Atomic, Molecular and Optical Physics Commons^™

Indium Segregation To The Selvedge Of In4Se3 (001), Archit Dhingra, Zoe G. Marzouk, Esha Mishra, Pavlo V. Galiy, Taras M. Nenchuk, Peter Dowben

Peter Dowben Publications

Thermal motion of the surface atoms will lead to a decrease in photoemission intensity, while surface segregation may result in an increase of some phostoemission intensities. For In4Se3(001), both effects are seen. The Debye–Waller factor plot, based on the temperature dependent X-ray photoemission spectroscopy (XPS) measurements on In4Se3(001), suggests an upper bound of 203 ± 6 K for the effective Debye temperature, based on the surface component of the In 3d5/2 core-level. Indium is found to segregate to selvedge (subsurface region) of the crystal.

Site Selective Adsorption Of The Spin Crossover Complex Fe(Phen)2(Ncs)2 On Au(111), Sumit Beniwal, Suchetana Sarkar, Felix Baier, Birgit Weber, Peter Dowben, Axel Enders

Peter Dowben Publications

The iron(II) spin crossover complex Fe(1,10-phenanthroline)₂(NCS)₂, dubbed Fe-phen, has been studied with scanning tunneling microscopy, after adsorption on the 'herringbone' reconstructed surface of Au(111) for sub-monolayer coverages. The Fe-phen molecules attach, through their NCS-groups, to the Au atoms of the fcc domains of the reconstructed surface only, thereby lifting the herringbone reconstruction. The molecules stack to form 1D chains, which run along the Au[110] directions. Neighboring Fe-phen molecules are separated by approximately 2.65 nm, corresponding to 9 atomic spacings in this direction. The molecular axis, defined by the two phenanthroline groups, is aligned perpendicular to the …

Generation Of Correlated Dual Frequency Combs With Pm Fiber Lasers For High-Precision Metrology, Hanieh Afkhamiardakani

Optical Science and Engineering ETDs

Intracavity Phase Interferometry (IPI) using two correlated, counter-propagating frequency combs (pulse trains) in mode-locked lasers has evolved into a powerful technique for high-precision metrology. In this method a physical parameter to be measured imparts a phase shift onto a pulse circulating in the laser cavity. Inside a laser cavity, that phase shift becomes a frequency shift (phase shift/round-trip time) applied to the whole frequency comb created by this pulse as it exits the cavity at each round-trip. This frequency shift is measured by interfering this comb with a reference comb created by a reference pulse circulating in the same mode-locked …

Growth Of Semi-Polar (11-22) Gan Epitaxial Layer On M-Plane Sapphire Via Mocvd, Anuar Mohd Afiq

Student Works (2020-2029)

In the past few years, semi-polar (11-22) GaN has attracted much intention in the field of optoelectronics including light-emitting diodes (LEDs), laser diodes (LDs) and photodetectors. Commercially, GaN-based optoelectronic devices are grown along c-plane direction. However, c-oriented GaN-based optoelectronics suffer from piezoelectric polarization, which hinders the device performances. Conversely, semi-polar (11-22) GaN exhibits almost zero piezoelectric polarization effect. Furthermore, as the GaN wurtzite lattice is inclined approximately 58° respective to c-plane, it provides more sites for doping incorporation such as indium, silicon, aluminium, etc. Therefore, the semi-polar (11-22) GaN is presumed to be one of a promising candidate for efficient …

Surface Termination And Schottky-Barrier Formation Of In4Se3(001), Archit Dhingra, Pavlo V. Galiy, Lu Wang, Nataliia S. Vorobeva, Alexey Lipatov, Angel Torres, Taras M. Nenchuk, Simeon J. Gilbert, Alexander Sinitskii, Andrew J. Yost, Wai-Ning Mei, Keisuke Fukutani, Jia Shiang Chen, Peter Dowben

