Open Access. Powered by Scholars. Published by Universities.®
- Discipline
- Keyword
-
- Climate change (3)
- New Hampshire (3)
- Global warming (2)
- New England (2)
- Sustainability (2)
-
- Aerosol equilibrium; dust; chemical transport model (1)
- Aerosol transport; aerosol radiative forcing; rural New England (1)
- Aerosols (1)
- Aerosols; PM2.5; MODIS (1)
- Aerosols; TRACE-P; Asia (1)
- Aerosols; radioisotopes; beryllium; stratosphere-troposphere exchange (1)
- Aerosols; special field campaigns; instrument comparison (1)
- Airborne aerosol sampling; inlet passing efficiency; tropical Pacific; PEM Tropics B (1)
- Airborne aerosol; chemical composition; intercomparison (1)
- Airborne formaldehyde measurements; tunable diode laser measurements; formaldehyde measurements at high latitudes; formaldehyde during TOPSE (1)
- Aircraft measurement intercomparison; chemistry instruments (1)
- Asian outflow; TRACE-P; aerosol-associated soluble ions; beryllium-7; lead-210 (1)
- Atmospheric chemistry; bromine; Arctic (1)
- Atmospheric composition and structure; troposphere; composition and chemistry; constituent transport and chemistry (1)
- Atmospheric mercury (1)
- Beryllium-7; Be-7; 7Be; ozone; stratosphere/troposphere exchange; polar sunrise (1)
- Biomass burning (1)
- Carbonyl sulfide (OCS); carbon disulfide (CS2); Asian emissions; emission inventories (1)
- Carrington event; ice core; nitrate; sep (1)
- Chemical data assimilation; ozone; ozone and reactive nitrogen budget (1)
- Chemical transport model; lateral boundary condition; ICARTT (1)
- Climate (1)
- Convection; vertical transport; chemical tracers (1)
- Dust (1)
- Firn densification; ice sheet; mass balance; satellite altimetry (1)
- Publication Year
Articles 91 - 120 of 155
Full-Text Articles in Atmospheric Sciences
An Estimate Of The Stratospheric Contribution To Springtime Tropospheric Ozone Maxima Using Topse Measurements And Beryllium-7 Simulations, Dale J. Allen, Jack E. Dibb, Brian Ridley, Kenneth E. Pickering, R. Talbot
An Estimate Of The Stratospheric Contribution To Springtime Tropospheric Ozone Maxima Using Topse Measurements And Beryllium-7 Simulations, Dale J. Allen, Jack E. Dibb, Brian Ridley, Kenneth E. Pickering, R. Talbot
Earth Sciences
Measurements of tropospheric ozone (O3) between 30°N and 70°N show springtime maxima at remote locations. The contribution of seasonal changes in stratosphere–troposphere exchange (STE) to these maxima was investigated using measurements from the Tropospheric Ozone Production about the Spring Equinox Experiment (TOPSE) campaign and the beryllium-7 (7Be) distribution from a calculation driven by fields from the Goddard Earth Observing System Data Assimilation System (GEOS DAS). Comparison with TOPSE measurements revealed that upper tropospheric model-calculated 7Be mixing ratios were reasonable (a change from previous calculations) but that lower tropospheric mixing ratios were too low most likely …
Coupled Evolution Of Brox-Clox-Hox-Nox Chemistry During Bromine-Catalyzed Ozone Depletion Events In The Arctic Boundary Layer, M J. Evans, D J. Jacob, E L. Atlas, C A. Cantrell, Fred Eisele, F Flocke, A Fried, R L. Mauldin, Brian Ridley, B Wert, R. Talbot, D R. Blake, B J. Heikes, J Snow, J Walega, Andrew Weinheimer, Jack E. Dibb
Coupled Evolution Of Brox-Clox-Hox-Nox Chemistry During Bromine-Catalyzed Ozone Depletion Events In The Arctic Boundary Layer, M J. Evans, D J. Jacob, E L. Atlas, C A. Cantrell, Fred Eisele, F Flocke, A Fried, R L. Mauldin, Brian Ridley, B Wert, R. Talbot, D R. Blake, B J. Heikes, J Snow, J Walega, Andrew Weinheimer, Jack E. Dibb
Earth Sciences
Extensive chemical characterization of ozone (O3) depletion events in the Arctic boundary layer during the TOPSE aircraft mission in March–May 2000 enables analysis of the coupled chemical evolution of bromine (BrOx), chlorine (ClOx), hydrogen oxide (HOx) and nitrogen oxide (NOx) radicals during these events. We project the TOPSE observations onto an O3 chemical coordinate to construct a chronology of radical chemistry during O3 depletion events, and we compare this chronology to results from a photochemical model simulation. Comparison of observed trends in ethyne (oxidized by Br) and ethane …
Stratospheric Influence On The Northern North American Free Troposphere During Topse: 7be As A Stratospheric Tracer, Jack E. Dibb, R. Talbot, Eric Scheuer, Garry Seid, Linsey J. Debell, Barry Lefer, Brian Ridley
Stratospheric Influence On The Northern North American Free Troposphere During Topse: 7be As A Stratospheric Tracer, Jack E. Dibb, R. Talbot, Eric Scheuer, Garry Seid, Linsey J. Debell, Barry Lefer, Brian Ridley
Earth Sciences
