Chemistry Commons^™

Nanoparticles As Antioxidant Agents: A Comprehensive Review, Sulyman Olalekan Ibrahim, Halimat Yusuf Lukman, Fatimat Ronke Abdulkadir, Monsurat Yemisi Bello, Yusuf Oloruntoyin Ayipo, Halimah Funmilayo Babamale, Marili Funmilayo Zubair, Olubunmi Atolani

Al-Bahir Journal for Engineering and Pure Sciences

This study seeks to provide a comprehensive overview of the latest progress in the antioxidant properties of nanoparticles. Nanoparticles (NPs) have emerged as a promising tool in several domains of science and industry, including their application as antioxidant agents. The main knowledge gaps seem to be in correctly identifying the make-up of the naturally occurring phytochemicals that give these nano-antioxidants their extraordinary pharmacology and drug-like properties. In many instances, that characterization is done using spectroscopy instrumentation such as fourier-transform Infrared (FT-IR), scanning electron microscope (SEM), and X-ray diffraction analysis (XRD). From literature appraisals, it was discovered that a lot of …

Spectroscopic Characterization, Dft Calculations, In Vitro Pharmacological Potentials, And Molecular Docking Studies Of N, N, O-Schiff Base And Its Trivalent Metal Complexes, Ikechukwu P. Ejidike, Amani Direm, Cemal Parlak, Adebayo A. Adeniyi, Mohammad Azam, Athar Ata, Michael O. Eze, Joshua W. Hollett, Hadley S. Clayton

Michigan Tech Publications, Part 2

In this study, trivalent metal complexes of the category: [M(L)(H2O)nCly] obtained from the interaction of metal3+ ion salts with organic N, N, O-Schiff base (HL) (where: HL = 4-{(Z)-((2-{(E)-((2-hydroxyphenyl)methylidene)amino}ethyl)imino)methyl}-2-methoxyphenol; n, y = 1 or 2 and M = Ti(III), Fe(III), Ru(III), Cr(III) and Al(III)) were synthesized and characterized viz molar conductance, FT-IR, and UV–Vis spectroscopies, elemental analyses, thermal analyses (TGA and DTA), and UV–Vis spectroscopy, theoretical calculations. A distorted octahedral structure around the metal ions was proposed based on the obtained experimental and calculated data. Thermal examination of the complexes signposts the step-by-step disintegration to give the final decomposition product …

Positron Emission Tomography In Oncology And Environmental Science, Samantha Delaney

Dissertations, Theses, and Capstone Projects

The last half century has played witness to the onset of molecular imaging for the clinical assessment of physiological targets. While several medical imaging modalities allow for the visualization of the functional and anatomical properties of humans and living systems, few offer accurate quantitation and the ability to detect biochemical processes with low-administered drug mass doses. This limits how physicians and scientists may diagnose and treat medical issues, such as cancer, disease, and foreign agents.

A promising alternative to extant invasive procedures and suboptimal imaging modalities to assess the nature of a biological environment is the use of positron emission …

Predicting Rheology Of Uv-Curable Nanoparticle Ink Components And Compositions For Inkjet Additive Manufacturing, Cameron D. Lutz

Master's Theses

Inkjet additive manufacturing is the next step toward ubiquitous manufacturing by enabling multi-material printing that can exhibit various mechanical, electronic, and thermal properties. These characteristics are realized in the careful formulation of the inks and their functional materials, but there are many constraints that need to be satisfied to allow optimal jetting performance and build quality when used in an inkjet 3-D printer. Previous research has addressed the desirable rheology characteristics to enable stable drop formation and how the metallic nanoparticles affect the viscosity of inks. The contending goals of increasing nanoparticle-loading to improve material deposition rates while trying to …

Hydrothermal Synthesis Of (C5h14n2)[Cocl4]⸳0.5h2o: Crystal Structure, Spectroscopic Characterization, Thermal Behavior, Magnetic Properties And Biological Evaluation, Sandra Walha, Noureddine Mhadhbi, Basem F. Ali, Abdellah Kaiba, Ahlem Guesmi, Wesam Abd El-Fattah, Naoufel Ben Hamadi, Mark M. Turnbull, Ferdinando Costantino, Houcine Naïli

