Oceanography Commons^™

An Investigation Of Dissolved Organic Matter In A Shallow Coastal Bay Subject To Aureococcus Anophagefferens Blooms, Jean-Paul Simjouw

OES Theses and Dissertations

Aureococcus anophagefferens, the pelagophyte responsible for brown tide blooms, was identified in Chincoteague Bay in 1997 and has “bloomed” there since at least 1998. Aureococcus anophagefferens is capable of using dissolved organic nitrogen (DON) and dissolved organic carbon (DOC) substrates to support growth, and this utilization is hypothesized to give the organism a competitive advantage relative to other phytoplankton when inorganic nutrient concentrations are low or depleted. Because previous studies suggest dissolved organic matter (DOM) is important in initiating and sustaining brown tide blooms, a field study of the variations in DOC concentration and DOM composition was performed at …

Methods And Models For Estimating Advective Pore Water Exchange In Tidal Flats, Timothy J. Shaw

Faculty Publications

No abstract provided.

Modeling The Biogeochemical Cycle Of Selenium In The San Francisco Bay, Shannon L. Meseck

OES Theses and Dissertations

Due to recent concerns about selenium toxicity in the San Francisco Bay and the roles of refinery and San Joaquin River inputs on the selenium cycle, the model ECoS 3 (distributed from Plymouth Marine Laboratory, United Kingdom) was modified to simulate the biogeochemical cycle of selenium in the Northern Reach. The model is designed to simulate salinity, total suspended material, phytoplankton concentrations, dissolved selenium and its speciation (selenite, selenate, and organic selenide), and particulate selenium and its speciation (selenite + selenate, elemental selenium, and organic selenide). Actual data from 1999 were used to calibrate the model, while data from other …

Nitrate Anomaly In The Upper Nutricline In The Northern South China Sea - Evidence For Nitrogen Fixation, George T. F. Wong, Shi-Wei Chung, Fuh-Kwo Shiah, Chung-Chi Chen, Liang-Saw Wen, Kon-Kee Liu

OES Faculty Publications

[1] Up to 2 μM of nitrate anomaly, N*, were found in the upper nutricline at the South East Asia Time-series Study (SEATS) site in the northern South China Sea (SCS). These concentrations were among the higher values reported in the Pacific and indicate the significant contribution of the remineralization of nitrogen-rich organic matter formed by nitrogen fixation to the nutrient dynamics of the area. The concentrations were systematically higher, by up to 2.5 μM, in the Fall through the early Spring, during the northeast monsoon, than in the Summer, suggesting that the impact of nitrogen fixation was higher during …

Arctic Ice Export Events And Their Potential Impact On Global Climate During The Late Pleistocene, Dennis A. Darby, Jens F. Bischof, Robert F. Spielhagen, Steven A. Marshall, Stephen W. Herman

OES Faculty Publications

Ice sheets in the North American Arctic and, to a lesser extent, those in northern Eurasia calved large quantities of icebergs that drifted through Fram Strait into the Greenland Sea several times during the late Pleistocene. These icebergs deposited Fe oxide grains (45-250 mum) and coarse lithic clasts >250 mum matched to specific circum-Arctic sources. Four massive Arctic iceberg export events are identified from the Laurentide and the Innuitian ice sheets, between 14 and 34 ka (calendar years) in a sediment core from Fram Strait. These relatively short duration (<1-4 kyr) events contain 3-5 times the background levels of Fe oxide grains. They began suddenly, as indicated by a steep rise in the number of grains matched to an ice sheet source, suggesting rapid purges of ice through Fram Strait, due perhaps to collapse of ice sheets. The larger events from the northwestern Laurentide ice sheet are preceded by events from the Innuitian ice sheet. Despite the chronological uncertainties, the Arctic export events appear to occur prior to Heinrich events.

