Geochemistry Commons^™

The Effects Of Organic Matter Rich Topsoil On The Germination Growth And Metal Uptake Of Corn (Zea Mays) Grown In Flue Dust Contaminated Soil, Christopher Allen Impellitteri

OES Theses and Dissertations

The large biomass of corn (Zea mays) and promising results from a previous experiment (Chlopecka and Adriano, 1995) concerning metal uptake by corn indicate that corn may be a good candidate for phytoremediation of trace metal contaminated soil. Appling soil (acid, thermic, typic paleudult) was treated with increasing levels of a metal rich flue dust based on Zn concentration (0, 150, 300, 600, 1200, and 2400 mg/kg). Four replicates at each Zn treatment level were either limed to pH 6.3-6.5 and covered with a two inch thick layer of organic matter rich topsoil (OM), unlimed and covered with …

Biostratigraphic Analysis Of Southern Florida's Plio-Pleistocene Shell Beds, Dalton L. Rasmussen

OES Theses and Dissertations

Four molluscan assemblage zones in southern Florida corresponding to the Pinecrest Sand Member of the Tamiami Formation, and the Caloosahatchee, Bermont and Fort Thompson shell beds were identified following quantitative and qualitative analyses of the fossil molluscan fauna. Twenty-eight bulk sediment samples collected from 16 localities across southern Florida were processed for fossil material, and yielded nearly 60,000 specimens belonging to 311 species. A Q-mode cluster analysis compared sediment samples on the basis of 188 species whose abundances had been converted to binary presence-absence form. The cluster analysis was run four times using the Jaccard and Dice similarity coefficients as …

The Petrogenesis Of Andesites Produced During Regional Extension: Examples From The Northern Mccullough Range, Nv And Xitle Volcano, Mexico, Kelly Ann Boland

UNLV Theses, Dissertations, Professional Papers, and Capstones

Andesite dominated volcanic systems produced during regional crustal extension remain a relatively unexplored aspect of andesite petrogenesis. In the southern Basin and Range province, thick sections of andesite and basaltic andesite have been documented in areas including the Piute Range, California, the Eldorado Range, Nevada, and the McCullough Range, Nevada. The northern McCullough Range, located 20 miles south-southeast of Las Vegas, is an ideal place to study the petrogenesis of an andesite dominated system. This area contains a mid-Miocene stratocone composed mainly of a 1200 m thick section of andesite flows that formed synchronous with regional extension.

The northern McCullough …

Prolonged History Of Silicic Peralkaline Volcanism In The Eastern Pacific Ocean, Wendy A. Bohrson, Mary R. Reid, Anita L. Grunder, Matthew Heizler, T. Mark Harrison, Jeffrey Lee

All Faculty Scholarship for the College of the Sciences

Socorro Island, Mexico, is an alkaline and peralkaline volcanic island located in the eastern Pacific Ocean on a mid-ocean ridge spreading center that was abandoned at ∼3.5 Ma. Silicic peralkaline rocks comprise up to 80% of the surface of the island, rendering Socorro virtually unique in the Pacific Ocean. Precise, replicate ⁴⁰Ar/³⁹Ar ages of 21 peralkaline trachytes and rhyolites reveal a history of episodic volcanic activity from ∼540 to 370 ka that may have culminated with caldera formation; repose periods between these episodes may have had maximum duration of ∼30 kyr. After up to 200 kyr of …

Study Of Volcanic Sediments By Microbeam-Pixe Technique, Nazrul I. Khandaker, M. Ahmed, M. A. Garwan

Publications and Research

Single mineral grains in a suite of Cretaceous (85–90 Ma) volcanic sedimentary rocks were analyzed using the microbeam-PIXE technique to understand fundamental geological processes responsible for micro-scale variation in elemental composition across mineral zones, twinning, cleavage planes, fractures and grain boundaries. Distributions of major and trace elements show distinct geochemical features indicative of a specific geological setting and a subsequent diagenetic process in these volcanic sediments. Examples of mineral zoning, microstructures of variable chemistry and post-depositional fluid flow are discussed using the data on feldspar group of minerals.

