Earth Sciences Commons^™

Coupling Liquid Chromatography To Orbitrap Isotope Ratio Mass Spectrometry: Overcoming Isotope Effects Of Chromatography And Amount-Dependency By Peak Homogenization, Aoife Canavan, Leonhard Prechtl, Habib Al-Ghoul, Nils Kuhlbusch, Andrea M. Erhardt, Martin Elsner

Earth and Environmental Sciences Faculty Publications

Electrospray ionization Orbitrap mass spectrometry (ESI-Orbitrap-MS) has recently proven to be a powerful tool for compound- and position-specific stable isotope analysis, targeting isotopologues of multiple elements (H, C, N, O, S) in polar analytes. However, studies have so far mainly focused on pure analyte solutions via direct infusion. Here, we present the online coupling of liquid chromatography (LC) to ESI-Orbitrap-MS for stable isotope analysis of sulfamethoxazole (SMX), a synthetic antimicrobial, used as a model compound. Our study explored the fidelity of isotope values with two strategies for capturing and broadening chromatographic peaks after LC. When capturing the target analyte in …

Geoscience Mathematics Self-Efficacy Scale (Geomses) For Majors-Level Undergraduates: Psychometric Data, Michael Coe, Rory Mcfadden, Beth Pratt-Sitaula, Eric Baer

Science Education Resource Center (SERC)

Self-efficacy is often investigated as a key attitudinal component of academic persistence and performance, and self-efficacy surveys can serve in research models as efficient and non-threatening assessment tools to augment or substitute for achievement or performance measures. The Geoscience Mathematics Self-Efficacy Scale (GeoMSES) builds on prior work in measurement of self-efficacy for mathematics by focusing specifically on students’ capacity to apply mathematical skills to typical problems encountered in majors-level undergraduate geoscience courses or in professional geoscience settings. The scale was developed as part of program evaluation research for a set of learning modules designed to augment existing geoscience curricula. In …

Micronutrients (Trace Elements) For High Rainfall Pastures In Western Australia, Department Of Primary Industries And Regional Development, Western Australia

Natural resources factsheets

Micronutrient deficiencies can result from removal of agricultural products over many years, changes in soil acidity, or from large increases in plant biomass production and export. This page is specific to high rainfall pastures (more than 600mm average annual rainfall) in the south-west of Western Australia.

The Department of Primary Industries and Regional Development recommends tissue testing to check plant micronutrient nutrient needs.

Potassium For High Rainfall Pastures In Western Australia, Department Of Primary Industries And Regional Development, Western Australia

Natural resources factsheets

Potassium (K) deficiency can lead to a decline in clover content and severely limit pasture productivity in high rainfall pastures. Large amounts of potassium can be lost each year through leaching and removal of potassium in hay or silage.

This information is specific to high rainfall pastures receiving more than 600mm average annual rainfall in the south-west of Western Australia.

Soil Sampling High Rainfall Pastures In Western Australia, Department Of Primary Industries And Regional Development, Western Australia

Natural resources factsheets

Soil sampling and testing is an essential part of making good fertiliser decisions. Fertilisers are a large cost to farming pastures in high rainfall areas. This page is specific to sampling high rainfall pastures (more than 600mm average annual rainfall) in the south-west of Western Australia.

The Department of Primary Industries and Regional Development recommends soil sampling and testing as part of a plant nutrient management program.

Sulfur For High Rainfall Pastures In Western Australia, Department Of Primary Industries And Regional Development, Western Australia

Natural resources factsheets

Sulfur deficiency can substantially reduce pasture yield on sandy soils, particularly in wet years where the sulfate form of sulfur leaches below the root zone of pasture plants, making it unavailable.

This information applies specifically to high rainfall pastures (over 600mm average annual rainfall) in the south-west of Western Australia.

The Department of Primary Industries and Regional Development recommends basing fertiliser decisions on good evidence (soil and tissue test results)

Tissue Sampling And Analysis For High Rainfall Pastures In Western Australia, Department Of Primary Industries And Regional Development, Western Australia

Natural resources factsheets

Tissue testing helps identify nutrient deficiencies that impact plant health. In high rainfall areas ( > 600 mm), pastures are highly productive and have greater demand for both macro- and micronutrients. Micronutrient status is best assessed through plant tissue, as soil levels are difficult to measure accurately.

