Chemistry Commons^™

Removal Of Selenium Ions From Contaminated Aqueous Solutions By Adsorption Using Lemon Peels As A Non-Conventional Medium, Alanood A. Alsarayreh, Suha Anwer Ibrahim, Salem Jawad Alhamd, Thekra Atta Ibrahim, Mohammed Nsaif Abbas

Karbala International Journal of Modern Science

The disposal of heavy metals from various activities has become a pervasive issue. The investigation of sustain-able, low-cost adsorbents for the remediation of these hazardous pollutants has been widely disregarded. This research emphasizes the recovery of selenium ions from contaminated water using lemon peels as a cost-effective adsorbent. The adsorption was explored in a batch unit under various operational parameters, including initial selenium concentration (1-90 ppm), pH (1-11), agitation speed (100-500 rpm), adsorbent dose (0.4-5.5 g), contact time (5-180 minutes), and temperature (25-55 °C). The BET surface area of the lemon peels was found to be 27.86 m²/g before adsorption …

Platinum Nanoparticle-Based Collision Electrochemistry For Rapid Detection Of Breast Cancer Mcf-7 Cells, Fu-Xing Qin, Ming-Ke Li, Hui-Long Zhou, Wei Wen, Xiu-Hua Zhang, Sheng-Fu Wang, Zhen Wu

Journal of Electrochemistry

Cancer metastasis is the leading cause of death in cancer patients worldwide and one of the major challenges in treating cancer. Circulating tumor cells (CTCs) play a pivotal role in cancer metastasis. However, the content of CTCs in peripheral blood is minimal, so the detection of CTCs in real samples is extremely challenging. Therefore, efficient enrichment and early detection of CTCs are essential to achieve timely diagnosis of diseases. In this work, we constructed an innovative and sensitive single-nanoparticle collision electrochemistry (SNCE) biosensor for the detection of MCF-7 cells (human breast cancer cells) by immunomagnetic separation technique and liposome signal …

Highly Sensitive Detection Of Strontium Ions Using Metal-Organic Frameworks Functionalized Solid-State Nanochannels, Xu-Gang Wang, Zheng-Xu He, De-Fang Ding, Xue-Qin Luo, Li Dai, Wei-Qi Zhang, Qun Ma, Yu Huang, Fan Xia

Journal of Electrochemistry

Strontium-90, a highly radioactive isotope, accumulates within the food chain and skeletal structure, posing significant risks to human health. There is a critical need for a sensitive detection strategy for Strontium-90 in complex environmental samples. Here, solid-state nanochannels, modified with metal-organic frameworks (MOF) and specific aptamers, were engineered for highly sensitive detection of strontium ion (Sr²⁺). The synergistic effect between the reduced effective diameter of the nanochannels due to MOF and the specific binding of Sr²⁺ by aptamers amplifies the difference in ionic current signals, enhancing detection sensitivity significantly. The MOF-modified nanochannels exhibit highly sensitive detection of …

Goodbye With Tears! Deep Condolences To Academician Zhao-Wu Tian!, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

The Adviser Of Journal Of Electrochemistry Professor Christian Amatore Received The Chinese Government Friendship Award, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Journal Of Electrochemistry Is Selected To Entering Ici Journals Master List, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Author Spotlight, Fei Li, Yi-Ge Zhou, Yi-Lun Ying, Yong-Xin Li, Yu Huang, Zhen Wu

Journal of Electrochemistry

No abstract provided.

Single Nanobubble Formation On Au Nanoelectrodes And Au@Ws2 Nanoelectrodes: Voltammetric Analysis And Electrocatalysis, Xian-Zhun Luo, Xiao-Hu Chen, Yong-Xin Li

Journal of Electrochemistry

Taking advantage of the extremely small size of the gold nanodisk electrode, the single hydrogen nanobubble generated on the surface of the nanoelectrode was studied to evaluate its hydrogen evolution performance. It was found that compared with the bare gold nanodisk electrode, the bubble formation potential of the gold nanodisk electrode modified with tungsten disulfide quantum dots (WS₂ QDs) on the surface was more positive, indicating that its hydrogen evolution activity was higher. Microdynamic model analysis shows that the average standard rate constant of the rate-determining step of the hydrogen evolution reaction of gold nanoelectrodes modified with WS_{2 …}

Investigating Students' Expectations And Engagement In General And Organic Chemistry Laboratory Courses, Elizabeth B. Vaughan, Saraswathi Tummuru, Jack Barbera

