Geochemistry Commons^™

Strontium Isotopic Signatures Of The Streams And Lakes Of Taylor Valley, Southern Victoria Land, Antarctica: Chemical Weathering In A Polar Climate, W. B. Lyons, Carmen A. Nezat, Larry V. Benson, Thomas D. Bullen, Elizabeth Y. Graham, Jesicca Kidd, Kathleen A. Welch, James M. Thomas

United States Geological Survey: Staff Publications

We have collected and analyzed a series of water samples from three closed-basin lakes (Lakes Bonney, Fryxell, and Hoare) in Taylor Valley, Antarctica, and the streams that flow into them. In all three lakes, the hypolimnetic waters have different ⁸⁷Sr/⁸⁶Sr ratios than the surface waters, with the deep water of Lakes Fryxell and Hoare being less radiogenic than the surface waters. The opposite occurs in Lake Bonney. The Lake Fryxell isotopic ratios are lower than modern-day ocean water and most of the whole-rock ratios of the surrounding geologic materials. A conceivable source of Sr to the system …

From Sand To Sandstone: Documenting The Total Change During Diagenesis, Wilfrido Solano-Acosta

All-Inclusive List of Electronic Theses and Dissertations

The objective of this study is to provide a more comprehensive picture of sandstone diagenesis from a different perspective; starting from an analog sand serving as a precursor of a lithified sandstone.

The Petrology And Geochemistry Of Volcán Huaynaputina, Southern Peru, Steven R. Schubring

All-Inclusive List of Electronic Theses and Dissertations

The 1600 eruption of Vol can Huaynaputina in Southern Peru was one of the largest historic eruptions (VEl 6). The eruption proceeded in three stages containing the same mineral assemblage of plagioclase>homblende>biotite> Fe-Ti oxides±apatite. Differences in crystal content, vesicularity, volatile content, temperature estimates, and the presence of disequilibrium textures have brought into question the petrogenesis of the 1600 eruption products. This work strives to quantify the pre- and syn-eruption magmatic conditions in order to ascertain the petrogenesis of the eruption products. Stage I was less evolved(~ 73% Si02), volatile rich (:S 5.3% H20), crystal poor (17- 26 wt. …

Carbon Dynamics In Peat Bogs: Insights From Substrate Macromolecular Chemistry, Kuder Tomasz, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The macromolecular compositions of subfossil plants from boreal Sphagnum bogs and restiad bogs (New Zealand) have been studied by pyrolysis-gas chromatography/mass spectrometry to evaluate the extent of degradation in the anoxic zone (catotelm) of a peat bog. Degradation of vascular plant polysaccharides was apparent only into the upper catotelm. Sphagnum was degraded more slowly than vascular plants, but no cessation of degradation was observed. The inferred rate of degradation varied depending on type of plant, extent of aerobic, precatotelmic degradation, and mode of litter deposition (rooting versus at the surface). Environmental forcing on anaerobic carbon dynamics would potentially be largest …

At-Satellite Reflectance: A First Order Normalization Of Landsat 7 Etm+ Images, Chengquan Huang, Limin Yang, Collin Homer, Bruce K. Wylie, James E. Vogelmann, Thomas Defelice

United States Geological Survey: Publications

Regional Landsat applications often rely on clear and near cloud-free images. With the spectral value being represented by digital number (DN), however, such images contain substantial noises. A significant proportion of such noises can be normalized by converting the DN to at-satellite reflectance value. Being physically based and ready to automate, the conversion method can serve as a first order normalization of Landsat 7 images, making it possible to derive land surface information from such images more consistently.

