximum of 30 mA/cm2, the open circuit voltage has potential to be increased further to over 1 Volt. The main limitation that prevents further increase in the open-circuit voltage and therefore efficiency is the high defect density in the CdTe absorber layer. Reducing the defect density will increase the open-circuit voltage above 1 …


Biomechanical Strain As A Trigger For Pore Formation In Schlemm’S Canal Endothelial Cells, Sietse T. Braakman, Ryan M. Pedrigi, A. Thomas Read, James A. E. Smith, W. Daniel Stamer, C. Ross Ethier, Darryl R. Overby 2014 Imperial College London

Biomechanical Strain As A Trigger For Pore Formation In Schlemm’S Canal Endothelial Cells, Sietse T. Braakman, Ryan M. Pedrigi, A. Thomas Read, James A. E. Smith, W. Daniel Stamer, C. Ross Ethier, Darryl R. Overby

Department of Mechanical and Materials Engineering: Faculty Publications

The bulk of aqueous humor passing through the conventional outflow pathway must cross the inner wall endothelium of Schlemm’s canal (SC), likely through micron-sized transendothelial pores. SC pore density is reduced in glaucoma, possibly contributing to obstructed aqueous humor outflow and elevated intraocular pressure (IOP). Little is known about the mechanisms of pore formation; however, pores are often observed near dome-like cellular outpouchings known as giant vacuoles (GVs) where significant biomechanical strain acts on SC cells. We hypothesize that biomechanical strain triggers pore formation in SC cells. To test this hypothesis, primary human SC cells were isolated from three non-glaucomatous …


Altered Mechanobiology Of Schlemm’S Canal Endothelial Cells In Glaucoma, Darryl R. Overby, Enhua H. Zhou, Rocio Vargas-Pinto, Ryan M. Pedrigi, Rudolf Fuchshofer, Sietse T. Braakman, Ritika Gupta, Kristin M. Perkumas, Joesph M. Sherwood, Amir Vahabikashi, Quynh Dang, Jae Hun Kim, C. Ross Ethier, W. Daniel Stamer, Jeffrey J. Fredberg, Mark Johnson 2014 Imperial College London

Altered Mechanobiology Of Schlemm’S Canal Endothelial Cells In Glaucoma, Darryl R. Overby, Enhua H. Zhou, Rocio Vargas-Pinto, Ryan M. Pedrigi, Rudolf Fuchshofer, Sietse T. Braakman, Ritika Gupta, Kristin M. Perkumas, Joesph M. Sherwood, Amir Vahabikashi, Quynh Dang, Jae Hun Kim, C. Ross Ethier, W. Daniel Stamer, Jeffrey J. Fredberg, Mark Johnson

Department of Mechanical and Materials Engineering: Faculty Publications

Increased flow resistance is responsible for the elevated intraocular pressure characteristic of glaucoma, but the cause of this resistance increase is not known. We tested the hypothesis that altered biomechanical behavior of Schlemm’s canal (SC) cells contributes to this dysfunction. We used atomic force microscopy, optical magnetic twisting cytometry, and a unique cell perfusion apparatus to examine cultured endothelial cells isolated from the inner wall of SC of healthy and glaucomatous human eyes. Here we establish the existence of a reduced tendency for pore formation in the glaucomatous SC cell—likely accounting for increased outflow resistance—that positively correlates with elevated subcortical …


Polymer Aggregation Correlated Transition From Schottky-Junction To Bulk Heterojunction Organic Solar Cells, Bin Yang, Zhengguo Xiao, Jinsong Huang 2014 University of Nebraska–Lincoln

Polymer Aggregation Correlated Transition From Schottky-Junction To Bulk Heterojunction Organic Solar Cells, Bin Yang, Zhengguo Xiao, Jinsong Huang