Peter Dowben Publications

The surface termination of In₄Se₃(001) and the interface of this layered trichalcogenide, with Au, was examined using x-ray photoemission spectroscopy. Low energy electron diffraction indicates that the surface is highly crystalline, but suggests an absence of C2v mirror plane symmetry. The surface termination of the In₄Se₃(001 is found, by angle-resolved x-ray photoemission spectroscopy, to be In, which is consistent with the observed Schottky barrier formation found with this n-type semiconductor. Transistor measurements confirm earlier results from photoemission, suggesting that In₄Se₃(001 is an n-type semiconductor, so that Schottky barrier …

Questaal: A Package Of Electronic Structure Methods Based On The Linear Muffin-Tin Orbital Technique, Dimitar Pashov, Swagata Acharya, Walter R.L. Lambrecht, Jerome Jackson, Kirill Belashchenko, Athanasios Chantis, Francois Jamet, Mark Van Schilfgaarde

Kirill Belashchenko Publications

This paper summarises the theory and functionality behind Questaal, an open-source suite of codes for calculating the electronic structure and related properties of materials from first principles. The formalism of the linearised muffin-tin orbital (LMTO) method is revisited in detail and developed further by the introduction of short-ranged tight-binding basis functions for full-potential calculations. The LMTO method is presented in both Green's function and wave function formulations for bulk and layered systems. The suite's full-potential LMTO code uses a sophisticated basis and augmentation method that allows an efficient and precise solution to the band problem at different levels of theory, …

The Emergence Of The Local Moment Molecular Spin Transistor, Guanhua Hao, Ruihua Cheng, Peter Dowben

Peter Dowben Publications

Local moment molecular systems have now been used as the conduction channel in gated spintronics devices, and some of these three terminal devices might even be considered molecular spin transistors. In these systems, the gate voltage can be used to tune the molecular level alignment, while applied magnetic fields have an influence on the spin state, altering the magnetic properties, and providing insights to the magnetic anisotropy. More recently, the use of molecular spin crossover complexes, as the conduction channel, has led to devices that are both nonvolatile and have functionality at higher temperatures. Indeed, some devices have now been …

Probing Ferroelectricity By X-Ray Absorption Spectroscopy In Molecular Crystals, Fujie Tang, Xuanyuan Jiang, Hsin Yu Ko, Jianhang Xu, Mehmet Topsakal, Guanhua Hao, Alpha T. N'Diaye, Peter Dowben, Deyu Lu, Xiaoshan Xu, Xifan Wu

Peter Dowben Publications

We carry out X-ray absorption spectroscopy experiment at the oxygen K edge in croconic acid (C₅H₂O₅) crystal as a prototype of ferroelectric organic molecular solid, whose electric polarization is generated by proton transfer. The experimental spectrum is well reproduced by the electron-hole excitation theory simulations from configuration generated by ab initio molecular dynamics simulation. When inversion symmetry is broken in the ferroelectric state, the hydrogen bonding environment on the two bonded molecules become inequivalent. Such a difference is sensitively probed by the bound excitation in the pre-edge, which is strongly localized on the excited …

Effects Of Intrinsic Defects And Alloying With Fe On The Half-Metallicity Of Co2Mnsi, G. G. Baez Flores, Ivan A. Zhuravlev, Kirill Belashchenko

Kirill Belashchenko Publications

The electronic structure and half-metallic gap of Co2MnSi in the presence of crystallographic defects, partial Fe substitution for Mn, and thermal spin fluctuations are studied using the coherent potential approximation and the disordered local moment method. In the presence of 5% Co or Mn vacancies the Fermi level shifts down to the minority-spin valence-band maximum. In contrast to NiMnSb, both types of Mn antisite defects in Co2MnSi are strongly exchange coupled to the host magnetization, and thermal spin fluctuations do not strongly affect the half-metallic gap. Partial substitution of Mn by Fe results in considerable changes in the Bloch spectral …