A Strategy For Estimating Tree Canopy Density Using Landsat 7 Etm+ And High Resolution Images Over Large Areas, C. Huang, Limin Yang, Bruce K. Wylie, Collin Homer

United States Geological Survey: Publications

INTRODUCTION

The Multi-Resolution Land Characteristics (MRLC) consortium was initiated in early 1990s to address the need for consistently developed national and regional land cover data (Loveland and Shaw, 1996). Through this consortium, a 1992-vintage National Land Cover Dataset (NLCD) was developed for the conterminous United States (Vogelmann et al., 2001), and a second generation National Land Cover Dataset (NLCD 2000) will be developed using 2000-vintage Landsat 7 Enhanced Thematic Mapper Plus (ETM+) images and ancillary data. The 2000 NLCD will consist of a suite of data layers relevant to many applications, including a tree canopy density layer describing percentage of …

Comparisons Of Gravity Anomalies At Pseudofaults, Fracture Zones, And Nontransform Discontinuities From Fast To Slow Spreading Areas, Sarah E. Kruse, Sarah F. Tebbens, David F. Naar, Qingyuan Y. Lou, Robert T. Bird

Geology Faculty Publications

Published mechanisms for rift tip propagation at spreading centers include extensional deformation and an initial period of slow spreading. We investigate whether the gravity signal and inferred crustal structure at pseudofaults formed in medium to superfast spreading environments resemble the gravity signal at fracture zones or nontransform discontinuities formed in slow spreading environments. We find that altimetry-based gravity anomalies on the Mathematician, Bauer, Easter, Juan Fernandez, and northern Chile Ridge pseudofaults, located in 75–150 mm/yr (full rate) seafloor spreading environments, are similar in amplitude and form to Atlantic fracture zones with 20–30 mm/yr spreading rates. A 5–15 mGal positive mantle …

Evolution Of The Kangmar Dome, Southern Tibet: Structural, Petrologic, And Thermochronologic Constraints, Jeffrey Lee, Bradley R. Hacker, William S. Dinklage, Yu Wang, Phillip Gans, Andrew Calvert, Jinglin Wan, Wenji Chen, Ann E. Blythe, William Mcclelland

All Faculty Scholarship for the College of the Sciences

Structural, thermobarometric, and thermochronologic investigations of the Kangmar Dome, southern Tibet, suggest that both extensional and contractional deformational histories are preserved within the dome. The dome is cored by an orthogneiss which is mantled by staurolite + kyanite zone metasedimentary rocks; metamorphic grade dies out up section and is defined by a series of concentric kyanite-in, staurolite-in, garnet-in, and chloritoid-in isograds. Three major deformational events, two older penetrative events and a younger doming event, are preserved. The oldest event, D1, resulted in approximately E-W trending tight to isoclinal folds of bedding with an associated moderately to steeply north dipping axial …

Land Cover Trends Dataset, 1973–2000, Christopher E. Soulard, William Acevedo, Roger F. Auch, Terry L. Sohl, Mark A. Drummond, Benjamin M. Sleeter, Daniel G. Sorenson, Steve Kambly, Tamara S. Wilson, Janis L. Taylor, Kristi L. Sayler, Michael P. Stier, Christopher A. Barnes, Steve C. Methven, Thomas R. Loveland, Rachel Headley, Mark S. Brooks

United States Geological Survey: Publications

The U.S. Geological Survey Land Cover Trends Project is releasing a 1973–2000 time-series land-use/land-cover dataset for the conterminous United States. The dataset contains 5 dates of land-use/land-cover data for 2,688 sample blocks randomly selected within 84 ecological regions. The nominal dates of the land-use/land-cover maps are 1973, 1980, 1986, 1992, and 2000. The land-use/land-cover maps were classified manually from Landsat Multispectral Scanner, Thematic Mapper, and Enhanced Thematic Mapper Plus imagery using a modified Anderson Level I classification scheme. The resulting land-use/land-cover data has a 60-meter resolution and the projection is set to Albers Equal-Area Conic, North American Datum of 1983. …

Multibeam Sonar Backscatter Lineaments And Anthropogenic Organic Components In Lacustrine Silty Clay, Evidence Of Shipping In Western Lake Ontario, C F Michael Lewis, L A. Mayer, Prasanta K. Mukhopadhyay, Michael A. Kruge, John P. Coakley, M D. Smith

