Chemistry Commons^™

Characterization Of Epoxy Resins For Use In The Resin Transfer Molding Process, Christina Kaye Short

Dissertations, Theses, and Masters Projects

No abstract provided.

Cross-Linking Additives As Smoke Suppressants For Poly(Vinyl Chloride), Steven Alfred Terranova

Dissertations, Theses, and Masters Projects

No abstract provided.

Intelligent Processing Of Pmr-15, Sean Michael Hart

Dissertations, Theses, and Masters Projects

No abstract provided.

Thermal Characterization Of Carbon Monoxide Oxidation Catalysts Using Thermogravimetric Analysts And Differential Scanning Calorimetry, Rene A. Bartgis

Chemistry & Biochemistry Theses & Dissertations

Catalysts composed of platinum and/or palladium on tin (IV) oxide supports, with and without silica gel, as well as catalysts composed of gold on manganese oxide, have been developed for the recombination of carbon monoxide and oxygen to form carbon dioxide for use in carbon dioxide lasers. A thermogravimetric method and a differential scanning calorimetric method have been developed for the thermal characterization of these catalysts. The mass loss data and the enthalpy changes determined as the catalysts lost water were then related to existing activity data for these catalysts. No relationship was found between the thermal data and the …

Reactivities Of Some Aromatic Compounds At Supercritical Water Conditions, Chun-Cheng Tsao

Masters Theses

The goals of this study are the removal of nitrogen from the extraction products of coal by Supercritical Water and the development of an understanding of the reactions leading to this removal. Six model compounds with structures similar to the intermediates of the coal liquefaction processes were studied. Benzylamine generated toluene through hydrogen abstraction after the C-N bond rupture. To a lesser extent, the oxidation of the benzylic carbon took place leading to benzene formation. Both reaction pathways occurred with equal probability for benzylidenebenzylamine, producing comparable yields of benzene and toluene. Benzaldehyde generated benzene through the oxidation/decarboxylation sequence. Benzyl alcohol …

The Preparation Of And Upper Atmospheric Effects On Kevlar Films, Patricia Lynne Pate

Dissertations, Theses, and Masters Projects

No abstract provided.

The Imidization Of Pmr-15 Aromatic Thermosetting Polyimide, Thomas Clifton Prettyman

Dissertations, Theses, and Masters Projects

No abstract provided.

Dielectric And Kinetic Analysis Of Thermosetting Polyester Resin, Patricia Haverty Tully

Dissertations, Theses, and Masters Projects

No abstract provided.

The Synthesis Of New Maleimide Addition Polymer Precursors, Richard B. Brown

Chemistry & Biochemistry Theses & Dissertations

1H-2,3-dimethylpyrrolo(1,2-a) benzimidazol-l-one (27) and 1H,9H- 2,3,7,8-tetramethyl-bispyrrolo(1,2-a:6,7-a')benzodiimidazo1-1,9-dione (32) have been synthesized from dimethylmaleic anhydride and o-phenylenediamine and 1,2,4,5-tetraaminobenzene, respectively. The presence of reactive olefinic double bonds in the synthesized compounds was of interest as a site for possible addition polymerization.

The synthetic route involved, in both cases, a simple nucleophilic substitution reaction between the diamine(or tetraamine) and the anhydride to form an intermediate amide-acid-amine which rapidly cyclized to the imide amine. The final ring closure required more rigorous conditions and occurred at melt reaction temperatures.

Investigation Of The Platinum-Rich Portion Of The Platinum-Tantalum Phase Diagram, Bob Dean Browning

Theses and Dissertations

The Pt-Ta binary system was investigated at two isotherms;1000°C and 1500°C, and at eleven alloy compositions in the range of 50 to 100 atomic percent platinum. The alloys were examined by x-ray diffraction and metallography. Three intermetallic compounds, Pt₂Ta, Pt₃Ta, and Pt₄Ta were found to exist in this composition range. The Pt₄Ta intermetallic appeared only at the 1500°C isotherm. Platinum dissolved tantalum substitutionally to 90 atomic percent at 1500 °C and to approximately 80 atomic percent at 1000 °C.

A Calorimetric Investigation Of Zirconium, Titanium, And Zirconium Alloys From 60 To 960°C, James L. Scott

Masters Theses

Structural materials for nuclear reactors must meet three stringent conditions: they must have adequate mechanical properties at the operating temperature, they must be corrosion resistant to the heat transfer medium (air, water, or alkali metals), and they must not absorb neutrons excessively. This last requirement is a particularly stringent one, for it is met by only four accessible metals: aluminum, magnesium, beryllium, and zirconium, as Table I shows.

For reactors which operate at low temperatures, aluminum serves as an excellent constructional material, but it cannot be used for more efficient high-temperature reactors, because of its low elevated temperature strength associated …

Pyrochemical Changes In Missouri Halloysite, Frank Joseph Zvanut

Doctoral Dissertations

"For centuries it has been known that the application of heat to a clay or a clay body produces changes that make it an entirely different substance from the original raw clay. Ever since the earliest civilizations produced crude building brick by baking formed clay bodies in the sun's rays, mankind has been speculating on the nature of the changes that convert soft, friable, plastic clays into hard, strong, non-plastic, rock-like masses. It has been only within the last two decades, however, that progress has been made in the solution of problems dealing with the resultant products in fired clay …

Design Of A Lead Blast Furnace, Walter Irving Phillips, Andrew Jackson Seltzer

Bachelors Theses

"In order to get the approximate size of the Furnace we made the following assumptions, being guided as far as possible by the practice of the Globe Smelting Works at Denver, Colorado whenever that could be ascertained"--page 1.

Analytical Determination Of Copper Products, Charles Dosh Smith

Bachelors Theses

"It is a well known fact that the presence of impurities in copper products has been a source of annoyance to the Chemist. The object of this thesis was to make myself familiar with the actions of different impurities in copper products, and the methods for the determination of Arsenic in the same"--page 1.

Neutralization Of Free Acid (H₃P O₄) In Commercial Mono-Calcium Phosphate (Ca H₄ (Po₄), George William Harris, Harry Adam Grine

Bachelors Theses

"The object of this thesis has been a systematic research based on the characteristic properties and reactions of mono-calcium phosphate, Ca H₄ (PO₄)₂, tending towards the development of a process for neutralizing the free phosphoric acid, H₃PO₄ formed during its manufacture"--page 1.

Action Of Caustic Hydroxides Upon Aluminum, Herbert Fordyce. Rogers

Bachelors Theses

No abstract provided.

Assay Of Copper Matte For Gold And Silver, Walter E. Soest

Bachelors Theses

"Ores containing copper, and especially copper matte, have always been very annoying in assaying for the precious metals. In assaying copper matte, and ores containing much copper, by the usual method of scorification, the losses of silver an gold are considerable, owing to the fact that in order to obtain lead buttons, which are soft and free from copper, repeated scorifications are necessary, and moreover it is impossible to obtain lead buttons which are entirely free from copper"--page 1.

White Lead, Evans Walker Buskett

Bachelors Theses

No abstract provided.

Producer Gas, Edward P. Dwyer

Bachelors Theses

"Producer gas, so named owing to being produced in special forms of apparatus known as Producers. The fuel is decomposed into combustible gases, whereby most of the C is burnt to CO, whilst the H either remains free, or is converted into carburretted Hydrogen. Directly above the grate carbonic anhydride is formed but thus is rapidly converted into carbonic oxide; reaction as follows: CO₂ + C = 2CO.

Amongst these heavy carburetted hydrogen (C₂H₄) is that which principally increases the value of the gas as fuel and the drier the fuel used the more of the gas is produced. A …