Dual-Axis Solar Tracker, Bryan Kennedy

All Undergraduate Projects

Renewable energies, and fuels that are not fossil fuel-based, are one of the prolific topics of debate in modern society. With climate change now becoming a primary focus for scientists and innovators of today, one of the areas for the largest amount of potential and growth is that of the capturing and utilization of Solar Energy. This method involves using a mechanical system to track the progression of the sun as it traverses the sky throughout the day. A dual-axis solar tracker such as the one designed and built for this project, can follow the sun both azimuthally and in …

Diffusion Doping Of Cobalt In Rod-Shape Anatase Tio2 Nanocrystals Leads To Antiferromagnetism†, Shahzahan Mia, Shelton J.P. Varapragasam, Aravind Baride, Choumini Balasanthiran, Balamurugan Balasubramanian, Robert M. Rioux, James D. Hoefelmeyer

Nebraska Center for Materials and Nanoscience: Faculty Publications

Cobalt(II) ions were adsorbed to the surface of rod-shape anatase TiO2 nanocrystals and subsequently heated to promote ion diffusion into the nanocrystal. After removal of any remaining surface bound cobalt, a sample consisting of strictly cobalt-doped TiO2 was obtained and characterized with powder Xray diffraction, transmission electron microscopy, UV-visible spectroscopy, fluorescence spectroscopy, X-ray photoelectron spectroscopy, SQUID magnetometry, and inductively-coupled plasma atomic emission spectroscopy. The nanocrystal morphology was unchanged in the process and no new crystal phases were detected. The concentration of cobalt in the doped samples linearly correlates with the initial loading of cobalt(II) ions on the nanocrystal surface. Thin …

Detection Of Decoupled Surface And Bulk States In Epitaxial Orthorhombic Sriro3 Thin Films, Prescott E. Evans, Takashi Komesu, Le Zhang, Ding-Fu Shao, Andrew J. Yost, Shiv Kumar, Eike F. Schwier, Kenya Shimada, Evgeny Y. Tsymbal, Xia Hong, P. A. Dowben

Peter Dowben Publications

We report the experimental evidence of evolving lattice distortion in high quality epitaxial orthorhombic SrIrO3(001) thin films fully strained on (001) SrTiO3 substrates. Angle-resolved X-ray photoemission spectroscopy studies show that the surface layer of 5 nm SrIrO3 films is Sr–O terminated, and subsequent layers recover the semimetallic state, with the band structure consistent with an orthorhombic SrIrO3(001) having the lattice constant of the substrate. While there is no band folding in the experimental band structure, additional super-periodicity is evident in low energy electron diffraction measurements, suggesting the emergence of a transition layer with crystal symmetry evolving from the SrTiO3 substrate …

Manipulation Of The Molecular Spin Crossover Transition Of Fe(H2b(Pz)2)2(Bipy) By Addition Of Polar Molecules, Paulo S. Costa, Guanhua Hao, Alpha T. N'Diaye, Lucie Routaboul, Pierre Braunstein, Xin Zhang, Jian Zhang, Thilini K. Ekanayaka, Qin Yin Shi, V. L. Schlegel, Bernard Doudin, Axel Enders, Peter Dowben

Peter Dowben Publications

The addition of various dipolar molecules is shown to affect the temperature dependence of the spin state occupancy of the much studied spin crossover Fe(II) complex, [Fe{H2B(pz)2}2(bipy)] (pz = pyrazol-1-yl, bipy = 2,2′-bipyridine). Specifically, the addition of benzimidazole results in a re-entrant spin crossover transition, i.e. the spin state starts in the mostly low spin state, then high spin state occupancy increases, and finally the high spin state occupancy decreases with increasing temperature. This behavior contrasts with that observed when the highly polar p -benzoquinonemonoimine zwitterion C6H2(..NH2)2(..O)2 was mixed with [Fe{H2B(pz)2}2(bipy)], which resulted in locking [Fe{H2B(pz)2}2(bipy)] largely into a low …