The Department of Primary Industries and Regional Development recommends tissue testing to assess the effectiveness of fertiliser and soil testing programs, and diagnose emerging macronutrient and micronutrient deficiencies that could cause production losses.

Environmental Impact Of Nitrogen And Phosphorus Fertilisers In High Rainfall Pasture Areas Of Western Australia, Department Of Primary Industries And Regional Development, Western Australia

Natural resources factsheets

The most commonly used nitrogen and phosphorus fertilisers in the high rainfall (>600mm annual average) south-west of Western Australia can be leached into the groundwater and washed into waterways, resulting in serious environmental and economic damage.

The Department of Primary Industries and Regional Development recommends regular soil testing and consultation with FertCare-accredited advisers to reduce leaching losses and increase profit from added nutrients.

A Stable Isotope Comparison Of The Biogenic Carbonate Of Mammalian Tooth Enamel From The Modern Ohio River Valley And Fort Ancient Buffalo Sites, Sara Elizabeth Slack

Theses, Dissertations and Capstones

δ¹⁸O and δ¹³C values change in response to anthropogenic factors (Ghosh & Brand, 2003). Little is known about the effects of anthropogenic climate and land use change on the ecology of the Ohio River Valley. The goal of this research was to quantify the effects of European colonization on the native ecology of the region. The specific questions of this research were: (1) How have mammalian tooth enamel δ¹⁸O and δ¹³C compositions shifted over time within the Ohio River Valley in response to anthropogenic climate change and vegetation? (2) Are there differences …

Nebraska Statewide Groundwater-Level Monitoring Report 2025, Aaron R. Young, Mark E. Burbach, Sue Olafsen Lackey, Robert Matthew Joeckel, Jeffrey Westrop

Conservation and Survey Division: Faculty and Staff Publications

No abstract provided.

Comparative Assessments Of Methane Flux Measurement Techniques In Serpentinite-Influenced Groundwater Wells, Madison J. Stetson

Open Access Master's Theses

Methane (CH₄₎ emissions from continental serpentinizing systems represent a significant component of Earth’s carbon cycling. Despite increasing recognition of serpentinite-hosted water-rock interactions as a source of trace gases, standardized field methodologies for quantifying trace gas flux from groundwater wells and similar subsurface conduits remain limited. This study addresses that gap by evaluating the reliability and replicability of three chamber-based sampling methods for measuring gas flux in serpentinite-hosted groundwater systems accessed by groundwater monitoring wells. Field measurements were conducted at the Coast Range Ophiolite Microbial Observatory (CROMO) within the McLaughlin Natural Reserve in Lower Lake, California, a site …

Geochemical And Petrological Observations Of The June Lake Basalt, Eastern California, Daniel Jacob Abel

Cal Poly Humboldt theses and projects

The June Lake basalt is a monogenetic cinder cone and 11-km-long lava flow in eastern California located ~10 km NW of the Long Valley caldera. The stratigraphic position of the June Lake basalt between Tahoe and Tioga glacial deposits suggests an eruption age of only ~20-45ka. This age places the June Lake Basalt among the youngest volcanic eruptions in the Long Valley-Mono Basin region, where volcanic activity spans from the late Pliocene to the Holocene. The goal of this study is to use field observations coupled with whole-rock and crystal geochemical analyses to investigate the magma source and pre-eruption magma …

Depth And Soil Physical Context Govern Soil Organic Carbon, While Woody Cover Moderates Native Vegetation Relationships In California Rangelands, Dabid Zuniga Garcia

