Environmental Engineering Commons^™

Integrated Data Fusion And Mining (Idfm) Technique For Monitoring Water Quality In Large And Small Lakes, Benjamin Vannah

Electronic Theses and Dissertations

Monitoring water quality on a near-real-time basis to address water resources management and public health concerns in coupled natural systems and the built environment is by no means an easy task. Furthermore, this emerging societal challenge will continue to grow, due to the ever-increasing anthropogenic impacts upon surface waters. For example, urban growth and agricultural operations have led to an influx of nutrients into surface waters stimulating harmful algal bloom formation, and stormwater runoff from urban areas contributes to the accumulation of total organic carbon (TOC) in surface waters. TOC in surface waters is a known precursor of disinfection byproducts …

Assessment, Optimization, And Enhancement Of Ultrafiltration (Uf) Membrane Processes In Potable Water Treatment, Christopher Boyd

Electronic Theses and Dissertations

This dissertation reports on research related to ultrafiltration (UF) membranes in drinking water applications. A pilot-scale investigation identified seasonal surface water quality impacts on UF performance and resulted in the development of a dynamic chemically enhanced backwash protocol for fouling management. Subsequent analysis of UF process data revealed limitations with the use of specific flux, transmembrane pressure (TMP), and other normalization techniques for assessing UF process fouling. A new TMP balance approach is presented that identifies the pressure contribution of membrane fouling and structural changes, enables direct process performance comparisons at different operating fluxes, and distinguishes between physically and chemically …

Evaluation Of The Biodegradability And Toxicity Of Pca And Mpca, Juan Rueda

Electronic Theses and Dissertations

The main types of hypergolic propellants used at Kennedy Space Center (KSC) are hydrazine (HZ) and monomethylhydrazine (MMH). HZ and MMH are classified as hazardous materials and they are also known to be potentially carcinogenic to humans; therefore, handling these substances and their waste is strictly regulated. The wastes streams from HZ and MMH have been estimated to be the main hazardous wastes streams at KSC. Currently at KSC these wastes are first neutralized using citric acid and then they are transported on public roads for incineration as hazardous materials. A new method using alpha ketoglutaric acid (AKGA) was proposed …

Development Of A Chemical Kinetic Model For A Fluidized-Bed Sewage Sludge Gasifier, Wyatt Champion

Electronic Theses and Dissertations

As the need for both sustainable energy production and waste minimization increases, the gasification of biomass becomes an increasingly important process. What would otherwise be considered waste can now be used as fuel, and the benefits of volume reduction through gasification are seen in the increased lifespan of landfills. Fluidized-bed gasification is a particularly robust technology, and allows for the conversion of most types of waste biomass. Within a fluidized-bed gasifier, thermal medium (sand) is heated to operating temperature (around 1350°F) and begins to fluidize due to the rapid expansion of air entering the bottom of the reactor. This fluidization …

Near-Road Dispersion Modeling Of Mobile Source Air Toxics (Msats) In Florida, Kurt Westerlund

Electronic Theses and Dissertations

There is a growing public concern that emissions of mobile source air toxics (MSATs) from motor vehicles may pose a threat to human health. At present, no state or federal agencies require dispersion modeling of these compounds, but many agencies are concerned about potential future requirements. Current air pollution professionals are familiar with Federal Highway Administration (FHWA) and U.S. Environmental Protection Agency (EPA) requirements for dispersion modeling to produce predicted concentrations for comparison with appropriate standards. This research examined a method in which the potential near-road concentrations of MSATs were calculated. It was believed that by assessing MSATs in much …

Study Of The Effect Of Surface Morphology On Mass Transfer And Fouling Behavior Of Reverse Osmosis And Nanofiltration Membrane Processes, Yuming Fang

Electronic Theses and Dissertations

Reverse osmosis (RO) and nanofiltration (NF) membranes are pressure driven, diffusion controlled process. The influence of surface characteristics on membrane process performance is considered significant and is not well understood. Current mass transport models generally assume constant mass transfer coefficients (MTCs) based on a homogeneous surface. This work evaluated mass transfer processes by incorporating surface morphology into a diffusion-based model assuming MTCs are dependent on the thickness variation of the membrane’s active layer. To mathematically create such a surface layer, Gaussian random vectors embedded in a software system (MATLAB) were used to generate a three-dimensional ridge and valley active layer …

Using Gis To Delineate Headwater Stream Origins In The Appalachian Coal-Belt Region Of Kentucky, Jonathan A. Villines