Quantitative Study Of The Energy Changes In Voltage-Controlled Spin Crossover Molecular Thin Films, Aaron Mosey, Ashley S. Dale, Guanhua Hao, Alpha T. N’Diaye, Peter Dowben, Ruihua Cheng

Peter Dowben Publications

Voltage-controlled nonvolatile isothermal spin state switching of a [Fe{H2B(pz)₂}₂(bipy)] (pz=tris(pyrazol-1-1y)-borohydride, bipy=2,2’-bipyridine) film, more than 40 to 50 molecular layers thick, is possible when it is adsorbed onto a molecular ferroelectric substrate. Accompanying this high spin and low spin state switching, at room temperature, we observe a remarkable change in conductance, thereby allowing not only non-volatile voltage control of the spin state (“write”), but also current sensing of the molecular spin state (“read”). Monte Carlo Ising model simulations of the high spin state occupancy, extracted from x-ray absorption spectroscopy, indicate that the energy difference between the low …

Ferroelectric Domain Wall Memristor, James P. V. Mcconville, Haidong Lu, Bo Wang, Yueze Tan, Charlotte Cochard, Michele Conroy, Kalani Moore, Alan Harvey, Ursel Bangert, Long-Qing Chen, Alexei Gruverman, J. M. Gregg

Alexei Gruverman Publications

A domain wall-enabled memristor is created, in thin film lithium niobate capacitors, which shows up to twelve orders of magnitude variation in resistance. Such dramatic changes are caused by the injection of strongly inclined conducting ferroelectric domain walls, which provide conduits for current flow between electrodes. Varying the magnitude of the applied electric-field pulse, used to induce switching, alters the extent to which polarization reversal occurs; this systematically changes the density of the injected conducting domain walls in the ferroelectric layer and hence the resistivity of the capacitor structure as a whole. Hundreds of distinct conductance states can be produced, …

Chiral Magnetism And High-Temperature Skyrmions In B20-Ordered Co-Si, Balamurugan Balasubramanian, Priyanka Manchanda, Rabindra Pahari, Zhen Chen, Wenyong Zhang, Shah R. Valloppilly, Xingzhong Li, Anandakumar Sarella, Lanping Yue, Ahsan Ullah, Pratibha Dev, David A. Muller, Ralph Skomski, George C. Hadjipanayis, David J. Sellmyer

Nebraska Center for Materials and Nanoscience: Faculty Publications

Magnets with chiral crystal structures and helical spin structures have recently attracted much attention as potential spin-electronics materials, but their relatively low magnetic-ordering temperatures are a disadvantage. While cobalt has long been recognized as an element that promotes high-temperature magnetic ordering, most Co-rich alloys are achiral and exhibit collinear rather than helimagnetic order. Crystallographically, the B20-ordered compound CoSi is an exception due to its chiral structure, but it does not exhibit any kind of magnetic order. Here, we use nonequilibrium processing to produce B20-ordered Co_1+xSi_1−x with a maximum Co solubility of x = 0.043. Above a critical …

Rod-Shape Theranostic Nanoparticles Facilitate Antiretroviral Drug Biodistribution And Activity In Human Immunodeficiency Virus Susceptible Cells And Tissues, Bhavesh D. Kevadiya, Brendan Ottemann, Insiya Z. Mukadam, Laura Castellanos, Kristen Sikora, James R. Hilaire, Jatin Machhi, Jonathan Herskovitz, Dhruvkumar Soni, Mahmudul Hasan, Wenting Zhang, Anandakumar Sarella, Jered Garrison, Joellyn Mcmillan, Benson Edagwa, R. Lee Mosley, Richard W. Vachet, Howard E. Gendelman

Nebraska Center for Materials and Nanoscience: Faculty Publications

Human immunodeficiency virus theranostics facilitates the development of long acting (LA) antiretroviral drugs (ARVs) by defining drug-particle cell depots. Optimal drug formulations are made possible based on precise particle composition, structure, shape and size. Through the creation of rod-shaped particles of defined sizes reflective of native LA drugs, theranostic probes can be deployed to measure particle-cell and tissue biodistribution, antiretroviral activities and drug retention.