Intra-Annual Variation In The Stable Oxygen And Carbon And Trace Element Composition Of Sclerosponges, P. K. Swart, S. Thorrold, B. Rosenheim, A. Eisenhauer, C. G. A. Harriason, M. Grammer, C. Latkoczy

Biological Sciences Faculty Publications

This paper presents data to support the presence of (1) intra-annual signals in the chemical composition (δ¹⁸O and Sr/Ca) of the skeletons ofsclerosponges from the Bahamas and (2) variable rates of skeletal accretion. These conclusions are based on data obtained by using a microsampling method for the stable oxygen and carbon isotopes in which material was extracted at a resolution of one sample every 34 μm and a laser microprobe which obtained trace element data every 20 μm (Sr, Mg, and Pb). An age model was established using a combination of changes in the concentration of Pb, the …

Dark Production: A Significant Source Of Oceanic Cos, M. Von Hobe, Gregory A. Cutter, A. J. Kettle, M. O. Andreae

OES Faculty Publications

Carbonyl sulfide (COS) in air and dissolved in seawater was determined during a cruise in August 1999 in the Sargasso Sea in the northwest Atlantic Ocean. Dissolved concentrations at the sea surface displayed only a weak diel cycle with a mean of 8.6 ± 2.8 pmol dm⁻³ owing to low abundance of photochemical precursors and high temperatures causing rapid hydrolysis. Depth profiles measured over the oceanic mixed layer revealed significant vertical gradients of COS concentration with higher values at the surface, suggesting that the rate of photochemical production at the surface exceeds the rate of vertical mixing. The mean …

Dynamical Sedimentary Models Of Shallow Marine Environments, Yong Zhang

OES Theses and Dissertations

This treatise represents a contribution of quantitative, dynamical sedimentary modeling to the analytical understanding of sedimentary processes in shallow marine environments. The dynamical sedimentary models in this treatise numerically simulate the sedimentary processes from an event time scale, based on the fundamental physics of sediment dynamics in coastal and shelf depositional environments, to a longer, facies time scale. The simulated geologic processes serve to the illustrate shoreface equilibrium profile, shelf storm bed generation, and the shelf sedimentary facies system.

This treatise presents a nearshore profile evolution model for the abandoned Huanghe Delta, a two-dimensional storm deposition model, and a sedimentary …

A Preliminary Assessment Of Tidal Flooding Along The New Hampshire Coast: Past, Present And Future, Larry G. Ward, Jamie R. Adams

Faculty Publications

This report presents the results of a preliminary study that examines several critical coastal issues for New Hampshire including sea level fluctuations (past, present and future), shoreline migrations, and tidal flooding. Included are: 1) an analysis of sea level changes over the Holocene and resulting shoreline migrations, 2) an assessment of low-lying areas with elevations below selected tidal flooding datums in coastal areas, and 3) an assessment of increases in low-lying areas that are potentially at risk to tidal flooding over the next century due to sea level rise.

Uptake Of Dissolved Organic Selenides By Marine Phytoplankton, Stephen B. Baines, Nicholas S. Fisher, Martina A. Doblin, Gregory A. Cutter

OES Faculty Publications

Se is present in multiple oxidation states in nature, each of which has unique chemical and biological reactivities. As a consequence, the rate of Se incorporation into food webs or its role as either a limiting nutrient or a toxic substance is a function of complex biogeochemistry. In particular, little is understood about the accumulation of dissolved organic selenides by phyto- or bacterioplankton. We assessed the bioavailability of dissolved organic selenides to marine and estuarine phytoplankton by presenting various algal species with filtered lysates of the diatom, Thalassiosira pseudonana, grown on media amended with radiolabeled selenite (⁷⁵Se[IV]). …

Control Of Phytoplankton Growth By Iron Supply And Irradiance In The Subantarctic Southern Ocean: Experimental Results From The Saz Project, P. W. Boyd, A. C. Crossley, G. R. Ditullio, F. B. Griffiths, D. A. Hutchins, B. Queguiner, Peter N. Sedwick, T. W. Trull

