Environmental Engineering Commons^™

Effects Of Solvent Composition And Hydrogen Pressure On The Catalytic Conversion Of 1,2,4,5-Tetrachlorobenzene To Cyclohexane, Margaret Elizabeth Cone

USF Tampa Graduate Theses and Dissertations

Halogenated hydrophobic organic compounds (HHOCs) such as 1,2,4,5-tetrachlorobenzene (TeCB) present a threat to both human health and the environment. The common occurrence and recalcitrant nature of HHOCs as soil contaminants necessitate an effective soil remediation method. Wee and Cunningham (2008, 2011, 2013) proposed a clean-up technology called Remedial Extraction and Catalytic Hydrodehalogenation (REACH), which pairs solvent extraction of HHOC contaminants from soil with catalytic hydrodehalogenation to destroy contaminants. Wee and Cunningham (2008, 2011, 2013) utilized a palladium (Pd) catalyst to hydrodehalogenate TeCB to benzene. However, benzene is still a toxic contaminant. Prior research has demonstrated that Pd-catalyzed hydrodehalogenation (HDH) can …

Modeling Nitrogen Transformations In A Pilot Scale Marine Integrated Aquaculture System, Brian Mccarthy

USF Tampa Graduate Theses and Dissertations

Integrated aquaculture systems (IAS) are a type of recirculating aquaculture systems (RAS) where the wastewater is treated and returned to the fish tanks. The important difference between the two is that in an IAS, wastes from the aquaculture component are recovered as fertilizer to produce an agricultural product whereas in an RAS, waste organics, nutrients and solids are treated and discharged. A pilot marine IAS at Mote Aquaculture Research Park in Sarasota, FL was studied for this project. Water quality monitoring, measurements of fish health and growth rates of fish and plants were performed over a two-year period to determine …

Socioeconomic Factors' And Water Source Features' Effect On Household Water Supply Choices In Uganda And The Associated Environmental Impacts, Christine M. Prouty

USF Tampa Graduate Theses and Dissertations

Over the last twenty years or more, Uganda has benefitted from significant strides in water and sanitation initiated by the United Nations' Millennium Development Goals. While the rapid progress towards development has been vastly beneficial, it is also important that it does not occur at the expense of the environment. The environmental impacts of these water sources must be evaluated and understood. However, to develop a robust understanding of the impact requires inclusion of the community members who use these sources and their perceptions of them. Consequently, the goal of this research is to investigate the interrelationships between socioeconomic factors, …

Community And Household Management Strategies For Water Supply And Treatment In Rural And Peri-Urban Areas In The Developing World, Ryan William Schweitzer

USF Tampa Graduate Theses and Dissertations

Eighty percent of the 780 million people worldwide that access water from an unimproved source live in rural areas. In rural areas, water systems are often managed by community based organizations and many of these systems do not provide service at the designed levels. The Sustainability Analysis Tool developed in Chapter 2 can inform decision making, characterize specific needs of rural communities in the management of their water systems, and identify weaknesses in training regimes or support mechanisms. The framework was tested on 61 statistically representative geographically stratified sample communities with rural water systems in the Dominican Republic. The results …

Evaluation Of A Pilot Land-Based Marine Integrated Aquaculture System, Suzanne Boxman

USF Tampa Graduate Theses and Dissertations

Recirculating aquaculture systems (RAS) produce aquaculture products on land with minimal discharge of waste products and minimal water loss. High costs associated with waste treatment for RAS have triggered the growth of integrated aquaculture systems (IAS) which incorporate macrophytes (aquatic plants) into the treatment train. The objective of this research was to examine a pilot scale inland marine IAS with three different methods for solids treatment: a sand filter followed by a plant bed, only a plant bed, and geotextile bags. Florida Pompano (Trachinotus carolinus) were grown along with Smooth Cordgrass (Spartina alterniflora), Black Needle Rush …

Embodied Energy And Carbon Footprint Of Household Latrines In Rural Peru: The Impact Of Integrating Resource Recovery, Christopher M. Galvin

USF Tampa Graduate Theses and Dissertations

Over seventy percent of the 2.5 billion people who still lack access to basic sanitation worldwide live in rural areas (WHO/UNICEF, 2012). Despite concerns of water scarcity, resource depletion, and climate change little research has been conducted on the environmental sustainability of household sanitation technologies common in rural areas of developing countries or the potential of resource recovery to mitigate the environmental impacts of these systems. The environmental sustainability, in terms of embodied energy and carbon footprint, was analyzed for four household sanitation systems: (1) Ventilated Improved Pit (VIP) latrine, (2) pour-flush latrine, (3) composting latrine, and (4) biodigester latrine. …

Assessment Of A Modified Double Agar Layer Method To Detect Bacteriophage For Assessing The Potential Of Wastewater Reuse In Rural Bolivia, Sakira N. Hadley