Methods: Herein, we created multimodal rilpivirine (RPV) ¹⁷⁷lutetium labeled bismuth sulfide nanorods (¹⁷⁷LuBSNRs) then evaluated their structure, morphology, configuration, chemical composition, biological responses and adverse reactions. Particle biodistribution was analyzed by single …

Svat4: A Computer Program For Visualization And Analysis Of Crystal Structures, Xingzhong Li

Nebraska Center for Materials and Nanoscience: Faculty Publications

SVAT4 is a computer program for interactive visualization of three-dimensional crystal structures, including chemical bonds and magnetic moments. A wide range of functions, e.g. revealing atomic layers and polyhedral clusters, are available for further structural analysis. Atomic sizes, colors, appearance, view directions and view modes (orthographic or perspective views) are adjustable. Customized work for the visualization and analysis can be saved and then reloaded. SVAT4 provides a template to simplify the process of preparation of a new data file. SVAT4 can generate high-quality images for publication and animations for presentations. The usability of SVAT4 is broadened by a software suite …

A Short Remark On Vortex As Fluid Particle From Neutrosophic Logic Perspective, Victor Christianto, Florentin Smarandache

Branch Mathematics and Statistics Faculty and Staff Publications

In a previous paper in this journal (IJNS), it is mentioned about a possible approach to re-describe QED without renormalization route. As it is known that in literature, there are some attempts to reconcile vortex-based fluid dynamics and particle dynamics. Some attempts are not quite as fruitful as others. As a follow up to previous paper, the present paper will discuss two theorems for developing unification theories, and then point out some new proposals including by Simula (2020) on how to derive Maxwell equations in superfluid dynamics setting; this could be a new alternative approach towards “fluidicle” or “vorticle” model …

Slow Light With Interleaved P-N Junction To Enhance Performance Of Integrated Mach-Zehnder Silicon Modulators, Marco Passoni, Dario Gerace, Liam O'Faolain, Lucio Claudio Andreani

Cappa Publications

Slow light is a very important concept in nanophotonics, especially in the context of photonic crystals. In this work, we apply our previous design of band-edge slow light in silicon waveguide gratings [M. Passoni et al, Opt. Express 26, 8470 (2018)] to Mach-Zehnder modulators based on the plasma dispersion effect. The key idea is to employ an interleaved p-n junction with the same periodicity as the grating, in order to achieve optimal matching between the electromagnetic field profile and the depletion regions of the p-n junction. The resulting modulation efficiency is strongly improved as compared to common modulators based on …

New Heusler Compounds In Ni-Mn-In And Ni-Mn-Sn Alloys, Xingzhong Li, W.-Y. Zhang, Shah R. Valloppilly, David J. Sellmyer

Nebraska Center for Materials and Nanoscience: Faculty Publications

Rapidly quenched ternary Ni-Mn-T (T = In, Sn) alloys exhibit features associated with magnetic skyrmions, so that XRD, TEM, EDS, SAED and HREM investigations were carried out for structural characterization on the two alloy systems. In this paper, we report a new type of Mn-rich Heusler compound with a cubic unit cell, a = 0.9150 nm in Ni-Mn-In and a = 0.9051 nm in Ni-Mn-Sn, which coexist with a Ni-rich full-Heusler compound with defects, a = 0.6094 nm in Ni-Mn-In and a = 0.6034 nm in Ni-Mn-Sn. A further analysis of the experimental results reveals a close structural relationship between …

University Physics I: Classical Mechanics, Julio Gea-Banacloche

Open Educational Resources

This is a textbook for the first semester of University Physics for scientists and engineers. It covers classical mechanics, and a brief introduction to thermodynamics. The presentation and approach are similar to Mazur’s “The Principles and Practice of Physics,” in that conservation laws are introduced before forces, and one-dimensional systems thoroughly covered before moving to two dimensions. Although the course is “calculus based,” the book has been written with the understanding that many students may be taking calculus simultaneously as a corequisite, so the use of calculus is relatively sparse.

