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Full-Text Articles in Engineering

A Comparative Study Of Three Inverse Kinematic Methods Of Serial Industrial Robot Manipulators In The Screw Theory Framework, Emre Sariyildiz, Eray Cakiray, Hakan Temeltas Jan 2011

A Comparative Study Of Three Inverse Kinematic Methods Of Serial Industrial Robot Manipulators In The Screw Theory Framework, Emre Sariyildiz, Eray Cakiray, Hakan Temeltas

Faculty of Engineering and Information Sciences - Papers: Part B

In this paper, we compare three inverse kinematic formulation methods for the serial industrial robot manipulators. All formulation methods are based on screw theory. Screw theory is an effective way to establish a global description of rigid body and avoids singularities due to the use of the local coordinates. In these three formulation methods, the first one is based on quaternion algebra, the second one is based on dual-quaternions, and the last one that is called exponential mapping method is based on matrix algebra. Compared with the matrix algebra, quaternion algebra based solutions are more computationally efficient and they need …


On-Chip Stimulated Brillouin Scattering, Ravi Pant, Christopher Poulton, Duk-Yong Choi, Hannah Mcfarlane, Samuel Hile, Enbang Li, Luc Thevenaz, Barry Luther-Davies, Stephen J. Madden, Benjamin J. Eggleton Jan 2011

On-Chip Stimulated Brillouin Scattering, Ravi Pant, Christopher Poulton, Duk-Yong Choi, Hannah Mcfarlane, Samuel Hile, Enbang Li, Luc Thevenaz, Barry Luther-Davies, Stephen J. Madden, Benjamin J. Eggleton

Faculty of Engineering and Information Sciences - Papers: Part A

We demonstrate on-chip stimulated Brillouin scattering (SBS) in an As2S3 chalcogenide rib waveguide. SBS was characterized in a 7cm long waveguide with a cross-section 4μm x 850nm using the backscattered signal and pump-probe technique. The measured Brillouin shift and its full-width at half-maximum (FWHM) linewidth were ~7.7 GHz and 34 MHz, respectively. Probe vs. pump power measurements at the Brillouin shift were used to obtain the gain coefficient from an exponential fit. The Brillouin gain coefficient obtained was 0.715 x 10−9 m/W. A probe gain of 16 dB was obtained for a CW pump power of ~300 mW.


Octave Spanning Supercontinuum In An As2s3 Taper Using Ultralow Pump Pulse Energy, Darren D. Hudson, Stephen A. Dekker, Eric C. Magi, Alexander C. Judge, Stuart D. Jackson, Enbang Li, J S. Sanghera, L B. Shaw, I D. Aggarwal, Benjamin J. Eggleton Jan 2011

Octave Spanning Supercontinuum In An As2s3 Taper Using Ultralow Pump Pulse Energy, Darren D. Hudson, Stephen A. Dekker, Eric C. Magi, Alexander C. Judge, Stuart D. Jackson, Enbang Li, J S. Sanghera, L B. Shaw, I D. Aggarwal, Benjamin J. Eggleton

Faculty of Engineering and Information Sciences - Papers: Part A

An octave spanning spectrum is generated in an As2S3 taper via 77 pJ pulses from an ultrafast fiber laser. Using a previously developed tapering method, we construct a 1.3 μm taper that has a zero-dispersion wavelength around 1.4 μm . The low two-photon absorption of sulfide-based chalcogenide fiber allows for higher input powers than previous efforts in selenium-based chalcogenide tapered fibers. This higher power handling capability combined with input pulse chirp compensation allows an octave spanning spectrum to be generated directly from the taper using the unamplified laser output.


