Oil, Gas, and Energy Commons^™

Simulation Of The Pyrolysis Process Of Tar-Rich Coals In An H2O Atmosphere Based On The Reactive Force Field Molecular Dynamics, Huang Zibo, Liu Qianru, Liu Hong, Zhou Wenjing, Wei Jinjia

Coal Geology & Exploration

Objective Tar-rich coal resources, abundant in China, can be converted into energy products (e.g., chemicals and gas/liquid fuels) through pyrolysis, thus alleviating the country’s dependence on oil and gas imports. A thorough understanding of the product evolution and reaction mechanisms of the pyrolysis of tar-rich coals is crucial to research into the clean and efficient conversion processes of coals. Methods Based on the reactive force field molecular dynamics (ReaxFF MD), this study simulated the pyrolysis process of tar-rich coals (long-flame coals) and explored the impacts of the H₂O atmosphere on the distribution of pyrolytic products, along with the …

Spatiotemporal Distributions Of Typical Contaminants From The In-Situ Pyrolysis Of Tar-Rich Coals, Tian Hua, Zhang Ruolin, Wang Qianji, Wu Xiaoyu, Zhang Lei, Zhang Lingru, Fang Siyuan

Coal Geology & Exploration

Objective and Methods Under high temperatures, oil and gas produced from the in situ pyrolysis of tar-rich coals will migrate toward and accumulate in the overburden strata after passing through the fracture zones on the coal seam roof, causing potential contamination risks for the underground environment. To understand the release and distribution characteristics of typical contaminants generated from the underground pyrolysis of tar-rich coals, this study investigated the typical tar-rich coals from the Shenfu mining area of the Jurassic coalfield in northern Shaanxi Province. Based on data on the stratigraphic structures and lithology and using the self-developed equipment for similarity …

Downhole Heaters For In-Situ Pyrolysis Of Tar-Rich Coals：A Review And Prospects, Wang Zhendong, Duan Zhonghui, Yang Fu, Ma Li

Coal Geology & Exploration

Significance China boasts abundant tar-rich coal resources, which prove to be potential coal-based oil and gas resources capable of ensuring China's energy security. Extracting hydrogen while preserving carbon through the in-situ pyrolysis of tar-rich coals has developed into a trend in the clean and low-carbon utilization of coal resources. Downhole heaters serve as critical equipment for the efficient in-situ pyrolysis of tar-rich coals. Advances Based on investigations and the systematic collection of relevant information and data, this study offers a brief introduction of the currently used methods for in-situ convection heating, focusing on the present situation of the research and …

Exploring The Pyrolysis Of Tar-Rich Coals Under The Catalysis Of Cerium-Modified Magnetic Core-Shell Hzsm-5, Zhou Anning, Zhang Zhi, Chen Yongan, Zhang Huaiqing, Bai Zhuangwei, Shi Zhiwei, He Xinfu

Coal Geology & Exploration

Objective Tar-rich coals are valuable resources integrating coal, tar, and gas properties. Catalytic pyrolysis serves as a significant approach for achieving green and low-carbon development of tar-rich coals. However, the research and development of efficient and recyclable catalysts for the pyrolysis of tar-rich coals remains highly challenging. Methods With HZSM-5@SiO₂@MgFe₂O₄ (HSMF) as the raw material, this study prepared HZSM-5@SiO₂@MgFe₂O₄ (mHSMF) with a hierarchical porous structure using the hydrothermal method and alkali modification, followed by the preparation of cerium-modified mHSMF (5-CeO₂/mHSMF) using the precipitation method. Employing a fixed-bed reactor, …

Table Of Contents, The Editors

Coal Geology & Exploration

No abstract provided.

