Open Access. Powered by Scholars. Published by Universities.®

Oceanography Commons™

Open Access. Powered by Scholars. Published by Universities.®

Earth Sciences

Institution
Keyword
Publication Year
Publication
Publication Type
File Type

Articles 421 - 450 of 542

Full-Text Articles in Oceanography

Cold Climate In The Eastern Australian Mid- To Late Permian May Reflect Cold Upwelling Waters, Andrew T. Jones, Tracy D. Frank, Christopher R. Fielding Aug 2006

Cold Climate In The Eastern Australian Mid- To Late Permian May Reflect Cold Upwelling Waters, Andrew T. Jones, Tracy D. Frank, Christopher R. Fielding

Department of Earth and Atmospheric Sciences: Faculty Publications

A suite of ice-rafted dropstones and glendonites throughout the Permian succession of eastern Australia indicates the cold climate associated with the late Paleozoic ice age persisted longest in this part of Gondwana. Paradoxically, these cold climate indicators are preserved in transgressive and highstand facies and formed at mid to high latitudes at a time when paleofloral and sedimentological data suggest equable onshore environments during the intervening lowstands and temperate conditions at the pole. These apparent inconsistencies suggest that eastern Australia was anomalously cold in the context of post-Sakmarian Gondwanan climates, and the distribution of sedimentary indicators could indicate localized cooling …

Go to article

Biogeochemistry Of Arsenic And Antimony In The North Pacific Ocean, Gregory A. Cutter, Lynda S. Cutter May 2006

Biogeochemistry Of Arsenic And Antimony In The North Pacific Ocean, Gregory A. Cutter, Lynda S. Cutter

OES Faculty Publications

The biogeochemical cycles of the metalloid elements arsenic and antimony were examined along a 15,000 km surface water transect and at 9 vertical profile stations in the western North Pacific Ocean as part of the 2002 IOC Contaminant Baseline Survey. Results show that the speciation of dissolved arsenic (As III, As V, and methylated As) was subtly controlled by the arsenate (AsV)/phosphate ratio. An additional fraction of presumed organic arsenic previously reported in coastal waters was also present (~15% of the total As) in oceanic surface waters. Dissolved inorganic antimony displayed mildly scavenged behavior that was confirmed by correlations with …

Go to article

Correlating Late Pleistocene Deposits On The Coastal Plain Of Virginia With The Glacial-Eustatic Sea-Level Curve, Timothy Wullschleger Scott Apr 2006

Correlating Late Pleistocene Deposits On The Coastal Plain Of Virginia With The Glacial-Eustatic Sea-Level Curve, Timothy Wullschleger Scott

OES Theses and Dissertations

Late Pleistocene sediments mapped along Virginia's southeastern coastal plain record deposition by high-frequency cycles during isotope stages 5 to 1. Correlations between several geologic units both south (S) and east (E) of the Chesapeake Bay have proven difficult due to insufficient dating methods. To improve these regional correlations, two members of the Tabb Formation on Virginia's southside and two formations on the southern Delmarva Peninsula were selected for stratigraphic analyses. Ground penetrating radar provided geologic details in areas where samples were collected for optically stimulated luminescence (OSL) dating. The stratigraphically older units, Sedgefield Member of the Tabb Formation (S) and …

Go to article

Thermometric Measurements Of The Molecular Sublayer At The Air-Water Interface, B. Ward Apr 2006

Thermometric Measurements Of The Molecular Sublayer At The Air-Water Interface, B. Ward

OES Faculty Publications

[1] A series of measurements was conducted in the AirSea Interaction Saltwater Tank (ASIST) to study the response of the air-water interfacial molecular sublayer under various heat flux and wind speed conditions. In-situ gradients were measured with a platinum-plated tungsten wire microthermometer, which resolved the temperature of the thermally conductive sublayer. Air-sea heat flux was controlled by changing the air-water temperature difference (ΔTAW) and the wind speed, and measurements were made for three ΔTAW regimes over a range of wind speeds. A function was fitted to the measured temperature profiles as a way of extracting the boundary …