A Singularity Free Trajectory Tracking Method For The Cooperative Working Of Multi-Arm Robots Using Screw Theory, Emre Sariyildiz, Hakan Temeltas Jan 2011

A Singularity Free Trajectory Tracking Method For The Cooperative Working Of Multi-Arm Robots Using Screw Theory, Emre Sariyildiz, Hakan Temeltas

Faculty of Engineering and Information Sciences - Papers: Part A

In this paper we present a singularity free trajectory tracking method for the cooperative working of multi-arm robot manipulators. It is based on an inverse kinematic transformation which determines the manipulator's joint angles corresponding to the end-effector trajectory given in the task space. The kinematic problem of multi-arm robot system is solved by using screw theory and quaternion algebra. Screw theory is an effective way to establish a global description of rigid body and avoids singularities due to the use of the local coordinates. Dual-quaternion is the most compact and efficient dual operator to express screw displacement. Inverse kinematic solutions …


Performance Analysis Of Numerical Integration Methods In The Trajectory Tracking Application Of Redundant Robot Manipulators, Emre Sariyildiz, Hakan Temeltas Jan 2011

Performance Analysis Of Numerical Integration Methods In The Trajectory Tracking Application Of Redundant Robot Manipulators, Emre Sariyildiz, Hakan Temeltas

Faculty of Engineering and Information Sciences - Papers: Part A

Differential kinematic is one of the most important solution methods in robot kinematics. The main advantage of the differential kinematic method is that it can be easily implemented any kind of mechanisms. Also, an accurate and efficient kinematic based trajectory tracking application can be easily implemented by using this method. In differential kinematic method, we use Jacobian as a mapping operator in the velocity space. Inversion of Jacobian matrix transforms the desired trajectory velocities, which are the linear and angular velocities of the end effector, into the joint velocities. The joint velocities are required to be integrated to obtain the …


A Kernel Fuzzy C-Means Clustering-Based Fuzzy Support Vector Machine Algorithm For Classification Problems With Outliers Or Noises, Xiaowei Yang, Guangquan Zhang, Jie Lu, Jun Ma Jan 2011

A Kernel Fuzzy C-Means Clustering-Based Fuzzy Support Vector Machine Algorithm For Classification Problems With Outliers Or Noises, Xiaowei Yang, Guangquan Zhang, Jie Lu, Jun Ma

Faculty of Engineering and Information Sciences - Papers: Part A

The support vector machine (SVM) has provided higher performance than traditional learning machines and has been widely applied in real-world classification problems and nonlinear function estimation problems. Unfortunately, the training process of the SVM is sensitive to the outliers or noises in the training set. In this paper, a common misunderstanding of Gaussian-function-based kernel fuzzy clustering is corrected, and a kernel fuzzy c-means clustering-based fuzzy SVM algorithm (KFCM-FSVM) is developed to deal with the classification problems with outliers or noises. In the KFCM-FSVM algorithm, we first use the FCM clustering to cluster each of two classes from the training set …


Theme-Based Comprehensive Evaluation In New Product Development Using Fuzzy Hierarchical Criteria Group Decision-Making Method, Jie Lu, Jun Ma, Guangquan Zhang, Yijun Zhu, Xianyi Zeng, Ludovic Koehl Jan 2011

Theme-Based Comprehensive Evaluation In New Product Development Using Fuzzy Hierarchical Criteria Group Decision-Making Method, Jie Lu, Jun Ma, Guangquan Zhang, Yijun Zhu, Xianyi Zeng, Ludovic Koehl

Faculty of Engineering and Information Sciences - Papers: Part A

One of the features of the digital ecosystem is the integration of human cognition and socio-economic themes into the process of new product development (NPD). In a socio-economic theme-based NPD, ranking a set of product prototypes that have been designed always requires the participation of multiple evaluators and consideration of multiple evaluation criteria. Using the well-being theme-based garment NPD as a background, this paper first presents a fuzzy hierarchical criteria group decision-making (FHCGDM) method which can effectively calculate final ranking results through fusing all assessment data from human beings and machines. It then presents a garment NPD comprehensive evaluation model …


A Comparison Study Of The Numerical Integration Methods In The Trajectory Tracking Application Of Redundant Robot Manipulators, Emre Sariyildiz, Hakan Temeltas Jan 2011

A Comparison Study Of The Numerical Integration Methods In The Trajectory Tracking Application Of Redundant Robot Manipulators, Emre Sariyildiz, Hakan Temeltas