We use 7Be, with HNO3 and O3, to identify air masses sampled from the NCAR C-130 during TOPSE that retained clear evidence of stratospheric influence. A total of 43 such air masses, spread fairly evenly across the February to May sampling period, and 40°N–86°N latitude range, were encountered. South of 55°N, nearly all clear stratospheric influence was restricted to altitudes above 6 km. At higher latitudes stratospherically influenced air masses were encountered as low as 2 km. Approximately 12% of all TOPSE sampling time at altitudes above 2 km was spent in stratospherically impacted air, above …
Ozone Depletion Events Observed In The High Latitude Surface Layer During The Topse Aircraft Program, Brian Ridley, Elliot Atlas, D Montzka, Edward V. Browell, C A. Cantrell, D R. Blake, N J. Blake, L Cinquini, Michael T. Coffey, L K. Emmons, Ronald C. Cohen, Russell J. Deyoung, Jack E. Dibb, Fred Eisele, F Flocke, A Fried, F E. Grahek, William B. Grant, Jonathan Hair, James W. Hannigan, B J. Heikes, Barry Lefer, R L. Mauldin, Jennie Moody, R E. Shetter, J Snow, R. Talbot, J A. Thornton, J Walega, Andrew Weinheimer, B Wert, Anthony Wimmers
Ozone Depletion Events Observed In The High Latitude Surface Layer During The Topse Aircraft Program, Brian Ridley, Elliot Atlas, D Montzka, Edward V. Browell, C A. Cantrell, D R. Blake, N J. Blake, L Cinquini, Michael T. Coffey, L K. Emmons, Ronald C. Cohen, Russell J. Deyoung, Jack E. Dibb, Fred Eisele, F Flocke, A Fried, F E. Grahek, William B. Grant, Jonathan Hair, James W. Hannigan, B J. Heikes, Barry Lefer, R L. Mauldin, Jennie Moody, R E. Shetter, J Snow, R. Talbot, J A. Thornton, J Walega, Andrew Weinheimer, B Wert, Anthony Wimmers
Earth Sciences
During the Tropospheric Ozone Production about the Spring Equinox (TOPSE) aircraft program, ozone depletion events (ODEs) in the high latitude surface layer were investigated using lidar and in situ instruments. Flight legs of 100 km or longer distance were flown 32 times at 30 m altitude over a variety of regions north of 58° between early February and late May 2000. ODEs were found on each flight over the Arctic Ocean but their occurrence was rare at more southern latitudes. However, large area events with depletion to over 2 km altitude in one case were found as far south as …
Investigations Into Free Tropospheric New Particle Formation In The Central Canadian Arctic During The Winter/Spring Transition As Part Of Topse, R J. Weber, D A. Orsini, B Wang, Eric Scheuer, R. Talbot, Jack E. Dibb, Garry Seid, Linsey J. Debell, R L. Mauldin, E Kosciuch, C A. Cantrell, Fred Eisele
Investigations Into Free Tropospheric New Particle Formation In The Central Canadian Arctic During The Winter/Spring Transition As Part Of Topse, R J. Weber, D A. Orsini, B Wang, Eric Scheuer, R. Talbot, Jack E. Dibb, Garry Seid, Linsey J. Debell, R L. Mauldin, E Kosciuch, C A. Cantrell, Fred Eisele
Earth Sciences
In this paper, we investigate the role of in situ new particle production in the central Canadian sub-Arctic and Arctic as part of the TOPSE experiment. Airborne measurements conducted primarily in the free troposphere were made from 50° to 90°W longitude and 60° to 85°N latitude during the period from February to May 2000. Data pertinent to this paper include 3–4 nm diameter (Dp) particles, ultrafine condensation nuclei (Dp > 3 nm), fine particles (0.2 < Dp < 3 μm), and the possible nucleation precursor, sulfuric acid, and its precursor, sulfur dioxide. For data averaged over this period, most species showed little evidence for a latitudinal trend. Fine aerosol number concentrations, however, showed a slight increase with latitude. The evolution of various species concentrations over the period of the study show that fine particles also had a consistent temporal trend, increasing at all altitudes from February to May, whereas sulfur dioxide at the surface tended to peak in late March. Ultrafine condensation nuclei and 3–4 nm particles showed no temporal trends. Little evidence for in situ new particle production was observed during the study, except for one atypical event where SO2concentrations were 3.5 ppbv, 2 orders of magnitude higher than typical levels. This paper cannot address the question of whether the observed condensation nuclei were …
Steady State Free Radical Budgets And Ozone Photochemistry During Topse, C A. Cantrell, Lee Mauldin, M Zondlo, Fred Eisele, E Kosciuch, R E. Shetter, Barry Lefer, S R. Hall, T L. Campos, Brian Ridley, J Walega, A Fried, B Wert, F Flocke, Andrew Weinheimer, James W. Hannigan, Michael T. Coffey, Elliot Atlas, S Stephens, B J. Heikes, J Snow, D R. Blake, N J. Blake, A Katzenstein, J Lopez, Edward V. Browell, Jack E. Dibb, Eric Scheuer, Garry Seid, R. Talbot