Go to article

Hydrographic Observations During The 2002 Ioc Contaminant Baseline Survey In The Western Pacific Ocean, C. I. Measures, Greg A. Cutter, W. M. Landing, R. T. Powell Mar 2006

Hydrographic Observations During The 2002 Ioc Contaminant Baseline Survey In The Western Pacific Ocean, C. I. Measures, Greg A. Cutter, W. M. Landing, R. T. Powell

OES Faculty Publications

The 2002 IOC Contaminant Baseline Survey in the western Pacific Ocean was the fourth in a series of cruises intended to establish the contemporary concentrations of trace elements and other materials in the major water masses of the ocean and to illuminate the pathways by which materials delivered to the surface ocean are incorporated in the subsurface waters. The expedition occupied 9 vertical profile stations encompassing the subtropical and subarctic gyre of the western North Pacific. In addition, underway surface water samples were collected during transits between the stations. This paper uses the temperature, salinity, nutrient, oxygen, and chlorophyll data …

Go to article

Evaluating The Biogeochemical Cycle Of Selenium In San Francisco Bay Through Modeling, Shannon L. Meseck, Gregory A. Cutter Jan 2006

Evaluating The Biogeochemical Cycle Of Selenium In San Francisco Bay Through Modeling, Shannon L. Meseck, Gregory A. Cutter

OES Faculty Publications

A biogeochemical model was developed to simulate salinity, total suspended material, phytoplankton biomass, dissolved selenium concentrations (selenite, selenate, and organic selenide), and particulate selenium concentrations (selenite + selenate, elemental selenium, and organic selenide) in the San Francisco Bay estuary. Model-generated estuarine profiles of total dissolved selenium reproduced observed estuarine profiles at a confidence interval of 91- 99% for 8 different years under various environmental conditions. The model accurately reproduced the observed dissolved speciation at confidence intervals of 81-98% for selenite, 72-91% for selenate, and 60-96% for organic selenide. For particulate selenium, model-simulated estuarine profiles duplicated the observed behavior of total …

Go to article

Iron In Ice Cores From Law Dome: A Record Of Atmospheric Iron Deposition For Maritime East Antarctica During The Holocene And Last Glacial Maximum, Ross Edwards, Peter N. Sedwick, Vin Morgan, Claude Boutron Jan 2006

Iron In Ice Cores From Law Dome: A Record Of Atmospheric Iron Deposition For Maritime East Antarctica During The Holocene And Last Glacial Maximum, Ross Edwards, Peter N. Sedwick, Vin Morgan, Claude Boutron

OES Faculty Publications

Total dissolvable iron (TDFe) was measured in sections of ice cores recovered from Law Dome on the coast of Wilkes Land, East Antarctica. These samples include ice dating from the Last Glacial Maximum (LGM), the Last Deglaciation, and the early and mid Holocene as well as samples from the Anthropocene that have been dated with seasonal to annual resolution. Combining our TDFe concentration data with estimates of the ice accumulation rate, we estimate the atmospheric iron deposition for Law Dome and the adjacent Southern Ocean during these periods. Our results indicate that the atmospheric iron deposition flux to this region …

Go to article

Nitrogen Fixation And Release Of Fixed Nitrogen By Trichodesmium Spp. In The Gulf Of Mexico, Margaret R. Mulholland, Peter W. Bernhardt, Cynthia A. Heil, Deborah A. Bronk, Judith M. O'Neil Jan 2006

Nitrogen Fixation And Release Of Fixed Nitrogen By Trichodesmium Spp. In The Gulf Of Mexico, Margaret R. Mulholland, Peter W. Bernhardt, Cynthia A. Heil, Deborah A. Bronk, Judith M. O'Neil