This revised version (Fall 2019) takes into account a number …

Boundary Conditions And Berry Phase In Magnetic Nanostructures, A. Ullah, B. Balamurugan, W. Zhang, D. J. Sellmyer, R. Skomski

Nebraska Center for Materials and Nanoscience: Faculty Publications

The effect of micromagnetic boundary conditions on the Berry curvature and topological Hall effect in granular nanostructures is investi- gated by model calculations. Both free surfaces and grain boundaries between interacting particles or grains affect the spin structure. The Dzyaloshinskii-Moriya interactions yield corrections to the Erdmann-Weierstrass boundary conditions, but the Berry curvature remains an exclusive functional of the local spin structure, which greatly simplifies the treatment of nanostructures. An explicit example is a model nanostructure with cylindrical symmetry whose spin structure is described by Bessel function and which yields a mean-field-type Hall-effect contribution that can be related to magnetic-force-microscopy images.

Crystal Structure And Dzyaloshinski–Moriya Micromagnetics, Ahsan Ullah, B. Balamurugan, Wuzhang Fang, Shah R. Valloppilly, Xingzhong Li, Rabindra Pahari, Lanping Yue, Andrei Sokolov, David J. Sellmyer, Ralph Skomski

Nebraska Center for Materials and Nanoscience: Faculty Publications

The relationship between atomic-scale and micromagnetic Dzyaloshinski–Moriya (DM) interactions has been investigated. By analyzing the Lifshitz invariants for different point groups, we have found that there is no unique link between the absence of inversion symmetry and DM interactions. The absence of inversion symmetry is a necessary condition for a net DM interaction in crystals, but several noncentrosymmetric point groups have zero DM interactions. In many cases, the key consideration is whether the crystals are polar and/or chiral. For example, MnSi-type spin spirals, which violate helical spin symmetry, are caused by the insertion of chiral atomic-scale building blocks into an …

Medium-Dependent Antibacterial Properties And Bacterial Filtration Ability Of Reduced Graphene Oxide, Alexander Gusev, Olga Zakharova, Dmitry S. Muratov, Nataliia S. Vorobeva, Mamun Sarker, Iaroslav Rybkin, Daniil Bratashov, Evgeny Kolesnikov, Aleš Lapanje, Denis V. Kuznetsov, Alexander Sinitskii

Nebraska Center for Materials and Nanoscience: Faculty Publications

Toxicity of reduced graphene oxide (rGO) has been a topic of multiple studies and was shown to depend on a variety of characteristics of rGO and biological objects of interest. In this paper, we demonstrate that when studying the same dispersions of rGO and fluorescent Escherichia coli (E. coli) bacteria, the outcome of nanotoxicity experiments also depends on the type of culture medium. We show that rGO inhibits the growth of bacteria in a nutrition medium but shows little effect on the behavior of E. coli in a physiological saline solution. The observed effects of rGO on E. …

Noncollinear Spin Structure In Fe3+Xco3−Xti2 (X = 0, 2, 3) From Neutron Diffraction, Haohan Wang, Balamurugan Balamurugan, Rabindra Pahari, Ralph Skomski, Yaohua Liu, Ashfia Huq, D. J. Sellmyer, Xiaoshan Xu