Steady State Free Radical Budgets And Ozone Photochemistry During Topse, C A. Cantrell, Lee Mauldin, M Zondlo, Fred Eisele, E Kosciuch, R E. Shetter, Barry Lefer, S R. Hall, T L. Campos, Brian Ridley, J Walega, A Fried, B Wert, F Flocke, Andrew Weinheimer, James W. Hannigan, Michael T. Coffey, Elliot Atlas, S Stephens, B J. Heikes, J Snow, D R. Blake, N J. Blake, A Katzenstein, J Lopez, Edward V. Browell, Jack E. Dibb, Eric Scheuer, Garry Seid, R. Talbot
Earth Sciences
A steady state model, constrained by a number of measured quantities, was used to derive peroxy radical levels for the conditions of the Tropospheric Ozone Production about the Spring Equinox (TOPSE) campaign. The analysis is made using data collected aboard the NCAR/NSF C-130 aircraft from February through May 2000 at latitudes from 40° to 85°N, and at altitudes from the surface to 7.6 km. HO2 + RO2 radical concentrations were measured during the experiment, which are compared with model results over the domain of the study showing good agreement on the average. Average measurement/model ratios are 1.04 (σ …
Springtime Photochemistry At Northern Mid And High Latitudes, Yuhang Wang, Brian Ridley, A Fried, C A. Cantrell, D D. Davis, Gao Chen, J Snow, B J. Heikes, R. Talbot, Jack E. Dibb, F Flocke, Andrew Weinheimer, N J. Blake, D R. Blake, R E. Shetter, Barry Lefer, Elliot Atlas, Michael T. Coffey, J Walega, B Wert
Springtime Photochemistry At Northern Mid And High Latitudes, Yuhang Wang, Brian Ridley, A Fried, C A. Cantrell, D D. Davis, Gao Chen, J Snow, B J. Heikes, R. Talbot, Jack E. Dibb, F Flocke, Andrew Weinheimer, N J. Blake, D R. Blake, R E. Shetter, Barry Lefer, Elliot Atlas, Michael T. Coffey, J Walega, B Wert
Earth Sciences
Physical and chemical properties of the atmosphere at 0–8 km were measured during the Tropospheric Ozone Production about the Spring Equinox (TOPSE) experiments from February to May 2000 at mid (40°–60°N) and high latitudes (60°–80°N). The observations were analyzed using a diel steady state box model to examine HOx and O3 photochemistry during the spring transition period. The radical chemistry is driven primarily by photolysis of O3 and the subsequent reaction of O(1D) and H2O, the rate of which increases rapidly during spring. Unlike in other tropospheric experiments, observed H2O2 …
Tunable Diode Laser Measurements Of Formaldehyde During The Topse 2000 Study: Distributions, Trends, And Model Comparisons, A Fried, Yuhang Wang, C A. Cantrell, B Wert, J Walega, Brian Ridley, Elliot Atlas, R E. Shetter, Barry Lefer, Michael T. Coffey, James W. Hannigan, D R. Blake, N J. Blake, Simone Meinardi, R. Talbot, Jack E. Dibb, Eric Scheuer, Oliver Wingenter, J Snow, B J. Heikes, Dieter Ehhalt
Tunable Diode Laser Measurements Of Formaldehyde During The Topse 2000 Study: Distributions, Trends, And Model Comparisons, A Fried, Yuhang Wang, C A. Cantrell, B Wert, J Walega, Brian Ridley, Elliot Atlas, R E. Shetter, Barry Lefer, Michael T. Coffey, James W. Hannigan, D R. Blake, N J. Blake, Simone Meinardi, R. Talbot, Jack E. Dibb, Eric Scheuer, Oliver Wingenter, J Snow, B J. Heikes, Dieter Ehhalt
Earth Sciences
Airborne measurements of formaldehyde (CH2O) were acquired employing tunable diode laser absorption spectroscopy (TDLAS) during the 2000 Tropospheric Ozone Production About the Spring Equinox (TOPSE) study. This study consisted of seven deployments spanning the time period from 4 February to 23 May 2000 and covered a wide latitudinal band from 40°N to 85°N. The median measured CH2O concentrations, with a few exceptions, did not show any clear temporal trends from February to May in each of five altitude and three latitude bins examined. Detailed measurement–model comparisons were carried out using a variety of approaches employing two …
Ozone, Aerosol, Potential Vorticity, And Trace Gas Trends Observed At High-Latitudes Over North America From February To May 2000, Edward V. Browell, Jonathan Hair, Carolyn Butler, William B. Grant, Russell J. Deyoung, Marta Fenn, Vincent G. Brackett, Marian B. Clayton, Lorraine A. Brasseur, David B. Harper, Brian Ridley, Andrzej Klonecki, Peter Hess, L K. Emmons, Xuexi Tie, Elliot Atlas, C A. Cantrell, Anthony Wimmers, D R. Blake, Michael T. Coffey, James W. Hannigan, Jack E. Dibb, R. Talbot, F Flocke, Andrew Weinheimer, A Fried, B Wert, J Snow, Barry Lefer
Ozone, Aerosol, Potential Vorticity, And Trace Gas Trends Observed At High-Latitudes Over North America From February To May 2000, Edward V. Browell, Jonathan Hair, Carolyn Butler, William B. Grant, Russell J. Deyoung, Marta Fenn, Vincent G. Brackett, Marian B. Clayton, Lorraine A. Brasseur, David B. Harper, Brian Ridley, Andrzej Klonecki, Peter Hess, L K. Emmons, Xuexi Tie, Elliot Atlas, C A. Cantrell, Anthony Wimmers, D R. Blake, Michael T. Coffey, James W. Hannigan, Jack E. Dibb, R. Talbot, F Flocke, Andrew Weinheimer, A Fried, B Wert, J Snow, Barry Lefer