Chemistry

The organic-inorganic compound (C₅H₁₄N₂)[CoCl₄]⸳0.5H₂O, I, was characterized by various physicochemical techniques. The X-ray diffraction analysis revealed that the compound crystallizes in the centrosymmetric space group C2/c of the monoclinic system. The atomic arrangement the Co(II) complex is built from isolated [CoCl₄]^2– anions, 1-methylpiperazine-1,4-diium [C₅H₁₄N₂]²⁺ cations and free water molecules. The crystal structure study showed that the cohesion of I is assured through N–H···Cl and N–H···O hydrogen bonds giving birth to a 3-D architecture. Hirshfeld surface analysis revealed that Cl···H/H···Cl and …

General Chemistry Ii: Chem 2134, Subha Pratihar

ATU Faculty OER Books and Materials

No abstract provided.

Development And Applications Of Flexible Piezoelectric Nanogenerators Using Batio3, Pdms, And Mwcnts For Energy Harvesting And Sensory Integration In Smart Systems, Islam Uddin Shipu, Dipasree Bhowmick, Nondon Lal Dey

Chemistry Faculty Publications and Presentations

Mechanical energy is a versatile and accessible green energy source, increasingly harnessed to power small-scale devices via innovative flexible piezoelectric nanogenerators (F- PNGs). These devices convert mechanical energy into electricity using lightweight materials such as Barium Titanate (BaTiO3), poly dimethyl siloxane (PDMS), and multi-walled carbon nanotubes (MWCNTs). In this design, BaTiO3 nanoparticles were embedded in a composite film with PDMS and MWCNTs, sandwiched between two copper electrodes. The BaTiO3/PDMS/MWCNT composite PENGs, synthesized for this study, produce an output voltage of ∼8 V through periodic cyclic beating. This represents an increase of about 16% compared to the PENGs without MWCNT doping. …

Moss Biomonitoring Of Lead Emissions From Hillsboro Airport, Daria Kolpakov

University Honors Theses

The objective of this experiment was to use biomonitoring as a method to determine lead concentration levels around Hillsboro Airport in Hillsboro, Oregon. Twenty-two samples were collected within a 2 km radius around Hillsboro Airport using a randomized sampling strategy. The concentrations of lead within the samples were determined using ICP-MS. The average lead concentration was (2.8 ± 5.0) mg/kg with a peak value of 21.6 mg/kg 0.57 km from Hillsboro Airport. As the average lead concentration was substantially skewed, Hillsboro Airport is likely to be the source of the lead increase.

Synthesis Of Dyes Sulfamidazole: Characterization, Evaluation, Molecular Docking And Global Descriptors By Density Functional Theory (Dft)., Athra G. Sager, Jawad Kadhim Abaies, Zeena R. Katoof

Karbala International Journal of Modern Science

In the present work, novel azo compounds of sulfamidazole were created via the reaction of diazonium salt of sulfamidazole with several aromatic molecules including (resorcinol, 2-nitro phenol, 3-nitro phenol, and 4-nitro phenol)) (Z1–Z4). The new compounds (Z1-Z4) were identified using FTIR, ¹HNMR techniques, in addition to melting point measurements. The biological activity of compounds (Z1-Z4) was studied against four kinds of bacteria including E. coli, Klebsiella pneumonia, Salmonella, and Staphylococcus aureus. The findings showed that all compounds (Z1-Z4) were active against the examined bacteria. Theoretical studies of the antibacterial ability of the prepared compound against DNA gyrase enzyme …

2-Tertbutylfuran At 550 And 700 K: A Multiplexed Photoionization Mass Spectrometric Investigation And Determination Of Cross Sections Of A Carbon- Bromine Bond And Various Brominated Organic Compounds, Ameyali Tapia