Cal Poly Humboldt theses and projects

Soil organic carbon (SOC) is central to soil function and an important component of climate mitigation in rangeland ecosystems, but the controls on SOC across California’s working rangelands remain understudied. Using data from Point Blue Conservation Science’s Rangeland Monitoring Network, this study evaluated how soil properties, vegetation structure, and recent climate relate to SOC concentration at depths of 0–10 cm and 10–40 cm across 145 ranches spanning four California regions. Linear mixed-effects models showed that SOC was consistently higher in topsoil than subsoil and highest in coastal sites relative to interior valleys. Bulk density was the strongest negative predictor of …

Metamorphosed Components In Cv Chondrites Camel Donga 003 And Camel Donga 040 As Evidence For Varying Degrees Of Metamorphism Within The Parent Body, Kathryn E. Stone

Honors Theses

The CV carbonaceous chondrites are a group of primitive stony meteorites that record early solar-system evolution processes. They are typically of low metamorphic grade, though some metamorphosed CVs have recently been found. Two CV chondrite breccias, Camel Donga 003 (CD 003) and Camel Donga 040 (CD 040) consist of multiple lithologies. CD 003 consists of three lithologies, one of which – Lithology C – has been metamorphosed to petrologic type ~3.7 (Alevy et al. 2025). CD 040 consists of two lithologies, one of which is metamorphosed to petrologic type 3.7 (Dunn and Alevy, 2024; Dunn et al. unpublished). Both samples …

Scanning Electron Microscopy As A Potential Tool For Distinguishing Charcoal From Dark, Oxidized, Biomass, João Vitor Dos Santos, Aleksandar I. Goranov, Lais Gomes Fregolente, Joao Marcos De Lima-Faria, Diego Stefani Teodoro Martinez, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

Condensed aromatic carbon (ConAC) is widely used as a proxy for organic materials derived from biomass burning. However, recent evidence shows that ConAC can be also formed through nonpyrogenic oxidative processes. This study presents a proof-of-concept investigation using scanning electron microscopy (SEM) to distinguish charcoal from dark, ConAC-rich materials produced by ambient oxidation of biomass. Pine wood exposed to long-term iron-mediated oxidation was compared with unaltered wood and a controlled laboratory-generated charcoal reference. Conventional geochemical analytical methods, including benzenepoly(carboxylic acid) (BPCA) analysis, Fourier transform–ion cyclotron resonance–mass spectrometry (FT-ICR-MS), solid-state 13C nuclear magnetic resonance (NMR) spectroscopy, and elemental analysis, confirmed substantial …

Assessment Of Local Amplification Causes At Coastal Strong Motion Stations With Elevated Ground Motion Residuals From The 2024 Tewksbury, New Jersey Earthquake, Patrick Daniele

Open Access Master's Theses

Elevated ground motion amplitudes at individual stations are commonly observed in earthquake datasets, yet the physical causes of these residuals are often not explicitly identified. This study investigates two seismic monitoring stations in southeastern New York that recorded amplified motions during the 2024 Mw 4.8 Tewksbury, New Jersey earthquake. A consistent set of established geophysical methods -- including multichannel analysis of surface waves (MASW), passive ambient noise arrays (MAM), stochastic inversion, horizontal-to-vertical spectral ratio (HVSR) analysis, and directional spectral ratio techniques -- was applied to directly characterize site conditions and identify the mechanisms contributing to amplification.

Results show that elevated …

Co2 Enhanced Oil Recovery In The Dickinson Lodgepole Mounds, University Of North Dakota. Energy And Environmental Research Center

EERC Brochures and Fact Sheets

Fact sheet about CO₂ enhanced oil recovery (EOR) in the Dickinson Lodgepole Mounds of Stark County, North Dakota. Includes geological information and how stored CO₂ increases local oil production.