OES Faculty Publications

During a 3-yr study in the Gulf of Mexico, we measured dinitrogen (N2) fixation and nitrogen (N) release by Trichodesmium and compared these rates with water column N demand and the estimated N necessary to support blooms of Karenia brevis, a toxic dinoflagellate that severely affects the West Florida shelf. Net and gross N2 fixation rates were compared in simultaneous incubations using 15N2 uptake and acetylene reduction, respectively. The difference between net and gross N2 fixation is assumed to be an approximation of the rate of N release. Results demonstrate that Trichodesmium in …

Go to article

Western Caribbean Sea Surface Temperatures During The Late Quaternary, Matthew W. Schmidt, Maryline J. Vautravers, Howard J. Spero Jan 2006

Western Caribbean Sea Surface Temperatures During The Late Quaternary, Matthew W. Schmidt, Maryline J. Vautravers, Howard J. Spero

OES Faculty Publications

[1] Mg/Ca ratios in the planktonic foraminifera Globigerinoides ruber from Colombian Basin core ODP 999A suggest that Caribbean sea surface temperatures ( SSTs) were from 2.1 to 2.7°C colder than the present during the last three glacial maximums. In comparison, faunal derived SSTs ( SIMMAX method) show that August SSTs in the Caribbean varied < 2° over the past 360 kyr, whereas February SSTs varied between 21.0°C and 26.5°C. Changes in the Mg/Ca-SST record contain a strong 23 kyr periodicity, suggesting the Mg/Ca-SST record reflects a warm season weighted SST average rather than an annual mean SST. Combining several dissolution indices, we identify brief periods of decreased carbonate preservation in our record and show that MIS 11 stands out as the most intensive dissolution cycle in the Caribbean over the last 460 kyr. Comparison of Caribbean SST change with a similar estimate of tropical SST variability in the western Pacific over the past 360 kyr reveals shifts in the east-west tropical SST gradient that are coeval with glacial-interglacial climate change and consistent both with a southward migration of the glacial ITCZ and with a glacial El Niño-like mode of tropical circulation.

Go to article

Past Glacial And Interglacial Conditions In The Arctic Ocean And Marginal Seas - A Review, Dennis A. Darby, Leonid Polyak, Henning A. Bauch Jan 2006

Past Glacial And Interglacial Conditions In The Arctic Ocean And Marginal Seas - A Review, Dennis A. Darby, Leonid Polyak, Henning A. Bauch

OES Faculty Publications

Past changes in the Arctic Ocean and its marginal seas have been profound, even during the last 10,000 years. Understanding these changes, such as those occurring during the transition from glacial to interglacial climates, are important for research on modern processes, because this knowledge provides a framework and unique perspective in which to view the modern physical and biological processes. This paper discusses our current understanding of past environmental change and processes relative to those currently in progress. Special emphasis is placed on the most recent transition from a glacial state to the modern interglacial conditions.

Go to article

Evaluating The Deep-Sea Coral Acanella From Hawaii As A Paleoceanographic Archive, Geraldine Hourigan Lantier Jan 2006

Evaluating The Deep-Sea Coral Acanella From Hawaii As A Paleoceanographic Archive, Geraldine Hourigan Lantier

Geology Theses and Dissertations

Deep-sea corals have emerged as potential proxies of changing paleoceanographic properties. The utility of deep-sea corals for the purpose of interpreting paleoclimatic reconstructions is still in the discovery phase. However, long life spans, a relatively stable habitat, and unique growth geometry provide support to the growing body of research that has identified deep-sea corals as indicators of past climate and ocean properties. Two colonies of Acanella were collected from the permanent thermocline at depths between 414 and 437 m in the Makapuu Coral Bed, Oahu, HI in 1997 by submersible. Here I present results from a pilot study of the …

Go to article

Assessing The Paleoceanographic Potential Of The Coral Montipora Venosa At Fanning Atoll, Central Equatorial Pacific, Alexa Stolorow Jan 2006

Assessing The Paleoceanographic Potential Of The Coral Montipora Venosa At Fanning Atoll, Central Equatorial Pacific, Alexa Stolorow