Faculty of Engineering and Information Sciences - Papers: Part A

Differential kinematic has a wide range application area in robot kinematics. The main advantage of the differential kinematic is that it can be easily implemented any kind of mechanisms. In differential kinematic method, Jacobian is used as a mapping operator in the velocity space. The joint velocities are required to be integrated to obtain the pose of the robot manipulator. This integration can be evaluated by using numerical integration methods, since the inverse kinematic equations are highly complex and nonlinear. Thus, the performances of the numerical integration methods affect the trajectory tracking application. This paper compares the performances of numerical …


Study On Oxidation Of Stainless Steels During Hot Rolling, Z Y. Jiang, D B. Wei, K Tieu, J X. Huang, A W. Zhang, X Shi, S H. Jiao Jan 2011

Study On Oxidation Of Stainless Steels During Hot Rolling, Z Y. Jiang, D B. Wei, K Tieu, J X. Huang, A W. Zhang, X Shi, S H. Jiao

Faculty of Engineering and Information Sciences - Papers: Part A

The oxidation of stainless steels 304 and 304L during hot rolling is studied in this paper. Results show the oxide scale thickness decreases significantly with an increase of reduction, and the oxide scales of both 304 and 304L stainless steels were found more deformable than the steel substrate. Surface roughness shows a complicated transfer during the hot rolling process due to the complexity of oxide scale characteristics. Also, surface roughness decreases with an increase of reduction. The friction coefficient increases with reduction in all cases, and the increase is more significant in the case of the 304 stainless steel than …


Skin Dosimetry Of Thyroid Radioiodine With Moskin Detector: A Phantom Study, K Chuamsaamarkkee, I Fuduli, D Cutajar, C Lian, S Harvey, Anatoly B. Rosenfeld Jan 2011

Skin Dosimetry Of Thyroid Radioiodine With Moskin Detector: A Phantom Study, K Chuamsaamarkkee, I Fuduli, D Cutajar, C Lian, S Harvey, Anatoly B. Rosenfeld

Faculty of Engineering and Information Sciences - Papers: Part A

Radioiodine treatment is administered radioactive iodine to treat the thyroid cancer or to ablate a thyroid remnant. However, due to the risk of radiation, there is a possibility that the patient will experience side effects. Skin dose is an important parameter for quantifying patient dose. The aim of this study is to use a MOSFET detector for real time skin dosimetry. At the Centre for Medical Radiation Physics (CMRP), University of Wollongong, a new type of MOSFET detector called MOSkin is being developed to measure the skin dose, with real-time read out. This paper discusses the pre-clinical characterization the MOSkin …


Discrete Element Modelling: Trouble-Shooting And Optimisation Tool For Chute Design, Andrew P. Grima, Thomas Fraser, David B. Hastie, Peter W. Wypych Jan 2011

Discrete Element Modelling: Trouble-Shooting And Optimisation Tool For Chute Design, Andrew P. Grima, Thomas Fraser, David B. Hastie, Peter W. Wypych

Faculty of Engineering and Information Sciences - Papers: Part A

Conveyor transfer stations play a key role in many industries that handle bulk materials. Transfer stations can be rather sensitive to changes in material properties and can lead to relentless problems regarding reliability, wear, bottlenecking and blockages. Wet and sticky ores are typically difficult to handle materials due to their obnoxious ability to form a cohesive arch, adhere to surfaces and poor flow ability. Mines that are situated in areas with seasonal high rainfalls or that have started to exploit newer and more difficult to mine and handle ores, often from below the water table, experience vast difficulty in reliably …


Synthesis, Characterization, Dna Interaction And Cleavage, And In Vitro Cytotoxicity Of Copper(Ii) Mixed-Ligand Complexes With 2-Phenyl-3-Hydroxy-4(1h)-Quinolinone, Roman Buchtik, Zdenek Travnicek, Jan Vanco, Radovan Herchel, Zdenek Dvorak Jan 2011

Synthesis, Characterization, Dna Interaction And Cleavage, And In Vitro Cytotoxicity Of Copper(Ii) Mixed-Ligand Complexes With 2-Phenyl-3-Hydroxy-4(1h)-Quinolinone, Roman Buchtik, Zdenek Travnicek, Jan Vanco, Radovan Herchel, Zdenek Dvorak

