Geochemistry Commons^™

Hydrogeology And Hydrogeochemistry Of The Shallow Alluvial Aquifer Zone, Las Vegas Valley, Nevada, Harry Stephen Wild Jr.

UNLV Theses, Dissertations, Professional Papers, and Capstones

In Las Vegas Valley, Nevada, the shallow alluvial aquifer zone is a possible source of contamination to the principal alluvial aquifers that provide 30% of the public drinking water supply for the valley. Development of the principal aquifers has lowered pressure head in the principal aquifers and created the potential for downward seepage from the shallow aquifer zone. This study was undertaken to characterize the hydrogeology and hydrogeochemistry of the shallow alluvial aquifer zone and to compare the hydrogeochemistry of the shallow and principal alluvial aquifer zones.

A 37 well shallow ground water monitoring network was established and water-level, water-quality, …

Hydrogeology And Hydrogeochemistry Of The Tekonsha Moraine And Adjacent Interlobate Deposits In Charleston Township, Kalamazoo County, Michigan, Victor V. Melbardis

Masters Theses

Hydrogeochemical analyses and hydrogeologic interpretations provide the basis for an understanding of local ground-water flow, in a 12 square mile study area, transected by the Tekonsha Moraine and bound by glaciofluvial deposits. Glacial tills separate an upper and lower aquifer system throughout most of the area.

Degraded and tritiated ground water is present in the lower aquifer system. A negative correlation (-0.62) between tritium concentrations and depth is statistically significant (.04). In this local system, hydrochemical trends are characterized by decreases in sulfate percentages and increases in bicarbonate in the direction of ground-water flow. Statistical evaluation of the hydrochemical data …

Metal Mobilization From A Near-Shore Lake Sediment Under Simulated Acidic Groundwater Inputs, Raveendra V. Ika

OES Theses and Dissertations

Simulation of acidic groundwater passing through lake sediments was conducted under controlled conditions in a laboratory. Three sediment cores collected intact from the near-shore region of an acidic lake were subjected to simulated groundwater inputs of initially identical chemistry for a seven day period. Following this period water being used in the simulation for two of the sediment cores was acidified by hydrochloric acid (HC1) addition to examine the ability of these sediments to neutralize acidic groundwater with varying H⁺ concentration.

Simulated acidic water passing through the sediment cores mobilized significant amounts of metals. The sediment acted as a …

Geochemical Evolution Of Ferruginous Bauxite Deposits In Northwestern Oregon And Southwestern Washington, Joseph Michael Fassio

Dissertations and Theses

Ferruginous bauxite deposits developed from flows of the Columbia River Basalt Group in northwestern Oregon and southwestern Washington. Samples of the iron pisolite and the gibbsite nodular zones from the upper portion of the weathering profile of drill core from Columbia County, Oregon and Cowlitz County, Washington, were analyzed by instrumental neutron activation. The mineralogy was determined using Xray diffraction and Mossbauer spectroscopy.

The gibbsite nodular zone is above the clay-rich saprolite or relic basalt zone. The nodules contain relic vesicles and well preserved relic plagioclase microlites. Gibbsite occurs with poorly crystalline goethite and hematite in the gibbsite nodular zone. …

Biological Markers In Lower Jurassic Synrift Lacustrine Black Shales, Hartford Basin, Connecticut, U.S.A., Michael A. Kruge, John F. Hubert, Jay F. Akes, Paul E. Meriney

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The East Berlin Formation (Lower Jurassic, Hartford basin, Connecticut, U.S.A.) is distinctive for its six cyclic units of lacustrine black shale and gray mudstone. separated by playa and fluvial redbeds. The black shales arc each about a meter thick and were deposited in subtropical, thermally stratified, oligomictic lakes, the youngest of which (lakes 3 through 6) were large enough to flood most of the basin and attained depths of several tens of meters.

The saturate fractions of solvent extracts of organic-rich black shales from each of the six lakes, collected at fresh roadcuts near East Berlin, arc dominated by extended …

Organic Geochemistry Of A Lower Jurassic Synrift Lacustrine Sequence, Hartford Basin, Connecticut, U.S.A., Michael A. Kruge, John F. Hubert, David F. Bensley, John C. Crelling, R Jay Akes, Paul E. Meriney

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Synrift terrestrial strata of the Lower Jurassic East Berlin Formation (Hartford basin, Connecticut, U.S.A.) record cyclical expansion and contraction of major lakes, six of which were deep enough to develop anoxic bottom waters. We have studied one representative lacustrine sequence in detail, sampling a new roadcut near the village of East Berlin. The section examined is 4 m thick, with a gray siltstone at the base, deposited in shallow water, overlain by an organic-rich black shale (deep water), succeeded in turn by another gray siltstone, deposited as the lake waters gradually receded. The upper gray siltstone is chemically distinct from …

Mining In Maine : Past, Present, And Future, Carolyn A. Lepage

Maine Collection

Mining in Maine : Past, Present, and Future

by Carolyn A. Lepage, Michael E. Foley, and Woodrow B. Thompson

Maine Geological Survey, Department of Conservation, Augusta, Me., 1990.