Master's Theses

This thesis presents the combustion study of 2-tertbutylfuran (2-TBF) in reaction with atomic oxygen (O(3P)). Data was collected at the Advanced Light Source (ALS) of the Lawrence Berkeley National Lab, using tunable vacuum ultraviolet radiation coupled with a multiplexed mass spectrometer to acquire the data. These data were taken at low pressures of 7 and 8 torr at temperatures of 550 K and 700 K, respectively. Primary products of the system were identified and characterized, while reaction pathways of the products are currently being studied to ensure thermodynamic feasibility. Branching fractions of the system were also calculated, to view the …

Anion Binding And Sensing Using Cs124-Sensitized Luminescent Terbium Complexes, Alessandro Rizzi, Minhee Lee, Wade Grabow, Olivia Brooks, Helena Nguyen, Neal Yakelis, Clarisse Vanderfeltz

Honors Projects

Two terbium complexes with varying degrees of intramolecular coordination, Tb:DO2A-Cs124 and Tb:DOTA-Cs124, were prepared. Their capacity to detect biologically and environmentally relevant anions through their luminescence changes was investigated. Tb:DOTA-Cs124 demonstrated exceptional selectivity as a sensor for nitrite, while Tb:DO2A-Cs124 detects nitrite, phosphates, and a range of carboxylate-containing anions.

Molecular-Level Studies Of Nanopatterned Biomolecules With Atomic Force Microscopy, Ashley R. Walker

LSU Doctoral Dissertations

Atomic force microscopy (AFM) is an analytical technique in which a tipped probe is gently scanned across the surface in a raster pattern to generate digital images of a sample at the nanoscale. The AFM instrument has three general operational modes, which are contact, non-contact and tapping-mode, that can be used to examine materials at the atomic level. Single-molecular details of biological molecules and other soft organic materials can be captured with minimal denaturation in either ambient or liquid environments when using tapping-mode AFM. In tapping-mode, the probe is driven to oscillate vertically while the tip is scanned across the …

Investigating Co2 Adsorption Behavior In Metal-Organic Frameworks By Solid-State Nmr, Yan Ham Ng

Electronic Thesis and Dissertation Repository

With increasing demands in controlling carbon dioxide emissions, metal-organic frameworks (MOFs) are considered as promising candidates for CO₂ capture due to their large CO₂ adsorption capacity. In this study, the adsorption behavior of CO₂ molecules in [Zn₂(TRZ)₂(NH₂-BDC)] (TRZ=1,2,4-triazolate, NH₂-BDC=2-amino-1,4-benzenedicarboxylic acid), and CALF-20 are studied. Moreover, water is ubiquitous in the atmosphere and could have a negative impact on the MOF’s gas adsorption. Therefore, understanding the behavior and dynamics of water and CO₂ in MOFs is of fundamental importance. Solid-state nuclear magnetic resonance (SSNMR) is a powerful technique which …

Comparison Of Ligands In Palladium-Catalyzed Electrochemical Allyl 4-Pyridinylation, Wei-Jie Ding, Chun-Hui Yang, Zhong-Tao Feng, Shi-Rong Lu, Xu Cheng

Journal of Electrochemistry

4-CN-pyridine is a widely applied 4-pyridinylation reagent for diverse transformations. Conventionally, the reaction proceeds via an open-shell radical cross-coupling pathway. Following our previous study, in this work, we report the Pd-catalyzed allyl 4-pyrinylation reaction under electrochemical conditions. The reaction proceeds via radical-polar crossover pathway in which the role of phosphine ligand in reactivity and selectivity was extensively investigated.

Nickel-Catalyzed Α-Arylation Of Α-Cyanoacetates Enabled By Electrochemistry, Zi-Meng Li, Zhang-Jian Li, Anat Milo, Ping Fang, Tian-Sheng Mei

Journal of Electrochemistry

β-Amino acids have a wide range of applications in the field of pharmaceuticals. Utilizing a combination strategy of nickel catalysis and paired electrolysis, a catalytic α-arylation protocol of carbonyl compounds has been developed. This protocol affords various a-aryl-a-cyanoacetates, which can be reduced to high-value-added α-aryl-β-amino acids. The cross-coupling reaction of electron-deficient aryl bromides with a-cyanoacetates achieves the expected products with good yields and functional group compatibility under mild conditions. Excessive electron-richness in initial aryl bromides facilitates the self-coupling of desired products. DFT calculations confirm that the presence of electron-rich aryl substitutions decreases the …