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

A multibeam sonar survey (95 kHz) covering more than 500 km² of western Lake Ontario revealed anomalous lineaments of relatively high backscatter. The lineaments did not align with or parallel the most prominent structural zones beneath the lake as expected. Instead, the principal lineaments lay on lines between ports on opposite sides of the lake, especially between Toronto and Welland Canal, and Toronto and Niagara River mouth. As the lineaments underlie current and historical shipping routes used during the steamship era, they are interpreted as an acoustic response to shipping debris cumulated in the near-surface bottom sediment. An exploratory …

Mineral Paragenesis And Ore Fluids At The Turquoise Ridge Gold Deposit, Nevada, Michiko Shigehiro

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this study, mineral assemblages and related fluid inclusions at the Turquoise Ridge Carlin-type gold deposit were examined to answer the following questions: (1) What is the ore-stage mineral paragenesis? (2) At what pressures and temperatures did the deposits form? (3) What are the sources of ore fluids?

Pyrite with gold, jasperoid quartz, stibnite, orpiment, realgar, and calcite were successively deposited at Turquoise Ridge. Microthermometric data and isotopic ratios of inclusion fluids in ore-related minerals indicate entrapment of multiple generations of fluids in pre-ore, ore-, and late-ore stage minerals. Primary fluid inclusions in an ore-stage jasperoid quartz crystal have salinities …

The Geochronology And Geochemistry Of The Bearhead Rhyolite, Jemez Volcanic Field, New Mexico, Leigh Justet

UNLV Theses, Dissertations, Professional Papers, and Capstones

Around 82% of mapped Bearhead Rhyolite (Main Cluster) and Peralta Tuff appears to have been derived from a relatively long-lived (~680 ka), large, shallow (Earth's surface) magma chamber that did not produce a caldera-forming eruption. Although volatile contents were great enough (~ wt.% H₂O), no large-scale explosive eruptions occurred because magma may have been tectonically vented. The lack of systematic chemical variation within the Main Cluster with time during this ~680 ka interval may imply that erupted magmas were physically separated from each other by fault-formed cupolas in the roof of the magma chamber. These results are significant …

Geochemistry And Petrogenesis Of The Bonanza King Mafic Intrusive Complex, Trinity Terrane Ophiolite, California, Keith R. Willse

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Bonanza King mafic intrusive complex (MIC) (>25 km^2₎ of the Trinity terrane ophiolite, northern California, consists of cogenetic plutonic and dike lithologies. Steep intrusive contacts exist between cumulate pyroxenite, isotropic gabbro, and peridotite country rock. Near vertical east-west trending, bimodal dikes intruded gabbro and are centered within the complex. Geochemical modeling indicates taht accumulation/fractionation of a gabbroic parental magma produced lithologic trends of cumulate pyroxenite and fractionated gabbro and dike lithologies. Similarities between all lithologies suggest cogenetic formation of all the elements of the Bonanza King MIC during the Late Silurian (431 +/- 3).

Parental magma …

The Origin Of Brucite In Hydrothermally Altered Limestone Near Devil Peak, Nevada, Rhonda L. Knupp

UNLV Theses, Dissertations, Professional Papers, and Capstones

Open-space brucite was identified in veins crosscutting hydrothermally altered limestone near the Devil Peak rhyolite plug in southern Nevada. The brucite occurs with serpentine, calcite, chalcedony, hydromagnesite, dolomite, and clinochlore.

Brucite usually forms as a replacement mineral, but textural evidence indicates that the brucite at Devil Peak precipitated in open space. The presence of chalcedony in veins indicates the temperature of the hydrothermal fluid was <180^oC during and after mineral deposition. Thermodynamic modeling shows this temperature is too low for replacement brucite to form, thus the low temperature of alteration may be a factor in this unusual occurrence of …

Effects Of Organic Matter And Iron-Rich Clay On Mobility Of Trace Metals From Flue Dust Contaminated Soil, Scott Ephraim Lewis

OES Theses and Dissertations

The enhanced leaching of trace metals through soil becomes a concern for human health if dissolved trace metals reach groundwater and migrate into a public water system. A serial batch extraction procedure was implemented to determine the effects of Vitagrow © organic matter and Fe-Rich TM clay on the mobility of trace metals (Zn, Pb, and Cd) from a flue dust treated (0, 600, 1200, and 2400 μgig Zn) Appling soil.