Contents: Introduction / The Early Years: Pre-Civil War / The Civil War to World War II / The War Years of the 1940's / The Postwar Years: 1940's to 1960 / The 1960's / The 1970's / Maine Mineral Resources Association / The 1980's / Current Mining and Exploration / Future Potential / Acknowledgments / References

Origin, Sedimentary Geochemistry, And Correlation Of Middle And Late Ordovician K-Bentonites: Constraints From Melt Inclusions And Zircon Morphology, Carsten Schirnick

Geology Theses and Dissertations

The present study of Paleozoic K-bentonites demonstrates that the geochemistry of melt inclusions and the morphology of zircons can be studied by inexpensive and simple-to-use methods, which rely on phenocrysts. Constraints are obtained that lead to (a) the origin of these altered volcanic ashes, (b) the geochemistry of ash-to-K-bentonite-alteration, and (c) the reliable correlation of extensively altered volcanic ashes (i.e. K-bentonites).
Silicic melt inclusions (i.e. non-devitrified) have been found in quartz and zircon phenocrysts contained within Ordovician and Devonian K-bentonites from New York State, the Upper Mississippi Valley, and Pennsylvania. Origin, source, and tectonic setting of the volcanism that produced …

Application Of A Trace Element Fractionation Model To Cumulate Gabbroic Xenoliths Of Mauna Kea, Hawaii, Ulrike Eberle

Geology Theses and Dissertations

A trace element fractionation model originally designed to relate plutonic rocks containing a trapped glass component to a complementary volcanic rock suite was applied to olivine and opaque-oxide gabbroic xenoliths from the summit cone of Mauna Kea, Hawaii.
The mathematical model which is based on the Rayleigh Fractionation Law was extended to include the various phases present in these two groups of gabbros and was generalized to treat multiple trace elements, in this case four. These results were incorporated in a new FORTRAN program using the interval-bisection method to greatly improve the convergence time in the numerical solutions.
Calculated results …

Petrology And Major Element Geochemistry Of Basaltic Glasses From The Blanco Trough, Northeast Pacific, Glenn A. Gaetani

Geology Theses and Dissertations

The original electron microprobe analyses of suite of basaltic glasses recovered in 1968 by W.G. Melson and co-workers from the Blanco Trough have extremely unusual characteristics. Their compositions plot in a region of the normative Ol-Di-Pl-SiO2 tetrahedron which suggests that they represent liquids in equilibrium with an upper mantle assemblage of olivine + orthopyroxene at 10-15 kb. Given the present state of controversy surrounding the composition and depth of origin of primary MORB, natural examples of such liquids would be very important. The major element variations observed in the suite imply that the dominant phases are olivine and an iron-aluminum …

Geochemistry Of Garnet Xenocrysts And Garnet-Bearing Xenoliths In Ordovician Bentonites, Barbara Bock

Geology Theses and Dissertations

Within outcrops of the black Utica shales south of the Mohawk Valley narrow re-entrants parallel with stratification are visible, often accompanied -by a marked orange-staining of the underlying strata. These rentrant features indicate the presence of bentonites weathered back faster then the enclosing shales. These bentonites are presumably magmatic ashes related to extensive volcanism when an island arc collided with the North American continent in the late Ordovician about 450 million years ago (Taconic orogeny).
Bentonites are good stratigraphic markers because of the short time-interval they represent and the large area they cover. Therefore they are commonly used as correlation …

A Geochemical Study Of The Eagle Creek Formation In The Columbia River Gorge, Oregon, Rachel Ann Carlin

Dissertations and Theses

The Early Miocene Eagle Creek Formation, a series of volcanic mudflows and debris flows, is exposed in the Columbia River Gorge about 64 kilometers east of Portland, Oregon. Eighty-seven samples were analyzed using instrumental neutron activation analysis for trace element concentrations. Eleven samples were analyzed by Dr. Peter Hooper at Washington State University using X-ray Fluorescence for major element chemistry. These data were used to determine that the Eagle Creek Formation compositionally ranges from andesite to dacite.

