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Isotopic (Δ13c, Δ14c) Analysis Of Organic Acids In Marine Samples Using Wet Chemical Oxidation, Susan Q. Lang, G. L. Früh-Green, S. M. Bernasconi, L. Wacker 2013 University of South Carolina - Columbia

Isotopic (Δ13c, Δ14c) Analysis Of Organic Acids In Marine Samples Using Wet Chemical Oxidation, Susan Q. Lang, G. L. Früh-Green, S. M. Bernasconi, L. Wacker

Faculty Publications

We present a method for the isolation and off-line isotope analysis of formate and acetate in marine samples. Organic acids are separated by high performance liquid chromatography and collected in glass Exetainer® screw-capped vials that have been prespiked with an oxidant and flushed with helium. The vials are subsequently heated to convert the organic compounds to CO2 for radiocarbon and δ13C analysis. Small aliquots are sampled for measurement of δ13C by isotope ratio mass spectrometry, whereas the majority of the CO2 is saved for radiocarbon analysis by accelerator mass spectrometry using a gas ion …


Extreme Wave Events In Ireland: 14 680 Bp–2012, Laura Cooke, John M. Dudley, Frédéric Dias 2013 Technological University Dublin

Extreme Wave Events In Ireland: 14 680 Bp–2012, Laura Cooke, John M. Dudley, Frédéric Dias

Articles

The island of Ireland is battered by waves from all sides, most ferociously on the west coast as the first port of call for waves travelling across the Atlantic Ocean. However, when discussing ocean events relevant to the nation of Ire- land, one must actually consider its significantly larger designated continental shelf, which is one of the largest seabed territories in Europe. With this expanded definition, it is not surprising that Ireland has been subject to many oceanic events which could be designated as “extreme”; in this paper we present what we believe to be the first catalogue of such …


Conservation Mooring Study, Urban Harbors Institute, University of Massachusetts Boston 2013 University of Massachusetts Boston

Conservation Mooring Study, Urban Harbors Institute, University Of Massachusetts Boston

Urban Harbors Institute Publications

Most boaters who moor their vessels in Massachusetts waters have traditionally employed free swinging moorings that use heavy bottom chain. In important sensitive habitats such as eelgrass beds, these types of moorings often have negative impacts on the benthic habitat – from the circular movement of the chain around the anchor point, and/or from the anchor itself.

This document objectively describes the different characteristics of conventional moorings versus conservation moorings designed to minimize disruption to the benthic habitat. This report includes discussions on the following topics:

  • Technologies available
  • Ecological impacts
  • Functional differences
  • Economical differences
  • Regulatory issues

These comparisons, along with …


Implementation And Model To Model Intercomparison Of 12 Heat Stress Metrics, Jonathan Robert Buzan 2013 Purdue University

Implementation And Model To Model Intercomparison Of 12 Heat Stress Metrics, Jonathan Robert Buzan

Open Access Theses

Earth system models simulate the dynamics of the most complex systems on our planet with some success. Despite the overwhelming sophistication of these models, which include dynamical interactions of ocean, atmosphere, vegetation, ice, and land-surface properties, they fail to include the most important element. People. Humans are also a complex physical-biological system and coupling of human physiology within an Earth Systems Modeling framework is challenging. This thesis presents results that tackle one particular component of human physiological climate interaction--a representation of heat stress on human physiology. Twelve different metrics were implemented and analyzed. These metrics represent a variety of philosophical …


The Influence Of The Tibetan Plateau Elevation On The Global And Asian Monsoons, Rene Paul Acosta 2013 Purdue University

The Influence Of The Tibetan Plateau Elevation On The Global And Asian Monsoons, Rene Paul Acosta

Open Access Theses

It has been long hypothesized that large-scale topographic changes, such as the surface uplift of the Tibetan Plateau, impacts the development of the South Asian and East Asian monsoons and influences other monsoon regions. However, recent modeling has shown that spatial distribution of the global monsoon, which includes the South Asian and East Asian monsoons is largely unaffected by the elevation of the plateau. In this study, we present results from a series of modern day simulations using CESM1.0 in a mixed-layer (slab ocean) configuration. The Tibetan Plateau height is varied from double that of the modern maximum plateau elevation …


Chemical Consequences Of Chicxulub Impact Ejecta Reentry, Devon Donald Parkos 2013 Purdue University