Chemistry Faculty Publications and Presentations

Students’ expectations for their laboratory coursework are theorized to have an impact on their learning experiences and behaviors, such as engagement. Before students’ expectations and engagement can be explored in different types of undergraduate chemistry laboratory courses, appropriate measures of these constructs must be identified, and evidence of validity and reliability for the data collected with these instruments must be investigated. This study collected evidence related to response process validity, internal structure validity, and single administration reliability for version 2 of the Meaningful Learning in the Laboratory Instrument (MLLIv2) and a measure of student engagement in the undergraduate chemistry laboratory. …

Carbon Restoration Potential On Global Land Under Water Resource Constraints, Shouzhang Peng, César Terrer, Benjamin Smith, Philippe Ciais, Qinggong Han, Jialan Nan, Joshua B. Fisher, Liang Chen, Lei Deng, Kailiang Yu

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Ecosystem restoration is a critical nature-based solution to mitigate climate change. However, the carbon sequestration potential of restoration, defined as the maximum achievable carbon storage, has likely been overestimated because previous studies have not adequately accounted for the competition between ecosystem water demands for maximizing carbon sequestration and human water needs. Here we used a comprehensive process-based model combined with extensive land-use data and evaporation recycling accounting for land–atmosphere feedback to estimate the water requirements associated with ecosystem restoration. We found that achieving the carbon sequestration potential of restoration would significantly reduce global water availability per capita by 26%, posing …

Gas Chromatography-Mass Spectrometry (Gc-Ms), Computational Analysis, And In Vitro Effect Of Essential Oils From Two Aromatic Plants, Bubonium Graveolens And Launaea Arborescens Growing In Southwest Algeria Against Potato Cyst Nematodes, Souad Ziane, Chaouki Selles, Khaldun M. Al Azzam, Bounoua Nadia, Belal O. Al-Najjar, Ali Al-Samydai, Obada A. Sibai, El-Sayed Negim

Karbala International Journal of Modern Science

The study tested the nematicidal effects of essential oils from Bubonium graveolens and Launaea arborescens on the potato cyst nematode Globodera rostochiens. The chemical composition of the essential oils was analyzed using GC-MS. To determine the concentration that killed 50% of the nematode population (LC50), five concentrations of the essential oils were applied to the tested organisms. The effects of essential oils on the hatching of cyst nematode (Globodera rostochiensis sp.) eggs in vitro demonstrated a wide variety of effects ranging from no impact to mild, moderate, and strong effects, which increased dramatically with exposure duration and concentration. All the …

Broken Su(3) Description Of Energy Levels And Decay Properties In Gadolinium Isotopes (A=156-160), Fahmi Sh. Radhi, Amir Abdul Ameer Mohammed Ali Dr., Ali H. Al-Musawi

Karbala International Journal of Modern Science

This study presents an in-depth examination of the energy levels and decay properties of Gadolinium (Gd) isotopes with mass numbers (A=156-160), utilizing the Interacting Boson Model-1 (IBM-1) within a broken SU(3) symmetry framework. Through this approach, we systematically calculated and analyzed the energy spectra, B(E2) transition probabilities, quadrupole moments, and potential energy surface (PES) which provided valuable insights into the shape and collective behavior of nuclei, as well as the decay properties of the selected Gd isotopes. The broken SU(3) symmetries provide a good description to the isotopes under study. This comprehensive analysis enhances the understanding of the nuclear structure …

Skin Microbiome: Current Target For Cosmeceuticals, Priyanka Kakkar, Neeraj Wadhwa

Karbala International Journal of Modern Science

Skin acts as a barrier to the external environment and perform various functions like maintaining internal homeostasis, sensations to touch based stimuli, vitamin D production and defence against foreign pathogens, prevent dehydration. Skin has its own diverse microbiota like bacteria, virus, fungi that is collectively called as skin microbiome. Skin microbiome balance is disturbed (condition called dysbiosis) by both internal and external factors which lead to skin problems like acne, psoriasis, dandruff. It is important to maintain the healthy skin ecosystem. Cosmeceuticals i.e., combination of cosmetic and pharmaceuticals, is a recent trend in the skin care industry where we add …

Raw Data For High Entropy Stabilized Platinum Diborides For Poison-Resistant Catalysis, Michael Yeung, Ting Wang

Chemistry Department Faculty Scholarship

Raw data for the publication High-Entropy-Stabilized Platinum Diborides for Poison-Resistant Catalysis including Powder X-ray Diffraction and Nuclear Magnetic Resonance data.