OES Faculty Publications

The influence of irradiance and Fe supply on phytoplankton processes was studied, north (47°S, 142°E) and south (54°S, 142°E) of the Subantarctic Front in austral autumn (March 1998). At both sites, resident cells exhibited nutrient stress (F_v/F_m 0 at 47°S and 9% I₀ at 54°S because of MLDs of 40 (47°S) and 90 m (54°S), when these stations were occupied. The greater MLD at 54°S is reflected by tenfold higher cellular chlorophyll a levels in the resident phytoplankton. In the 47°S experiment, chlorophyll a levels increased to >1 μg/L^-1 only in the high-Fe treatments, regardless …

Control Of Phytoplankton Growth By Iron And Silicic Acid Availability In The Subantarctic Ocean: Experimental Results From The Saz Project, D. A. Hutchins, Peter N. Sedwick, G. R. Ditullio, P. W. Boyd, B. Queguiner, F. B. Griffiths, C. Crossley

OES Faculty Publications

Subantarctic Southern Ocean surface waters in the austral summer and autumn are characterized by high concentrations of nitrate and phosphate but low concentrations of dissolved iron (Fe, similar to0.05 nM) and silicic acid (Si, <1 muM). During the Subantarctic Zone AU9706 cruise in March 1998 we investigated the relative importance of Fe and Si in controlling phytoplankton growth and species composition at a station within the subantarctic water mass (46.8degreesS, 142degreesE) using shipboard bottle incubation experiments. Treatments included unamended controls; 1.9 nM added iron (+Fe); 9 muM added silicic acid (+Si); and 1.9 nM addediron plus 9 muM added silicic acid (+Fe+Si). We followed a detailed set of biological and biogeochemical parameters over 8 days. Fe added alone clearly increased community growth rates and nitrate drawdown and altered algal community composition relative to control treatments. Surprisingly, small, lightly silicified pennate diatoms grew when Fe was added either with or without Si, despite the extremely low ambient silicic acid concentrations. Pigment analyses suggest that lightly silicified chrysophytes (type 4 haptophytes) may have preferentially responded to Si added either with or without Fe. However, for many of the parameters measured the +Fe+Si treatments showed large increases relative to both the +Fe and +Si treatments. Our results suggest that iron is the proximate limiting nutrient for chlorophyll production, photosynthetic efficiency, nitrate drawdown, and diatom growth, but that Si also exerts considerable control over algal growth and species composition. Both nutrients together are needed to elicit a maximum growth response, suggesting that both Fe and Si play important roles in structuring the subantarctic phytoplankton community.

Holocene Sediment Records From The Continental Shelf Of Mac. Robertson Land, East Antarctica, Peter N. Sedwick, Peter T. Harris, Lisette G. Robertson, Gary M. Mcmurtry, Maximilian D. Cremer, Philip Robinson

OES Faculty Publications

Geochemical records are presented for five sediment cores from basins on the continental shelf of Mac. Robertson Land, East Antarctica. The cores contain 2-4 m thick sequences of hemipelagic, siliceous mud and ooze (SMO) deposited under seasonally open marine conditions. The inner and middle shelf SMO sequences are massive dark olive green material, whereas the outer shelf SMO sequences are dark olive material interspersed with light olive green layers similar to1-10 cm thick. The biogenic material is dominated by marine diatoms including Fragilariopsis curta, Fragilariopsis cylindrus, and Chaetoceros spp. in the dark-colored SMO and Corethron criophilum in the …

Introduction To Special Section: Saz Project, T. W. Trull, Peter N. Sedwick, F. B. Griffiths, S. R. Rintoul

OES Faculty Publications

Oceanographic processes in the subantarctic region contribute crucially to the phys. and biogeochemical aspects of the global climate system. To explore and quantify these contributions, the Antarctic Cooperative Research Center organized the SAZ Project, a multidisciplinary, multiship study carried out south of Australia in the austral summer of 1997-1998. We present an overview of the SAZ Project and some of its major results.