Geochemical Stratigraphy Of The Dooley Rhyolite Breccia And Tertiary Basalts In The Dooley Mountain Quadrangle, Oregon, David Neale Whitson

Dissertations and Theses

The Dooley Rhyolite Breccia in northeast Oregon was erupted between 12 and 16 million years ago, from central vents and linear feeder dikes within the Dooley Mountain quadrangle. The peraluminous, high-silica rhyolites of the formation were erupted over an irregular highland of eroded pre-Tertiary metamorphic rocks locally overlain by intracanyon, Eocene Clarno-type basalt flow(s). The Dooley Rhyolite Braccia is exposed in a tectonically disrupted, north-south trending graben across the Elkhorn Range. The formation is variable in thickness with maximum thickness exceeding 660 meters in the south and 600 meters in the north half of the quadrangle. Volumetrically the formation is …

Sedimentology, Structure, And Geochemistry Of The Galice Formation: Sediment Fill Of A Back-Arc Basin And Island Arc In The Western Klamath Mountains, Rosann Park-Jones

Geology Theses and Dissertations

The western Jurassic belt of the Klamath Mountains is an ideal locale for the study of ophiolite genesis, island arc development, and study of flysch deposition from a nearby eroding island arc and continental margin. Closure and imbrication of an inferred back-arc basin coincided with the Late Jurassic Nevadan orogeny (ca 150 Ma). The Galice Formation is the youngest formation involved in the Nevadan orogeny (Lanphere et al., 1968). In the type section in southwestern Oregon, the Galice structurally overlies the Rogue Formation volcaniclastics. The Rogue Formation has been previously interpreted as an island arc assemblage (Garcia, 1979). The type …

Discrimination Of Subparallel Beach Ridges Using Detrital Ilmenite Composition And Fourier Shape Analysis, Allen E. Evans Jr.

OES Theses and Dissertations

Elemental composition (Fe, Ti, Mn, Mg, V, Cu, Ni, Zn, and Cr) and Fourier shape analysis of magnetically separated detrital ilmenite from seven Pleistocene and modern beach sand deposits of the Southeastern Virginia Coastal Plain were used to distinguish each deposit. Geomorphic expression, crosscutting relationships and proximity to the present shoreline differentiates the relative age of the seven sampled beach deposits. Analysis of ilmenite elemental composition, independent of geomorphic expression, distinguished beach sands of

different age and was successful in determining that each beach contained ilmenite similar in composition. Of the seven beach ridges tested, subtle yet significant differences in …

Isotope Content And Temperature Of Precipitation In Southern Nevada, August 1983-August 1986, W. K. Milne, Larry Benson, P. W. Mckinley

United States Geological Survey: Publications

From August 1983 through August 1986, 429 precipitation samples of 112 precipitation events were collected at 12 stations in southern Nevada. Some of these samples were analyzed for oxygen-18, deuterium, and tritium. The results of these analyses as well as the air temperature and the precipitation measured at the collection sites are tabulated in this report. The sampling program provides a data base for future interpretive studies on the timing and origin of ground-water recharge in the Yucca Mountain region, of southern Nevada.

The stable-isotope composition of precipitation is the result of fractionation processes that occur in the atmosphere. Isotopic …

Identification Of Endmembers For Magma Mixing In Little Sitkin Volcano, Alaska, Douglas A. Wolf

Geology Theses and Dissertations

Little Sitkin island is an Aleutian calc-alkalic volcanic center that has erupted a suite of lavas ranging from andesite through rhyodacite. Whole-rock chemistry of these lavas indicates contrasting evolutionary processes; major-oxide silica variation diagrams exhibit linear trends that are suggestive of magma-mixing while trace-element trends are largely controlled by accessory-phase fractionation.
Plagioclase, the dominant phenocryst phase in all lavas, commonly occurs in two distinct populations with markedly different compositions and textures. Both normal and reverse zonation is noted in the plagioclase and clinopyroxene of several samples. In addition, clinopyroxene is found as rims on orthopyroxene grains and as cores with …

Granitic Pegmatites In The Southeastern Adirondacks: Their Use As Indicators Of Temperature, Pressure, And Fluid Conditions During A Late Stage Of The Grenville Orogeny, John P. Mihalich