Theses and Dissertations--Biosystems and Agricultural Engineering

Human activity such as surface mining can have substantial impacts on the natural environment. Performing a Cumulative Hydrologic Impact Assessment (CHIA) of such impacts on surface water systems requires knowing the location and extent of these impacted streams. The Jurisdictional Determination (JD) of a stream’s protected status under the Clean Water Act (CWA) involves locating and classifying streams according to their flow regime: ephemeral, intermittent, or perennial. Due to their often remote locations and small size, taking a field inventory of headwater streams for surface mining permit applications or permit reviews is challenging. A means of estimating headwater stream location …

A Hydro-Climatic Modeling Framework For Adaptive Water Resources Management In The Great Lakes Basin, Rabi Gyawali

Dissertations, Master's Theses and Master's Reports - Open

This dissertation addresses water resources decision making in the Great Lakes Basin by developing a multi-model framework for climate change impact assessment, including integrated climate and hydrologic modeling. Physically based watershed models, using soil moisture accounting and temperature index (degree-day) snowmelt algorithms, are developed, calibrated and validated to simulate baseflow, snowmelt, and surface runoff under historic conditions. Comparison with an existing model of the Great Lakes basin, the NOAA Large Basin Runoff Model (LBRM), showed improvements resulting from the increased spatial resolution and use of a more process-based snow algorithm in the Hydrologic Engineering Center's Hydrologic Modeling System (HECHMS). As …

Assessment Of Seismic Damage Of Buildings And Related Environmental Impacts, Carley A. Feese

Dissertations, Master's Theses and Master's Reports - Open

Sustainable development has only recently started examining the existing infrastructure, and a key aspect of this is hazard mitigation. To examine buildings under a sustainable perspective requires an understanding of a building's life-cycle environmental costs, including the consideration of associated environmental impacts induced by earthquake damage. Damage repair costs lead to additional material and energy consumption, leading to harmful environmental impacts. Merging results obtained from a seismic evaluation and life-cycle analysis for buildings will give a novel outlook on sustainable design decisions. To evaluate the environmental impacts caused by buildings, long-term impacts accrued throughout a building's lifetime and impacts associated …

Stilling Basin Scour Remediation Using Air Injection And Flat Plate Extension, Rachael Barlock

Dissertations, Master's Theses and Master's Reports - Open

The South Florida Water Management District (SFWMD) is responsible for managing over 2500 miles of waterways and hundreds of water control structures. Many of these control structures are experiencing erosion, known as scour, of the sediment downstream of the structure. Laboratory experiments were conducted in order to investigate the effectiveness of two-dimensional air diffusers and plate extensions (without air injection) on a 1/30 scale model of one of SFWMD gated spillway structures, the S65E gated spillway. A literature review examining the results of similar studies was conducted. The experimental design for this research was based off of previous work done …

Purification Of Sodium Sulfate By Crystallization, Perla Teresita Torres

Open Access Theses & Dissertations

Sodium sulfate can be recovered from a dilute solution by concentrating it by conventional water treatment techniques like reverse osmosis and electrodialysis; however, those processes also concentrate impurities like arsenic. The sodium sulfate would have commercial use if it can be recovered in an arsenic-free form. This study demonstrated that sodium sulfate could be separated from impurities using slow cooling crystallization in a novel apparatus developed and designed during the experimentation. This device is called a heat exchanger crystallizer and allows slow cooling crystallization in order to grow pure crystals of sodium sulfate decahydrate. Crystals grown in the heat exchanger …

Classification Of Irish Beaches To Determine Their Potential For Erosion, Aidan O'Connell

Theses

The objective of this literature review is to gather the relevant information regarding beach characteristics and beach erosion in order to undertake the project development stage of the thesis project. The background information that was reviewed was the different zones that are located on a beach; the functions of a beach and what most beaches are commonly used for; how beaches were formed; the legislation that is related to the beach or any work that is required to be carried out on a beach and some background information on the erosion of beaches.

The most relevant beach characteristics that impact …

Determinants Of Neighborhood Exposure To Extreme Heat: A Spatial Examination Of El Paso And Juárez, 2010, Faraj Mohamad Aboargob

Open Access Theses & Dissertations

Numerous studies have been conducted on the modification of local weather by the urban environment. In studying urban environmental effects on the urban heat island (UHI), researchers have investigated influences such as land use, vegetation density, topography, population density, and neighborhood socioeconomic status. Many studies have used data collected from field observations, while other studies relied solely on computer modeling. This Dissertation research used a spatial analysis approach, which has been less widely employed, to investigate neighborhood level biophysical, built environmental and socio-demographic determinants of the El Paso and Juárez UHI. The research utilized inexpensive data obtained from US and …

An Evaluation Of The Cerro Process As An Efficient Ro Concentrate Management System, Guillermo Guadalupe Delgado