Strategic Value And Scientific Exploration Of In-Situ Pyrolysis Of Tar-Rich Coals, Wang Shuangming, Shi Qingmin, Sun Qiang, Cui Shidong, Kou Bingyang, Qiao Junwei, Geng Jishi, Zhang Lei, Tian Hua, Jiang Pengfei, Cai Yue, Liu Lang

Coal Geology & Exploration

Background Given China's significant demand shortfall of oil and gas, numerous constraints on oil and gas supply, an arduous task of green and low-carbon energy transition of coals, tar-rich coals, a type of coal resource integrating the properties of coal, oil, and gas, have great potential for increasing the oil and gas supply of the country. Advances Despite the successful engineering test conducted in Yulin, Shaanxi Province, in-situ pyrolysis of tar-rich coals remains in its exploratory stage. This technology holds great strategic value in two aspects: (1) It enables reduced demand shortfall of oil and gas in China to enhance …

Numerical Simulations Of The Evolutionary Patterns Of Multi-Physical Fields During The In-Situ Pyrolysis Of Tar-Rich Coals, Yang Fu, Cheng Xiangqiang, Li Mingjie, Wu Zhiqiang, Wei Jinjia, Cao Husheng

Coal Geology & Exploration

Objective The in-situ pyrolysis of tar-rich coals, an emerging technology for coal resource utilization characterized by cleanliness, high efficiency, and safety, is still in its initial development stage. This technology is greatly influenced by the evolutionary patterns of multi-physical fields and critical process parameters. Methods A numerical simulation model involving multi-physical fields was established by coupling fluid flow, heat transfer, and chemical reactions, and its reliability was verified by comparing the numerical simulation results with the pyrolysis experimental results of cylindrical coal samples. Based on the pilot test conditions, the impacts of permeability, heat-carrier flow rate, and fracture zone height …

Impacts Of The Caking Property Of Tar-Rich Coals On Their Pore Structure Evolution And Seepage During Pyrolysis, Chang Zhibing, Wang Chuchu, Kuang Wenhao, Tang Ying, Wu Xiaodan, Liu Shuqin

Coal Geology & Exploration

Objective The in-situ pyrolysis of tar-rich coals stands as a technique whereby coal seams are heated underground to produce tar and gas products. During the in-situ pyrolysis, the injection of heating media and the production of tar and gas are affected by the pore structure and permeability of coal seams. Since pyrolysis of caking tar-rich coals is accompanied by the formation of colloids, the pore structure and permeability of caking tar-rich coals differ from those of non-caking tar-rich coals. Methods Caking tar-rich coals were pyrolyzed at 300, 400, 500, and 600 ℃. During the pyrolysis, the pore parameters of the …

Identification Of Tar-Rich Coal Based On The True Density And Natural Gamma Ray Response Of Coals, Shi Qingmin, Geng Xuhu, Wang Shuangming, Cai Yue, Han Bo, Wang Shengquan, Zhang Zhehao, He Yufei

Coal Geology & Exploration

Objective Tar yield, derived from the Gray-King assay, serves as the sole metric for evaluating tar-rich coal. However, insufficient exploration data hinder its effective application in the fine-scale evaluation of extensive tar-rich coal. Methods Based on binary classification, this study proposed the optimal thresholds for tar-rich coal identification using true density (ρ) and natural gamma-ray (GR) log. Moreover, this study elucidated the intrinsic mechanisms behind the significant petrophysical parameter responses of tar-rich coal. Results and Conclusions Key findings are as follows: (1) Coals with various metamorphic grades differ in identification threshold. For instance, long-flame tar-rich coal, the optimal …

A Log-Based Method For Evaluating The Tar Yield Of Tar-Rich Coal, Tian Han, Li Ning, Wang Shuangming, Wu Hongliang, Feng Zhou, Wang Kewen, Wang Guiwen