Effects Of Iron, Silicate, And Light On Dimethylsulfoniopropionate Production In The Australian Subantarctic Zone, G. R. Ditullio, P. N. Sedwick, D. R. Jones, P. W. Boyd, A. C. Crossley, D. A. Hutchins

OES Faculty Publications

Shipboard bottle incubation experiments were performed to investigate the effects of iron, light, and silicate on algal production of particulate dimethylsulfoniopropionate (DMSP_p) in the Subantarctic Zone (SAZ) south of Tasmania during March 1998. Iron enrichment resulted in threefold to ninefold increases in DMSP_p concentrations relative to control treatments, following 7 and 8-day incubation experiments. Additions of Fe and Si preferentially stimulated the growth of lightly-silicified pennate diatoms and siliceous haptophytes, respectively, to which we attribute the increased DMSP_p production in the incubation bottles. Both of these algal groups were previously believed to be low DMSP_{p …}

Modifications Of The C37 Alkenone And Alkenoate Composition In The Water Column And Sediment: Possible Implications For Sea Surface Temperature Estimates In Paleoceanography, Joan O. Grimalt, Jürgen Rullkötter, Marie-Alexandrine Sicre, Roger Summons, John Farrington, H. Rodger Harvey, Miguel Goñi, Ken Sawada

OES Faculty Publications

The literature pertaining to C37 alkenone and C37 and C38 alkenoate production and diagenesis has been reviewed and evaluated for issues that might jeopardize their usefulness in paleotemperature estimation. We also examined the use of the C37 alkenones as paleoproductivity indicators, the stability of their δ13C isotopic compositions, and their incorporation into the nonsolvent extractable organic matter fraction. Biological transformation of organic matter by bacteria and zooplankton does not appear to cause significant changes to the ratio of C37:2 and C37:3 alkenones, but there are major alterations in the relative composition of alkenoates. Studies of water column processes and postdepositional …

Alteration Processes Of Alkenones And Related Lipids In Water Columns And Sediments, H. Rodger Harvey

OES Faculty Publications

Alkenones produced by the haptophyte algae are currently being used as indices of sea surface temperature in recent and past ocean environments, but limited information is available concerning the impact of biotic and abiotic processes on the integrity of these long chain lipids. This synthesis provides selected background information on major alteration processes that must be considered before such indices can be used with confidence. A number of processes in the water column and surface sediments have the potential to impact the structural integrity of alkenones and compromise their ability as temperature markers. Processes discussed include the alteration of alkenone …

Iron And Manganese In The Ross Sea, Antarctica: Seasonal Iron Limitation In Antarctic Shelf Waters, Peter N. Sedwick, Giacomo R. Ditullio, Denis J. Mackey

OES Faculty Publications

Dissolved iron and manganese and total dissolvable iron were measured in water column samples from the Polynya Region of the southern Ross Sea in cruises in Nov.-Dec. 1994 (spring 1994) and Dec. 1995 to Jan. 1996 (summer 1995). Iron and manganese addition bottle incubation experiments were also performed on these cruises to assess the nutritional sufficiency of ambient iron and manganese concentrations for phytoplankton growth. Generally high dissolved iron concentrations (>0.5 nM) and relatively complex iron and manganese vertical profiles were obtained in spring 1994 vs. summer 1995. Dissolved iron concentrations in the upper water column averaged 1.0 nM …

Physical Control Of Biological Processes In The Central Equatorial Pacific: A Data Assimilative Modeling Study, Marjorie Anne Macwhorter Friedrichs

OES Theses and Dissertations

A five-component data assimilative ecosystem model is developed in order to investigate the effects of physical processes encompassing a wide range of space and time scales, on the lower trophic levels of the highly dynamic central equatorial Pacific (140°W). Many of the biological processes included in the ecosystem model respond to environmental fluctuations with time scales between one and ten days, which are not typically resolved by basin to global scale circulation models. Therefore, the ecosystem model is forced using daily observations from the TAO mooring array. Model simulations successfully reproduce data collected both during and after the 1991–92 El …

Limitation Of Algal Growth By Iron Deficiency In The Australian Subantarctic Region, Peter N. Sedwick, Giacomo R. Ditullio, David A. Hutchins, Philip W. Boyd, F. Brian Griffiths, A. Clive Crossley, Thomas W. Trull, Bernard Queguiner