Geology Theses and Dissertations

As interest in global climate change increases, so does the need for better and more extensive climate proxies. The central equatorial Pacific has been established as the region with the largest ENSO-related sea surface temperature (SST) and precipitation (PPT) anomalies, which are known to impact global interannual climate variability. To date, the coral genus Porites has been most commonly utilized for coral-based paleo-reconstructions of ENSO and lower frequency phenomena. However, due to questions of biological artifacts in coral, to more fully understand coral-based reconstruction, different coral genera need to be analyzed.
In this study, oxygen (δ18O) and carbon (δ13C) isotopic …

Go to article

Pelagic Functional Group Modeling: Progress, Challenges And Prospects, Raleigh R. Hood, Edward A. Laws, Robert A. Armstrong, Nicholas R. Bates, Christopher W. Brown, Craig A. Carlson, Fei Chai, Scott C. Doney, Paul G. Falkowski, Richard A. Feely, Marjorie A. M. Friedrichs Jan 2006

Pelagic Functional Group Modeling: Progress, Challenges And Prospects, Raleigh R. Hood, Edward A. Laws, Robert A. Armstrong, Nicholas R. Bates, Christopher W. Brown, Craig A. Carlson, Fei Chai, Scott C. Doney, Paul G. Falkowski, Richard A. Feely, Marjorie A. M. Friedrichs

CCPO Publications

In this paper, we review the state of the art and major challenges in current efforts to incorporate biogeochemical functional groups into models that can be applied on basin-wide and global scales, with an emphasis on models that might ultimately be used to predict how biogeochemical cycles in the ocean will respond to global warming. We define the term "biogeochemical functional group" to refer to groups of organisms that mediate specific chemical reactions in the ocean. Thus, according to this definition, "functional groups" have no phylogenetic meaning-these are composed of many different species with common biogeochemical functions.

Substantial progress has …

Go to article

Estimation Of Iron Solubility From Observations And A Global Aerosol Model, Chao Luo, N. M. Mahowald, N. Meskhidze, Y. Chen, R. L. Siefert, A. R. Baker, Anne M. Johansen Dec 2005

Estimation Of Iron Solubility From Observations And A Global Aerosol Model, Chao Luo, N. M. Mahowald, N. Meskhidze, Y. Chen, R. L. Siefert, A. R. Baker, Anne M. Johansen

All Faculty Scholarship for the College of the Sciences

Mineral aerosol deposition is the dominant source of iron to the open ocean. Soil iron is typically insoluble and understanding the atmospheric processes that convert insoluble iron to the more soluble forms observed over the oceans is crucial. In this paper, we model several proposed processes for the conversion of Fe(III) to Fe(II), and compare with cruise observations. The comparisons show that the model results in similar averaged magnitudes of iron solubility as measured during 8 cruises in 2001–2003. Comparisons show that results of cases including cloud, SO2 and hematite processing are better than the other approaches used using …

Go to article

Interaction Of Sea Ice Sediments And Surface Sea Water In The Arctic Ocean: Evidence From Excess 210Pb, M. Baskaran Jun 2005

Interaction Of Sea Ice Sediments And Surface Sea Water In The Arctic Ocean: Evidence From Excess 210Pb, M. Baskaran

Environmental Science and Geology Faculty Research Publications

We measured the activities of 210Pb, 226Ra, 238U and 137Cs in a suite of ice-rafted sediments (IRS) from the Arctic Ocean in an attempt to assess the interaction of sea ice sediments and surface water. The concentrations of these nuclides were compared to those of the benthic sediments in the coastal and shelf regions of the Arctic Ocean, which are believed to be the major source region for the IRS. The concentration factors (CF = activity of a nuclide in IRS/average activity in benthic sediments) are ∼1 and 4-92 for 137Cs and 210Pb, respectively. …

Go to article

Women In Oceanography: Women Of The Academy And The Sea, Suzanne O'Connell, Mary Anne Holmes Mar 2005

Women In Oceanography: Women Of The Academy And The Sea, Suzanne O'Connell, Mary Anne Holmes

Department of Earth and Atmospheric Sciences: Faculty Publications

Women have played an active role in all areas of oceanography. Defining the number of women oceanographers is not an easy task because the discipline is so broad and the boundaries between subdisciplines are not always distinct.