Novel In Situ Synthesis Of Copper Oxide Nanoparticles In Epoxy Network: Kinetics, Composite Mechanical And Dielectric Properties, Elena Bobina, Maxim Danilaev, Safaa.M.R.H. Hussein, Sergey Karandashov, Vladimir Kuklin, Ivan Lounev, Konstantin Faizullin

Karbala International Journal of Modern Science

>Mechanical properties of polymer composites with dispersed nanoparticles (CDNP) depend on interaction between the nanoparticles and the polymer matrix. Strength of polymer composites significantly decreases when there is no interaction between dispersed nanoparticles and the polymer. This limits the application of functional polymer composites with dispersed nanoparticles. In this study, CDNP based on ED-20 epoxy resin with dispersed copper oxide nanoparticles was obtained.These nanoparticles were synthesized in epoxy resin before curing: the nanoparticles were obtained by decomposition of copper hydroxide by heating its solution in ED-20 resin.The kinetics of copper oxide nanoparticles formation in CDNP samples were studied using two …

Elm And Lightgbm: A Hybrid Machine Learning Technique With Intelligent Iot To Predict The Cardiovascular Disease, Gorapalli Srinivasa Rao, G Muneeswari

Karbala International Journal of Modern Science

Cardiologists can more accurately classify a patient's condition by performing an accurate diagnostic and prognosis of cardiovascular disease (CVD). The clinical diagnosis, and therapies processes within the medical field have been substantially accelerated by ML-based approaches enabled by IoT-based systems. This structure is based on IoT-based system with enabled ML approach. This study investigates an approach known as ensemble categorization, which enhances the precision of weak algorithms by integrating multiple classifiers. For effective CVD classification, we utilized Ensemble learning machine (ELM) and Light GBM. The appropriate traits are chosen to speed up the categorization process using the Gorilla Troops Optimizer …

Comparing Proliferation Rates And Collagen Production Of Cells Treated With Cuhars, Katie Elizabeth Mckenzie

Master's Theses

Cartilage is the padding in joints that protects the bones and aids in motion. Problems with the cartilage in the knee can be caused by mechanical damage or diseases like osteoarthritis. Chondrocytes make cartilage. The objective of this study is to determine the doubling time of chondrocytes per passage. I also want to determine the base amount of collagen-II created by chondrocytes as they age. I also want to determine how long it takes CuHARS to break down in different cell medias. Chondrocytes, human dermal fibroblasts, and CRL 2303 cells were grown and cultured for over a year. During that …

A Review Of The Toxicity Of Ingredients In E-Cigarettes, Including Those Ingredients Having The Fda's "Generally Recognized As Safe (Gras)" Regulatory Status For Use In Food., Nada O F Kassem, Robert M. Strongin, Andrea M. Stroup, Marielle C. Brinkman, Ahmad El-Hellani, Hanno C. Erythropel, Arash Etemadi, Vernat Exil, Maciej L. Goniewicz, Noura O. Kassem, Theodore P. Klupinski, Sandy Liles, Thivanka Muthumalage, Alexandra Noël, David H. Peyton, Qixin Wang, Multiple Additional Authors

Chemistry Faculty Publications and Presentations

Some firms and marketers of electronic cigarettes (e-cigarettes; a type of electronic nicotine delivery system (ENDS)) and refill liquids (e-liquids) have made claims about the safety of ingredients used in their products based on the term "GRAS or Generally Recognized As Safe" (GRAS). However, GRAS is a provision within the definition of a food additive under section 201(s) (21 U.S.C. 321(s)) of the U.S. Federal Food Drug and Cosmetic Act (FD&C Act). Food additives and GRAS substances are by the FD&C Act definition intended for use in food, thus safety is based on oral consumption; the term GRAS cannot serve …