Earth Sciences
Ozone (O3) and aerosol scattering ratio profiles were obtained from airborne lidar measurements on thirty-eight flights over seven deployments covering the latitudes of 40°–85°N between 4 February and 23 May 2000 as part of the Tropospheric Ozone Production about the Spring Equinox (TOPSE) field experiment. Each deployment started from Broomfield, Colorado, with bases in Churchill, Canada, and on most deployments, Thule Air Base, Greenland. Nadir and zenith lidar O3 measurements were combined with in situ O3measurements to produce vertically continuous O3 profiles from near the surface to above the tropopause. Potential vorticity (PV) distributions …
A 700-Year Record Of Atmospheric Circulation Developed From The Law Dome Ice Core, East Antarctica, Joseph M. Souney Jr, Paul A. Mayewski, Ian D. Goodwin, David Meeker, Vin Morgan, Mark Aj Curran, Tas D. Van Ommen, Anne S. Palmer
A 700-Year Record Of Atmospheric Circulation Developed From The Law Dome Ice Core, East Antarctica, Joseph M. Souney Jr, Paul A. Mayewski, Ian D. Goodwin, David Meeker, Vin Morgan, Mark Aj Curran, Tas D. Van Ommen, Anne S. Palmer
All Materials
A 700-year, high-resolution, multivariate ice core record from Dome Summit South (DSS) (66°46′S, 112°48′E; 1370 m), Law Dome, is used to investigate sea level pressure (SLP) variability in the region of East Antarctica. Empirical orthogonal function (EOF) analysis reveals that the first EOF (LDEOF1) of the combined glaciochemical, oxygen isotope ratio, and accumulation rate record from DSS represents most of the variability in sea salt seen in the record. LDEOF1 is positively correlated (at least 95% confidence level) to instrumental June mean SLP across most of East Antarctica. Over the last 700 years, LDEOF1 levels at Law Dome were the …
Measurements Of Pernitric Acid At The South Pole During Iscat 2000, D Slusher, L Gregory Huey, D Tanner, G Chen, D D. Davis, Martin Buhr, J Nowak, Fred Eisele, E Kosciuch, R L. Mauldin, Barry Lefer, R E. Shetter, Jack E. Dibb
Measurements Of Pernitric Acid At The South Pole During Iscat 2000, D Slusher, L Gregory Huey, D Tanner, G Chen, D D. Davis, Martin Buhr, J Nowak, Fred Eisele, E Kosciuch, R L. Mauldin, Barry Lefer, R E. Shetter, Jack E. Dibb
Earth Sciences
The first measurements of pernitric acid at the South Pole were performed during the second Investigation of Sulfur Chemistry in the Antarctic Troposphere (ISCAT 2000). Observed HO2NO2 concentrations averaged 25 pptv. Simple steady-state calculations constrained by measurements show that the lifetime of pernitric acid was largely controlled by dry deposition, with thermal decomposition becoming increasingly important at warmer temperatures. We determined that the pernitric acid equilibrium constant is less uncertain than indicated in the literature. One consequence of pernitric acid deposition to the snow surface is that it is an important sink for both NOx and HOx. Another is that …
Studies Of Peroxyacetyl Nitrate (Pan) And Its Interaction With The Snowpack At Summit, Greenland, Kevin M. Ford, Bradley M. Campbell, P B. Shepson, Steven B. Bertman, R E. Honrath, Matthew C. Peterson, Jack E. Dibb
Studies Of Peroxyacetyl Nitrate (Pan) And Its Interaction With The Snowpack At Summit, Greenland, Kevin M. Ford, Bradley M. Campbell, P B. Shepson, Steven B. Bertman, R E. Honrath, Matthew C. Peterson, Jack E. Dibb
Earth Sciences
Peroxyacetyl nitrate (PAN) was measured in ambient and snowpack interstitial air at Summit, Greenland, in June and July of 1998 and 1999 and at a rural/forest site in the Keewenaw Peninsula of Michigan in January of 1999. At Summit, we found that PAN typically represented between 30 and 60% of NOy. In the summer of 1999, a significant diel variation in both PAN/NOy and NOx/NOy was observed, but this was much less pronounced in 1998. Experiments during SNOW99 near Houghton, Michigan, indicated that PAN undergoes weak uptake onto snow grain surfaces. At Summit, we …
Shouldn’T Snowpacks Be Sources Of Monocarboxylic Acids?, Jack E. Dibb, Matthew Arsenault
Shouldn’T Snowpacks Be Sources Of Monocarboxylic Acids?, Jack E. Dibb, Matthew Arsenault
Earth Sciences
We report the first measurements of the mixing ratios of acetic (CH3COOH) and formic (HCOOH) acids in the air filling the pore spaces of the snowpacks (firn air) at Summit, Greenland and South Pole. Both monocarboxylic acids were present at levels well above 1 ppbv throughout the upper 35 cm of the snowpack at Summit. Maximum mixing ratios in Summit firn air reached nearly 8 ppbv CH3COOH and 6 ppbv HCOOH. At South Pole the mixing ratios of these acids in the top 35 cm of firn air were also generally >1 ppbv, though their maximums …
