Earth Sciences Commons^™

Analyzing Surface Water And Groundwater Interactions From Pfas Contamination In The West Plains Region Of Spokane County, Jerusha R. Hampson

2026 Symposium

The West Plains region of Spokane County has been significantly impacted by PFAS contamination due to the decades-long use of aqueous film-forming foam (AFFF) for firefighting training at both Fairchild Air Force Base (FAFB) and the Spokane International Airport (SIA). Groundwater contamination is significant, but surface waters are impacted by the contamination as well. Groundwater flows to the north and east, meaning surface water bodies that make up the northern and eastern boundaries (Deep Creek, Hangman Creek, and the Spokane River) can be impacted by PFAS contamination. The West Plains aquifer system is complex but combining data about aquifer flow …

Preliminary Geologic Assessment And Pfas Occurrence In Western Cheney, Washington, Sydney Frandsen

2026 Symposium

In 2021 Cheney Water Well #5 was closed due to toxic per- and polyfluoroalkyl substances (PFAS) levels above the current State Action Limits and the National Drinking Water Protection Act (https://www.cityofcheney.org/207/Water), which is a concern since PFAS has been associated to types of cancer, birth defects, and other negative human and environmental health concerns (https://doh.wa.gov/communityand-environment/contaminants/pfas). The City of Cheney also tested two downgradient deep-groundwater-wells (Cheney wells #6 and 7) and halted investigation due to the wells being below state and federal drinking water standards. However, a local resident’s shallow groundwater well tested to be above federal and state levels of …

Groundwater Responses To Tidal Restoration At Pelican Marsh And Sea-Level Rise In Elkhorn Slough, California, Julie E. Nelson

Graduate Theses and Dissertations

Coastal wetlands represent a dynamic but vulnerable terrestrial-aquatic interface with future resilience controlled by historic hydrologic alterations, sea-level rise, and groundwater extraction. In diked coastal settings, poor tidal connectivity can degrade habitat from the impoundment of freshwater or hypersaline surface waters. Restoring tidal connectivity could foster marsh revitalization, but altering the surface hydrologic system could lead to unwanted salinity intrusion in shallow aquifers. Saline groundwater intrusion degrades freshwater quality and, while inevitable with sea-level rise, could be accelerated with tidal marsh restoration. To investigate this, I developed a steady-state groundwater flow model of Pelican Marsh, a diked, muted tidal marsh …

Spatiotemporal Dynamics Of Mountain Front Recharge Flow Paths And Their Contribution To Alluvial Aquifer Water Supply, Mikaela Bollag-Miller

Graduate Student Theses, Dissertations, & Professional Papers

Mountain Front Recharge (MFR) is a critical recharge source for alluvial basin aquifers throughout the Intermountain West, yet the spatial and temporal dynamics of distinct recharge pathways remain poorly constrained. This study investigates the seasonal and spatial dynamics of MFR pathways and evaluates their impact on the Missoula Aquifer, a sole-source alluvial aquifer in western Montana, USA. MFR includes both surface-water inflows from mountain areas and Mountain Block Recharge (MBR), the groundwater contribution to the basin aquifer. A valley-scale water balance was employed to estimate first-order contributions and temporal fluctuations of MBR flow paths. A three-layer steady-state MODFLOW groundwater model …

Bridging The Gap: Evaluating Gnss-Derived Total Water Storage As A Groundwater Monitoring Tool In The Colorado River Basin, Michelle Lee Barton

Graduate Student Theses, Dissertations, & Professional Papers

Groundwater resources in the Colorado River Basin are critically stressed yet remain under-monitored and under-regulated, creating urgent need for reliable, continuous observations at multiple spatial scales. This study evaluates the performance of the University of Montana Global Navigation Satellite Systems (GNSS) terrestrial water storage dataset as a tool for bridging groundwater monitoring gaps across the Upper and Lower Colorado River Basins between 2006 and 2024. We compare GNSS-derived total water storage and groundwater storage estimates against NASA’s Gravity Recovery and Climate Experiment (GRACE) satellite observations and in-situ groundwater well measurements at regional and sub-regional scales. We employ a Bayesian autoregressive …