Coal Geology & Exploration

Objective As a kind of coal-based oil and gas resource, tar-rich coal is significant for the supply of oil and gas resources, as well as the clean and efficient utilization of coals. Presently, the identification of tar-rich coals primarily depends on the Gray-King assay. In contrast, there is a lack of studies on the accurate identification and evaluation of tar-rich coal using geophysical methods. Methods This study investigated coals in the Jurassic Xishanyao and Badaowan Formations in Santanghu Basin, Xinjiang. Based on petrophysical experiments, as well as the typical log response characteristics of tar-rich coal, this study developed a new …

A Method For Predicting The Tar Yield Of Tar-Rich Coals Based On The Bp Neural Network Using Multiple Indicators Of Coal Petrography And Coal Quality, Qiao Junwei, Wang Changjian, Zhao Hongchao, Shi Qingmin, Zhang Yu, Fan Qi, Wang Duo, Yuan Dandan

Coal Geology & Exploration

Objective Tar yield, the most important coal quality parameter for coal utilization through low-temperature pyrolysis, determines the clean utilization of tar-rich coals. However, various constraints result in limited test data on tar yield in the geological exploration stage of coals, substantially restricting the fine-scale assessment and efficient utilization of tar-rich coals. Methods To achieve more scientific and accurate fine-scale tar-rich coal assessments, this study examined 1073 sets of lithotype and coal quality data obtained previously from a Jurassic coalfield in northern Shaanxi. From these data, 141 sets with 20 lithotype and coal quality parameters regarding macerals, proximate analysis, ultimate analysis, …

Performance Of Carbon Foams Based On Heavy Tar Produced By Tar-Rich Coal Pyrolysis, Zhang Lei, Liu Chunjiang, Song Ruikang, Wang Qi, Chen Ya, Huang Pengcheng

Coal Geology & Exploration

Objective Preparing graphitized foam materials using heavy tar produced by the pyrolysis of tar-rich coals plays a significant role in the high-value utilization of tar-rich coal resources. Methods This study aims to prepare high-performance carbon foam materials by investigating the relationships between various reaction conditions and carbon foam performance. First, using mesophase asphalt prepared with heavy tar as the precursor, carbon foams were developed via the high-temperature self-foaming method. Then, the effects of different reaction temperatures, heating rates, and reaction pressures on the performance of coal tar-based carbon foams were examined. Finally, quadratic multinomial regression equations were established using Box-Behnken …

Molecular Modeling Of Tar-Rich Coals From Northern Shaanxi And Their Molecular Dynamic Characteristics In The Process Of Pyrolysis For Tar Extraction, Guo Wei, Yang Panxi, Yu Zunyi, Yang Fu, Wang Jing, Ma Li, Li Hongqiang, Yang Bolun, Wu Zhiqiang

Coal Geology & Exploration

Objective The pyrolysis process and mechanism of tar-rich coals remain unclear due to their complex structures. Therefore, it is necessary to investigate the structure-activity relationship between their structure and the distributions of their pyrolytic products and determine the mechanism behind their pyrolysis for tar extraction. Methods Focusing on typical tar-rich coals from northern Shaanxi Province, this study calculated and constructed the molecular model of the coals using characterization methods such as carbon-13 nuclear magnetic resonance (¹³C NMR), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS), determining the molecular formula at C₄₄₄H₃₈₀O_{74 …}

Advances In Research On Hydrogenation Saturation Of Polycyclic Aromatic Hydrocarbons In Coal Tar, He Xinfu, Gao Fan, Wu Hongju, Zhang Xiaoqin, Ma Tao, Shi Zhiwei, Zhou Anning, Zhang Yating

Coal Geology & Exploration

Significance Polycyclic aromatic hydrocarbons (PAHs), a predominant component in coal tar, can be used to produce jet fuels with high energy density and thermal stability through hydrogenation saturation. Based on the characteristics of the PAH hydrogenation process, this study proposed that primary challenges in PAH hydrogenation saturation include the resonance energy of PAHs themselves, the spatial site resistance of hydrogenation intermediates, and the competitive adsorption of feedstocks and intermediates on active sites in the catalysts. Progress Based on the review of research progress in catalysts for PAH hydrogenation saturation in recent years, this study analyzed the substantial factor influencing the …