Airborne Sampling Of Aerosol Particles: Comparison Between Surface Sampling At Christmas Island And P-3 Sampling During Pem-Tropics B, Jack E. Dibb, R. Talbot, Garry Seid, C. E. Jordan, Eric Scheuer, Elliot Atlas, Nicola J. Blake, D R. Blake
Airborne Sampling Of Aerosol Particles: Comparison Between Surface Sampling At Christmas Island And P-3 Sampling During Pem-Tropics B, Jack E. Dibb, R. Talbot, Garry Seid, C. E. Jordan, Eric Scheuer, Elliot Atlas, Nicola J. Blake, D R. Blake
Earth Sciences
Bulk aerosol sampling of soluble ionic compounds from the NASA Wallops Island P-3 aircraft and a tower on Christmas Island during PEM-Tropics B provides an opportunity to assess the magnitude of particle losses in the University of New Hampshire airborne bulk aerosol sampling system. We find that most aerosol-associated ions decrease strongly with height above the sea surface, making direct comparisons between mixing ratios at 30 m on the tower and the lowest flight level of the P-3 (150 m) open to interpretation. Theoretical considerations suggest that vertical gradients of sea-salt aerosol particles should show exponential decreases with height. Observed …
Relationships Between Synoptic-Scale Transport And Interannual Variability Of Inorganic Cations In Surface Snow At Summit, Greenland: 1992-1996, J F. Slater, Jack E. Dibb, Barry D. Keim, D W. Kahl
Relationships Between Synoptic-Scale Transport And Interannual Variability Of Inorganic Cations In Surface Snow At Summit, Greenland: 1992-1996, J F. Slater, Jack E. Dibb, Barry D. Keim, D W. Kahl
Earth Sciences
To fully utilize the long-term chemical records retrieved from central Greenland ice cores, specific relationships between atmospheric circulation and the variability of chemical species in the records need to be better understood. This research examines associations between the variability of surface snow inorganic cation chemistry at Summit, Greenland (collected during 1992–1996 summer field seasons) and changes in air mass transport pathways and source regions, as well as variations in aerosol source strength. Transport patterns and source regions are determined through 10-day isentropic backward air mass trajectories during a 1 month (late May to late June) common season over the 5 …
Photochemical Production Of Gas Phase No X From Ice Crystal No3 −, R E. Honrath, S Guo, Matthew C. Peterson, M P. Dziobak, Jack E. Dibb, Matthew Arsenault
Photochemical Production Of Gas Phase No X From Ice Crystal No3 −, R E. Honrath, S Guo, Matthew C. Peterson, M P. Dziobak, Jack E. Dibb, Matthew Arsenault
Earth Sciences
Recent measurements have demonstrated that sunlight irradiation of snow results in the release of significant amounts of gas phase NOx (NO+NO2). We report here the results of a series of experiments designed to test the hypothesis that the observed NOx production is the result of nitrate photolysis. Snow produced from deionized water with and without the addition of nitrate was exposed to natural sunlight in an outdoor flow chamber. While NOx release from snow produced without added NO−3 was minimal, the addition of 100 µM NO−3resulted in the release …
Release Of No(X) From Sunlight-Irradiated Midlatitude Snow, R E. Honrath, Matthew C. Peterson, M P. Dziobak, Jack E. Dibb, Matthew Arsenault, S A. Green
Release Of No(X) From Sunlight-Irradiated Midlatitude Snow, R E. Honrath, Matthew C. Peterson, M P. Dziobak, Jack E. Dibb, Matthew Arsenault, S A. Green
Earth Sciences
Photochemical production and release of gas-phase NO(x) (NO + NO2) from the natural snowpack at a remote site in northern Michigan were investigated during the Snow Nitrogen and Oxidants in Winter study in January 1999. Snow was collected in an open 34 L chamber, which was then sealed with a transparent Teflon cover and used as an outdoor flow and reaction chamber. Significant increases in NO(x) mixing ratio were observed in synthetic and ambient air pulled through the sunlit chamber. [NO(x)] enhancements were correlated to ultraviolet sunlight intensity, reaching ~300 pptv under partially overcast midday, mid-winter conditions. These findings are …
Tropospheric Reactive Odd Nitrogen Over The South Pacific In Austral Springtime, Jack E. Dibb, R. Talbot, Eric Scheuer, J D. Bradshaw, S T. Sandholm, D R. Blake, N J. Blake, Elliot Atlas, F Flocke
Tropospheric Reactive Odd Nitrogen Over The South Pacific In Austral Springtime, Jack E. Dibb, R. Talbot, Eric Scheuer, J D. Bradshaw, S T. Sandholm, D R. Blake, N J. Blake, Elliot Atlas, F Flocke
Earth Sciences