Hydrothermal Vents In Sulfuric Acid Speleogenesis Karst: Isolated Feeders With Pristine Hypogenic Water Or Interconnected Conduits With Rapid Flow And Recycled Water?, Jakub Mareš, Marek Audy, Serban M. Sarbu, Jan Kukačka, Romeo Eftimi, Jiří Bruthans

International Journal of Speleology

Underwater connectivity and flow paths in the saturated zone of hypogenic sulfuric acid speleogenesis (SAS) karst remain unclear, despite sustained research over the past 30 years. Being regarded as sources of pristine H₂S-charged water, narrow inflow conduits called "feeders" are typically considered primary sources of water and hotspots of speleogenesis. In southeastern Albania, there is a newly discovered active SAS karst system comprising numerous caves and springs. Tracer tests were conducted to investigate the connection of these caves to the surrounding springs and to characterize the flow paths. The results show that water flows from cave lakes to …

A Combined Multi-Isotope And Machine Learning Approach To Determine Groundwater Salinity And Solute Sources, Lower Valley Area, El Paso County, Texas, Gloria A. Ortiz Gamboa

Open Access Theses & Dissertations

Groundwater salinization is increasingly troublesome in aquifers in and around El Paso, Texas, where concern for available water resources has grown due to frequent droughts and increasing population. Both groundwater and surface water have experienced an increase in total dissolved solids (TDS), a trend that can pose future health and economic problems for residents who primarily rely on groundwater. To address this issue, this research focuses on the Hueco Bolson Aquifer and the Rio Grande Alluvial Aquifer within the Lower Valley area of El Paso, Texas, utilizing a multi-analysis approach to evaluate and determine solute sources and their possible end-members …

Dream Pilot Project: Analysis Of Groundwater Development At Six Villages In Ethiopia, Lindsay K. Gordon

All Graduate Reports and Creative Projects, Fall 2023 to Present

This study presents a hydrogeologic assessment of the Distributed Renewable Energy Agriculture Modalities (DREAM) pilot project, an ongoing groundwater development initiative in rural Ethiopia. This project integrates solar-powered groundwater infrastructure across six villages to improve water access, agricultural productivity, and economic stability.

Fourteen production wells were installed at Murche, four at Dalle, and additional test wells at Murche, Dalle, Chefe Kora, and Huluku. Transmissivity values and the number of wells at Murche suggest that local water needs are currently being met. In contrast, fewer wells were drilled at Dalle. This reflects the high cost of well construction relative to yield, …

One Year Of Analysis Of Pfas Contamination In Surface Waters Of The West Plains Region Of Spokane County, Jerusha R. Hampson

2025 Symposium

The West Plains has been significantly impacted by PFAS contamination due to the decades-long use of aqueous film-forming foam (AFFF) for firefighting training at both Fairchild Air Force Base (FAFB) and the Spokane International Airport (SIA). Groundwater contamination is significant, but less work had been done to understand contamination in surface waters. We now have over a year of data with most locations were sampled seasonally. Though FAFB and SIA are likely sources for some of the contamination, other, smaller sources exist. Surface waters are important to study as they form the boundaries of the West Plains and often function …

Using Radium Isotopes To Compare Nutrient Inputs Via Submarine Groundwater Discharge To Offshore Export On The West Florida Shelf, Andrew L. Lindgren

OES Theses and Dissertations

Radium isotopes have been used to trace submarine groundwater discharge (SGD) and associated nutrient and metal inputs into the coastal ocean. They have also been used to estimate rates of diffusive mixing and export fluxes of dissolved constituents offshore. However, use of both approaches in tandem to determine the fate of groundwater inputs after they enter the coastal ocean is still relatively unexplored. Radium isotopes and nutrients were measured in two cross-shelf cruises on the West Florida Shelf in different seasons and in quarterly sampling of offshore wells. Through 226Ra mass balance and 223Ra-derived diffusive mixing rates, inputs of nutrients …

Hydrogeochemical Characterization Of The Ahtanum Alluvial Fan For Managed Aquifer Recharge, Yakima Basin, Washington, Brook M. Bauer

All Master's Theses

Overallocation of water resources in the Yakima River Basin, central Washington, has prompted investigation into facilitated aquifer recharge to enhance water supply during drought as part of the Yakima Basin Integrated Plan (YBIP). This study evaluates and characterizes the recharge potential of the Ahtanum Creek alluvial fan within the lower Ahtanum Sub-Basin by integrating geologic, hydraulic, and geochemical data.