OES Faculty Publications

In March 1998 we measured iron in the upper water column and conducted iron- and nutrient-enrichment bottle-incubation experiments in the open-ocean Subantarctic region southwest of Tasmania, Australia. In the Subtropical Convergence Zone (∼42°S, 142°E), silicic acid concentrations were low (< 1.5μM) in the upper water column, whereas pronounced vertical gradients in dissolved iron concentration (0.12-0.84 nM) were observed., presumably reflecting the interleaving of Subtropical and Subantarctic waters, and mineral aerosol input. Results of a bottle-incubation experiment performed at this location indicate that phytoplankton growth rates were limited by iron deficiency within the iron-poor layer of the euphotic zone. In the Subantarctic water mass (∼46.8°S, 142°E), low concentrations of dissolved iron (0.05-0.11nM) and silicic acid (< 1μM) were measured throughout the upper water column, and our experimental results indicate that algal growth was limited by iron deficiency. These observations suggest that availability of dissolved iron is a primary factor limiting phytoplankton growth over much of the Subantarctic Southern Ocean in the late summer and autumn.

Chemical Signals From Submarine Fluid Advection Onto The Continental Shelf, W. S. Moore, Timothy J. Shaw

Faculty Publications

No abstract provided.

The Biogeochemical Cycling Of Dissolved Organic Nitrogen In Estuarine Sediments, David J. Burdige, Shilong Zheng

OES Faculty Publications

Benthic fluxes and pore-water profiles of dissolved organic nitrogen and carbon (DON and DOC, respectively) were determined in seasonal studies at contrasting sites in Chesapeake Bay. Pore-water dissolved organic matter (DOM) concentrations were elevated over bottom-water values, generally increased with depth, and ranged from 15 to similar to 160 μM for DON and ~200-2000 μM for DOC. Pore-water DOM concentrations and the C:N ratio of this material showed spatial (depth) and temporal changes that varied among the sites studied. These trends appeared to be related to differences in the types of sediment organic matter (SOM) undergoing remineralization, as well as …

Iron In Ice Cores From Law Dome, East Antarctica: Implications For Past Deposition Of Aerosol Iron, R. Edwards, Peter N. Sedwick, Vin Morgan, C. F. Boutron, S. Hong

OES Faculty Publications

Total-dissolvable iron has been measured in sections of three ice cores from Law Dome, East Antarctica, and the results used to calculate atmospheric iron deposition over this region during the late Holocene and to provide a preliminary est. of aerosol iron deposition during the Last Glacial Maximum (LGM). Ice-core sections dating from 56-2730 BP (late Holocene) and ∼18 000 BP (LGM) were decontaminated using trace-metal clean techniques, and total-dissolvable iron was determined in the acidified meltwaters by flow-injection analysis. Our results suggest that the atmospheric iron flux onto the Law Dome region has varied significantly over time-scales ranging from seasonal …

Lead Isotopes And Selected Metals In Ice From Law Dome, Antarctica, K. J. R. Rosman, W. Chisholm, C. F. Boutron, S. Hong, R. Edwards, Vin Morgan, Peter N. Sedwick

OES Faculty Publications

The isotopic composition. of Pb and the concentrations of Pb, Ba and Bi were measured in selected ice-core samples from Law Dome, East Antarctica, to a depth of 1196 m. The range of concentrations found in decontaminated ice was 0.03-1.5 pg g^-1 for Pb, 0.9-6.1 pg g^-1 for Ba and 0.4-17 fg g^-1 for Bi, excluding the deepest sample which contained ∼1 ppm of rock dust. The abundances of all four stable lead isotopes were measured and gave ²⁰⁶Pb/²⁰⁷Pb ratios ≤ ∼1.23. A value of ²⁰⁸Pb/²⁰⁷Pb = 2.78 was measured in …

Identification Of Past Climate Variability Of The Eastern Pacific Ocean Using Both D13c And D18o Records In Corals From Clipperton Atoll (1994-1906), Lei Ren