The distribution of reactive nitrogen species over the South Pacific during austral springtime appears to be dominated by biomass burning emissions and possibly lightning and stratospheric inputs. The absence of robust correlations of reactive nitrogen species with source-specific tracers (e.g., C2H2 [combustion], CH3Cl [biomass burning], C2Cl4 [industrial],210Pb [continental], and 7Be [stratospheric]) suggests significant aging and processing of the sampled air parcels due to losses by surface deposition, OH attack, and dilution processes. Classification of the air parcels based on CO enhancements indicates that the greatest influence was found in …
Chemical Nox Budget In The Upper Troposphere Over The Tropical South Pacific, Martin G. Schultz, Daniel J. Jacob, J D. Bradshaw, S T. Sandholm, Jack E. Dibb, R. Talbot, Hanwant B. Singh
Chemical Nox Budget In The Upper Troposphere Over The Tropical South Pacific, Martin G. Schultz, Daniel J. Jacob, J D. Bradshaw, S T. Sandholm, Jack E. Dibb, R. Talbot, Hanwant B. Singh
Earth Sciences
The chemical NOx budget in the upper troposphere over the tropical South Pacific is analyzed using aircraft measurements made at 6-12 km altitude in September 1996 during the Global Tropospheric Experiment (GTE) Pacific Exploratory Mission (PEM) Tropics A campaign. Chemical loss and production rates of NOx along the aircraft flight tracks are calculated with a photochemical model constrained by observations. Calculations using a standard chemical mechanism show a large missing source for NOx; chemical loss exceeds chemical production by a factor of 2.4 on average. Similar or greater NOx budget imbalances have been reported in analyses of data from previous …
Composition And Distribution Of Aerosols Over The North Atlantic During The Subsonic Assessment Ozone And Nitrogen Oxide Experiment (Sonex), Jack E. Dibb, R. Talbot, Eric Scheuer
Composition And Distribution Of Aerosols Over The North Atlantic During The Subsonic Assessment Ozone And Nitrogen Oxide Experiment (Sonex), Jack E. Dibb, R. Talbot, Eric Scheuer
Earth Sciences
We report the mixing ratios of aerosol-associated soluble ions (focusing on SO4= and NO3−) and HNO3 over the North Atlantic during NASA's Subsonic Assessment Ozone and Nitrogen Oxide Experiment (SONEX). The SONEX campaign was designed to quantify the impacts of jet emissions in the North Atlantic Flight Corridor (NAFC) by sampling both directly within and far removed from the organized track system. Beryllium-7 activities were also measured to assess the magnitude of stratospheric influence in the SONEX study region. Mixing ratios of aerosol-associated SO4= and NO3− above 8 km during …
Reactive Nitrogen Budget During The Nasa Sonex Mission, R. Talbot, Jack E. Dibb, Eric Scheuer, Y Kondo, M Koike, H B. Singh, L Salas, F Fukui, J O. Ballenthin, R F. Meads, T M. Miller, D E. Hunton, A A. Viggiano, D R. Blake, N J. Blake, Elliot Atlas, F Flocke, D J. Jacob, L Jaegle
Reactive Nitrogen Budget During The Nasa Sonex Mission, R. Talbot, Jack E. Dibb, Eric Scheuer, Y Kondo, M Koike, H B. Singh, L Salas, F Fukui, J O. Ballenthin, R F. Meads, T M. Miller, D E. Hunton, A A. Viggiano, D R. Blake, N J. Blake, Elliot Atlas, F Flocke, D J. Jacob, L Jaegle
Earth Sciences
The SASS Ozone and Nitrogen Oxides Experiment (SONEX) over the North Atlantic during October/November 1997 offered an excellent opportunity to examine the budget of reactive nitrogen in the upper troposphere (8–12 km altitude). The median measured total reactive nitrogen (NOy) mixing ratio was 425 parts per trillion by volume (pptv). A data set merged to the HNO3 measurement time resolution was used to calculate NOy (NOy sum) by summing the reactive nitrogen species (a combination of measured plus modeled results) and comparing it to measured NOy (NOy meas.). Comparisons were done for tropospheric …
Maximum Temperature Trends In The Himalaya And Its Vicinity: An Analysis Based On Temperature Records From Nepal For The Period 1971–94, Arun B. Shrestha, Cameron P. Wake, Paul A. Mayewski, Jack E. Dibb
Maximum Temperature Trends In The Himalaya And Its Vicinity: An Analysis Based On Temperature Records From Nepal For The Period 1971–94, Arun B. Shrestha, Cameron P. Wake, Paul A. Mayewski, Jack E. Dibb
Earth Sciences
Analyses of maximum temperature data from 49 stations in Nepal for the period 1971–94 reveal warming trends after 1977 ranging from 0.068 to 0.128C yr21 in most of the Middle Mountain and Himalayan regions, while the Siwalik and Terai (southern plains) regions show warming trends less than 0.038C yr21. The subset of records (14 stations) extending back to the early 1960s suggests that the recent warming trends were preceded by similar widespread cooling trends. Distributions of seasonal and annual temperature trends show high rates of warming in the high-elevation regions of the country (Middle Mountains and Himalaya), while low warming …