Four main hydrogeologic units (unconsolidated, semi-consolidated, consolidated basin-fill deposits, and Columbia River Basalt aquifers) were identified from stratigraphic analysis of well logs across seven transects spanning the active fan and abandoned alluvial terrace portions of the alluvial fan study area. Stable …

Origins And Mechanisms Of Mobility Of Geogenic Arsenic Contamination In Toutle And Silver Lake, Wa, Usa, William A. Hays

All Master's Theses

Arsenic (As), a common contaminant in groundwater, is toxic to human health and has a maximum contaminant level of 10 ppb set by both the World Health Organization and the U.S. Environmental Protection Agency (ATSDR, 2007). In Toutle, WA, USA (30 km west of Mount Saint Helens), a private well, labelled TOU1, was previously identified with ~670 ppb of As and was the impetus of this study. This study targeted private wells in the vicinity of TOU1 to identify the extent of the arsenic contamination, identify the aquifer(s) of concern, and identify the mechanism(s) of mobility.

The wells were screened …

The Δ¹³C Signature Of Dissolved Organic And Inorganic Carbon Reveals Complex Carbon Transformations Within A Salt Marsh, Meagan J. Eagle, Kevin D. Kroeger, John W. Pohlman, Joseph J. Tamborski, Zhaohui Aleck Wang, T. W. Brooks, Jennifer O. Keefe Suttles, Adrian Mann

OES Faculty Publications

Coastal wetlands have high rates of atmospheric CO₂ uptake, which is subsequently respired back to the atmosphere, stored as organic matter within flooded, anoxic soils, or exported to the coastal ocean. Transformation of fixed carbon occurs through a variety of subsurface aerobic and anaerobic microbial processes, and results in a large inventory of dissolved carbon. Carbon source and the roles of aerobic respiration, sulfate reduction, and methane cycling were evaluated within salt marsh peat and the underlying sandy subterranean estuary. There is a large increase in dissolved inorganic carbon (DIC, 7,350 ± 3,900 μmol L^-¹), dissolved organic carbon …

Groundwater Pumping Impacts On Stream Depletion In Humboldt County, Ca: Integrating Analytical Models And Field Data, Andy Hans Heise

Cal Poly Humboldt theses and projects

This study addresses the significant concern of stream depletion from groundwater pumping in Humboldt County, CA. The objective of this study is to develop an analytical model for estimating stream depletion and integrating field data into model parameters.

The methodology involved conducting a field study near three operating wells by a stream, installing stream gages upstream and downstream of the wells, and recording pumping rates and schedules for two of the wells. The third well’s pumping data was synthetically generated, for privacy concerns of the well owner. The StreamDepletR package was used for estimating depletion rates in a stream in …

Investigating Crystalline Rock Weathering In Distinct Climate And Ecological Settings: Insights From Shallow Seismic Refraction, Rachel Uecker