Go to article

Burial Of Terrestrial Organic Matter In Marine Sediments: A Re-Assessment, David J. Burdige Jan 2005

Burial Of Terrestrial Organic Matter In Marine Sediments: A Re-Assessment, David J. Burdige

OES Faculty Publications

Calculations based on recent observations indicate that approximately one third of the organic matter presently being buried in marine sediments may be of terrestrial origin, with the majority of this terrestrial organic matter (TOM) burial occurring in muddy, deltaic sediments. These calculations further suggest that the remineralization of terrestrial organic matter in the oceans is also much less efficient than that of marine organic matter. These two underappreciated observations have important implications in terms of our understanding of the controls on the global carbon cycle. From a paleoceanographic perspective, the results presented here also suggest that changes in TOM burial …

Go to article

Iron In The Sargasso Sea (Bermuda Atlantic Time-Series Study Region) During Summer: Eolian Imprint, Spatiotemporal Variability, And Ecological Implications, Peter N. Sedwick, T. M. Church, A. R. Bowie, C. M. Marsay, S. J. Ussher, K. M. Achilles, P. J. Lethaby, R. J. Johnson, M. M. Sarin, D. J. Mcgillicuddy Jan 2005

Iron In The Sargasso Sea (Bermuda Atlantic Time-Series Study Region) During Summer: Eolian Imprint, Spatiotemporal Variability, And Ecological Implications, Peter N. Sedwick, T. M. Church, A. R. Bowie, C. M. Marsay, S. J. Ussher, K. M. Achilles, P. J. Lethaby, R. J. Johnson, M. M. Sarin, D. J. Mcgillicuddy

OES Faculty Publications

We report iron measurements for water column and aerosol samples collected in the Sargasso Sea during July-August 2003 (summer 2003) and April-May 2004 (spring 2004). Our data reveal a large seasonal change in the dissolved iron (dFe) concentration of surface waters in the Bermuda Atlantic Time-series Study region, from ∼1-2nM in summer 2003, when aerosol iron concentrations were high (mean 10 nmol/m-3), to ∼0.1-0.2nM in spring 2004, when aerosol iron concentrations were low (mean 0.64 nmol/m-3). During summer 2003, we observed an increase of ∼0.6nM in surface water dFe concentrations over 13 days, presumably due to …

Go to article

A Unique Seasonal Pattern In Phytoplankton Biomass In Low-Latitude Waters In The South China Sea, Chun-Mao Tseng, George T. F. Wong, I.-I. Lin, C.-R. Wu, K.-K. Liu Jan 2005

A Unique Seasonal Pattern In Phytoplankton Biomass In Low-Latitude Waters In The South China Sea, Chun-Mao Tseng, George T. F. Wong, I.-I. Lin, C.-R. Wu, K.-K. Liu

OES Faculty Publications

A distinctive seasonal pattern in phytoplankton biomass was observed at the South East Asian Time series Study (SEATS) station (18°N, 116°E) in the northern South China Sea (SCS). Surface chlorophyll-a, depth integrated chlorophyll-a and primary production were elevated to 0.3 mg/m3, ~35 mg/m2 and 300 mg-C/m2/d, respectively, in the winter but stayed low, at 0.1 mg/m3, ~15 mg/m2 and 110 mg-C/m2/d as commonly found in other low latitude waters, in the rest of the year. Concomitantly, soluble reactive phosphate and nitrate+nitrite in the mixed layer also became …

Go to article

Variability Of Sea Ice Cover In The Chukchi Sea (Western Arctic Ocean) During The Holocene, Anne De Vernal, Claude Hillaire-Marcel, Dennis A. Darby Jan 2005

Variability Of Sea Ice Cover In The Chukchi Sea (Western Arctic Ocean) During The Holocene, Anne De Vernal, Claude Hillaire-Marcel, Dennis A. Darby