Chemical Characteristics Of Air From Differing Source Regions During The Pacific Exploratory Mission-Tropics A (Pem-Tropics A), Ashley S. Board, H Fuelberg, G L. Gregory, B J. Heikes, Martin G. Schultz, D R. Blake, Jack E. Dibb, S T. Sandholm, R. Talbot
Chemical Characteristics Of Air From Differing Source Regions During The Pacific Exploratory Mission-Tropics A (Pem-Tropics A), Ashley S. Board, H Fuelberg, G L. Gregory, B J. Heikes, Martin G. Schultz, D R. Blake, Jack E. Dibb, S T. Sandholm, R. Talbot
Earth Sciences
Ten-day backward trajectories are used to determine the origins of air parcels arriving at airborne DC-8 chemical measurement sites during NASA's Pacific Exploratory Mission-Tropics A (PEM-T) that was conducted during August-October 1996. Those sites at which the air had a common geographical origin and transport history are grouped together, and statistical measures of chemical characteristics are computed. Temporal changes in potential temperature are used to determine whether trajectories experience a significant convective influence during the 10-day period. Those trajectories that do not experience a significant convective influence are divided into four geographical categories depending on their origins and paths. Air …
Constraints On The Age And Dilution Of Pacific Exploratory Mission-Tropics Biomass Burning Plumes From The Natural Radionuclide Tracer 210pb, Jack E. Dibb, R. Talbot, David Meeker, Eric Scheuer, N J. Blake, D R. Blake, G L. Gregory, G W. Sachse
Constraints On The Age And Dilution Of Pacific Exploratory Mission-Tropics Biomass Burning Plumes From The Natural Radionuclide Tracer 210pb, Jack E. Dibb, R. Talbot, David Meeker, Eric Scheuer, N J. Blake, D R. Blake, G L. Gregory, G W. Sachse
Earth Sciences
During the NASA Global Troposphere Experiment Pacific Exploratory Mission-Tropics (PEM-Tropics) airborne sampling campaign we found unexpectedly high concentrations of aerosol-associated 210Pb throughout the free troposphere over the South Pacific. Because of the remoteness of the study region, we expected specific activities to be generally less than 35 μBq m−3 but found an average in the free troposphere of 107 μBq m−3. This average was elevated by a large number of very active (up to 405 μBq m−3) samples that were associated with biomass burning plumes encountered on nearly every PEM-Tropics flight in the southern …
Ozone And Aerosol Distributions And Air Mass Characteristics Over The South Pacific During The Burning Season, Marta Fenn, Edward V. Browell, Carolyn Butler, William B. Grant, Susan A. Kooi, Marian B. Clayton, G L. Gregory, Reginald E. Newell, Yong Zhu, Jack E. Dibb, H Fuelberg, Bruce E. Anderson, A R. Bandy, D R. Blake, J D. Bradshaw, B J. Heikes, G W. Sachse, S T. Sandholm, H B. Singh, R. Talbot, D C. Thornton
Ozone And Aerosol Distributions And Air Mass Characteristics Over The South Pacific During The Burning Season, Marta Fenn, Edward V. Browell, Carolyn Butler, William B. Grant, Susan A. Kooi, Marian B. Clayton, G L. Gregory, Reginald E. Newell, Yong Zhu, Jack E. Dibb, H Fuelberg, Bruce E. Anderson, A R. Bandy, D R. Blake, J D. Bradshaw, B J. Heikes, G W. Sachse, S T. Sandholm, H B. Singh, R. Talbot, D C. Thornton
Earth Sciences
In situ and laser remote measurements of gases and aerosols were made with airborne instrumentation to establish a baseline chemical signature of the atmosphere above the South Pacific Ocean during the NASA Global Tropospheric Experiment (GTE)/Pacific Exploratory Mission-Tropics A (PEM-Tropics A) conducted in August-October 1996. This paper discusses general characteristics of the air masses encountered during this experiment using an airborne lidar system for measurements of the large-scale variations in ozone (O3) and aerosol distributions across the troposphere, calculated potential vorticity (PV) from the European Centre for Medium-Range Weather Forecasting (ECMWF), and in situ measurements for comprehensive air …
Concentrations And Snow-Atmosphere Fluxes Of Reactive Nitrogen At Summit, Greenland, J W. Munger, D J. Jacob, S M. Fan, A S. Colman, Jack E. Dibb
Concentrations And Snow-Atmosphere Fluxes Of Reactive Nitrogen At Summit, Greenland, J W. Munger, D J. Jacob, S M. Fan, A S. Colman, Jack E. Dibb
Earth Sciences
Concentrations and fluxes of NOy (total reactive nitrogen), ozone concentrations and fluxes of sensible heat, water vapor, and momentum were measured from May 1 to July 20, 1995 at Summit, Greenland. Median NOy concentrations declined from 947 ppt in May to 444 ppt by July. NOy fluxes were observed into and out of the snow, but the magnitudes were usually below 1 μmol m−2 h−1 because of the low HNO3 concentration and weak turbulence over the snow surface. Some of the highest observed fluxes may be due to temporary storage by equilibrium sorption of …