Faculty of Engineering - Papers (Archive)

A series of mixed-ligand complexes [Cu(qui)(L)]NO3·xH2O (1–6), where Hqui = 2-phenyl-3-hydroxy-4(1H)-quinolinone, L = 2,2′-bipyridine (bpy) (1), 1,10-phenanthroline (phen) (2), bis(2-pyridyl)amine (ambpy) (3), 5-methyl-1,10-phenanthroline (mphen) (4), 5-nitro-1,10-phenanthroline (nphen) (5) and bathophenanthroline (bphen) (6), have been synthesized and fully characterized. The X-ray structures of [Cu(qui)(phen)]NO3·H2O (2) and [Cu(qui)(ambpy)]NO3 (3a) show a slightly distorted square-planar geometry in the vicinity of the central copper(II) atom. An in vitro cytotoxicity study of the complexes …


Preliminary Evaluations On Laser - Tandem Gmaw, Ruham P. Reis, John Norrish, Dominic Cuiuri Jan 2011

Preliminary Evaluations On Laser - Tandem Gmaw, Ruham P. Reis, John Norrish, Dominic Cuiuri

Faculty of Engineering - Papers (Archive)

Recently there has been considerable research and development activity in the use of lasers for welding operations, turning this process into an important tool for a variety of applications. Although it is possible to use lasers as a unique source of heat to promote union of materials, the combination of the beam provided by a laser system with an arc welding process has been studied widely and applied in the so-called hybrid welding systems. Generally, the final result of such a combination is an increase in the weld penetration depth, width and welding travel speed. Despite these advantages, there are …


Oxidative Acetylenic Coupling Reactions As A Surface Chemistry Tool, Simone Ciampi, Michael James, Nadim A. Darwish, Erwann Luais, Bin Guan, Jason Brian Harper, J Justin Gooding Jan 2011

Oxidative Acetylenic Coupling Reactions As A Surface Chemistry Tool, Simone Ciampi, Michael James, Nadim A. Darwish, Erwann Luais, Bin Guan, Jason Brian Harper, J Justin Gooding

Australian Institute for Innovative Materials - Papers

A novel method to prepare redox monolayers on silicon electrodes has been developed that employs CuI-catalyzed oxidative acetylenic coupling reactions for molecular electronic type applications. As the first case study, ethynylferrocene was covalently immobilized onto an acetylene-terminated monolayer on a Si(100) surface to give a 1,3-diyne (CC-CC-) linked redox assembly. The derivatization process requires no protection/de-protection steps, nor activation procedures. The effect of the conjugated diyne linkage on the rate of electron transfer between tethered ferrocenyl units and the silicon electrode is benchmarked against well-established "click" products (i.e. 1,2,3-triazole linkage). The surfaces, after each step, are characterized thoroughly using X-ray …


Mesoporous Silicon Photonic Crystal Microparticles: Towards Single-Cell Optical Biosensors, Bin Guan, Astrid I. Magenau, Krisopher A. Kilian, Simone Ciampi, Katharina Gaus, Peter J. Reece, J Justin Gooding Jan 2011

Mesoporous Silicon Photonic Crystal Microparticles: Towards Single-Cell Optical Biosensors, Bin Guan, Astrid I. Magenau, Krisopher A. Kilian, Simone Ciampi, Katharina Gaus, Peter J. Reece, J Justin Gooding

Australian Institute for Innovative Materials - Papers

In this paper we demonstrate the possibility of modifying porous silicon (PSi) particles with surface chemistry and recognition molecules (antibodies) such that these devices could potentially be used for single-cell identification or sensing. This is achieved by modifying PSi Rugate filters via hydrosilylation with surface chemistry that serves firstly, to protect the silicon surfaces from oxidation; secondly, renders the surfaces resistant to nonspecific adsorption of proteins and cells and thirdly, allows further functionality to be added such as the coupling of antibodies. The surface chemistry remained unchanged after sonication of the PSi to form PSi microparticles. The ability to monitor …