USF Tampa Graduate Theses and Dissertations

Water scarcity is a global concern that impacts many developing countries, forcing people to depend on unclean water sources for domestic, agricultural, and industrial needs. Wastewater is an alternative water source that contains nutrients needed for crop growth. Wastewater reuse for agriculture can cause public health problems because of human exposure to pathogens. Pathogen monitoring is essential to evaluate the compliance of wastewater with established World Health Organization (WHO) and U.S. Environmental Protection Agency (EPA) wastewater reuse guidelines. Indicator organisms are commonly used to detect pathogens in water and wastewater because they are quick and easy to measure, non-pathogenic, and …

Effect Of Solids Retention Time On The Denitrification Potential Of Anaerobically Digested Swine Waste, Maureen Njoki Kinyua

USF Tampa Graduate Theses and Dissertations

Three continuously stirred tank reactors (CSTR) were operated in semi continuous mode treating swine waste using anaerobic digestion. The reactors were used to test the effect of solid retention time (SRT) on CH4 yield, total ammonia nitrogen (TAN) concentrations, % volatile solids (VS), chemical oxygen demand (COD) and volatile fatty acids (VFA) removal, readily biodegradable COD concentration and the denitrification potential for the effluent in a biological nutrient removal (BNR) system. During Phase I of the study, the three reactors were operated at the same 28 day SRT for 16 weeks. SRTs were then changed during the 12 week Phase …

Derivation Of A Fuzzy National Phosphorus Export Model Using 84 Irish Catchments, Ahmed Nasr, Michael Bruen

Articles

Implementation of appropriate management strategies to mitigate diffuse phosphorus (P) pollution at the catchment scale is vitally important for the sustainable development of water resources in Ireland. An important element in the process of implementing such strategies is the prediction of their impacts on P concentrations in a catchment using a reliable mathematical model. In this study, a state-of-the-art adaptive neuro-fuzzy inference system (ANFIS) has been used to develop a new national P model capable of estimating average annual ortho-P concentrations at un-gauged catchments. Data from 84 catchments dominated by diffuse P pollution were used in developing and testing the …

Chemical Weathering And Mobility Of Inorganic Species In Dry Disposed Ash: An Insight From Geochemical Fractionation And Physicochemical Analysis, S.A. Akinyemi, W.M. Gitari, A. Akinlua, L.F. Petrik

Coal Combustion and Gasification Products Journal Archive

The burning of low-grade coal produces vast amounts of ash and other solid by-products. In South Africa, coal combustion by-products undergo disposal on land as dry heaps or slurried to dams. In this study, the geochemical partitioning, transport, and mobility of elements in dry disposed ash dumps were investigated using a modified sequential extraction scheme. The chemical and mineralogical compositions of 50 drilled core samples were investigated by X-ray fluorescence (XRF), X-ray diffraction (XRD), and inductively coupled plasma mass spectrometry. Ternary plots of major elements as determined by XRF showed that the 15-year-old and 2-week-old dry disposed ashes are sialic, …

Investigation Of Mercury Use, Release, Deposition, And Exposures In The Tampa Bay Area, Ryan Algernon Michael

USF Tampa Graduate Theses and Dissertations

I investigate the links between mercury use, release, deposition, and population exposure in Tampa Bay, with the focus of identifying levers for reducing population mercury exposures. To achieve this, I investigated the trends in mercury use and release by products and processes in the Tampa Bay area using a Material Flow Analysis. Analysis of USEPA National Emissions Inventory data over time (1999 - 2008) identified relevant air source emission categories, and explored and compared state and regional trends in mercury emissions. To understand source contributions to wet deposited mercury in the Tampa Bay area, I analyzed trends in mercury deposition …

2013 Nebraska Groundwater Quality Monitoring Report

Nebraska Department of Environmental Quality: Reports

The 2001 Nebraska Legislature passed LB329 (Neb. Rev. Stat. §46-1304) which, in part, directed the Nebraska Department of Environmental Quality (NDEQ) to report on groundwater quality monitoring in Nebraska. Reports have been issued annually since December 2001. The text of the statute applicable to this report follows: “The Department of Environmental Quality shall prepare a report outlining the extent of ground water quality monitoring conducted by natural resources districts during the preceding calendar year. The department shall analyze the data collected for the purpose of determining whether or not ground water quality is degrading or improving and shall present the …

Sustainability Of Water And Wastewater Infrastructure: Using A Public-Private Partnership Model For Project Financial Assessment, Rebecca Werner Trotter

Electronic Theses and Dissertations

To supplement current and future budget shortfalls for improvements to water and wastewater infrastructure, Public-Private Partnerships (PPPs or P3) are being advocated by the American Society of Civil Engineers (ASCE) and others as a practical mechanism to ensure financial sustainability. A PPP involves a partnership between a government entity and a concessionaire--consisting of one or more private companies acting as a single, private incorporation--who make an agreement on funding, building, and operating a usually government-provided service, such as drinking water and wastewater infrastructure. This is different from a traditional contract between a government entity and a contractor because the concessionaire …

Runoff Nutrient Transport As Affected By Land Application Method, Swine Growth Stage, And Runoff Rate, J. E. Gilley, Shannon L. Bartelt-Hunt, S. J. Lamb, X. Li, D. B. Marx, D. D. Snow, D. B. Parker, B. L. Woodbury