Green Transition Situations And Development Suggestions For Upstream Petroleum Industry, Lirong Dou, Feng Gao, Yun Peng, Xi Wang, Liang Xiong

Bulletin of Chinese Academy of Sciences (Chinese Version)

In the current global energy transition process, which is accelerating overall but with further uncertainty, the global oil and gas industry is showing four major trends: a shift in business structure from oil and gas dominance to multi-energy complementarity, a shift in market structure from globalization to differentiation between the Eastern and Western hemispheres, a shift in policy orientation from radical transition to orderly development, and an expansion of technological innovation from traditional to emerging fields. Governments of various countries and international oil companies have made adjustments to policies, strategic goals, implementation paths, and other aspects based on their own …

The Growth Of Ethanol In Brazil: Sugarcane, Corn, And A Few Other Things, Fabio Mattos

Cornhusker Economics

Although we can expect more ethanol produced from corn in the coming years, it is unclear whether it will keep expanding at the same pace as in recent years or how much it will contribute to total ethanol production.

One point to keep an eye on is the typical dynamics of markets. If supply and demand conditions and price movements make corn-ethanol more profitable, ethanol plants in Brazil will keep increasing their production. If it makes more economic sense to produce corn-ethanol (as it happened recently), they will use more corn to produce ethanol.

Supply and demand conditions for ethanol, …

Influence Of The Moisture On Fumes Derived From The Anfo Detonation, Andrzej Biessikirski, Mateusz Pytlik, Michał Dworzak, Michał Twardosz, Mariusz Wądrzyk, Rafał Janus

Journal of Sustainable Mining

ANFO is one of the most commonly used explosives in open-pit mining, usually produced by mixing systems on the blast site. One of the problems usually not considered is the moisture”s influence on the stored ammonium nitrate(V). The influence of moisture on fumes and the detonation process has been investigated by placing ammonium nitrate(V) prills in the climatic chamber. In the investigation, the influence was evaluated for ANFO samples which were produced based on the two types of fuel oils. It was concluded that the 3.0% moisture level resulted in the lowest NOx content in both case studies. Further increased …

Optimization Of A Plate Beam System For Energy Harvesting Using A Piezoelectric Material, Jose Manuel Almendros Espantaleon

Doctoral Dissertations and Master's Theses

With a continuously growing demand for power, driven by the need to reduce our environmental footprint, this research provides an examination of the potential of energy harvesting with smart materials technology and its practical applications. The energy harvesting system considered here works on generating energy through vibrations of a piezoelectric material beam which will undergo sustained vibrations due to flow of air over its surface. It is assumed that sustained limit cycle oscillations of this system will occur at the flutter velocity. This research creates an optimization framework to obtain the best values of parameters that will result in the …

Table Of Contents, The Editors

Coal Geology & Exploration

No abstract provided.

Factors Influencing The Productivity And Technology Optimization Of Horizontal Wells For Moderately Deep Coalbed Methane In The Northern Zhengzhuang Block, Zhang Cong, Li Kexin, Jia Huimin, Zhang Wuchang, Yang Ruiqiang, Li Jun, Wang Qi, Hou Weiming

Coal Geology & Exploration

[Objective] Hydraulic fracturing of vertical wells was adopted during the early production of moderately deep coalbed methane (CBM) of the northern Zhengzhuang block in the Qinshui Basin, generally yielding low productivity and inefficiency. In contrast, single-casing fracturing of horizontal wells has increased the single-well production to 10‒50 times that of vertical wells, establishing horizontal wells as the dominant development well type. However, the horizontal wells differ greatly in CBM production. This study aims to determine the factors influencing the productivity of horizontal wells using staged fracturing for moderately deep CBM in the northern Zhengzhuang block and improve the production performance. …