Critical Property In Relaxor-Pbtio3 Single Crystals - Shear Piezoelectric Response, Fei Li, Shujun Zhang, Zhuo Xu, Xiaoyong Wei, Thomas R. Shrout Jan 2011

Critical Property In Relaxor-Pbtio3 Single Crystals - Shear Piezoelectric Response, Fei Li, Shujun Zhang, Zhuo Xu, Xiaoyong Wei, Thomas R. Shrout

Australian Institute for Innovative Materials - Papers

The shear piezoelectric behavior in relaxor-PbTiO 3 (PT) single crystals is investigated with regard to the crystal phase. High levels of shear piezoelectric activity, d 15 or d 24 >2000 pC N -1, are observed for single-domain rhombohedral (R), orthorhombic (O), and tetragonal (T) relaxor-PT crystals. The high piezoelectric response is attributed to a flattening of the Gibbs free energy at compositions close to the morphotropic phase boundaries, where polarization rotation is easily accomplished by applying a perpendicular electric field. The shear piezoelectric behavior of perovskite ferroelectric crystals is discussed with respect to ferroelectric-ferroelectric phase transitions and the dc bias …


Block-Copolymer-Assisted Synthesis Of Hydroxyapatite Nanoparticles With High Surface Area And Uniform Size, Yu Huang, Masataka Imura, Yoshihiro Nemoto, Chao Hung Cheng, Yusuke Yamauchi Jan 2011

Block-Copolymer-Assisted Synthesis Of Hydroxyapatite Nanoparticles With High Surface Area And Uniform Size, Yu Huang, Masataka Imura, Yoshihiro Nemoto, Chao Hung Cheng, Yusuke Yamauchi

Australian Institute for Innovative Materials - Papers

We report the synthesis of hydroxyapatite nanoparticles (HANPs) by the coprecipitation method using calcium D-gluconate and potassium hydrogen phosphate as the sources of calcium and phosphate ions, respectively, and the triblock copolymer F127 as a stabilizer. The HANPs were characterized using scanning electron microscopy, x-ray diffraction, and nitrogen adsorption/desorption isotherms. Removal of F127 by solvent extraction or calcination alters the structure of HANPs. The solvent-extracted HANPs were single crystals with their 〈001〉 axis oriented along the rod axis of the HANP, whereas the calcined HANPs contained two crystal phases that resulted in a spherical morphology. The calcined HANPs had much …


In-Field Jc Improvement By Oxygen-Free Pyrene Gas Diffusion Into Highly Dense Mgb2 Superconductor, Minoru Maeda, Jung Ho Kim, Y Zhao, Yoon-Uk Heo, K Takase, Y Kubota, C Moriyoshi, F Yoshida, Y Kuroiwa, S X. Dou Jan 2011

In-Field Jc Improvement By Oxygen-Free Pyrene Gas Diffusion Into Highly Dense Mgb2 Superconductor, Minoru Maeda, Jung Ho Kim, Y Zhao, Yoon-Uk Heo, K Takase, Y Kubota, C Moriyoshi, F Yoshida, Y Kuroiwa, S X. Dou

Australian Institute for Innovative Materials - Papers

Oxygen-free pyrene gas as a carbon (C) dopant was delinked and incorporated into highly dense MgB2 structure via a gas phase diffusion method. The technique offers the advantages that molecular C is homogeneously distributed into MgB2 and substituted at the boron sites without any severe deterioration of grain connectivity. The C substitution causes a significant shrinkage of the a-lattice parameter and an increase in the lattice strain, resulting in high disorder. The introduction of structural disorder as a result of C doping leads to a considerable enhancement of the in-field critical current density (Jc) and upper critical …


Ammonium Octahydrotriborate (Nh4b3h8): New Synthesis, Structure, And Hydrolytic Hydrogen Release, Zhenguo Huang, Xuenian Chen, Teshome Yisgedu, Edward A. Meyers, Sheldon Shore, J C. Zhao Jan 2011