The addition of an organic matter (OM) amendment to the Appling soil enhanced Pb mobility and reduced soluble Zn and Cd. In general, average solution concentrations of trace metals …

Compositional Variations In The Fire Clay Coal Bed Of Eastern Kentucky: Geochemistry, Petrography, Palynology, And Paleoecology, Cortland F. Eble, James C. Hower, William Morton Andrews Jr.

Report of Investigations--KGS

Bench samples of the Fire Clay coal bed, collected from 28 localities in a study area of eight 7.5-minute quadrangles in the Eastern Kentucky Coal Field, were analyzed geochemically, petrographically, and palynologically to determine any spatial or temporal trends among the studied parameters.

At most sample sites the Fire Clay is split by a flint-clay parting of probable volcanic origin. The upper bench of the Fire Clay coal generally is thick, laterally continuous, low in ash yield and sulfur content, has a moderate to high calorific value, and is high in total vitrinite content. In contrast, the lower bench generally …

Classification Of Torbanite And Cannel Coal. I. Insights From Petrographic Analysis Of Density Fractions., Zhiwen Han, Michael A. Kruge, John C. Crelling, David F. Bensley

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Torbanite and cannel coal are considered to be coals because of their low mineral content and overall physical morphology. However, the texture and composition of the organic matter in torbanite and cannel coal are similar to the kerogen occurring in oil shales and lacustrine source rocks. Therefore, understanding the nature and origin of organic components in torbanite and cannel coal is of significance in the study of kerogen and petroleum formation. In this research, a set of torbanites and cannel coals from different locations throughout the world were petrographically characterized and processed using a density gradient centrifugation (DGC) technique. Microscopically, …

A Biogeochemical Comparison Of Fossil (Carboniferous) And Modern Crustose Red Algae, Michael A. Kruge, John E. Utgaard, William Ferry

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The nature of the contribution of the various types of algae to sedimentary organic matter continues to be a topic of research interest. Crustose red algae have however received less attention than other types. The fossil calcareous red algae (Rhodophyta) analyzed in this study are two relatively unrecrystallized specimens of Parachaetetes (Family Solenoporacea) from the lower part of the Ste. Genevieve Formation (Carboniferous, Visean) in Union County, Illinois, USA. They occurred in the patch reef phase of a small carbonate mudmound-patchreef. The three modern specimens (collected and identified by F. Collier) are the crustose algae Lithothamnion, Clathromorphum and Phymatolithon …

Chemistry Of Maceral And Groundmass Density Fractions Of Torbanite And Cannel Coal, Zhiwen Han, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Microscopically, torbanite and cannel coal are composed of coarser macerals set in a fine-grained to amorphous groundmass. It is often assumed that the amorphous groundmass is genetically related to the distinct macerals. The separation of macerals and groundmass from 14 late Paleozoic torbanite, cannel, and humic coals permits the analysis of individual constituents using elemental analysis and flash pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). Cluster and principal component analyses of the Py-GC/MS data further reveal the chemical similarities and differences between the various constituents. Pyrolyzates of Botryococcus-related alginites are characterized by an abundance of normal alkadienes, alkenes, and alkanes. Even their …

Classification Of Torbanite And Cannel Coal. Ii. Insights From Organic Geochemical And Multivariate Statistical Analysis, Zhiwen Han, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Petrographic and megascopic criteria have traditionally been used as the basis for the classification of torbanite and cannel coal. For this study, it was hypothesized that modern analytical organic geochemical and multivariate statistical techniques could provide an alternative approach. Towards this end, the demineralized residues of 14 torbanite (rich in Botryococcus-related alginite) and cannel (essentially, rich in organic groundmass and/or sporinite) coal samples were analyzed by pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). Cluster analysis performed on the Py-GC/MS data clearly distinguished the torbanite from the cannel coal, demonstrating a consistency between the chemical properties and the petrographic composition. All the torbanite …