All Dissertations

Despite decades of research, understanding the subsurface of the critical zone (CZ) remains a challenge, constrained by limited access to information at depth. Traditionally, boreholes, outcrops, soil pits, and near-surface (<1 meter) geochemical measurements provided access to and quantified CZ structure. These methods, though valuable in their detail, are spatially limited, and many landscape-scale weathering hypotheses are based on these observations. In recent years, geophysical techniques have been applied to characterize large-scale CZ structure and test the validity of existing hypotheses. This dissertation harnesses nearly 10 kilometers of seismic refraction data from diverse ecoregions across the United States to challenge prevailing assumptions about weathering patterns and CZ evolution. The objective of this work is to characterize the interpreted range of weathered materials in each ecoregion and connect them to remotely-sensed information like canopy height, elevation, slope, and aspect. To do this, this work first investigates differences in weathering at depth in a north and south-facing slope system in the Laramie Range, Wyoming. The motivation for this work came from nearly a century of soil and geochemical studies from the western United States that show a greater degree and depth of weathering on north-facing slopes when compared to south-facing slopes. Our seismic refraction data were used to show that there is not a significant difference in weathering thickness at depth between north and south-facing aspects at the study site, thus conflicting with the hypothesis that there would be. Next, the hypothesis that the depth of weathering is affected by elevation was tested in the San Jacinto Mountains in southern California. The motivation for this work came from several geochemical studies in the Sierra Nevada Mountains that show ecologically prosperous mid-elevations possess an ideal combination of temperature and precipitation to produce a greater degree and depth of weathering. Again, the seismic results from the San Jacinto Mountains provided observations that conflict with the existing hypothesis that climate conditions dominate the thickness of weathering seen in rocks. Lastly, I used seismic refraction data and topographic curvature to build a groundwater model of a watershed in the Carolina Piedmont. The results of this model reveal that seismic refraction as an application for including more realistic geometry in groundwater models can improve model calibration fits. This model is the first of its kind, and, therefore, is an important step forward in merging geophysical data with the hydrogeologic and modeling field and, with further development, can be used to explore the role of topographic and regional groundwater flow as a driver of CZ evolution.

Carbon Dioxide Dynamics In The Carbonate Critical Zone, Savoy Experimental Watershed, Arkansas, Usa, Michael Darvin Jones

Graduate Theses and Dissertations

The dynamics of carbon dioxide (CO₂) within the Earth’s critical zone (CZ) are essential for driving spatial and temporal variations of carbonate dissolution and precipitation, which are fundamental to subsurface porosity and permeability development. However, there is still a significant knowledge gap regarding the patterns of CO₂ transport and production within the carbonate critical zone (CCZ). In this study, we investigated these dynamics within a mantled karst terrain at the Savoy Experimental Watershed (SEW) in Northwest Arkansas.

Previous monitoring of partial pressure of CO₂ (PCO₂) and dissolution rates at karst springs in …

Characterizing Groundwater Flow Across The Barrier Island-High Marsh Interface, Dean Michael Wrobel

Electronic Theses and Dissertations

The freshwater resources of barrier islands are influenced by a variety of hydrogeologic factors, which create unique regions of groundwater composition. Factors including evapotranspiration, geologic constraints, tidal forcing, and meteoric inputs influence subterranean flow creating a groundwater salinity gradient throughout the island-marsh setting which directly influences the spatial distribution of dominant vegetation on the island. Rising sea levels and variation in local climate may alter the hydrologic balance on barrier islands, potentially shifting salinity gradients and ecological baselines on short timescales. The intrusion of saltwater into the barrier island freshwater system could result in the shifting of ecotones and potential …

Preliminary Analysis Of Per-And Polyfluoroalkyl Substances (Pfas) In Surface Waters Of The West Plains Region Of Spokane County, Jerusha Hampson

2024 Symposium

Per-and Polyfluoroalkyl Substances (PFAS) have become a national issue as regulatory limits for these toxins have just recently been put into the Clean Water Act. The West Plains has been significantly impacted by PFAS contamination due to the decades-long use of aqueous film-forming foam (AFFF) for firefighting training at both Fairchild Airforce Base and the Spokane International Airport. Though research is still underway, it is known that PFAS contamination in West Plains groundwater is significant and widespread. This study focuses on West Plains surface waters, as there is currently less information about how these water bodies are impacted by PFAS. …

Mapping The Invisible: Machine Learning And Geovisualization Methods For Groundwater Management, Khalid Galal Elhaj

Dissertations

Groundwater is a vital global resource, yet mapping and managing aquifers remains challenging due to costs and complexities. This doctoral dissertation pioneers novel data-driven methodologies harnessing machine learning and hydrogeology domain knowledge to sustainably characterize and monitor aquifer systems. The overarching hypothesis investigated is that time series clustering of historical well hydrographs can enable low-cost delineation of aquifer boundaries by detecting response similarities between wells sharing the same aquifer. To test this, three interconnected studies were conducted. First, a specialized time series clustering framework was developed incorporating a global temporal alignment index and custom dissimilarity metrics tuned for hydrogeology. The …