Open Access Theses & Dissertations

The Concentrate Enhanced Recovery Reverse Osmosis (CERRO) Process is a new method to treat RO concentrate and brackish water with high concentrations of silica and calcium sulfate. Prior investigations have shown that the CERRO process can treat this kind of water without fouling or scaling the membranes, but the main factors that allow the system to operate in such conditions were not studied. The research presented here is an evaluation of the CERRO process as an efficient RO concentrate management system. The parameters of operation of the system were evaluated and improved. The precipitation of calcium sulfate was identified as …

Urban Impact Of Dissolved Metals In The Paso Del Norte Segment Of The Rio Grande, Sumayeh Ahmad Freiwan

Open Access Theses & Dissertations

The Paso del Norte segment of the Rio Grande experiences two seasons per year; the (wet) irrigation season and the (dry) non-irrigation season. The goal of this study was to improve the understanding of occurrence and contribution of dissolved metals in this region during the non-irrigation season. The objectives of this study were to (1) evaluate the impact of anthropogenic sources of metals on the Rio Grande water quality during the non-irrigation season, and (2) estimate the metal loads carried by the flow to the downstream region of El Paso. In order to evaluate the surface water quality of the …

Method Development For A Chemical And Biological Analysis Of Glucocorticoids In Wastewater, Maria Carmen Lozano

Open Access Theses & Dissertations

Glucocorticoids are a class of steroid hormones that can either be produced synthetically or naturally by the adrenal glands. The synthetic glucocorticoids are highly prescribed in the United States for their anti-inflammatory and immunosuppressive properties to treat a variety of ailments and diseases; however, these have been implicated in a number of adverse human conditions such as obesity, metabolic syndrome, immune-suppression, delayed puberty, adrenal insufficiency and Cushing Syndrome, among others. Ongoing research has shown that synthetic and natural hormones are transported to aquatic environments via mammalian excretion or wastewater effluent, and as a result, the release of glucocorticoids into the …

Experimental Study On The Fabrication Of Advanced Materials For Energy Applications Using High Energy Mechanical Milling, Ashvin Kumar Narayana Swamy

Open Access Theses & Dissertations

The reaction of aluminum (Al) powder with water has the potential for on demand hydrogen generation. Conventional Al powders, however, react with water slowly due to a highly protective oxide layer on the particle surface. Current methods for Al activation involve harmful and expensive materials. The nano-scale Al powders also remain very expensive and have problems such as a large amount of oxide on the surface. The use of aluminum in an energy generation cycle is also hindered by the fact that, although Al is the most abundant metal in the Earth's crust, its recovery from ore consumes a lot …

Synthetic Asphaltene As A Novel Dye In Dye Sensitized Solar Cells Dsscs, Hassan Sharif

Open Access Theses & Dissertations

This dissertation approves the possibility of the first time use of synthetic asphaltene as new dye in dye sensitized solar cells. In which the conversion efficiency of synthetic asphaltene DSSC has improved up to 2.0 %. Synthetic asphaltene sample was prepared from the starting material as in literature and applied for various solar cell parameters of TiO2 based dyesensitized solar cell DSSC. DSSCs were fabricated using the synthetic asphaltene as dye. Different variables and parameters were carried out to test the photovoltaic performance of the cells, these parameters include open-circuit voltage, short-circuit current; fill factor. The first result was obtained …

Adsorption Of Arsenic, Chromium, And Uranium From Saline Water On Clinoptilolite And The Treatment Of The Spent Regenerant By Duffusion Dialysis, Mutiu Olaitan Tanimola

Open Access Theses & Dissertations

Among various water purification and recycling technologies, adsorption is a fast, inexpensive and universal method. The development of low-cost adsorbents has led to the rapid growth of research interests in this field. The objective of this present study is the optimization of process parameters in adsorption of arsenic, chromium and uranium ions. The adsorption behavior of natural zeolite (clinoptilolite) has been studied in order to determine its applicability in treating water containing arsenic, chromium and uranium. The multiple adsorption of arsenic As (V), trivalent chromium Cr (III)] and uranium (VI) on natural zeolite (clinoptilolite) in single component and multiple component …

The Investigation Of The Practice Of Frugal Innovation Across Cultures And The Introduction Of An Instructional Model For Streamlining The Design Process, Andres Efren Bolanos

Open Access Theses & Dissertations

The central objectives of this dissertation are to analyze frugal innovation, apply foundational methodologies that contribute to product design, and discover the important contextual information for successful development. This dissertation describes a systematic procedure in designing frugally innovated products. The institutional design will encompass environmental, social, and economic impacts into the entire products' life cycle. Also, a comparison is made between two developing nations' contextual factors to reveal the formulation of frugal innovation.