Chemical Weathering Of Volcanic Ash As A Probable Origin Of Chert In The Reid's Mistake Formation Of The Newcastle Coal Measures, Sydney Basin, Australia, Adil M. Wadia

All-Inclusive List of Electronic Theses and Dissertations

Chert is normally considered to be marine biogenic in origin. However, chert lenses and nodules in the volcanic ash horizon of the Reid's Mistake Formation at Swansea Head, Newcastle Coal Measures of the Sydney Basin appear to have formed differently. Their mode of occurrence and their close association with paper-thin clay layers within the same volcanic unit suggest that they formed as a result of chemical weathering of volcanic ash. This hypothesis is supported by the data gathered from thin section petrography and x-ray diffraction analyses. Petrographic studies indicate the precipitation of microcrystalline to cryptocrystalline quartz and the dissolution/replacement/alteration of …

The Geomorphological History Of An Alluvial Fan Complex In Nelson County, Virginia, Melinda Ann Youngblood

OES Theses and Dissertations

An alluvial fan complex blankets a portion of the Rockfish Valley in Nelson County Virginia, located along the eastern slope of the Blue Ridge Mountains. The seven-km² field area contains three mappable relict alluvial surfaces (Qf1, Qf2, and Qf3) and one modern surface (Qa1), each of which is underlain by fluvial deposits dominated by greenstone and charnokite cobbles. The four surfaces were mapped according to topographic position and degree of stream dissection. Alluvial deposits underlying each surface were characterized using a 3-part clast weathering scale based on greenstone clast weathering rinds and using soil development criteria (clay content, Munsell …

Water Quality In The Central Nebraska Basins, Nebraska, 1992-95, S. A. Frenzel, R. B. Swanson, T. L. Huntzinger, J. K. Stamer, P. J. Emmons, Ronald B. Zelt

United States Geological Survey: Publications

This report is intended to summarize major findings that emerged between 1992 and 1995 from the water-quality assessment of the Central Nebraska Basins Study Unit and to relate these findings to water-quality issues of regional and national concern. The information is primarily intended for those who are involved in waterresource management. Indeed, this report addresses many of the concerns raised by regulators, water-utility managers, industry representatives, and other scientists, engineers, public officials, and members of stakeholder groups who provided advice and input to the USGS during this NAWQA Study-Unit investigation. Yet, the information contained here may also interest those who …

Hydrogeology In The Vicinity Of The Nebraska Management Systems Evaluation Area Site, Centra! Nebraska, Virginia L. Mcguire, John M. Kilpatrick

United States Geological Survey: Publications

From 1991 to 1992, the U.S. Geological Survey participated with the U.S. Department of Agriculture and the University of Nebraska-Lincoln in research activities at the Nebraska Management Systems Evaluation Area (MSEA) site near Shelton, Nebraska. The purpose of the U.S. Geological Survey study was to define the hydrogeologic system in the vicinity of the Nebraska MSEA site to aid the interpretation of ground-water sampling results by other researchers. The primary aquifer in the study area is the High Plains aquifer, which consists of an unconfined part, the shallow aquifer; a silt and clay unit that acts as a confining layer; …

Identification Of Past Climate Variability Of The Eastern Pacific Ocean Using Both D13c And D18o Records In Corals From Clipperton Atoll (1994-1906), Lei Ren

Geology Theses and Dissertations

The ENSO (El Nino and the Southern Oscillation) is a fundamental ocean-atmosphere phenomenon that dominates interannual global climate variability. Reconstructing past ENSO events is therefore important for documenting and understanding the past behavior of the global climate system and enabling us to predict future climate change. However, the present understanding of ENSO events has been mainly based on the instrumental record of Pacific climate which provides detailed data only for the past few decades. Recent studies have shown that the stable isotope record in coral skeletons can be used as a valuable indicator of paleoclimatic changes in tropical regions, and …

Effective Elastic Thickness Of The Lithosphere Along The Easter Seamount Chain, Sarah E. Kruse, Zhengro J. Liu, David F. Naar, Robert A. Duncan