OES Faculty Publications

Dinocysts from cores collected in the Chukchi Sea from the shelf edge to the lower slope were used to reconstruct changes in sea surface conditions and sea ice cover using modern analogue techniques. Holocene sequences have been recovered in a down-slope core (B15: 2135 m, 75°44'N, sedimentation rate of ~1cm kyr-1) and in a shelf core (P1: 201 m, 73°41'N, sedimentation rate of ~22 cm kyr-1). The shelf record spanning about 8000 years suggests high-frequency centennial oscillations of sea surface conditions and a significant reduction of the sea ice at circa 6000 and 2500 calendar (cal) …

Go to article

Hydrographic And Biological Changes In The Taiwan Strait During The 1997-1998 El Niño Winter, S. Shang, C. Zhang, H. Hong, Q. Liu, G. T. F. Wong, C. Hu, B. Huang Jan 2005

Hydrographic And Biological Changes In The Taiwan Strait During The 1997-1998 El Niño Winter, S. Shang, C. Zhang, H. Hong, Q. Liu, G. T. F. Wong, C. Hu, B. Huang

OES Faculty Publications

During the 1997–1998 El Niño event, the average sea surface temperature (SST) in the Taiwan Strait (TWS) in the winter was ~1.4°C higher than that of the winter climatological mean. The areal ratio of the warm water (≥2°C above the regional mean) to the cold water (≥2°C below the regional mean) in the TWS increased by 25% while the area of the eutrophic water (chlorophyll a >1 mg m-3) was halved. Field observations also indicate that the mixed layer in the TWS became more nutrient-poor during this winter. These observations are consistent with a diminished advection of the …

Go to article

Monsoon-Driven Biogeochemical Processes In The Arabian Sea, Jerry D. Wiggert, Raleigh Hood, Karl Banse, John Kindle Jan 2005

Monsoon-Driven Biogeochemical Processes In The Arabian Sea, Jerry D. Wiggert, Raleigh Hood, Karl Banse, John Kindle

Faculty Publications

Although it is nominally a tropical locale, the semiannual wind reversals associated with the Monsoon system of the Arabian Sea result annually in two distinct periods of elevated biological activity. While in both cases monsoonal forcing drives surface layer nutrient enrichment that supports increased rates of primary productivity, fundamentally different entrainment mechanisms are operating in summer (Southwest) and winter (Northeast) Monsoons. Moreover, the intervening intermonsoon periods, during which the region relaxes toward oligotrophic conditions more typical of tropical environments, provide a stark contrast to the dynamic biogeochemical activity of the monsoons. The resulting spatial and temporal variability is great and …

Go to article

Relating Water And Otolith Chemistry In Chesapeake Bay, And Their Potential To Identify Essential Seagrass Habitats For Juveniles Of An Estuarine-Dependent Fish, Spotted Seatrout (Cynoscion Nebulosus), Emmanis Dorval Apr 2004

Relating Water And Otolith Chemistry In Chesapeake Bay, And Their Potential To Identify Essential Seagrass Habitats For Juveniles Of An Estuarine-Dependent Fish, Spotted Seatrout (Cynoscion Nebulosus), Emmanis Dorval

Biological Sciences Theses & Dissertations

A quantitative understanding of habitat use of estuarine-dependent fishes is critical to the conservation of their most essential habitats. Because recruitment and fitness may be influenced by the quality of juvenile habitats, developing methods to quantify habitat-specific survivorship is pivotal to such understanding. An initial step to quantify survivorship is to validate the habitat-specific natural tags contained in otoliths. To this aim I investigated the variability in the chemistry of surface waters and otoliths of juvenile spotted seatrout, Cynoscion nebulosus, in five seagrass habitats of Chesapeake Bay, namely: Potomac, Rappahannock, York, Island, and Eastern Shore. I measured Mg, Ca, …

Go to article

Estimation Of Primary Production And Carbon Flux In Antarctic Coastal Waters: A Modeling Study, Hae-Cheol Kim Jan 2004