Geology Theses and Dissertations

The ENSO (El Nino and the Southern Oscillation) is a fundamental ocean-atmosphere phenomenon that dominates interannual global climate variability. Reconstructing past ENSO events is therefore important for documenting and understanding the past behavior of the global climate system and enabling us to predict future climate change. However, the present understanding of ENSO events has been mainly based on the instrumental record of Pacific climate which provides detailed data only for the past few decades. Recent studies have shown that the stable isotope record in coral skeletons can be used as a valuable indicator of paleoclimatic changes in tropical regions, and …

Heat And Salt Changes On The Continental Shelf West Of The Antarctic Peninsula Between January 1993 And January 1994, John M. Klinck

CCPO Publications

Hydrographic measurements from four cruises between January 1993 and January 1994 over the continental shelf west of the Antarctic Peninsula allow analysis of seasonal changes in heat and salt content of this region. Changes above the permanent pycnocline (about 150 m) follow a seasonal pattern of cooling and increasing in salt from summer to winter and warming and freshening from winter to summer. These near-surface changes expressed as net heating or salting rate, were above 80 W m(-2) and 4 mg salt m(-2) s(-1). The year to year difference was small compared to the seasonal changes. There was no seasonal …

Fluxes Of Copper-Complexing Ligands From Estuarine Sediments, Stephen A. Skrabal, John R. Donat, David J. Burdige

OES Faculty Publications

Most studies of the organic complexation of Cu in natural waters have focused on distributions and processes in the water column, where a significant fraction of Cu-complexing ligands may be biologically produced. We present direct evidence for a flux of Cu-complexing ligands from estuarine sediments, demonstrating that sediments are a significant, yet previously unrecognized source of the ligands. Fluxes of Cu-complexing ligands from Chesapeake Bay sediments range from 300 to 1,200 nmol m^-2 d^-1, exceeding fluxes of total dissolved Cu by 3->40-fold, suggesting that any Cu fluxing from the sediments is likely to be organically complexed. …

Regulation Of Algal Blooms In Antarctic Shelf Waters By The Release Of Iron From Melting Sea Ice, Peter N. Sedwick, Giacomo R. Ditullio

OES Faculty Publications

During summer 1995-96, we measured iron in the water column and conducted iron-enrichment bottle-incubation experiments at a station in the central Ross Sea (76°30'S, 170°40'W), first, in the presence of melting sea ice, and 17 days later, in ice-free conditions. We observed a striking temporal change in mixed-layer dissolved iron concentrations at this station, from 0.72-2.3 nM with sea ice present, to 0.16-0.17 nM in ice-free conditions. These changes were accompanied doubling of algal (diatom) biomass. Our incubation experiments suggest that conditions were iron-replete in the presence of sea ice, and iron-deficient in the absence of sea ice. We surmise …

Observation Of Shelfwater Overrunning The Southern Slope Sea, Ajoy Kumar

OES Theses and Dissertations

Analyses of two years (1992 and 1993) of high resolution (1.47 km²) sea surface temperature satellite images of the southern Mid-Atlantic Bight (MAB), showed that unusually extensive overhang of shelf water occurs episodically, and coherently over along shelf distances of several hundred kilometers. These episodes are dubbed overrunning of the Slope Sea by shelf water. The overrunning volume has a "face" and a "back" (southern and northern limit). It transports substantial quantities of shelf water southward, and does not retreat onto the shelf, but eventually joins the western edge of the Gulf Stream in the vicinity of Chesapeake …

A One-Dimensional Model For Storm Breaching Of Barrier Islands, Cheol Shik Shin

Civil & Environmental Engineering Theses & Dissertations

A set of numerical models is developed for simulating the four stages of barrier breaching characterized by one horizontal spatial dimension.

The SBEACH model is employed for the first stage of dune/beach erosion. The Lax-Wendroff two-step explicit scheme for Stage II is developed to simulate initiation of ocean flood propagation on initially dry barrier islands and the method of characteristics (MOC), is employed to compute additional boundary data. The development of the Preissmann implicit scheme for water motion and a forward time centered space explicit scheme for sediment motion in Stages III and IV provide a tool to study the …