Ammonium Octahydrotriborate (Nh4b3h8): New Synthesis, Structure, And Hydrolytic Hydrogen Release, Zhenguo Huang, Xuenian Chen, Teshome Yisgedu, Edward A. Meyers, Sheldon Shore, J C. Zhao

Australian Institute for Innovative Materials - Papers

A metathesis reaction between unsolvated NaB3H8 and NH4Cl provides a simple and high-yield synthesis of NH4B3H8. Structure determination through X-ray single crystal diffraction analysis reveals weak N—Hδ+- - -Hδ-—B interaction in NH4B3H8 and strong N—Hδ+—Hδ-—B interaction in NH4B3H8·18-crown-6·THF adduct. Pyrolysis of NH4B3H8 leads to the formation of hydrogen gas with appreciable amounts of other volatile boranes below 160°C. Hydrolysis experiments show that …


Dye-Sensitized Cualo2 Photocathodes For Tandem Solar Cell Applications, Andrew Nattestad, Xiaoli Zhang, Udo Bach, Yi-Bing Cheng Jan 2011

Dye-Sensitized Cualo2 Photocathodes For Tandem Solar Cell Applications, Andrew Nattestad, Xiaoli Zhang, Udo Bach, Yi-Bing Cheng

Australian Institute for Innovative Materials - Papers

Dye-sensitized solar cells (DSCs) using the p-type semiconductor CuAlO2, in conjunction with a highly effective hole injecting dye and an iodide-triiodide-based electrolyte have been produced, demonstrating photocathodic behavior. An improved open-circuit voltage (VOC) of 333 mV was observed, compared to analogous devices using NiO, which can be explained by the CuAlO2 valence-band energy, which is lower on the vacuum scale than that of NiO. Incident photon-to-charge-carrier efficiency response confirms that the observed photocurrent is generated by the dye.


Dithienothiophene (Dtt)-Based Dyes For Dye-Sensitized Solar Cells: Synthesis Of 2,6-Dibromo-Dtt, Tae-Hyuk Kwon, Vanessa Armel, Andrew Nattestad, Douglas R. Macfarlane, Udo Bach, Samuel J. Lind, Keith C. Gordon, Weihua Tang, David J. Jones, Andrew Holmes Jan 2011

Dithienothiophene (Dtt)-Based Dyes For Dye-Sensitized Solar Cells: Synthesis Of 2,6-Dibromo-Dtt, Tae-Hyuk Kwon, Vanessa Armel, Andrew Nattestad, Douglas R. Macfarlane, Udo Bach, Samuel J. Lind, Keith C. Gordon, Weihua Tang, David J. Jones, Andrew Holmes

Australian Institute for Innovative Materials - Papers

A one-pot synthesis of 2,6-dibromodithieno[3,2-b;2′,3′-d]thiophene (dibromo-DTT, 4) was developed. A key step was bromodecarboxylation of DTT-2,6-dicarboxylic acid, obtained by saponification of the diester 1. The donor-acceptor dye DAHTDTT (13), based on a central 2,6-bis[2′-(3′-hexylthienyl)]dithieno[3,2-b;2′,3′-d]thiophene core (9), was prepared and incorporated in a dye-sensitized solar cell (DSC), which exhibited an energy conversion efficiency of 7.3% with Voc of 697 mV, Jsc of 14.4 mA/cm2, and ff of 0.73 at 1 sun.


A Highly Ordered Titania Nanotube Array As A Supercapacitor Electrode, Maryam Salari, Seyed Hamed Aboutalebi, Konstantin Konstantinov, Hua-Kun Liu Jan 2011

A Highly Ordered Titania Nanotube Array As A Supercapacitor Electrode, Maryam Salari, Seyed Hamed Aboutalebi, Konstantin Konstantinov, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

We report the synthesis of self-organized titania nanotubes and nanocrystalline titania powders employing an alternative and novel approach. Integrating these nanostructures in a binder-free working electrode improved the capacitance up to 911 uF cm-2, which is around one to two orders of magnitude higher than the conventional electric double layer capacitors.