Department of Agricultural and Biological Systems Engineering: Faculty Publications

This study was conducted to measure the effects of slurry application method, swine growth stage, and flow rate on runoff nutrient transport. Swine slurry was obtained from production units containing grower pigs, finisher pigs, or sows and gilts. The swine slurry was applied using broadcast, disk, or injection methods at a rate required to meet annual nitrogen requirements for corn. Three 30 min simulated rainfall events, separated by 24 h intervals, were applied to the experimental plots at an intensity of 70 mm h^-1. Inflow was applied at the top of each plot in four successive increments after …

Maize Evapotranspiration, Yield Production Functions, Biomass, Grain Yield, Harvest Index, And Yield Response Factors Under Full And Limited Irrigation, Koffi Djaman, Suat Irmak, William R. Rathje, Derrel L. Martin, Dean E. Eisenhauer

Department of Agricultural and Biological Systems Engineering: Faculty Publications

South-central Nebraska is one of the most extensively irrigated areas in the U.S., with over 65,000 active irrigation wells, and maize is the major agronomical crop produced. Maize production in this region requires supplementary irrigation for maximum productivity. Effective on-farm implementation of full and limited irrigation practices for potential improvements of crop productivity requires knowledge of locally developed crop yield response to water functions. In this study, the effects of full and limited irrigation practices on maize (Zea mays L.) plant height, leaf area index (LAI), grain yield and biomass production, actual crop evapotranspiration (ET_a), yield production functions, …

Water Productivity Of Corn And Dry Bean Rotation On Very Fine Sandy Loam Soil In Western Nebraska, William E. Spurgeon, C. Dean Yonts

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Subsurface drip irrigation (SDI) was used to irrigate corn and dry beans in a crop rotation study for four years from 2005 to 2008 to evaluate the accumulative effect of irrigation amount on yield and irrigation water use efficiency (I_WUE). This study was conducted on a very fine sandy loam soil using a short season corn hybrid typical for the area. Four irrigation treatments based on providing a fraction of the estimated crop evapotranspiration (ET_c) were evaluated. The treatments were designed to replace a certain percentage of ET_c and were denoted as I₁₂₅, …

Characterization Of Particulate Matter Concentrations (Pm10, Pm10-2.5, And Pm2.5) At High-Altitude School And Residential Mircroenvironments In Quito, Ecuador, Teresa Montoya

Open Access Theses & Dissertations

Air quality issues in Latin American countries are especially challenging because of the limited availability of resources to address them, lack of stringent standards and the rapid and uncontrolled growth of their cities increasing the number of vehicles on the road and the expansion of the industry. In particular, the city of Quito, Ecuador exacerbates its environmental issues by its high-altitude (2800 m above sea level) coupled by its location around a mountain valley and frequent temperature inversions.

This study focused on evaluating the spatial variation of the PM concentrations and the effectiveness of a central monitoring network in representing …

Modeling And Design Of Photocatalytic Reactors For Air Purification, Yangyang Zhang

USF Tampa Graduate Theses and Dissertations

Photocatalysis is a promising technique for the remediation of indoor air pollution. Photocatalysis utilizes semiconductor photocatalysts (such as TiO₂ or ZnO) and appropriate light to produce strong oxidizing agents (OH*) that are able to break down organic compounds and inactivate bacteria and viruses. The overall goal of the research is to develop an efficient photocatalytic reactor based on mass transfer for indoor air purification. This study has focused on the enhancement of the effectiveness of the photocatalytic process by the introduction of artificial roughness on the reactor catalyst surface. The major effect of artificial roughness elements on the catalytic …

Biological Control Of Manganese In Water Supplies In The Presence Of Humic Acids, Michael S. Snyder

Theses and Dissertations--Civil Engineering

The main objective of this study was to improve our understanding of biological filtration (biofilm type) treatment for manganese (Mn) removal in drinking water. Biological filtration treatment involves biofilms of Mn(II)-oxidizing microorganisms attached to solid filter material that remove and immobilize dissolved Mn(II) in raw water by conversion to black MnO_2(s) precipitates. Mn-biological filtration is an emerging green technology that can serve as an alternative to conventional physicochemical treatments but its full potential is hindered by various factors. These include lack of understanding the: (1) optimal removal conditions for Mn, (2) mechanisms for Mn releases of the accumulated Mn …

Hydrologic Characterization Of A Rain Garden Mitigating Stormwater Runoff From A Commercial Area, John T. Mcmaine

Theses and Dissertations--Biosystems and Agricultural Engineering

Impervious surfaces such as roads, sidewalks, and roofs increase the volume of runoff generated in a watershed. Traditional stormwater management techniques emphasize conveyance of runoff away from impervious surfaces in order to reduce flooding. Rain gardens are becoming popular as a different means to manage stormwater in such a way that runoff is captured and infiltrated onsite rather than conveyed offsite. A stormwater management system consisting of a rainwater harvest system, rain garden, and infiltration chamber was built at the Coca-Cola Refreshments USA, Inc. distribution center in Lexington, Kentucky during the fall of 2011. Precipitation, inflow, and water level were …