Department of Mechanical and Materials Engineering: Faculty Publications

The fullerene-based organic Schottky-junction solar cells have recently attracted intensive research interest because of their unique electrical performance, such as significant photocurrent generation from excitons created in fullerenes and large open-circuit voltage (VOC) output induced by high Schottky-barrier height between the anode and the fullerene acceptor. This manuscript reports another remarkably appealing advantage that the fullerene-based Schottky-junction solar cells are more stable than the bulk heterojunction counterparts. The better stability is likely due to mitigative polymer photo-oxidation and/or little morphological change of active film in the aged Schottky-junction devices. The transition from Schottky-junction to bulk heterojunction appears at …


Combustion Synthesis Of Molybdenum Silicides And Borosilicides For Ultrahigh-Temperature Structural Applications, Mohammad Shafiul Alam 2014 University of Texas at El Paso

Combustion Synthesis Of Molybdenum Silicides And Borosilicides For Ultrahigh-Temperature Structural Applications, Mohammad Shafiul Alam

Open Access Theses & Dissertations

Molybdenum silicides and borosilicides are promising structural materials for gas-turbine power plants. A major challenge, however, is to simultaneously achieve high oxidation resistance and acceptable mechanical properties at high temperatures. For example, molybdenum disilicide (MoSi2) has excellent oxidation resistance and poor mechanical properties, while Mo-rich silicides such as Mo5Si3 (called T1) have much better mechanical properties but poor oxidation resistance. One approach is based on the fabrication of MoSi2−T1 composites that combine high oxidation resistance of MoSi2 and good mechanical properties of T1. Another approach involves the …


Design Of Three Different Particle Size Distributions In Silver Paste Through Computer Simulation For Higher Electrical Conductivity, Kyungdeok Jang 2014 University of Texas at El Paso

Design Of Three Different Particle Size Distributions In Silver Paste Through Computer Simulation For Higher Electrical Conductivity, Kyungdeok Jang

Open Access Theses & Dissertations

In the field of printed electronics technology, researchers have tried to print highly conductive electrodes with fine width and height in order to manufacture high performance devices.

The purpose of this research is to print particle monolayer silver patterns which have better electrical conductivity than existing ones. The key idea of this experiment is to analyze silver inks with different sized particles. Let us consider a particle monolayer pattern printed with silver ink consisting of mono-sized particles. Inside of the pattern, there are some vacant spaces between the particles, which can lead to low electrical conductivity and discontinuity of the …


Fabrication Of A Nickel-Based Superalloy In Electron Beam Melting And Process Improvements Using Thermal Feedback From A Multi-Wavelength Pyrometer, Jonathan Minjares 2014 University of Texas at El Paso

Fabrication Of A Nickel-Based Superalloy In Electron Beam Melting And Process Improvements Using Thermal Feedback From A Multi-Wavelength Pyrometer, Jonathan Minjares

Open Access Theses & Dissertations

The focus of this research was to fabricate parts composed of a nickel-based superalloy containing high levels of aluminum and titanium (NSAT) by using electron beam melting (EBM) additive manufacturing (AM) technology and utilizing thermal feedback from a multi-wavelength pyrometer to perform process improvements leading to near defect-free parts. EBM is an AM technology that utilizes metal powder to fabricate parts in layer-by-layer manner. A multi-wavelength pyrometer was implemented in an Arcam S12 (Arcam AB, Sweden) EBM system to observe and record surface temperatures throughout fabrication. Temperature data from the EBM system and the multi-wavelength pyrometer were graphed using MATLAB …


Effect Of Rhenium On Short Term Oxidation Of Niobium Based Alloys For High Temperature Applications, Ruth M. Sierra 2014 University of Texas at El Paso

Effect Of Rhenium On Short Term Oxidation Of Niobium Based Alloys For High Temperature Applications, Ruth M. Sierra