Influence Of Biomass Combustion Emissions On The Distribution Of Acidic Trace Gases Over The Southern Pacific Basin During Austral Springtime, R. Talbot, Jack E. Dibb, Eric Scheuer, D R. Blake, N J. Blake, G L. Gregory, G W. Sachse, J D. Bradshaw, S T. Sandholm, H B. Singh
Influence Of Biomass Combustion Emissions On The Distribution Of Acidic Trace Gases Over The Southern Pacific Basin During Austral Springtime, R. Talbot, Jack E. Dibb, Eric Scheuer, D R. Blake, N J. Blake, G L. Gregory, G W. Sachse, J D. Bradshaw, S T. Sandholm, H B. Singh
Earth Sciences
This paper describes the large-scale distributions of HNO3, HCOOH, and CH3COOH over the central and South Pacific basins during the Pacific Exploratory Mission-Tropics (PEM-Tropics) in austral springtime. Because of the remoteness of this region from continental areas, low part per trillion by volume (pptv) mixing ratios of acidic gases were anticipated to be pervasive over the South Pacific basin. However, at altitudes of 2–12 km over the South Pacific, air parcels were encountered frequently with significantly enhanced mixing ratios (up to 1200 pptv) of acidic gases. Most of these air parcels were centered in the 3–7 …
Aerosol Chemical Composition And Distribution During The Pacific Exploratory Mission (Pem) Tropics, Jack E. Dibb, R. Talbot, Eric Scheuer, D R. Blake, N J. Blake, G L. Gregory, G W. Sachse, D C. Thornton
Aerosol Chemical Composition And Distribution During The Pacific Exploratory Mission (Pem) Tropics, Jack E. Dibb, R. Talbot, Eric Scheuer, D R. Blake, N J. Blake, G L. Gregory, G W. Sachse, D C. Thornton
Earth Sciences
Distributions of aerosol-associated soluble ions over much of the South Pacific were determined by sampling from the NASA DC-8 as part of the Pacific Exploratory Mission (PEM) Tropics campaign. The mixing ratios of all ionic species were surprisingly low throughout the free troposphere (2-12 km), despite the pervasive influence from biomass burning plumes advecting over the South Pacific from the west during PEM-Tropics. At the same time, the specific activity of 7Be frequently exceeded 1000 fCi m-3 through much of the depth of the troposphere. These distributions indicate that the plumes must have been efficiently scavenged by precipitation (removing the …
Evidence Of Nox Production Within Or Upon Ice Particles In The Greenland Snowpack, R E. Honrath, Matthew C. Peterson, S Guo, Jack E. Dibb, P B. Shepson, Bradley M. Campbell
Evidence Of Nox Production Within Or Upon Ice Particles In The Greenland Snowpack, R E. Honrath, Matthew C. Peterson, S Guo, Jack E. Dibb, P B. Shepson, Bradley M. Campbell
Earth Sciences
NOx and NOy were determined in the interstitial air of surface snow and in ambient air at Summit, Greenland. NOx levels in interstitial air were 3 to >10 times those in ambient air, and were generally greater than ambient NOy levels. [NOy] in interstitial air varied diurnally in a manner consistent with photochemical generation within the snowpack. These observations imply that photochemical reactions occurring within or upon the ice crystals of surface snow produced NOx from a N-reservoir compound within the snow. Average [NOX]:[HNO3] and [NOx]:[NOy] ratios in ambient air above the snow were elevated relative to other remote sites, …
Wet Deposition In A Global Size-Dependent Aerosol Transport Model: 2. Influence Of The Scavenging Scheme On 210pb Vertical Profiles, Surface Concentrations, And Deposition, W Guelle, Y J. Balkanski, Jack E. Dibb, M Schulz, F Dulac
Wet Deposition In A Global Size-Dependent Aerosol Transport Model: 2. Influence Of The Scavenging Scheme On 210pb Vertical Profiles, Surface Concentrations, And Deposition, W Guelle, Y J. Balkanski, Jack E. Dibb, M Schulz, F Dulac
Earth Sciences
The main atmospheric sink for submicron aerosols is wet removal. Lead 210, the radioactive decay product of 222Rn, attaches immediately after being formed to submicron particles. Here we compare the effects of three different wet-scavenging schemes used in global aerosol simulations on the 210Pb aerosol distribution using an off-line, size-resolved, global atmospheric transport model. We highlight the merits and shortcomings of each scavenging scheme at reproducing available measurements, which include concentrations in surface air and deposition, as well as vertical profiles observed over North America and western and central North Pacific. We show that model-measurement comparison of total …