Identification And Characterization Of Tornado Seismic Signals In The Central U.S., Seth Thompson

Theses and Dissertations--Earth and Environmental Sciences

Tornadoes cause extensive property damage and endanger lives. While Doppler radar can indicate the potential for tornado development, it cannot confirm that a tornado is in contact with the ground unless a debris signature is present. While on the ground, a significant amount of a tornado’s energy may be transferred into the earth as seismic vibrations. Thus, seismometers have the potential to detect on-the-ground tornadoes. Since 1960, only five papers have published seismic recordings from tornadoes. These studies have mostly reported on seismic waves generated by tornadoes at a relatively large range, from 0.01-2.5 Hz, representing uncertainty in the dominant …

Soil Organic Carbon And Soil Health Property Responses To Land Management Across Topographic Positions, Mia D. Makovsky

All Graduate Theses, Dissertations, and Other Capstone Projects

uring the last ice age, ice sheets advanced and retreated across the upper Midwest, leaving behind a landscape characterized by poorly drained hummocky topography. Well-aerated soils have formed on uplands and lowlands are dominated by hydric soils. These wetlands and hydric soils have potential to store large quantities of carbon, particularly compared to the well-aerated uplands, but many have been drained and cultivated for decades. Conservation agriculture methods have emerged to protect and conserve soil health from negative effects due to cultivation.The purpose of this study is to determine how agricultural management practices and landscape properties (e.g, topographic position) affect …

Fulbright Project In Iceland In The Summer Of 2026, Irina Filina

Nebraska Academy of Sciences: Programs and Proceedings

This upcoming Fulbright project is inspired by an ongoing debate in the scientific community about the tectonic origin of Iceland. A long-standing theory of Iceland’s formation by excessive magmatism at the Mid-Atlantic spreading center over the well-known hot spot (i.e., oceanic crustal affinity) was recently challenged by the alternative hypothesis that the Icelandic crust is continental in nature and is being stretched and gradually modified by magmatic processes. Based on this hypothesis, a new sunken continent, Icelandia, has been proposed. One of the foundations for the proposed Icelandia is the presence of felsic lavas (indicative of continental flavor in the …

An Integrated Approach To Groundwater Management In Northern New Jersey Watersheds, Toritseju Oyen

Theses, Dissertations and Culminating Projects

Groundwater deterioration has emerged as a pressing global concern, with widespread observations of declining water quality in various regions. The predominant cause of this deterioration is attributed to anthropogenic activities, which are deeply intertwined with daily human practices that contaminate water resources. Over the decades, many forested and wetland areas have been converted mainly for increased urbanization and industrialization use in northern New Jersey. The region’s watershed, already characterized as a low-yield aquifer, is facing deterioration because of continuous change in land cover. Anthropogenic activities aimed at providing solutions to problems, such as food scarcity, icy roads during the winter …

Preliminary Investigation Of The Carbon Storage Potential In The Fort Worth Basin: Reservoir Characterization And Modeling Of The Lower Atoka Grant South Sand In Tarrant County, Texas, Mary Ann M. Moody

Earth & Environmental Sciences Theses

Carbon capture and storage (CCS) is crucial for mitigating atmospheric carbon dioxide (CO₂) emissions that rise from industrial activities. Paleozoic sedimentary basins in Texas are significant reservoirs for hydrocarbon production, and when depleted, show promise for CCS. Long-term reservoir storage suitability requires a multifaceted approach, including site screening and ranking, as well as reservoir characterization, modeling, and simulation. This project first evaluates the CCS potential for the Fort Worth Basin in North Central Texas, then focuses on reservoir characterization of the Lower Atoka Grant South (STH) Sand in Tarrant County and finally assesses the sand’s CO₂ storage …

Modeling Landslide-Generated Tsunami For Hazard Analysis: A Case-Study Of Grewingk, Ak, Cassidy J. Deer

All Master's Theses

Landslide-generated tsunamis pose an increasing hazard in glacial and paraglacial environments, where glacial retreat results in slope instability and the potential for mass movement events into a body of water. This thesis analyzes a landslide–generated tsunami at Grewingk Lake in October 1967 by integrating numerical simulations from the D-Claw and GeoClaw models, which are both derived from the Clawpack framework for solving hyperbolic conservation laws. By modeling landslide dynamics and wave propagation in a coupled manner, this study seeks to improve understanding of the hazard, risks and spatial impact at Grewingk. The D-Claw and GeoClaw modeling approaches complement each other …