Compact-Designed Supercapacitors Using Free-Standing Single-Walled Carbon Nanotube Films, Zhiqiang Niu, Weiya Zhou, Jun Chen, Guoxing Feng, Hong Li, Wenjun Ma, Jinzhu Li, Haibo Dong, Yan Ren, Duan Zhao, Sishen Xie Jan 2011

Compact-Designed Supercapacitors Using Free-Standing Single-Walled Carbon Nanotube Films, Zhiqiang Niu, Weiya Zhou, Jun Chen, Guoxing Feng, Hong Li, Wenjun Ma, Jinzhu Li, Haibo Dong, Yan Ren, Duan Zhao, Sishen Xie

Australian Institute for Innovative Materials - Papers

We reported the realization of assembling compact-designed supercapacitors using large-scaled freestanding and flexible single-walled carbon nanotube (SWCNT) films as both anode and cathode. A prototype of the processing procedures was developed to obtain the uniform spreading of the SWCNT films onto the separators serving as both electrodes and charge collectors without metallic current collectors, leading to a simplified and lightweight architecture. The area of SWCNT film on a separator can be scaled up and its thickness can be extended. High energy and power densities (43.7 Wh kg-1 and 197.3 kW kg-1, respectively) were achieved from the prepared …


Sinteractive Anodic Powders Improve Densification And Electrochemical Properties Of Bazr0.8y0.2o3-O Electrolyte Films For Anode-Supported Solid Oxide Fuel Cells, Lei Bi, Emiliana Fabbri, Ziqi Sun, Enrico Traversa Jan 2011

Sinteractive Anodic Powders Improve Densification And Electrochemical Properties Of Bazr0.8y0.2o3-O Electrolyte Films For Anode-Supported Solid Oxide Fuel Cells, Lei Bi, Emiliana Fabbri, Ziqi Sun, Enrico Traversa

Australian Institute for Innovative Materials - Papers

The difficult sintering of BaZr0.8Y0.2O3-δ(BZY20) powders makes the fabrication of anode-supported BZY20 electrolyte films complex. Dense BZY20 membranes were successfully fabricated on anode substrates made of sinteractive NiO-BZY20 powders, prepared by a combustion method. With respect to traditional anode substrates made of powders prepared by mechanical mixing, the anode substrates made of the wet-chemically synthesized composite NiO–BZY20 powders significantly promoted the densification of BZY20 membranes: dense BZY20 films were obtained after co-pressing and co-firing at 1300°C, a much lower temperature than those usually needed for densifying BZY20 membranes. Improved electrochemical performance was …


Bazr(0.8)Y(0.2)O(3-Delta)-Nio Composite Anodic Powders For Proton-Conducting Sofcs Prepared By A Combustion Method, Lei Bi, Emiliana Fabbri, Ziqi Sun, Enrico Traversa Jan 2011

Bazr(0.8)Y(0.2)O(3-Delta)-Nio Composite Anodic Powders For Proton-Conducting Sofcs Prepared By A Combustion Method, Lei Bi, Emiliana Fabbri, Ziqi Sun, Enrico Traversa

Australian Institute for Innovative Materials - Papers

BaZr0.8Y0.2O3-∂ (BZY)-NiO composite powders with different BZY-NiO weight ratios were prepared by a combustion method as anodes for proton-conducting solid oxide fuel cells (SOFCs). After heating to 1100°C for 6 h, the composite powders were made of a well-dispersed mixture of two phases, BZY and NiO. Chemical stability tests showed that the BZY-NiO anodic powders had good stability against CO2, whereas comparative tests under the same conditions showed degradation for BaCe0.7Zr0.1Y0.2O3-∂- NiO, which is at present the most used anode material for proton-conducting …


Position Preference And Diffusion Path Of An Oxygen Ion In Apatite-Type Lanthanum Silicate La9.33si6o26: A Density Functional Study, Ting Liao, Taizo Sasaki, Shigeru Suehara, Ziqi Sun Jan 2011

Position Preference And Diffusion Path Of An Oxygen Ion In Apatite-Type Lanthanum Silicate La9.33si6o26: A Density Functional Study, Ting Liao, Taizo Sasaki, Shigeru Suehara, Ziqi Sun