Estimation Of Primary Production And Carbon Flux In Antarctic Coastal Waters: A Modeling Study, Hae-Cheol Kim

OES Theses and Dissertations

This study presents results from models that are designed to simulate the underwater light field, to simulate phytoplankton primary production, and to estimate the fate of phytoplankton carbon in continental shelf waters of the west Antarctic Peninsula (WAP) and Ross Sea. Simulation of the underwater light field required derivation of new coefficient sets for power function-type cloud cover correction algorithms, which were found to be influenced by multiple reflections between the bottom of clouds and the surface. The coefficient sets indicate that the spectral effect of clouds on the properties of the surface irradiance was spectrally-neutral for wavelengths greater than …

Go to article

Sources And Cycling Of Carbonyl Sulfide In The Sargasso Sea, Gregory A. Cutter, Lynda S. Cutter, Katherine C. Filippino Jan 2004

Sources And Cycling Of Carbonyl Sulfide In The Sargasso Sea, Gregory A. Cutter, Lynda S. Cutter, Katherine C. Filippino

OES Faculty Publications

The cycling of the radiatively important gas carbonyl sulfide (OCS) was studied in surface waters of the Sargasso Sea. In August 1999, surface OCS concentrations averaged 8.6 pmol L-1, showed minor diel variations, and varied little with depth. An OCS precursor, total dissolved organic sulfur (DOS), was lowest at the surface (40 nmol L-1) and increased with depth. The photoproduction rate of OCS from in situ incubations averaged 9.6 pmol L-1 h-1, whereas dark production was 7.0 pmol L-1 h-1. Apparent quantum yields were 10-5-10-7 from 313-436 …

Go to article

Analytical Intercomparison Between Flow Injection-Chemiluminescence And Flow Injection-Spectrophotometry For The Determination Of Picomolar Concentrations Of Iron In Seawater, Andrew R. Bowie, Peter N. Sedwick, Paul J. Worsfold Jan 2004

Analytical Intercomparison Between Flow Injection-Chemiluminescence And Flow Injection-Spectrophotometry For The Determination Of Picomolar Concentrations Of Iron In Seawater, Andrew R. Bowie, Peter N. Sedwick, Paul J. Worsfold

OES Faculty Publications

A lab- and ship-based analytical intercomparison of two flow injection methods for the determination of iron in seawater was conducted, using three different sets of seawater samples collected from the Southern Ocean and South Atlantic. In one exercise, iron was determined in three different size-fractions (< 0.03 &μm, < 0.4 μm, and unfiltered) in an effort to better characterize the operational nature of each analytical technique with respect to filter size. Measured Fe concentrations were in the range 0.19 to 1.19 nM using flow injection with luminol chemiluminescence detection (FI-CL), and 0.07 to 1.54 nM using flow injection with catalytic spectrophotometric detection with N, N-dimethyl-p-phenylenediamine dihydrochloride (FI-DPD). The arithmetic mean for the FI-CL method was higher (by 0.09 nM) than the FI-DPD method for dissolved (< 0.4 μm) Fe, a difference that is comparable to the analytical blanks, which were as high as 0.13 nM ( CL) and 0.09 nM (DPD). There was generally good agreement between the FI-CL determinations for the < 0.03 μm size fraction and the FI-DPD determinations for the < 0.4 μm size fraction in freshly collected samples. Differences in total-dissolvable ( unfiltered) Fe concentrations determined by the two FI methods were more variable, reflecting the added complexity associated with the analysis of partially digested particulate material in these samples. Overall, however, the FI-CL determinations were significantly (P = 0.05) lower than the FI-DPD determinations for the unfiltered samples. Our results suggest that the observed, systematic inter-method differences reflect measurement of different physicochemical fractions of Fe present in seawater, such that colloidal and/or organic iron species are better determined by the FI-CL method than the FI-DPD method. This idea is supported by our observation that inter-method differences were largest for freshly collected acidified seawater, which suggests extended storage (>6 months) of acidified samples as a possible protocol for the determination of dissolved iron in seawater.