A Conserved Ethylene-Triggered Cell Death Mechanism May Underlie Hollow Stem Formation Across Plant Species, Mengxiao Yan, Weijuan Fan, Yinghui Meng, Jiamin Zhao, Wei Yang, Ziyin Xu, Yusen Gao, Haiyan Zhuang, Wuyu Zhou, Yuqin Wang, Qingjun Huang, Ling Yuan, Hongxia Wang, Jun Yang

Plant and Soil Sciences Faculty Publications

Hollow stems have independently evolved multiple times across the plant kingdom and play crucial roles in plant development and various environmental adaptations. However, the mechanisms underlying stem hollowness remain poorly understood. Water spinach (Ipomoea aquatica) is one of the few hollow-stemmed plants in the Convolvulaceae family (eudicot: asterid), and its hollow stems are essential for thriving in aquatic environments. Using histochemical staining and transcriptome analysis, we found that programmed cell death (PCD) is involved in cavity formation at water spinach shoot tips. Single-cell and spatial transcriptome analyses further revealed that ethylene and reactive oxygen species (ROS) likely drive …

Supplemental Bibliographic Details. From 2001 Mars Odyssey To Earth’S Climate Crisis: Integrating Gamma Spectroscopy, Martian Soil Simulants, And Plant Genomes For Agroecology, Anchored In Sri Lanka’S Mars-Context Serpentinites, Suniti Karunatillake, Maheshi Dassanayake, Carlos Gary Bicas

Planetary Science Lab

Bibliographic details follow to supplement hyperlinked citations in the multinational GANGOTRI-supporting project conceived by Karunatillake, Dassanayake, and Gary-Bicas

Below The Rows, Beyond The Roots: An Art Exhibition Depicting Agriculture Across The Globe, Maggie Enoch

Honors Theses and Capstones

In Below the Rows, Beyond the Roots, artist Maggie Enoch creates multimedia works inspired by her exposure to diverse agricultural systems and perspectives while studying geography and sustainable agriculture/food systems around the world. By integrating complex histories with the contemporary realities of farming, Maggie paints vivid pictures of the power of food in this five-piece exhibition.

Tracking Co2 Illinois Ccs Monitoring Wells, University Of North Dakota. Energy And Environmental Research Center

EERC Brochures and Fact Sheets

Fact sheet about the Illinois carbon capture and storage (CCS) project. Includes information on the project's CO₂ monitoring system.

Bridging Functions And Values: Advancing Wetland Ecosystem Service Assessment Through Use Of A Service Capacity Index, William J. Kleindl, Sarah P. Church, Kai C. Rains, Mark C. Rains, Eric D. Stein, Morgan K. Suddreth

School of Geosciences Faculty and Staff Publications

Wetland service or values are often assumed to occur at a comparable level to wetland function (i.e., higher functioning wetlands provide more services). However, services are seldom directly evaluated because of the lack of structured assessment approaches. For wetland ecosystem service to be effectively incorporated in regulatory and monitoring programs, there needs to be parsimonious assessment tools that can be applied systematically, repeatably, and rapidly. This approach begins by disentangling existing terminology and clearly defining all the terms necessary to support the assessment of ecosystem services (ES). We provide context to illustrate how these terms have been variously employed in …

Last Glacial Maximum And Late Glacial Aeolian Sand Activity, South-Central Indiana, Usa, H. M. Loope, J. L. Antinao, P.R. Hanson, P. M. Jacobs, D. A. Grimley

Conservation and Survey Division: Faculty and Staff Publications

No abstract provided.

On The Contribution Of The Gulf Stream To High Frequency Coastal Sea Level Variability, Tal Ezer

CCPO Publications

Long-term Atlantic Ocean and Gulf Stream (GS) variability were linked in past studies to coastal sea level (CSL) change along the U.S. East Coast - a weakening GS can lead to rise in CSL and increased coastal flooding. However, high frequency variability (HFV) in CSL is, in most cases, attributed to atmospheric weather events. This study is focused on HFV (intraseasonal variations with periods between similar to 1 week and similar to 2 months) in the GS and in CSL. First, wavelet and spectral analysis of observations of the Florida Current transport and CSL characterized the HFV in the data, …