Geology Theses and Dissertations

Granitic pegmatites associated with the Grenville orogeny intrude a mid-Proterozoic, upper amphibolite to near granulite facies terrane in the southeastern Adirondack Mountains of New York State. The inferred anatectic, fluid-saturated, and minimum melt characteristics of the pegmatites suggest that they can be used as analogs of the "granite" or "haplogranite" system, and as indicators of crustal temperature, pressure, and fluid conditions during a late stage of the Grenville orogeny. Bulk chemical compositions of seven simple, undeformed pegmatites in the southeastern Adirondacks indicate that they are generally depleted in silica and sodium, and enriched in potassium, relative to experimental data on …

Geology, Geochemistry, And Geochronology Of The Lems Ridge Olistostrome, Klamath Mountains, California, Matthias Ohr

Geology Theses and Dissertations

The Lems Ridge olistostrome (LRO), located within the western Jurassic belt of the Klamath Mountains geologic province, is a melange unit showing a distinct block-in-matrix fabric. The conformable relationship to both an igneous basement and the overlying flysch of the Late Jurassic Galice Formation points to a sedimentary origin. The lack of pervasive deformation and the internal stratification also support a predominantly olistostromal origin of the LRO. The matrix of the LRO consists of pebbly mudstone which interfingers with tuffaceous greenstone and tuff-breccias. Subordinate beds of chert, argillite, and sandstone are also present. The matrix contains abundant ophiolitic clasts, fragments …

Structural, Remote Sensing And Multivariate Correlation Methods As Aids To Mineral Exploration, Central Ireland, D.W. Coller, M.F. Critchley, J.M. Dolan, Ciaran Mcdonnell, C.J. Murphy, W.E.A. Phillips, D.J. Sanderson

Books/Book chapters

This work discusses structural, remote sensing and multivariate correlation methods as aids to mineral exploration in West Central Ireland. The work was performed as part of the EU-funded CREST project.

Transient Electromagnetic Sounding For Groundwater, David V. Fitterman, Mark T. Stewart

Geology Faculty Publications

The feasibility of using the transient electromagnetic sounding (TS or TDEM) method for groundwater exploration can be studied by means of numerical models. As examples of its applicability to groundwater exploration, we study four groundwater exploration problems: (1) mapping of alluvial fill and gravel zones over bedrock; (2) mapping of sand and gravel lenses in till; (3) detection of salt or brackish water interfaces in freshwater aquifers; and (4) determination of hydrostratigraphy. These groundwater problems require determination of the depth to bedrock; location of resistive, high-porosity zones associated with fresh water; determination of formation resistivity to assess water quality; and …

Biomarker Geochemistry Of The Miocene Monterey Formation, West San Joaquin Basin, California: Implications For Petroleum Generation, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Much of the Miocene Monterey Formation of California is rich in biogenic sediment, especially organic matter and silica. Because of the geologic structure, the Monterey in the subsurface near Lost Hills in the San Joaquin Basin forms a natural laboratory for the study of the diagenetic responses of these materials. Rocks of similar age and lithology are buried to depths ranging between 500 and 3500 m, and are thus exposed to a temperature range of 45–130°C. The diagenetic progression of silica from opal-A to opal-CT to microquartz is well-documented in Monterey burial history studies. However, diagenetic indicators need to be …

A Stratigraphic-Geochemical Study Of The Troutdale Formation And Sandy River Mudstone In The Portland Basin And Lower Columbia River Gorge, Rodney Duane Swanson

Dissertations and Theses

Hyaloclastic sediment forms an identifiable stratigraphic interval within the Troutdale Formation that can be traced from the Bridal Veil channel to the Portland basin. Hyaloclastic sediment composed chiefly vitric sands is found interbedded with muds, sandy muds and gravels penetrated by wells in northeast Portland are correlated with the upper member of the Troutdale Formation. These beds are characteristic of the informal upper member of the Troutdale Formation in the Bridal Veil channel of the ancestral Columbia River (Tolan and Beeson, 1984) and the type area of the Troutdale Formation exposed along the Sandy River (Trimble, 1963). Fluvially deposited hyaloclastic …

The Geology, Geochemistry, And Alteration Of Red Butte, Oregon: A Precious Metal-Bearing Paleo Hot Spring System, Carol Susan Evans

Dissertations and Theses

Red Butte is located 60 km south of Vale, Oregon, about 20 km west of the Oregon/Idaho border. The butte is within the Owyhee Upland physiographic province of eastern Oregon which lies at the intersection of the Western Snake River Plain, the High Lava Plains, and the Northern Basin and Range provinces.