Geology Faculty Publications

Bathymetry and gravity data collected during Legs 5, 6, and 7 of the 1993 GLORIA Expedition and the recently released 2-min altimetry-derived global gravity grid are used to determine the effective elastic thickness of the lithosphere along the Easter Seamount Chain (ESC). Forward modeling, admittance, and coherence methods yield consistent results. With the exception of the eastern and western ends of the ESC the effective elastic thickness along the chain is ∼1–4 km. The thin elastic thickness for the majority of the ESC seamounts is compatible with a young seafloor age at the time of loading derived from new radiometric …

Volcanology And Geochemistry Of Pliocene And Quaternary Basalts On Citadel Mountain, Lunar Crater Volcanic Field, Pancake Range, Nevada, Loretta D. Dickson

UNLV Theses, Dissertations, Professional Papers, and Capstones

Alkali basalts on Citadel Mountain form the southern margin of the Lunar Crater Volcanic Field (LCVF) in the central Great Basin, Nevada. Citadel Mountain comprised of a faulted, north tilted section of Tertiary andesite and ash-flow tuff is capped by Pliocene and Quaternary alkali basalt flows that erupted from six major cinder cones. The basalt flows on Citadel Mountain can be divided into two groups (older and younger) based on age and isotopic signatures. The older basalt group is characterized by higher ⁸⁷ Sr/⁸⁶Sr and lower E_Nd and the younger group has lower ⁸⁷Sr/⁸⁶Sr …

Microanalytical Investigations Of Gold-Bearing Rocks From The An Najadi Region In Saudi Arabia, Nazrul I. Khandaker, M. Ahmed, M. M. Hariri, M. A. Garwan, K. R. Khan, M. M. Al-Ohali

Publications and Research

The Proton Induced X-ray Emission technique with a scanning microbeam (micro-PIXE) and Scanning Electron Microscopy (SEM) were employed to study gold-bearing rocks from the An Najadi and adjacent regions situated within the exposed northeastern part of the Arabian Shield. These microanalytical investigations, together with routine petrological and ore microscopic studies, demonstrated the presence of important partitioning of major minerals and trace elements in several samples. These measurements also revealed microstructural features including brecciation within quartz grains and metal concentrations within these fracture-controlled micro-conduits. Results showed promise in terms of using distinctive geochemical signatures for ore body recognition. Of particular interest …

Geochemistry, Stratigraphy And Provenance Of The Portland Hills Silt In The Tualatin Mountains, Portland, Oregon, John L. Lawes Iii

Dissertations and Theses

Soil morphology and geochemistry of loess were investigated at nine sites in the Tualatin Mountains west of Portland and at additional sites in The Dalles, eastern Washington and Puget Sound. A total of forty samples were examined using Instrumental Neutron Activation Analysis (INAA).

Stratigraphic relationships and soil development suggest that the PHS ages of Lentz (1977) be revised. The age of the Portland Hills Silt (PHS) ranges from 12,000 to at least 960,000 years before present.

The geochemistry of the PHS supports the Lentz (1977) hypothesis of the PHS as a loess of continental origin. Thorium/scandium ratios in the PHS …

Geochemical Characteristics And Correlations Within The Triassic-Jurassic Age Gabbs And Sunrise Formations Of West Central Nevada, Karen Elizabeth Boelling

Dissertations and Theses

Trace and minor element geochemistry was determined using Instrumental Neutron Activation Analysis for ninety-six (96) limestone and calcareous siltstone samples from four stratigraphic sections in the Triassic-Jurassic age Gabbs and Sunrise formations of west central Nevada. Geochemical data support lithologic and faunal interpretations of relative basin positions of the Sunrise Formation stratigraphic sections, as well as basin development (including transgressive­-regressive sequences) during deposition of the Gabbs and Sunrise formations at New York Canyon (Gabbs Valley Range). All sections show characteristics of both oceanic and continental island arc sources. Rare positive Eu anomalies relative to chondrites suggest that the Gabbs Formation …