Go to article

Black Carbon In Estuarine And Coastal Ocean Dissolved Organic Matter, Antonio Mannino, H. Rodger Harvey Jan 2004

Black Carbon In Estuarine And Coastal Ocean Dissolved Organic Matter, Antonio Mannino, H. Rodger Harvey

OES Faculty Publications

We measured black carbon (BC) in ultrafiltered, high-molecular weight dissolved organic matter (UDOM) in surface waters of Delaware Bay, Chesapeake Bay, and the adjacent Atlantic Ocean (U.S.A.) to investigate the importance of riverine and estuarine dissolved organic matter (DOM) as a source of BC to the ocean. BC was 5-72% of UDOM-C (27 ± 17%), which corresponds to 8.9 ± 6.5% of dissolved organic carbon (DOC), with higher values in the heavily urbanized midbay region of the Delaware Estuary and lower yields in the river and coastal ocean. The spatial and seasonal distributions of BC along the salinity gradient of …

Go to article

A Holocene Record Of Changing Arctic Ocean Ice Drift Analogous To The Effects Of The Arctic Oscillation, Dennis A. Darby, Jens F. Bischof Jan 2004

A Holocene Record Of Changing Arctic Ocean Ice Drift Analogous To The Effects Of The Arctic Oscillation, Dennis A. Darby, Jens F. Bischof

OES Faculty Publications

The Arctic Oscillation (AO) controls the configuration of the Transpolar Drift (TPD). If thicker ice from the Beaufort Gyre were exported, the volume of fresh water/sea ice in the Nordic seas would significantly increase, decreasing the formation of North Atlantic deep water. This would cool large parts of the Northern Hemisphere and affect global climate. Therefore, in order to understand how the global climate system functions, it is imperative to know how the TPD changed over the last millennium or more. The provenance of grains in a sediment core located near the confluence of the TPD and the Beaufort Gyre …

Go to article

Stable Isotopic And Trace Metal Analyses Of Two Porites Lobata Colonies - Oahu, Hawaii: Implications For Past Seasonal Variation And Sea Surface Temperatures And Anthropogenic Effects On The Reef Environment, Jonathan Macdonald Jan 2004

Stable Isotopic And Trace Metal Analyses Of Two Porites Lobata Colonies - Oahu, Hawaii: Implications For Past Seasonal Variation And Sea Surface Temperatures And Anthropogenic Effects On The Reef Environment, Jonathan Macdonald

Geology Theses and Dissertations

Corals from the western and equatorial Pacific Ocean have been extensively studied for the purposes of generating paleoclimate reconstructions spanning the last several hundred years. However, in the central subtropical North Pacific, there are currently few published coral records extending beyond 10 to 20 years. The hermatypic coral species Porites lobata and Porites lutea have proven to be useful indicators of paleoclimate and past sea surface conditions at other locations. Here I have analyzed two Porites lobata coral cores collected from colonies from opposite sides of Oahu, Hawaii to assess their utility for developing multi-decadal length climatic reconstructions in this …

Go to article

Modeled And Observed Empirical Orthogonal Functions Of Currents In The Yucatan Channel, Gulf Of Mexico, Lie-Yauw Oey, Tal Ezer, Wilton Sturges Jan 2004

Modeled And Observed Empirical Orthogonal Functions Of Currents In The Yucatan Channel, Gulf Of Mexico, Lie-Yauw Oey, Tal Ezer, Wilton Sturges

CCPO Publications

Candela et al. [2003] have reported empirical orthogonal function (EOF) analyses based on 23-month current-meter and acoustic Doppler current profiler measurements in the Yucatan Channel. Those authors noted the difference between EOFs obtained from observations and their z-level models and EOFs calculated by Ezer et al. [2003] from the results of a terrain-following model. Here a new analysis is reported that explains this difference, and that also suggests the importance of shelf-edge meander mode of the core Loop Current in the channel. We show that the terrain-following model gives EOFs with characteristics similar to those observed when data from the …

Go to article

First Prev Next Last