The butte is composed of Miocene to Pliocene lacustrine and fluvial volcaniclastic sediments. The topography of the butte is controlled by silicification of the sandstones and mudstones which cap it. Silicification and hydrothermal alteration are both structurally and stratigraphically controlled. North-trending normal faults dominate the area, and show …

Leachate Monitoring In Naturally Saline Groundwater Chesapeake Landfill Chesapeake Virginia, T. Britt Mcmillan

OES Theses and Dissertations

Groundwater chemistry around the Chesapeake municipal landfill was monitored over a one year period. Ten sample sites as well as two surface water sites were used to monitor water quality. Two wells, one at 3 m and the other at 10 m were located at each site. Surface water samples were taken from the Elizabeth River, north of the landfill, and a tidal channel, west of the landfill. Seven groundwater sites were downgradient of the landfill and three sites were upgradient (control sites).

The landfill overlies a tidal marsh, approximately 100 m south of the intracoastal waterway (Elizabeth River). Dredge …

Geochemistry Of Alteration And Mineralization Of The Wind River Gold Prospect, Skamania County, Washington, Krista I. Mcgowan

Dissertations and Theses

The Wind River gold prospect is located in TSN, R7E of Skamania County, Washington, and is an epithermal gold-quartz vein system hosted in volcanic rocks of the Ohanapecosh Formation, a late Eocene to middle Oligocene unit of calcalkaline chemical composition. Andesitic pyroclastic rocks of the Ohanapecosh Formation are the host of mineralization in the study area, and form the lowest of several stratigraphic subunits. These pyroclastic rocks are overlain by two sequences of lava flows which cap the ridges and are folded by an anticlinal warp over the length of Paradise Ridge, plunging gently to the southeast. Toward the west, …

Geology And Geochemistry Of Hydrothermal Alteration, Eastern Portion Of The North Santiam Mining Area, J. Michael Pollock

Dissertations and Theses

The Ruth Mine is a base-metal vein deposit near the eastern margin of a reported porphyry copper deposit in the Western Cascade Range in Oregon. Uplift of the Western Cascade Range has resulted in a deeply dissected terrain in which more than a kilometer of the stratigraphy overlying the porphyry-style mineralization is preserved and exposed. The stratigraphic units, which are middle Tertiary in age, have been given arbitrary letter designations beginning with the lowest unit (Unit A) through the uppermost unit (Unit D).

Unit A is composed of fragmental rocks of andesitic composition. Overlying and interlayered with Unit A are …

The Continental Crust: Its Composition And Evolution, Stuart Ross Taylor, Scott M. Mclennan

Department of Geosciences Faculty Publications

Graduates in geology, geochemistry and geophysics will find this book a valuable reference text. The book begins by describing the known composition of the present upper crust, then deals with possible compositions for the total crust and the inferred composition of the lower crust. The question of the uniformity of crustal composition throughout geological time is discussed, the rate of growth of the crust and the effects of extraction of the crust on mantle compositions are considered. Finally, the question of early pre-geological crusts on Earth is debated and comparisons are given with crusts on the Moon, Mercury, Mars, Venus …

Chemical Composition Of Ground Water In The Yucca Mountain Area, Nevada, 1971-84, Larry Benson, P. W. Mckinley

United States Geological Survey: Publications

Fifteen test wells in the Yucca Mountain area of southern Nevada have been sampled for chemical analysis at least once during 1971-84. Samples were obtained by pumping water from the entire well bore (composite sample), and, in three instances, by pumping from one or more isolated intervals within a well bore. Sodium was the most abundant cation, and bicarbonate was the most abundant anion in all water samples. Samples from the deep carbonate aquifer penetrated by well UE-25p#l contained higher relative concentrations of calcium and magnesium than did samples from overlying volcanic tuffs. Concentrations of the stable isotopes of oxygen …

The Use Of Ilmenite Element Composition For The Determination Of Provenance, Yu W. Tsang

OES Theses and Dissertations

Fifty three samples were taken from three major rivers and their tributaries in Virginia: the James, Roanoke. and Potomac-Shenandoah Rivers. Samples were obtained from the Valley and Ridge. Blue Ridge and Piedmont provinces. The possible source rock types for these samples were determined by comparison of tributary ilmenite composition with drainage basin rock types. Ilmenite element concentration varied with different rock types. Ti was usually high for the ilmenite derived from non-mafic igneous rocks. Mg and Cr were high for the ilmenite from mafic igneous rocks. Zn was low for metamorphic ilmenite. The ilmenite from sedimentary rocks tended to have …