Organic Geochemistry And Petrology Of Oil Source Rocks, Carpathian Overthrust Region, Southeastern Poland — Implications For Petroleum Generation, Michael A. Kruge, Maria Mastalerz, Andrzej Solecki, B Artur Stankiewicz

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The organic matter rich Oligocene Menilite black shales and mudstones are widely distributed in the Carpathian Overthrust region of southeastern Poland and have excellent hydrocarbon generation potential, according to TOC, Rock-Eval, and petrographic data. Extractable organic matter was characterized by an equable distribution of steranes by carbon number, by varying amounts of 28,30-dinor-hopane, 18α(H)-oleanane and by a distinctive group of C₂₄ ring-A degraded triterpanes. The Menilite samples ranged in maturity from pre-generative to mid-oil window levels, with the most mature in the southeastern portion of the study area. Carpathian petroleum samples from Campanian-Oligocene sandstone reservoirs were similar …

Hydrogeology, Hydrogeochemistry, And Spoil Settlement At A Large Mine-Spoil Area In Eastern Kentucky: Star Fire Tract, David R. Wunsch, James S. Dinger, Page B. Taylor, Daniel I. Carey, C. Douglas R. Graham

Report of Investigations--KGS

An applied research program at the Star Fire surface mine in eastern Kentucky, owned and operated by Cypress-AMAX Coal Co., defined spoil characteristics to develop and monitor water resources, which will help identify a reliable water supply for future property development. Water stored in the mine spoil may provide a usable ground-water supply, and the spoil could also be engineered to provide base flow to surfacewater reservoirs.

Ground-water recharge enters the spoil by way of sinking streams, ground-water flow from bedrock in contact with the mine spoil, and a specially designed infiltration basin. Ground water discharges predominantly from springs and …

Geochemical Evolution Of A Mid-Miocene Synextensional Volcanic Complex: The Dolan Springs Volcanic Field, Northwestern Arizona, Scott Michael Mcdaniel

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Dolan Springs volcanic field (DSV), of northwestern Arizona, is dominated by andesite and basaltic-andesite flows and breccias, with minor amounts of basalt, rhyolite, and ash-flow tuff. Geochemistry is used here as a tool to evaluate the roles and contributions of the lithospheric and asthenospheric mantles to magmatism related to Miocene extension in the Colorado River extension corridor (CREC). The majority of synextensional volcanic rocks in the DSV are geochemically similar to regional trends, but rare tholeiitic basalts erupted near the end of extension. The tholeiites have trace element signatures similar to ocean island basalt (OIB), but have isotopic values …

Geology And Geochemistry Of Tertiary Volcanic Rocks In The Northern Reveille And Southern Pancake Ranges, Nye County, Nevada, Kelly Brian Rash

UNLV Theses, Dissertations, Professional Papers, and Capstones

The northern Reveille and southern Pancake Ranges, located in the south-central Great Basin, experienced a prolonged history of Tertiary volcanism. Volcanic activity in this area began with the eruption of large-volumes of ash-flow tuffs from calderas of the central Nevada caldera complex. The Reveille Range and the southernmost portion of the Pancake Range are the site of two calderas that are the sources for the tuff of Goblin Knobs and tuff of northern Reveille Range. The tuff of Goblin Knobs (70.4-75.3 wt.% SiO₂) erupted from the caldera of Goblin Knobs (25.6 Ma) and is the thickest (~1700 m) …

A Petrographic And Fluid Inclusion Study Of The Purple Vein And Post/Betze Orebodies, Carlin, Nevada, Jan B. Lamb

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Purple Vein (Meikle Mine) and Post/Betze orebodies, two Carlin-type, gold deposits, display important differences in size, alteration, silicification, pyritization, and gold grade. A core hole was examined from each deposit to gather petrographic and microthermometric data to determine the mineral paragenesis, to determine fluid pressure, temperature, and composition to compare of the two orebodies, and to determine depths of formation.