Characterizing Mountainous Bedrock Groundwater Systems Across Gradients In Topography And Lithology In Western Montana, David L. Baude

Graduate Student Theses, Dissertations, & Professional Papers

Mountain aquifer groundwater systems remain one of the least understood hydrologic systems in upland hydrology. In this study, we aim to characterize bedrock groundwater system dynamics and bedrock-saprolite interactions across a variety of landscape positions and lithology. We investigate groundwater hydraulics, recharge temperature and elevation, residence times, and bedrock recharge rates across two mountainous headwater catchments in west central Montana. We used a suite of environmental tracers (³H, CFCs, SF₆, and ⁴He) and residence time distribution models to estimate groundwater mean residence times over a range of timescales from decades to millennia. Tracers were sampled …

A General Framework For Modeling Subregional Path Effects, T. E. Buckreis, P. Wang, S. J. Brandenberg, J. P. Stewart

Civil & Environmental Engineering Faculty Publications

Next Generation Attenuation (NGA) West2 ground motion models (GMMs) include regional path adjustments for broad jurisdictional regions, which necessarily averages spatially variable path effects within those regions. We extend that framework to account for systematic variations in attenuation within subregions defined in consideration of geologic differences. In recent years, cell-based methods which systematically account for spatial variations by summing the attenuation effects over a fine discretization of uniform-rectangular cells (e.g., Dawood and Rodriquez-Marek 2013; Kuehn et al. 2019) have been shown to be an effective alternative to regionalization and a step towards modelling non-ergodic path effects. The main drawbacks of …

Ice-Marginal Volcanic Sequence In Iceland Found On A Nondescript Gradual Hillslope: An Unexpected Record Of Ice Thickness Late In Deglaciation, Audrey R. Putnam, Kristen L. Siebach, Candice C. Bedford, Sarah L. Simpson, Michael T. Thorpe, Joseph J. Tamborski

OES Faculty Publications

Volcanism increases when glaciers melt because isostatic rebound during deglaciation decreases the pressure on the mantle, which enhances decompression melting. Anthropogenic climate change is now causing ice sheets and valley glaciers to melt around the world and this deglaciation could stimulate volcanic activity and associated hazards in Iceland, Antarctica, Alaska, and Patagonia. However, current model predictions for volcanic activity associated with anthropogenic deglaciation in Iceland are poorly constrained, in part due to uncertainties in past volcanic output over time compared to ice sheet arrangements. Further work specifically characterizing glaciovolcanic and ice-marginal volcanoes in Iceland is needed to reconstruct volcanic output …

Shallow Groundwater Distributions And Changes With Sea Level Rise In Seattle, Washington, Taylor L. Watson

Graduate Theses and Dissertations

Sea level rise (SLR) associated hazards, such as coastal flooding and erosion, are pressing issues of great concern for coastal communities across the globe. Shallow and emergent groundwater can contribute to groundwater hazards such as flooding, landslides, or damage to shallow infrastructure. This study investigates the shallow groundwater within Seattle, Washington, and projects how it will respond to SLR using interpolation and numerical groundwater modeling methods. Then, a geologic modeling method is presented as a preliminary investigation of heterogeneity and anisotropy within the aquifer system. In the results for the present-day interpolation, ~6 % of the coastal buffer –the total …

Transforming Agriculture In The Pilbara: Newman Managed Aquifer Recharge (Mar) Feasibility Assessment, Michael J. Donn, Joanne L. Vanderzalm, Olga V. Barron

Natural resources commissioned reports

In the Newman region, DPIRD commissioned an assessment of the potential for managed aquifer recharge (MAR) near Newman using surplus water resulting from mine dewatering as the water supply for irrigated agriculture. The objectives of the MAR assessment were to:

• identify focus area for MAR feasibility assessment within the initial larger area of interest for MAR
• assess the viability of MAR with mine dewater near Newman to support development of irrigated agriculture, in keeping with national and state MAR guidelines
• identify key risks associated with MAR with mine dewater for irrigation supply, and identify knowledge/investigation required to adequately assess risks …

Groundwater System Characterisation: Fortescue Alluvial Fan, Michael J. Donn, Olga V. Barron, Axel Suckow, Chris Turnadge, John A. Simons, Robert J. Paul, Christopher Schelfhout Dr