Chemical Consequences Of Chicxulub Impact Ejecta Reentry, Devon Donald Parkos

Open Access Theses

The Chicxulub impact 66.0 million years ago initiated the second biggest extinction in the Phanerozoic Eon. The global reentry of material ejected by the impact generated a strong pulse of thermal radiation that wiped out much of the terrestrial biota. The cause of the marine extinction, however, has remained elusive. This report shows that reentering ejecta produces enough NOx to acidify the upper ocean and cause a massive marine extinction. Using non-equilibrium chemically reacting flow simulations coupled with atmospheric transport modeling, it is determined that enough NOx reached the stratosphere and precipitated to overpower the carbonate buffer and acidify the …


Rock Glaciers In The Eastern Cascades, Washington, Mark Weidenaar 2013 Central Washington University

Rock Glaciers In The Eastern Cascades, Washington, Mark Weidenaar

Undergraduate Honors Theses

The eastern portion of Washington State's Cascade Range is a place not previously examined for rock glaciers, due to proximity to the Pacific Ocean and its associated marine-influenced climate. The objectives of this study were to determine spatial, activity, and genesis patterns, and paleoclimatic implications of Eastern Cascade rock glaciers. Using Google Earth, I found 103 rock glaciers in the study area. Rock glaciers are more common further east of the Cascade crest and more north in latitude, with the largest concentrations occurring east of Lake Chelan (22) and in the Pasayten Wilderness (28) in the North Cascades. None were …


Radio Signals From Electron Beams In Terrestrial Gamma Ray Flashes, Valerie Connaughton, Joseph R. Dwyer, Eric Cramer 2013 The University of Alabama in Huntsville

Radio Signals From Electron Beams In Terrestrial Gamma Ray Flashes, Valerie Connaughton, Joseph R. Dwyer, Eric Cramer

Aerospace, Physics, and Space Science Faculty Publications

We show that the rate of association between terrestrial gamma ray flashes (TGFs) observed by the Fermi gamma ray burst monitor and VLF discharges detected by the World Wide Lightning Location Network (WWLLN) depends strongly on the duration of the TGF, with the shortest TGFs having associated WWLLN events over 50% of the time, and the longest TGFs showing a less than 10% match rate. This correlation is stronger if one excludes the WWLLN discharges that are not simultaneous (within 200 ms) with the TGF. We infer that the simultaneous VLF discharges are from the relativistic electron avalanches that are …


The Angular Distribution Of Energetic Electron And X-Ray Emissions From Triggered Lightning Leaders, M. M. Schaal, Joseph R. Dwyer, Hamid K. Rassoul, Jonathan David Hill, Douglas M. Jordan, Martin A. Uman 2013 Florida Institute of Technology

The Angular Distribution Of Energetic Electron And X-Ray Emissions From Triggered Lightning Leaders, M. M. Schaal, Joseph R. Dwyer, Hamid K. Rassoul, Jonathan David Hill, Douglas M. Jordan, Martin A. Uman

Aerospace, Physics, and Space Science Faculty Publications

We investigate individual X-ray bursts from lightning leaders to determine if energetic electrons at the source (and hence X-rays) are emitted isotropically or with some degree of anisotropy. This study was motivated by the work of Saleh et al. (2009), which found the falloff of X-rays in concentric radial annuli, covering all azimuthal directions in each annulus, from the lightning channel to be most consistent with an isotropic electron source. Here we perform a statistical analysis of angular and spatial distributions of X-rays measured by up to 21 NaI/PMT detectors at the International Center for Lightning Research and Testing site …


Analysis Of The Experiment On Registration Of X-Rays From The Stepped Leader Of A Cloud-To-Ground Lightning Discharge, Leonid P. Babich, Igor M. Kutsyk, Evgeni N. Donsko, Joseph R. Dwyer 2013 Russian Federal Nuclear Center

Analysis Of The Experiment On Registration Of X-Rays From The Stepped Leader Of A Cloud-To-Ground Lightning Discharge, Leonid P. Babich, Igor M. Kutsyk, Evgeni N. Donsko, Joseph R. Dwyer

Aerospace, Physics, and Space Science Faculty Publications

Using a Monte Carlo technique to simulate the transport of runaway electrons (REs) and X-rays in the atmosphere and through attenuators covering detectors, we have modeled the results of experiments to detect X-rays from triggered lightning and stepped leaders of a natural cloud-to-ground lightning. In the model, bremsstrahlung of high-energy runaway electrons (REs) generated at the leader front is assumed to be the origin of X-rays. Specific fluxes (per one RE) of photons and bremsstrahlung energy at the detectors were calculated. The analysis was executed with monoenergetic and exponential initial energy distributions of REs with different angular distributions. To reproduce …