Australian Institute for Innovative Materials - Papers

Using density functional theory, we investigated the position preference and diffusion mechanisms of interstitial oxygen ions in lanthanum silicate La9.33Si6O26, which is an apatite-structured oxide and a promising candidate electrolyte material for solid oxide fuel cells. The reported lanthanum vacancies were explicitly taken into account by theoretically determining their arrangement with a supercell model. The most stable structures and the formation energies of oxygen interstitials were determined for each charged state. It was found that the double-negatively charged state is stable over a wide range of the Fermi level, and that the excess oxygen …


5-Chloro-1-Phenyl-1h-Pyrazol-4-Amine, A Korzanski, Pawel W. Wagner, Maciej Kubicki Jan 2011

5-Chloro-1-Phenyl-1h-Pyrazol-4-Amine, A Korzanski, Pawel W. Wagner, Maciej Kubicki

Australian Institute for Innovative Materials - Papers

No abstract provided.


Fabrication, Magnetic, And Ferroelectric Properties Of Multiferroic Bifeo3 Hollow Nanoparticles, Yi Du, Z. Cheng, S X. Dou, Darren J. Attard, Xiaolin Wang Jan 2011

Fabrication, Magnetic, And Ferroelectric Properties Of Multiferroic Bifeo3 Hollow Nanoparticles, Yi Du, Z. Cheng, S X. Dou, Darren J. Attard, Xiaolin Wang

Australian Institute for Innovative Materials - Papers

Hollow BiFeO3nanoparticles were synthesized by an electrospray route for the first time. The phase purity and structure have been investigated by x-ray diffraction and Raman spectroscopy. Transmission and scanning electron microscope investigations revealed that the as-obtained BiFeO3 hollow spheres were polycrystalline, with a shell thickness of 35 nm. The formation mechanism can be possibly explained by Ostwald ripening. Raman spectra have verified decreased vibrational frequencies in BiFeO3nanoparticles. These hollow and core-shell multiferroicnanoparticles exhibit significantly enhanced ferromagnetism from 5 to 600 K due to a broken spiral spin structure. The ferroelectricity of hollow BiFeO3 particles …


Domain Wall Conductivity In Oxygen Deficient Multiferroic Ymno3 Single Crystals, Yi Du, Xiaolin Wang, Dapeng Chen, S X. Dou, Z. Cheng, Michael J. Higgins, Gordon G. Wallace, Jiazhao Wang Jan 2011

Domain Wall Conductivity In Oxygen Deficient Multiferroic Ymno3 Single Crystals, Yi Du, Xiaolin Wang, Dapeng Chen, S X. Dou, Z. Cheng, Michael J. Higgins, Gordon G. Wallace, Jiazhao Wang

Australian Institute for Innovative Materials - Papers

The transport properties of domain walls in oxygen deficient multiferroic YMnO3 single crystals have been probed using conductive atomic force microscopy and piezoresponse force microscopy. Domain walls exhibit significantly enhanced conductance after being poled in electric fields, possibly induced by oxygen vacancy ordering at domain walls. The electronic conduction can be understood by the Schottky emission and Fowler-Nordheim tunnelling mechanisms. Our results show that the domain wall conductance can be modulated through band structure engineering by manipulating ordered oxygen vacancies in the poling fields.


Feasibility Study Of Microgrid Application In Langkawi And Socotra Islands, Ahmed Haidar Jan 2011

Feasibility Study Of Microgrid Application In Langkawi And Socotra Islands, Ahmed Haidar

Faculty of Engineering and Information Sciences - Papers: Part A

Alternative Energy is becoming a popular and an essential energy resource in the current century. This paper investigates the effect of using a hybrid microgrid system in Langkawi and Socotra Islands. Configuration of the optimal hybrid system is selected based on the best components and its sizing with appropriate operation strategy to provide a cheap efficient, reliable and cost effective system. The total net present cost for the two Islands has been determined using HOMER program based on the Island’s data. This finding will help to install sources of renewable energy in places that will ensure low cost and performance …