The parageneses determined were divided into three stages. (1) The Early Mineralization Stage contains quartz, pyrobitumen, barite, sphalerite, sulfosalts, quartz, and pyrite in the Purple Vein deposit and consists of calcite in the Post/Betze deposit. High salinity basinal brines, …

Hydrogeochemical Delineation Of A Groundwater Flow System, Berrien County, Michigan, Patrick J. Bartnik

Masters Theses

The objective of this study was to examine the possibility of determining groundwater flow directions from natural variations in groundwater chemistry. Groundwater samples were analyzed for major cation and anion concentrations. These data were to have been contoured and then compared with groundwater flow maps generated by conventional methods. The purpose was to determine whether a correlation could be drawn between the two methods. However, the results of the study did not allow for this comparison.

The plotted major cation and anion data did not lend themselves to contouring, which suggests that greater control may be required during the selection …

Organic Facies And Maturation Of Jurassic/Cretaceous Rocks, And Possible Oil-Source Rock Correlation Based On Pyrolysis Of Asphaltenes, Scotian Basin, Canada, Prasanta K. Mukhopadhyay, John A. Wade, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

This paper establishes source rock characterization and oil-oil and oil-source rock correlations of selected organic-rich shale source rocks and selected light oils and condensates from Jurassic and Cretaceous formations of the Scotian Basin. Multiple source rocks of Kerogen Types IIA (oil-prone), IIA-IIB (oil- and condensate-prone), IIB (condensate and gas prone), III (gas-prone), and IV (nonsource) are identified in various stratigraphic horizons. Vitrinite reflectance and T_max data indicate variable maturation histories, in different parts of the basin, which are related to differences in lithology-related heat conductivity and the presence of older sediments closer to areas of rifting. Multiple linear regression …

Fossil Charcoal In Cretaceous-Tertiary Boundary Strata: Evidence For Catastrophic Firestorm And Megawave, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Organic matter separated from calcareous sandstone from the upper portion of a deep-water tsunami deposit at Arroyo el Mimbral, Taumalipas (Mexico), which marks the biostratigraphically-defined Cretaceous-Tertiary boundary, consists primarily of fossil charcoal, including semifusinite and pyrofusinite. Analytical pyrolysis-gas chromatography-mass spectrometry revealed the highly aromatic and polyaromatic character of the organic matter assemblage, typical of the products of partial combustion. The organic matter probably originated as terrestrial vegetation that was caught in a firestorm and subsequently transported far offshore in the backwash of a megawave. These data are consistent with the hypothesis of combustion of large masses of vegetation triggered by …

Field Test Of A Calcite Dissolution Rate Law: Fort’S Funnel Cave, Mammoth Cave National Park, J. Scott Slunder

Masters Theses & Specialist Projects

The laboratory-derived calcite dissolution rate law of Plummer et al. (1978) is the most widely used and mechanistically detailed expression currently available for predicting dissolution rates as a function of water chemistry. Such rate expressions are of great use in understanding timescales associated with limestone karst development. Little work has gone into the field testing of the rate law under natural conditions.

This work compared measured dissolution rates measured by a crystal weight loss experiment in Buffalo Creek within Fort’s Funnel Cave, which lies within a pristine, forested catchment of Mammoth Cave National Park. Continuous water chemistry sampling over the …

The Geology Of The Tuff Of Bridge Spring: Southern Nevada And Northwestern Arizona, Shirley Ann Morikawa

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Tuff of Bridge Spring (TBS) is a regionally-widespread, andesite to rhyolite (59.50 to 74.91 wt. %) ash-flow tuff of mid-Miocene age (ca. 15.2 Ma) that is exposed in the northern Colorado River extensional corridor of southern Nevada and northwestern Arizona. Determination of the areal distribution, geochronology, lithology, geochemistry, and internal stratigraphy of the TBS is important for its establishment as a reliable stratigraphic reference horizon for tectonic reconstructions of the extensional corridor during the middle Miocene. Based on reoccurring patterns of major and trace element variation, the TBS is divided into constant Cr/variable SiO₂ and variable Cr/variable SiO …