The Lewis Acidity Of Imidazole-Derived Diaryliodonium Zwitterions, Cyrus Rose

University Honors Theses

Diaryliodonium salts can be used as effective aryl-transfer agents in reactions to form novel molecules with diverse applications including pharmaceuticals and agrochemicals without using harsh reaction conditions and transition metal reagents. In recent years, interest in the applications of the Lewis acidity of iodonium ion catalysts has increased. Despite this, the quantification of the Lewis acidities of diaryliodonium salts are scarce. Even rarer, there has not been much study into the Lewis acidities of zwitterionic diaryliodonium salts. For zwitterions, there is no counter anion that would come into consideration in regard to its Lewis acidity. To expand the understanding of …

Pet And Polyolefin Plastics Supply Chains In Michigan: Present And Future Systems Analysis Of Environmental And Socio-Economic Impacts, Utkarsh S. Chaudhari, Kamand Sedaghatnia, Barbara K. Reck, Kate Maguire, Anne T. Johnson, David Watkins, Robert M. Handler, Tasmin Hossain, Damon S. Hartley, Vicki S. Thompson, Alejandra Peralta, Jenny L. Apriesnig, David Shonnard

Michigan Tech Publications, Part 2

Many actions are underway at global, national, and local levels to increase plastics circularity. However, studies evaluating the environmental and socio-economic impacts of such a transition are lacking at regional levels in the United States. In this work, the existing polyethylene terephthalate and polyolefin plastics supply chains in Michigan were compared to a potential future (‘NextCycle’) scenario that looks at increasing Michigan’s overall recycling rate to 45%. Material flow analysis data was combined with environmental and socio-economic metrics to evaluate the sustainability of these supply chains for the modeled scenarios. Overall, the NextCycle scenario for these supply chains achieved a …

Supplemental Information. Theoretical Rotational And Vibrational Spectral Data For The Hypermagnesium Oxide Species Mg2o And Mg2o+, Athena R. Flint, Brent R. Westbrook, Ryan C. Fortenberry

Faculty and Student Publications

Tables to accompany a forthcoming article in the journal ChemPhysChem.

Chm110 Principles Of Chemistry Lecture Slides, Leah S. Cohen

Open Educational Resources

These modified slides contain information from the first ten chapters from the General, Organic, and Biochemistry: connecting Chemistry to Your Life textbook by Blei & Odian.

Analysing An Imbalanced Stroke Prediction Dataset Using Machine Learning Techniques, Viswapriya Subramaniyam Elangovan, Rajeswari Devarajan, Osamah I. Khalaf, Mhd Saeed Sharif, Wael Elmedany

Karbala International Journal of Modern Science

A stroke is a medical condition characterized by the rupture of blood vessels within the brain which can lead to brain damage. various symptoms may be exhibited when the brain's supply of blood and essential nutrients is disrupted. To forecast the possibility of brain stroke occurring at an early stage using Machine Learning and Deep Learning is the main objective of this study. Timely detection of the various warning signs of a stroke can significantly reduce its severity. This paper performed a comprehensive analysis of features to enhance stroke prediction effectiveness. A reliable dataset for stroke prediction is taken from …

Potential Enhancement Of Microbial Disinfection Using Oxygen Enriched Cold Atmospheric-Pressure Argon (Ar/O2) Plasma Jet, Waleed O. Younis, Mahmoud M. Berekaa, Mostafa A. Ellbban, Abdel-Sattar S. Gadallah, Jamal Q. Almarashi, Abdel-Aleam H. Mohamed

Karbala International Journal of Modern Science

Oxygen activated cold-atmospheric-pressure-argon plasma jet (APPJ) has gained prominence over the regular argon plasma especially in disinfection and decontamination. As an objective of the current research, an oxygen-enriched argon system was built, where plasma produced through a vessel metallic tube that is introduced into alumina one. A sinusoidal high voltage signal of 25 kHz was used to generate plasma jet. Potential impact of oxygen enriched APP jet (Ar/O₂) in decontamination of different microbial cells was observed. For examination, suspension of each tested microbe was placed in contact with plasma jet nearly 10 mm away from the jet nozzle …

A Potential Of Watercress Nasturtium Officinale Bioactive Compounds In Inhibiting Infectious Myonecrosis Virus (Imnv) By Targeting Rna-Dependent Rna Polymerase (Rdrp) Virus From Several Countries: In Silico Approach, Qurrota A’Yunin, Fatchiyah Fatchiyah, Maftuch Maftuch, Feri Eko Hermanto, Muhammad Hermawan Widyananda, Narendra Santika Hartana, Muhaimin Rifa’I, Yoga Dwi Jatmiko