Xiaoshan Xu Papers

Neutron powder diffraction has been used to investigate the spin structure of the hard-magnetic alloy Fe_3+xCo_3−xTi₂ (x = 0, 2, 3). The materials are produced by rapid quenching from the melt, they possess a hexagonal crystal structure, and they are nanocrystalline with crystallite sizes D of the order of 40 nm. Projections of the magnetic moment onto both the crystalline c axis and the basal plane were observed. The corresponding misalignment angle exhibits a nonlinear decrease with x, which we explain as a micromagnetic effect caused by Fe-Co site disorder. The underlying physics is a …

Nonvolatile Voltage Controlled Molecular Spin State Switching, G. Hao, A. Mosey, X. Jiang, A. J. Yost, K. R. Sapkota, G. T. Wang, X. Zhang, J. Zhang, A. T. N'Diaye, R. Cheng, X. Xu, P. A. Dowben

Xiaoshan Xu Papers

Voltage-controlled room temperature isothermal reversible spin crossover switching of [Fe{H₂B(pz)₂}₂(bipy)] thin films is demonstrated. This isothermal switching is evident in thin film bilayer structures where the molecular spin crossover film is adjacent to a molecular ferroelectric. The adjacent molecular ferroelectric, either polyvinylidene fluoride hexafluoropropylene or croconic acid (C₅H₂O₅), appears to lock the spin crossover [Fe{H₂B(pz)₂}₂(bipy)] molecular complex largely in the low or high spin state depending on the direction of ferroelectric polarization. In both a planar two terminal diode structure and a …

Proximitized Materials, Igor Žutić, Alex Matos-Abiague, Benedikt Scharf, Hanan Dery, Kirill Belashchenko

Kirill Belashchenko Publications

Advances in scaling down heterostructures and having an improved interface quality together with atomically thin two-dimensional materials suggest a novel approach to systematically design materials. A given material can be transformed through proximity effects whereby it acquires properties of its neighbors, for example, becoming superconducting, magnetic, topologically nontrivial, or with an enhanced spin–orbit coupling. Such proximity effects not only complement the conventional methods of designing materials by doping or functionalization but also can overcome their various limitations. In proximitized materials, it is possible to realize properties that are not present in any constituent region of the considered heterostructure. While the …

Controlling The Magnetocrystalline Anisotropy Of E-Fe2o3, Imran Ahamed, Ralph Skomski, Arti Kashyap

Nebraska Center for Materials and Nanoscience: Faculty Publications

The magnetocrystalline anisotropy of pristine and Co-substituted ε-Fe₂O₃ is investigated by density functional calculations. The epsilon-iron oxide is the only polymorph of Fe₂O₃ magnetoelectric in its antiferromagnetic ground states other crystalline forms being α-Fe₂O₃ (hematite), β-Fe₂O₃, and γ-Fe₂O₃ (maghemite). The magnetizations of the four iron sublattices are antiferromagnetically aligned with slightly different magnetic moments resulting in a ferrimagnetic structure. Compared to the naturally occurring hematite and maghemite, bulk ε-Fe₂O₃ is difficult to prepare, but ε-Fe₂O₃ nanomaterials of different …

High Energy Product Of Mnbi By Field Annealing And Sn Alloying, Wenyong Zhang, Balamurugan Balasubramanian, Parashu Kharel, Rabindra Pahari, Shah R. Valloppilly, Xingzhong Li, Lanping Yue, Ralph Skomski, David J. Sellmyer

Nebraska Center for Materials and Nanoscience: Faculty Publications

Permanent-magnet materials are one cornerstone of today’s technology, abundant in disk drives, motors, medical equipment, wind gen- erators, and cars. A continuing challenge has been to reconcile high permanent-magnet performance with low raw-material costs. This work reports a Mn-Bi-Sn alloy exclusively made from inexpensive elements, exhibiting high values of Curie-temperature, magnetization, anisotropy, coercivity, and energy product. The samples are produced by field annealing of rapidly quenched Sn-containing MnBi alloys, where the improvement of the magnetic properties is caused by the substitutional occupancy of the 2c sites in the hexagonal NiAs structure by Sn. The substitution modifies the electronic structure of …