Natural resources commissioned reports

This report focuses on groundwater system characterisation in the region north of Newman, based on analysis of pre-existing data and data newly acquired during project activities. Groundwater system characterisation was an important research component supporting the assessment of managed aquifer recharge opportunities, using mine dewatering surplus generated (due to mining below the watertable) at large BHP Billiton Iron Ore operations in the eastern Pilbara mining zone, and aiming to support irrigated agriculture. The assessment area is located north of Ethel Gorge and covers the Upper Fortescue River floodplain and surroundings. The project added much knowledge to this largely ‘data-poor’ region, …

Evaluating The Feasibility Of Using Strain Measured During Sinusoidal Rate Pumping Tests To Characterize An Aquifer, Riley Blais

All Theses

Pumping tests with sinusoidal variation in pumping rate have been proposed as a method for improving aquifer characterization. These tests can interrogate a larger aquifer volume than slug tests and they can be more sensitive to small variations in drawdown. Current methods of using sinusoidal variations of rate are based on measuring pressure signals from the reservoir or aquifer, which requires access to monitoring wells. An alternative approach has been developed that measures the strain in the vadose zone instead of pressure in the reservoir. An instrument has been developed at Clemson University that can measure small strains using optical …

Groundwater Flow And Salt Marsh Migration: The Forest/Marsh Boundary, Camille Rossiello

Theses and Dissertations

Salt marshes migrate landward in response to sea level rise, but the rate of this migration is not constant and can be influenced by pulse disturbances. Long term observations at Sapelo Island, Georgia, show that salt marsh migration has occurred during droughts, but the mechanism for this migration is unclear. Drought is thought to influence salt marsh migration by reducing fresh groundwater discharge from the upland. Rising sea level also encroaches on the upland, which could cause movement of the freshwater lens inland. A two-dimensional numerical model was built to simulate groundwater flow and solute transport based on the Marsh …

A Conceptual Framework For Managed Aquifer Recharge In The Columbia River Basalts Of The Lower Yakima River Basin, Bethany Kharrazi

All Master's Theses

In the Yakima River Basin in south-central Washington, increasing demands for water, overallocation of surface water, and a changing climate are leading to a loss of water storage and increasing water deficits in drought years. A warming climate has reduced snowpack in the Cascade Range, a vital reservoir for the irrigated agricultural industry which supports the basin’s economy. Managed aquifer recharge (MAR) is a sustainable and cost-effective approach for securing water supply by storing water underground for recovery during drought. Diminishing groundwater levels in regional basalt aquifers over the last several decades suggest there is significant storage available for intentional …

Estimating Evapotranspiration And Analyzing Soil Moisture And Heat Flux Parameters At Taneum Creek, Central Washington, Edward Vlasenko

All Master's Theses

In the past two decades, stream restoration work, primarily in the form of wood emplacement, has been undertaken in the Taneum Creek watershed, resulting in increased channel-floodplain connectivity. One of the goals of stream restoration was to boost dry season groundwater storage in the shallow floodplain aquifer. However, any gains in groundwater due to increased connectivity may be nullified by increased evapotranspiration (ET) losses because of denser floodplain vegetation. Within the floodplain aquifer budget, ET is a major flow of water out of the system and is not well quantified.

In order to quantify ET, a monitoring site was established …

Evaluating The Sensitivity Of Crustal Deformation To Bedrock Hydrology In A Mountain Watershed, Brett J. Oliver

Graduate Student Theses, Dissertations, & Professional Papers

We evaluate the sensitivity of Earth's elastic deformation to groundwater hydraulic diffusivity using coupled groundwater and elastic deformation models. Seasonal changes in terrestrial water storage cause deformation to the Earth’s crust and deeper interior that is within the observational capacity of GPS instruments. We couple finite difference groundwater simulations with geodetic forward models of crustal displacement to investigate the ability of geodetic deformation to constrain bedrock hydrologic properties. We use MODFLOW-2005 to simulate seasonal changes in groundwater flow and storage, and then use the LoadDef elastic deformation model to forward model surface displacement caused by the change in terrestrial water …