Abstract for publication:

Alloying and solid-solution formation is a powerful technique that enhances and adds properties through elemental mixing, but unfortunately, some elements simply cannot mix as their chemical nature prevents a thermodynamically stable structure. For example, the inherent nobility of platinum group metals does not favor bond formation and precludes their incorporation into higher (boron-rich) metal borides. Here, we demonstrate that when using five or more constituents, the higher mixing entropy will overcome these chemical limitations and form a …

Effects Of Spontaneous Curvature On Interfacial Adsorption And Collapse Of Phospholipid Monolayers, Bret A. Brandner, Shankar B. Rananavare, Stephen B. Hall

Chemistry Faculty Publications and Presentations

To function effectively, pulmonary surfactant must adsorb rapidly to the alveolar air/water interface but avoid collapse from the surface when compressed to high interfacial densities. Prior studies show that phospholipids in the cylindrical monolayers of the inverse hexagonal (HII) phase adsorb quickly. The monolayers have negative curvature, defined by the concave shape of the hydrophilic face. Formation of the HII structures, however, involves significant disruption of chain-packing. Samples with significant spontaneous curvature, formed in the absence of applied force, may nonetheless have lamellar structures that optimize chain-packing. The experiments here tested whether planar lamellar bilayers formed by phospholipids with negative …

Local Hydroclimate Alters Interpretation Of Speleothem Δ18o Records, E. W. Patterson, V. Skiba, A. Wolf, M. L. Griffiths, D. Mcgee, T. N. Bùi, M. X. Trần, T. H. Đinh, Q. Đỗ-Trọng, Gregory R. Goldsmith, V. Ersek, K. R. Johnson

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Oxygen isotopes (δ¹⁸O) are the most commonly utilized speleothem proxy and have provided many foundational records of paleoclimate. Thus, understanding processes affecting speleothem δ¹⁸O is crucial. Yet, prior calcite precipitation (PCP), a process driven by local hydrology, is a widely ignored control of speleothem δ¹⁸O. Here we investigate the effects of PCP on a stalagmite δ¹⁸O record from central Vietnam, spanning 45 – 4 ka. We employ a geochemical model that utilizes speleothem Mg/Ca and cave monitoring data to correct the δ¹⁸O record for PCP effects. The resulting record …

Road Signs Detection Using Ssd Mobilenetv2, Zahraa Salah Dhaif, Nidhal K. El Abbadi

Karbala International Journal of Modern Science

One of the most critical challenges for self-driving vehicles is accurately identifying traffic signs, which are essential for self-navigation and decision-making. Systems for the detection and recognition of road signs play a crucial role in this process by providing vital information for the vehicle's decision-making. This study proposes an approach for road sign identification and recognition utilising the TensorFlow Object Detection API and the SSD MobileNet V2 FPN Lite model.

In this proposal, we combine the efficiency and accuracy of SSD with the lightweight architecture of MobileNet to achieve excellent performance in object detection benchmarks while maintaining a small model …

Effect Of Electronegativity On Environmentally Persistent Free Radical (Epfr) Formation, Persistence, And Toxicity On Transition Metal Oxides, Syed Monjur Ahmed

LSU Doctoral Dissertations

Environmentally persistent free radicals (EPFRs) are a group of emerging environmental pollutants. Owing to their resonance structures, EPFRs have significantly higher lifetimes than typical free radicals, and can induce the formation of reactive oxygen species (ROS) known to cause pulmonary and cardiovascular dysfunction. EPFRs form by the adsorption of organic precursors on a transition metal oxide (TMO) surface and exhibit enough stability to cause negative health and environmental effects. While aromatic and substituted aromatic precursors form EPFRs on TMO surface at elevated temperatures and numerous substituted organics are ubiquitous in various industrial processes and household products, studies have largely overlooked …

Microwave-Assisted Hydrothermal Synthesis Of Photocatalytic Truncated-Bipyramidal Tio2/Ti3cn Heterostructures Derived From Ti3cn Mxene, Muhammad Abiyyu Kenichi Purbayanto, Madhurya Chandel, Dominika Bury, Anna Wójcik, Dorota Moszczyńska, Anika Tabassum, Vadym Mochalin, Michael Naguib, Agnieszka Maria Jastrzębska