Modeling Terrestrial Gamma Ray Flashes Produced By Relativistic Feedback Discharges, Ningyu Liu, Joseph R. Dwyer 2013 Florida Institute of Technology

Modeling Terrestrial Gamma Ray Flashes Produced By Relativistic Feedback Discharges, Ningyu Liu, Joseph R. Dwyer

Aerospace, Physics, and Space Science Faculty Publications

This paper reports a modeling study of terrestrial gamma ray flashes (TGFs) produced by relativistic feedback discharges. Terrestrial gamma ray flashes are intense energetic radiation originating from the Earth’s atmosphere that has been observed by spacecraft. They are produced by bremsstrahlung interactions of energetic electrons, known as runaway electrons, with air atoms. An efficient physical mechanism for producing large fluxes of the runaway electrons to make the TGFs is the relativistic feedback discharge, where seed runaway electrons are generated by positrons and X-rays, products of the discharge itself. Once the relativistic feedback discharge becomes self-sustaining, an exponentially increasing number of …


Radio Emissions From Terrestrial Gamma-Ray Flashes, Joseph R. Dwyer, Steven A. Cummer 2013 Florida Institute of Technology

Radio Emissions From Terrestrial Gamma-Ray Flashes, Joseph R. Dwyer, Steven A. Cummer

Aerospace, Physics, and Space Science Faculty Publications

The theory of radio frequency (RF) emissions by terrestrial gamma-ray flashes (TGFs) is developed. These radio emissions, which are separate from the emission caused by lightning, are produced by the electric currents generated by runaway electrons and resulting low-energy electrons and ions. It is found from theory that the radio frequency pulses produced by TGFs are large enough to measure. Features of these signals depend strongly on certain aspects of the runaway acceleration process and so should provide additional information about the source mechanism(s) of this interesting atmospheric phenomenon. The RF emissions from several TGF models are calculated and compared …


Contribution Of The Pacific Decadal Oscillation To Global Mean Sea Level Trends, B. D. Hamlington, R. R. Leben, M. W. Strassburg, R. S. Nerem, K-Y. Kim 2013 Old Dominion University

Contribution Of The Pacific Decadal Oscillation To Global Mean Sea Level Trends, B. D. Hamlington, R. R. Leben, M. W. Strassburg, R. S. Nerem, K-Y. Kim

CCPO Publications

Understanding and explaining the trend in global mean sea level (GMSL) have important implications for future projections of sea level rise. While measurements from satellite altimetry have provided accurate estimates of GMSL, the modern altimetry record has only now reached 20 years in length, making it difficult to assess the contribution of decadal to multidecadal climate signals to the global trend. Here, we use a sea level reconstruction to study the 20 year trends in sea level since 1950. In particular, we show that the Pacific Decadal Oscillation (PDO) contributes significantly to the 20 year trends in GMSL. We estimate …


Intrusion Of Warm Surface Water Beneath The Mcmurdo Ice Shelf, Antarctica, A. A. Stern, M. S. Dinniman, V. Zagorodnov, S. W. Tyler, D. M. Holland 2013 Old Dominion University

Intrusion Of Warm Surface Water Beneath The Mcmurdo Ice Shelf, Antarctica, A. A. Stern, M. S. Dinniman, V. Zagorodnov, S. W. Tyler, D. M. Holland

CCPO Publications

A 6 month temperature record collected below McMurdo Ice Shelf in 2011-2012 shows the temporal and spatial structure of the summertime warm water signal that penetrates beneath the ice shelf. The strength and duration of the warm water intrusion suggest an annual melt rate at Windless Bight of 0.71 m/yr. A Ross Sea numerical model demonstrates a seasonal warm water pathway leading from the west side of the Ross Sea Polynya (RSP) toward McMurdo Sound. The warm water enters McMurdo Sound, subducts beneath the ice shelf and causes accelerated summer melting. Temperature data were recorded using Distributed Temperature Sensing fiber …


An Analysis Of Surface Air Temperature Trends And Variability Along The Andes, Eric Franquist 2013 University at Albany, State University of New York

An Analysis Of Surface Air Temperature Trends And Variability Along The Andes, Eric Franquist

Legacy Theses & Dissertations (2009 - 2024)