Open Access Theses & Dissertations

The effect of adding Re to Nb-based alloys and is intended to analyze in depth the microstructures of Nb based alloys with Re, Si and Cr additions, in atomic percentages. The binary alloys (Nb-5Re, Nb-5Si and Nb-5Cr) reveal the formation of a single phase, NbSS, NbSS+ Nb3Si and NbSS+NbCr2 respectively. The formation of the single phase was confirmed by TEM studies for the Nb-5Re alloy. Addition of Re to form ternary alloys, has helped in the formation of Nb5Si3 and (Nb, Re) Cr2, in Nb-5Re- 5Si and Nb-5Re-5Cr respectively. Quaternary alloy Nb-5Re-5Si-5Cr has Nb5Si3, NbCr2 and NbSS. The oxidation behavior …


Nanometric Structure-Property Relationship In Hafnium Oxide Thin Films Made By Sputter-Deposition, Mirella Vargas 2014 University of Texas at El Paso

Nanometric Structure-Property Relationship In Hafnium Oxide Thin Films Made By Sputter-Deposition, Mirella Vargas

Open Access Theses & Dissertations

Hafnium oxide (HfO2) is technologically an important material, which exhibits a unique set of properties such as a high dielectric constant (k~25) and wide band gap (~5.7 eV) which make this material attractive in the fields of microelectronics and optoelectronics. HfO2 has become the leading candidate to replace SiO2 dielectrics in gate oxides due to a higher permittivity and reportedly lower electron tunneling effects. HfO2 exhibits various polymorphs; the thermodynamic stability and phase existence depends on the temperature and pressure conditions. In addition, the controlled growth and manipulation of specific HfO2 crystal structures at the nanoscale dimensions is the driving …


Characterization Of High-Purity Niobium Structures Fabricated Using The Electron Beam Melting Process, Cesar Adrian Terrazas 2014 University of Texas at El Paso

Characterization Of High-Purity Niobium Structures Fabricated Using The Electron Beam Melting Process, Cesar Adrian Terrazas

Open Access Theses & Dissertations

Additive Manufacturing (AM) refers to the varied set of technologies utilized for the fabrication of complex 3D components from digital data in a layer-by-layer fashion. The use of these technologies promises to revolutionize the manufacturing industry. The electron beam melting (EBM) process has been utilized for the fabrication of fully dense near-net-shape components from various metallic materials. This process, catalogued as a powder bed fusion technology, consists of the deposition of thin layers (50 - 120µm) of metallic powder particles which are fused by the use of a high energy electron beam and has been commercialized by Swedish company Arcam …


Influence Of Microstructure On The Propagation Of Fatigue Cracks In Inconel 617, Benjiman Michael Albiston 2013 Boise State University

Influence Of Microstructure On The Propagation Of Fatigue Cracks In Inconel 617, Benjiman Michael Albiston

Boise State University Theses and Dissertations

Inconel 617 is a candidate material for use in the intermediate heat exchanger of the Next Generation Nuclear Plant. Because of the high temperatures and the fluctuations in stress and temperature, the fatigue behavior of the material is important to understand. The goal of this study was to determine the influences of the microstructure during fatigue crack propagation. For this investigation, Inconel 617 compact tension samples, fatigue tested by Julian Benz at the Idaho National Laboratory, were obtained. The testing conditions included two environments at 650 °C (lab air and impure-He) and varied testing parameters including: loading waveform (triangular, trapezoidal), …


Mode I Fracture Toughness Of Eight-Harness-Satin Carbon Cloth Weaves For Co-Cured And Post-Bonded Laminates, Josh E. Smith 2013 California Polytechnic State University, San Luis Obispo

Mode I Fracture Toughness Of Eight-Harness-Satin Carbon Cloth Weaves For Co-Cured And Post-Bonded Laminates, Josh E. Smith