Chemistry Faculty Research & Creative Works

TiO₂/MXene heterostructure has garnered significant interest as a photocatalyst due to its large surface area and efficient charge carrier separation at the interface. However, current synthesis methods produce TiO₂ without clear crystal faceting and often require complicated postprocessing step, limiting its practical applications. We demonstrate a facile and controlled microwave-assisted hydrothermal synthesis for transforming multilayered Ti₃CN MXene to a truncated-bipyramidal TiO₂/Ti₃CN heterostructure. The resulting TiO₂ nanocrystals at the Ti₃CN surface exhibited crystalline anatase truncated bipyramids, exposing {001} and {101} facets. We further tailored an indirect optical band gap …

Trichloroethylene (Tce) Metabolite S-(1,2-Dichlorovinyl)-L-Cysteine (Dcvc) Inhibits Lps-Stimulated Cxcl-2 Production In Thp-1 Cells, Erica Boldenow, Karena Moleakunnel, Audrey Luce, Lyric Johnson, Eleanor Scheeres

University Faculty Publications and Creative Works

Michigan Society of Toxicology Fall 2024 Meeting

Intelligrader: A Framework For Automatic Short Answer Grading, Inconsistency Check And Feedback In Educational Context - Conception, Implementation And Evaluation, Paradesi Sree Lakshmi, Jay B. Simha, Rajeev Ranjan

Karbala International Journal of Modern Science

Automatic Short Answer Grading (ASAG), an escalating realm in natural language understanding, constitutes a focal point of research within the broader field of learning analytics. Over time, many ASAG solutions have been proposed to address the difficulties in teaching. However, no work addressed three crucial aspects of evaluation together, i.e., i) automatic evaluation of brief subjective/descriptive answers written in English, ii) identifying the evaluation inconsistency, and iii) provision of providing feedback about inconsistent evaluation to the evaluator. The current work proposes IntelliGrader, a comprehensive ASAG system that addresses the above-mentioned issues. Automated grading is accomplished through a model answer-based approach. …

Isolation And Characterization Of Fermenting Bacterial Isolates From Vinegar Industry Waste In Local Markets Of Wasit Province, Tayseer Shamran Al-Deresawi

Karbala International Journal of Modern Science

The use of waste in the vinegar industry is an important practice of the food industry worldwide; however, this critical practice is neglected in many parts of Iraq. According to this, the current study was conducted to isolate and characterize fermenting bacterial organisms from this waste in Wasit Province, Iraq. Samples of vinegar industry by-products were collected from local businesses. These samples were prepared by using Hestrin-Schramm (HS) medium. Two methods, direct and indirect inoculations, were followed. The purified growth was examined using morphological and biochemical tests. Moreover, PCR was employed to confirm the identity of each bacterial isolate. The …

First Demonstration Of In Vivo Pde11a4 Target Engagement For Potential Treatment Of Age-Related Memory Disorders, Shams Ul Mahmood, Jeremy Eberhard, Charles S. Hoffman, Dennis Colussi, John Gordon, Wayne Childers, Elvis Amurrio, Janvi Patel, Michy P. Kelly, David P. Rotella

Department of Chemistry and Biochemistry Faculty Scholarship and Creative Works

PDE11A4 is a target of interest for the treatment of age-related memory disorders. A previous report from our laboratories described an amide series of potent, selective PDE11A4 inhibitors that was metabolically unstable. Investigation of heterocyclic amide isosteres for the labile amide moiety revealed distinct structure-activity relationships and identified several compounds with potency comparable to the amide series. This manuscript describes the characterization of structure-activity and structure-property relationships in this set, leading to the identification of an orally bioavailable, brain-penetrant, selective and potent PDE11A4 inhibitor. Target engagement experiments demonstrated PDE11A4 inhibition in the hypothalamus of mice that was absent in PDE11A4 …

Protocol For Evaluating Anion Exchange Membranes For Nonaqueous Redox Flow Batteries, Jessica L. Tami, Md Motiur R. Mazumder, Grace E. Cook, Shelley D. Minteer, Anne J. Mcneil

Chemistry Faculty Research & Creative Works

Nonaqueous redox flow batteries often suffer from reduced battery lifetime and decreased coulombic efficiency due to crossover of the redox-active species through the membrane. One method to mitigate this undesired crossover is to judiciously choose a membrane based on several criteria: swelling and structural integrity, size and charge of redox active species, and ionic conductivity. Most research to date has focused on reducing crossover by synthesizing modified redox-active molecules and/or new membranes. However, no standard protocol exists to compare membranes and a comprehensive study comparing membranes has yet to be done. To address both these limitations, we evaluate herein 26 …