Climate change is difficult to study in mountainous regions such as the Andes since steep changes in elevation cannot always be resolved by climate models. However, it is important to examine temperature trends in this region as rises in surface air temperature are leading to the melting of tropical glaciers. Local communities rely on the glacier-fed streamflow to get their water for drinking, irrigation, and livestock. Moreover, communities also rely on the tourism of hikers who come to the region to view the glaciers. As the temperatures increase, these glaciers are no longer in equilibrium with their current climate and …


The Motion Of Mesoscale Snowbands In Northeast U.S. Winter Storms, Jaymes Kenyon 2013 University at Albany, State University of New York

The Motion Of Mesoscale Snowbands In Northeast U.S. Winter Storms, Jaymes Kenyon

Legacy Theses & Dissertations (2009 - 2024)

The distribution of snowfall accumulation attending winter storms is a product of both precipitation intensity and duration. Many heavy snowfall events are associated with distinct mesoscale snowbands that strongly modulate snowfall accumulation. Mesoscale snowbands are known to be favored within environments characterized by frontogenesis in the presence of weak moist symmetric or gravitational stabilities. Although the development of mesoscale snowbands often can be anticipated at 24–36-h ranges, anticipating band residence time at a fixed location remains a forecasting challenge. However, given that snowband residence time is related to characteristics of band motion, improved understanding of band motion presents an opportunity …


Solar Radiation Measurements And Their Applications In Climate Research, Bangsheng Yin 2013 University at Albany, State University of New York

Solar Radiation Measurements And Their Applications In Climate Research, Bangsheng Yin

Legacy Theses & Dissertations (2009 - 2024)

Aerosols and clouds play important roles in the climate system through their radiative effects and their vital link in the hydrological cycle. Accurate measurements of aerosol and cloud optical and microphysical properties are crucial for the study of climate and climate change. This study develops/improves retrieval algorithms for aerosol single scattering albedo (SSA) and low liquid water path (LWP) cloud optical properties, evaluates a new spectrometer, and applies long-term measurements to establish climatology of aerosol and cloud optical properties. The following results were obtained.


Interactions Between African Easterly Waves And Moist Convection, Matthew Adam Janiga 2013 University at Albany, State University of New York

Interactions Between African Easterly Waves And Moist Convection, Matthew Adam Janiga

Legacy Theses & Dissertations (2009 - 2024)

African easterly waves (AEWs) over tropical Africa and the East Atlantic influence and are themselves influenced by moist convection. Data from the Tropical Rainfall Measuring Mission (TRMM) satellite, reanalyses, and in-situ observations are used to examine both directions of this two-way interaction.


Study Of Key Factors Influencing Dust Emission : An Assessment Of Geos-Chem And Dead Simulations With Observations, Kevin Scott Bartlett 2013 University at Albany, State University of New York

Study Of Key Factors Influencing Dust Emission : An Assessment Of Geos-Chem And Dead Simulations With Observations, Kevin Scott Bartlett

Legacy Theses & Dissertations (2009 - 2024)

Mineral dust aerosols can impact air quality, climate change, biological cycles, tropical cyclone development and flight operations due to reduced visibility. Dust emissions are primarily limited to the extensive arid regions of the world, yet can negatively impact local to global scales, and are extremely complex to model accurately. Within this dissertation, the Dust Entrainment And Deposition (DEAD) model was adapted to run, for the first known time, using high temporal (hourly) and spatial (0.3°x0.3°) resolution data to methodically interrogate the key parameters and factors influencing global dust emissions. The dependence of dust emissions on key parameters under various conditions …


Evaluating Drought In The United States Using The Emissivity Difference Vegetation Index, Hanisha Hirani 2013 University at Albany, State University of New York

Evaluating Drought In The United States Using The Emissivity Difference Vegetation Index, Hanisha Hirani

Legacy Theses & Dissertations (2009 - 2024)

As monitoring vegetation and crops becomes increasingly important due to climate change, there arises the need for a monitoring scheme that places more weight on water availability as an indication of vegetation health and vitality. The Emissivity Difference Vegetation Index (EDVI) is the first step towards that type of monitoring scheme. With the potential for diurnal studies, there are applications towards agriculture monitoring, wildfire monitoring, and much more. EDVI is a synergetic product retrieved from microwave, visible, and infrared satellite measurements, as well as reanalysis. Since microwave measurements are more sensitive to vegetation water content, EDVI has the potential to …


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