Groundwater Chemistry Analysis Of The Saginaw Formation In Delhi Township, Michigan, Sam L. Kitchin

Masters Theses

Groundwater chemistry and well data provided by the Ingham County (Michigan) Health Department were used to evaluate the distribution of inorganic chemical constituents in the groundwater flow system of the Saginaw Formation, in Delhi Township, Michigan. The data also were used to study the distribution of chemical constituents with respect to different rock types of the Saginaw Formation. The data were analyzed to examine if variations in the concentrations of the chemical constituents and the values of other chemical parameters relate to rock-water interactions, groundwater flow systems, or groundwater contamination.

The results indicate that patterns of increasing or decreasing concentrations …

Geochemistry, Alluvial Facies Distribution, Hydrogeology, And Groundwater Quality Of The Dallas-Monmouth Area, Oregon, Rodney R. Caldwell

Dissertations and Theses

The Dallas-Monmouth area, located in the west-central Willamette Valley, Oregon, consists of Tertiary marine and volcanic bedrock units which are locally overlain by alluvium. The occurrence of groundwater with high salinities has forced many rural residents to use public water supplies. Lithologic descriptions from driller's logs, geochemical (INAA), and x-ray diffraction analyses were used to determine alluvial facies distribution, geochemical and clay mineral distinctions among the units, and possible sediment sources. Driller's log, chemical and isotopic analysis, and specific conductance information from wells and springs were used to study the hydrogeologic characteristics of the aquifers and determine the distribution, characteristics, …

Water-Quality Assessment Of The Central Nebraska Basins: Summary Of Data For Recent Conditions Through 1990, Ronald B. Zelt, P. R. Jordan

United States Geological Survey: Publications

Among the first activities undertaken in each National Water-Quality Assessment (NAWQA) investigation are the compilation, screening, and statistical summary of available data concerning recent water-quality conditions in the study unit. The water-quality conditions of interest in addressing the objectives of the NAWQA program are those that are representative of the general water quality of a given stream reach or area of an aquifer. This report (1) identifies which existing water-quality data are suitable for characterizing general conditions in a nationally consistent manner and (2) describes, to the extent possible, recent, general water-quality conditions in the Central Nebraska Basins. The study …

Organic Geochemistry Of Permian Organic-Rich Sediments From The Sudetes Area, Sw Poland, Shareen R. Yawanarajah, Michael A. Kruge, Maria Mastalerz, Wojciech Sliwinski

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Lacustrine and marine sediments from the Permian rift-basins of southwestern Poland were analysed using GC-MS and petrographic techniques. High Pr/Ph ratios, gamma- and beta-carotanes and gammacerane in the lacustrine sediments indicate deposition under elevated water salinities. The primary organic matter is represented by bacterial and algal lipids with variable terrestrial input. Marine algal lipids with minor bacterial and cyanobacterial lipids are the primary source of organic matter in the marine sediments. Extended hopanes, n-alkanes with even-odd predominance and low Ts/Tm ratios are consistent with deposition in a closed, evaporitic basin with substantial carbonate sedimentation.

Correlation Of The Tioga Bentonites Using Rhyolitic Melt Inclusions Found In Quartz Phenocrysts As Geochemical Fingerprints, John W. Waechter

Geology Theses and Dissertations

The Tioga bentonites were first noted by Fettke in 1931 from well cuttings in the Tioga gas fields of Tioga County, Pennsylvania. They have been used by many investigators (Oliver, 1954, 1956; Dennison, 1963; Dennison and Textoris, 1967, 1978; Epstein, 1986; Smith and Way, 1983; Way et al., 1986) as a time-plane to correlate stratigraphic units from eastern Pennsylvania to Illinois and from southern Ontario to Virginia. The Tioga bentonites are recognized as seven major volcanic ash layers labeled Tioga-A - Tioga-G as well as several minor layers labeled Tioga-A1 - Tioga-A3 (Way et al., 1986). They occur within the …