Master's Theses

Mode I interlaminar fracture of 3k 8-Harness-Satin Carbon cloth, with identical fill and weft yarns, pre-impregnated with Newport 307 resin was investigated through the DCB test (ASTM D5528). Crack propagations along both the fill and weft yarns were considered for both post-bonded (co-bonded) and co-cured laminates. A patent-pending delamination insertion method was compared to the standard Teflon film option to assess its applicability to mode I fracture testing. The Modified Beam Theory, Compliance Calibration method, and Modified Compliance Calibration method were used for comparative purposes for these investigations and to evaluate the validity of the proposed Equivalent Stiffness (EQS) method. …


Kolsky Bar Experiment For High-Rate Large Deformations Of Polycarbonate, Jason Gerald Vogeler 2013 University of Nebraska-Lincoln

Kolsky Bar Experiment For High-Rate Large Deformations Of Polycarbonate, Jason Gerald Vogeler

Department of Engineering Mechanics: Dissertations, Theses, and Student Research

Polycarbonate (PC) is a tough, transparent engineering thermoplastic. Its impact strength and ability undergo large plastic deformations without shatter make PC an ideal protective material for impact-resilient eyewear, aircraft windows and transparent armor. A good understanding of the response of this material to large deformations at high strain rates is critical for its utilization in these applications. To this end, a striker-less Kolsky bar device is employed in this work for the needed material characterization. The apparatus allow impulsive torsion and/or compression loadings with pulse durations sufficiently long for the plastic flow behavior to develop fully. Three new testing techniques …


Ergonomichandle And Articulating Laparoscopictool, M. Susan Hallbeck, Dmitry Oleynikov, Kathryn Done, Tim Judkins, Allison DiMartino, Jonathan Morse, Lawton N. Verner 2013 Lincoln, NE

Ergonomichandle And Articulating Laparoscopictool, M. Susan Hallbeck, Dmitry Oleynikov, Kathryn Done, Tim Judkins, Allison Dimartino, Jonathan Morse, Lawton N. Verner

Department of Mechanical and Materials Engineering: Faculty Publications

The present invention relates to a laparoscopic apparatus. The apparatus includes a handle having a body portion, a top surface, opposite bottom surface, a proximal and distal end. The top surface of the base is contoured to compliment the natural curve of the palm. The apparatus further includes a shaft projecting from the distal end of the handle. The shaft has a proximal and distal end. A control sphere is located on the handle. The control sphere can be moved by one or more of a user's fingers to indicate direction. An end effector is located at the distal end …


Scalar Differential Equation For Slowly-Varying Thickness-Shear Modes In At-Cut Quartz Resonators With Surface Impedance For Acoustic Wave Sensor Application, Huijing He, Jiashi Yang, John A. Kosinski 2013 University of Nebraska-Lincoln

Scalar Differential Equation For Slowly-Varying Thickness-Shear Modes In At-Cut Quartz Resonators With Surface Impedance For Acoustic Wave Sensor Application, Huijing He, Jiashi Yang, John A. Kosinski

Department of Mechanical and Materials Engineering: Faculty Publications

For time-harmonic motions, we generalize a 2-D scalar differential equation derived previously by Tiersten for slowly-varying thickness-shear vibrations of AT-cut quartz resonators. The purpose of the generalization is to include the effects of surface acoustic impedance from, e.g., mass layers or fluids for sensor applications. In addition to the variation of fields along the plate thickness, which is considered in the usual 1-D acoustic wave sensor models, the equation obtained also describes in-plane variations of the fields, and therefore can be used to study the vibrations of finite plate sensors with edge effects. The equation is compared with the theory …


Compression Testing And Failure Modes Of Steel-Concrete Composite (Sc) Structures For Nuclear Containment, Patrick Michael Wanamaker, Amit H. Varma 2013 Purdue University

Compression Testing And Failure Modes Of Steel-Concrete Composite (Sc) Structures For Nuclear Containment, Patrick Michael Wanamaker, Amit H. Varma