Karbala International Journal of Modern Science

Infectious myonecrosis virus (IMNV) disease causes mass mortality and decreased shrimp production. The RdRp region projects to the interior, where it may function in transcription. The focus of this study was to determine the effect of amino acid polymorphisms from several countries on the structure of RdRp and identify the potential of watercress in inhibiting IMNV by targeting the RdRp protein of IMNV through an in silico approach. The results showed that the structure of the IMNV RdRp protein from Indonesia was similar to Mexico, and the protein structure from India_QDN was identical to India_QIL. Ligand binding affinity values showed …

Extraction Of Morphometric Features The Shape Of Mangrove Leaves Based On Digital Images And Classification Using The Support Vector Machine, Ishak Ariawan, Della Ayu Lestari, Luthfi Anzani, Tri Yanti, Cakra Rahardjo, M. Saleh, Sahril Angga Permana, Dea Aisyah Rusmawati

Karbala International Journal of Modern Science

At present, several botanists still rely on the use of manual estimating methods to assess the carbon content in mangrove. However, these methods have been reported to be extremely time-consuming, showing the need to develop a system for prediction. An effective solution lies in the creation of an artificial intelligence application, which can provide rapid and cost-effective results. In constructing this application, careful consideration must be given to the selection of parameters or attributes. Species is an essential parameter for the assessment of carbon content, but its determination has proven to be challenging due to the similarities of mangrove. The …

Releases Of Hazardous Materials And Waste From Transportation Incidents In The Us: An Analysis To Increase Environmental Resiliency, Elizabeth Irene Tautges

Master's Projects and Capstones

Excessive amounts of hazardous materials and waste are released into the environment from transportation incidents. The United States federal government has regulations on the movement of hazardous material and waste during transportation, but preventing environmental releases is not a major priority. Multiple external factors influence the release of hazardous material and waste into the environment. Transportation incidents can be prevented by modifying the information collected in emergency reports, adjusting transportation patterns and conditions, and expressing negative environmental impacts, preparing responder efforts to communicate effectively. The components of previous hazardous materials and waste releases emphasize the needed improvements for increasing environmental …

Non-Destructive Determination Of Surface Area In Reverse Phase Chromatographic Columns, Margaret Figus

Seton Hall University Dissertations and Theses (ETDs)

Excess adsorption isotherms of acetonitrile and methanol from water were measured on eight commercial columns. Columns used in this study represent the latest examples in column development and include three different poroshell columns (Kinotex C18, Ascentis C18, and Halo C18) as well as conventional columns with significantly different adsorbent geometries (Allure C18, YMC C18) and various hybrid-silica columns (Gemini C18, Xterra C18, and XBridge C18). Comparison of the excess adsorption isotherms measured on all these columns and expressed in surface-specific form demonstrated significant similarity of the adsorption properties of all columns, which allows the introduction of the Standard Excess Adsorption …

Advancing Simultaneous Extraction And Sequential Single-Particle Icp-Ms Analysis For Metallic Nanoparticle Mixtures In Plant Tissues, Lei Xu, Xingmao Ma, John Yang, Joel G. Burken, Paul Ki-Souk Nam, Honglan Shi, Hu Yang

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Engineered Nanoparticles (ENPs) Have Been Increasingly Used in Agricultural Operations, leading to an Urgent Need for Robust Methods to Analyze Co-Occurring ENPs in Plant Tissues. in Response, This Study Advanced the Simultaneous Extraction of Coexisting Silver, Cerium Oxide, and Copper Oxide ENPs in Lettuce Shoots and Roots using Macerozyme R-10 and Analyzed Them by Single-Particle Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). Additionally, the Standard Stock Suspensions of the ENPs Were Stabilized with Citrate, and the Long-Term Stability (Up to 5 Months) Was Examined for the First Time. the Method Performance Results Displayed Satisfactory Accuracies and Precisions and Achieved Low Particle Concentration …