Trace-Element Modelling Of Melting In Spinel Peridotites, Susanne Petra Vogel

Geology Theses and Dissertations

This study addresses three independent topics related to trace element modeling of spinel peridotites that are suggested by the pioneering work of Johnson et al. (1990) on abyssal harzburgites.
First, the fractional non-modal melting equation derived by Johnson and coworkers (1990) is algebraically modified to present a "one-element/two-phase" model. This model suggests a simple test for estimating mantle heterogeneity in the source rock of spinel lherzolites. This model is applied to data from the literature for samples from Dreiser Weiher, Germany; San Luis Potosi, Mexico; and Western Victoria, Australia.
Second, trace elements in clinopyroxenes of abyssal peridotites and continental spinel …

Reconnaissance Data For Selected Herbicides, Two Atrazine Metabolites, And Nitrate In Surface Water Of The Midwestern United States, 1989-90, Elisabeth A. Scribner, E. Michael Thurman, Donald A. Goolsby, Michael T. Meyer, Margaret S. Mills, Michael L. Pomes

United States Geological Survey: Publications

Water-quality data were collected from 147 rivers and streams during 1989-90 to determine the temporal and geographic distribution of selected preemergent herbicides, two atrazine metabolites, and nitrate in 10 Midwestern States. This report includes a description of the sampling design, data-collection techniques, laboratory and analytical methods, and a compilation of constituent concentrations and quality-assurance data. All water samples were collected by depth-integrating techniques at three to five locations across the wetted perimeter of each stream. Sites were sampled three times in 1989~before application of herbicides, during the first major runoff after application of herbicides, and in the fall during a …

Fluid Inclusion Studies Of The Morefield Pegmatite Amelia County, Virginia, John Richard Smerekanicz

OES Theses and Dissertations

The Morefield Pegmatite is a planar, nearly vertical body situated in Grenville age gneisses and schists in the southeast Piedmont of Virginia. It consists of a mineralogically simple albite-quartz outer zone and a texturally and mineralogically complex inner zone of microcline-topaz-quartz, with trace amounts of rare-element minerals. Fluid inclusions in samples of quartz, topaz, beryl, spessartite and albite that span the length, width and depth of both zones can be classified by chemical composition into two main groups: H₂O-rich solutions and CO₂- H₂O -rich fluids. The H₂O -rich inclusions consist of H …

Relation Of Groundwater Fluoride Concentrations To Sediment Mineralogy, Potomac Formation (Cretaceous), Southeastern Virginia, Paul Anthony Maciuika

OES Theses and Dissertations

Thirty-seven Early cretaceous sediment samples of the Potomac Formation were obtained from four cores to determine if fluoride bearing minerals are responsible for elevated fluoride concentrations in Potomac Formation groundwaters of southeastern Virginia. Investigative methods included total sediment fluoride and particle size analysis, semiquantitative mineralogical analysis (achieved by X-Ray Diffraction) and statistical methods (cluster, canonical and regression analysis). The sediments showed wide variation in textures, ranging from clean sands and gravels to silty clays. Sediment mineralogies were dependent on the prevailing size fraction, with quartz and feldspar dominating the sand and silt fractions, muscovite primarily being found in the silt …

Mineralogy, Geochemistry, And Dispersal Of Opaque Oxides On The Continental Shelf Of The Cascadia Margin, Kommajosyula Subramanya Ravi

Dissertations and Theses

Opaque oxide minerals (ilmenite, chromite, and magnetite) in sands from the Oregon continental shelf have been studied to establish the provenance, dispersal, and grade of potential shelf placer deposits. The study area extends southward from offshore of the Columbia River in northern Oregon to the Klamath River in northern California.