The Summer Undergraduate Research Fellowship (SURF) Symposium

Although being able to provide much cleaner power than burning coal and other fossil fuels, nuclear power plants are still a tough sell to the general public due to their history of being spontaneously dangerous. The containment structures surrounding these nuclear plants, however, can play a huge role in reducing the risks associated with them. Relatively new designs for these containment assemblies, known as SC (steel-concrete composite) structures, aim to increase the strength and durability of the containment facilities while keeping costs down. By varying the spacing between shear studs, the ratio of concrete to steel, and the ratio of …


Code Optimization For Phase Field Method, Sergio Andres Monsalve, Marisol Koslowski 2013 EAFIT University

Code Optimization For Phase Field Method, Sergio Andres Monsalve, Marisol Koslowski

The Summer Undergraduate Research Fellowship (SURF) Symposium

The Phase field model method for studying grain dislocation at atomic level after applying an external force to the materials being tested, enables simulate the behavior of different materials after applying stress. With the appropriate numerical method the simulation could change drastically the complexity of the algorithm. Finding the most accurate and stable numerical method for the phase field model give us a considerable improving in the performance of the code used to simulate the phase field dynamic dislocation in larger and more complex simulations can be performed. We made an statistic comparison between the different methods, comparing stability and …


Preparation Of Mesoporous Silica Supported Ruthenium Oxides And The Application And Kinetic Study In The Catalysis Of Water Oxidation, Yang Zhang 2013 Purdue University

Preparation Of Mesoporous Silica Supported Ruthenium Oxides And The Application And Kinetic Study In The Catalysis Of Water Oxidation, Yang Zhang

Open Access Dissertations

Photo-induced water splitting of water into H2 and O2 has been a major focus in the development of clean and renewable energy. The development of viable and efficient catalysts that facilitates O2 production remains the major challenge in the study of the corresponding half-reaction of water oxidation. There are plenty of metal oxides reported active in the catalysis of water oxidation. However, several important performance bench marks of those materials, such as the non-stoichiometric production of O2, slow reaction rate and/or low quantum efficiency, remain to be improved.

Ruthenium oxide (RuO2) has long been known as one of the most …


Fabricating Complex-Shaped Components By Room-Temperature Injection Molding Of Aqueous Ceramic Suspension Gels, Valerie Lynn Wiesner 2013 Purdue University

Fabricating Complex-Shaped Components By Room-Temperature Injection Molding Of Aqueous Ceramic Suspension Gels, Valerie Lynn Wiesner

Open Access Dissertations

Water-based ceramic suspension gels (CeraSGels) effectively produced dense, near-net shape ceramic parts by room-temperature injection molding, a novel processing method based on traditional ceramic injection molding. This alternative method eliminated the need for heating and cooling feedstocks to process, as is required in conventional injection molding, through control of the rheological response of the CeraSGels by simply varying polymer content without the use of any harsh crosslinking or curing agents or further chemical processes. The development of room-temperature injection molding initially focused on forming CeraSGels based on alumina, a readily available model material, in order to optimize suspension preparation and …


Design And Assembly Of Nanostructured Complex Metal Oxide Materials For The Construction Of Batteries And Thermoelectric Devices, Gautam Ganapati Yadav 2013 Purdue University

Design And Assembly Of Nanostructured Complex Metal Oxide Materials For The Construction Of Batteries And Thermoelectric Devices, Gautam Ganapati Yadav

Open Access Dissertations

Thermoelectric devices and lithium-ion batteries are among the fastest growing energy technologies. Thermoelectric devices generate energy from waste heat, whereas lithium-ion batteries store energy for use in commercial applications. Two different topics are bound with a common thread in this thesis - nanotechnology! In fact, nanostructuring is a more preferred term for the approach I have taken herein. Another commonality between these two topics is the material system I have used to prove my hypotheses - complex metal oxides.

Complex metal oxides can be used for both energy generation and storage as they are stable at high temperatures, are benign …


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