The Sloan Sag: A Mid-Miocene Volcanotectonic Depression, North-Central Mccullough Mountains, Southern Nevada, Hayden L. Bridwell

UNLV Theses, Dissertations, Professional Papers, and Capstones

In the Hidden Valley area of the north-central McCullough Mountains, southern Nevada, mid-Miocene andesite and dacite domes, flows and pyroclastic units (the Sloan volcanics) partially fill a sag in the underlying Hidden Valley volcanics. The 13.5 km diameter sag formed during and/or after the eruption of the Sloan volcanics. Sagging was accommodated by a combination of movement on the McCullough Wash fault system, and subsidence into evacuated chambers.

Major, trace and rare-earth element geochemistry suggests that the rocks of the Sloan volcanics belong to four groups, each of which were produced by partial melting of chemically distinct sources. With the …

An Analysis Of Dissolved Organic Compounds And Their Contribution To Iron Complexation In The Shallow Leachate Plume Of The West Kl Landfill Kalamazoo, Michigan, Eric Fahle

Masters Theses

High concentrations of dissolved iron are present in downgradient groundwater samples adjacent to the western border of the West KL Landfill. Analysis by Rudder (1988) of groundwater samples indicates oversaturation of selected iron oxides, iron sulfides and siderite in monitoring wells TW-4 and M3.

Previous research suggests that pyrogallol, gallic acid, tannic acid and similar organic compounds may retard the oxidation of ferrous iron in the shallow leachate plume of the West KL landfill (Rudder, 1988). Present research utilizing solid phase extraction, reverse phase high performance chromatography, Fourier transform IR spectrophotometry, UV/Visible spectrophotometry, and gas chromatography/mass spectroscopy indicate that pyrogallol, …

Sedimentological, Structural, And Organic Geochemical Controls On Natural Gas Occurrence In The Antrim Formation In Otsego County, Michigan, Timothy M. Dellapenna

Masters Theses

The prolific Antrim Formation natural gas reservoir in Otsego County, Michigan, has been examined using core descriptions, X-ray diffraction, petrographic, and geochemical analyses. New stratigraphy nomenclature is proposed for the Antrim and Ellsworth Shales. The Antrim Shale contains two distinctive lithofacies: (1) a fractured, non-bioturbated, silica-rich, organicrich black shale lithofacies; and (2) sparsely fractured, bioturbated, carbonaterich, organic-poor gray-green shale. Gas production comes from the Black shale facies.

Rock-Eval analysis demonstrates that the organic matter is a mixture of types I and II material. Low Tmax (435°C) and vitrinite reflectance (0.41-0.46%) values indicate a submature thermal maturation level. Del 13 carbon …

Chemical Analyses Of Water From Selected Wells And Springs In The Yucca Mountain Area, Nevada And Southeastern California, P. W. Mckinley, M. P. Long, Larry Benson

United States Geological Survey: Publications

Chemical analysis of water samples from 279 wells and springs in the Yucca Mountain area are presented. Where data are available, this report includes: site location expressed as Nevada Central Coordinates and latitude and longitude; source of data; name of analyzing laboratory; geologic unit from which water was obtained; lithology; water use; elevation of well or spring; well depth; depth to water; time pumped before taking the sample; yield; type of filtration; sampling method; date the sample was collected; and anion-cation balance.

Yucca Mountain, Nevada (fig. 1), is being investigated by the U.S. Geological Survey, in cooperation with the U.S. …

Mineral Paragenesis Of The Granulite Facies In The Lake George Area, New York, Boknam Ree

Geology Theses and Dissertations

The Lake George Area belongs to the southeastern part of the Adirondack Highlands. The rocks of this area show variations in mineral assemblages which are caused by differences in bulk chemical composition. This makes it unsuccessful to use a subdivision of the granulite facies which is suggested by de Waard (1965).
The CFM diagram (Abbott, 1982) is used to show the relationship between composition and paragenesis of the Lake George Area. In this study, a different result has been found in the order of partitioning of Fe between coexisting minerals, namely, garnet>hornblende>biotite>orthopyroxene>clinopyroxene. The hornblende granitic gneiss …