Binding Mechanism Of The Active Form Of Molnupiravir To Rdrp Of Sars-Cov-2 And Designing Potential Analogues: Insights From Molecular Dynamics Simulations., Justin Carbone, Nicholas J Paradis, Dylan Brunt, Chun Wu

College of Science & Mathematics Departmental Research

Molnupiravir, an FDA-approved nucleoside prodrug for treating COVID-19, converts into N4-hydroxycytidine triphosphate (NHC-TP), which integrates into SARS-CoV-2 RNA by its RNA-dependent RNA polymerase (RdRp) causing lethal mutations in viral proteins. Due to the risk of RdRp-mediated drug resistance and potential off-target effects on host polymerases (e.g., human polymerase II/HPolII), it is crucial to understand NHC-TP interactions at polymerase active sites for developing new, resistance-proof treatments. In this study, we used molecular dynamics (MD) simulations to probe key interactions between NHC-TP and SARS-CoV-2 RdRp and designed novel NHC-TP analogues with greater selectivity for SARS-CoV-2 RdRp over HPolII by a virtual screening …

Brownfield Topsoil Vertical Heterogeneity: Implications For Germination And Soil Microbial Functioning, Eshariah N. Dyson, Diane F. Hagmann, Cesar Idrovo, Jennifer Adams Krumins, Nina M. Goodey

Department of Chemistry and Biochemistry Faculty Scholarship and Creative Works

Soil vertical heterogeneity refers to the variation in soil properties and composition with depth. In uncontaminated soils, properties including the organic matter content and nutrient concentrations typically change gradually with depth due to natural processes such as weathering, leaching, and organic matter decomposition. In contaminated soils, heavy metals and organic contaminants can migrate vertically through leaching or root uptake and translocation by plants and macrobiota, if present, leading to vertical heterogeneity in contaminant concentrations at different depths. Contaminants can alter soil properties, and we investigated the implications of soil vertical heterogeneity for germination and microbial functioning. We collected soil from …

Examination Of Photoinduced Radicals In Two Crystal Forms Of Triphenylamine Bis-Urea Macrocycles, Md Faizul Islam, Gamage Isuri P. Wijesekera, Anmon J. Sindt, Mark D. Smith, Linda S. Shimizu

Faculty Publications

This study probes two solvates of triphenylamine (TPA) bis-urea macrocycle 1 and their activated structures to evaluate their maximum photoinduced radicals (PIRs), the subsequent decay of the radicals, and their regeneration. The hierarchical assembly of TPAs shows promise in stabilizing less substituted derivatives, potentially expanding the utility of TPAs that lack stabilizing para-substituents. Single crystal structure analysis reveals that host 1 adopts a planar conformation with the two ureas pointing in opposite directions when dimethoxyethane (DME) is encapsulated within the channel. Whereas previously, 1 adopted a bowl-shaped conformation with the two ureas pointing in the same direction (syn …

Examination Of Photoinduced Radicals In Two Crystal Forms Of Triphenylamine Bis-Urea Macrocycles, Md Faizul Islam, Gamage Isuri P. Wijesekera, Ammon J. Sindt, Mark D. Smith, Linda S. Shimizu

Faculty Publications

This study probes two solvates of triphenylamine (TPA) bis-urea macrocycle 1 and their activated structures to evaluate their maximum photoinduced radicals (PIRs), the subsequent decay of the radicals, and their regeneration. The hierarchical assembly of TPAs shows promise in stabilizing less substituted derivatives, potentially expanding the utility of TPAs that lack stabilizing para-substituents. Single crystal structure analysis reveals that host 1 adopts a planar conformation with the two ureas pointing in opposite directions when dimethoxyethane (DME) is encapsulated within the channel. Whereas previously, 1 adopted a bowl-shaped conformation with the two ureas pointing in the same direction (syn …

Efficient Phosphate Removal From Water Using Ductile Cast Iron Waste: A Response Surface Methodology Approach, Mai Hassan Dr., Nada Alkhashab Eng., Ahmed Osman Dr., Dalia A. Ali Eng

Chemical Engineering

Water scarcity is a critical issue worldwide. This study explores a novel method for addressing this issue by using ductile cast iron (DCI) solid waste as an adsorbent for phosphate ions, supporting the circular economy in water remediation. The solid waste was characterized using XRD, XRF, FTIR, and particle size distribution. Wastewater samples of different phosphate ion concentrations are prepared, and the solid waste is used as an adsorbent to adsorb phosphate ions using different adsorbent doses and process time. The removal percentage is attained through spectrophotometer analysis and experimental results are optimized to get the optimum conditions using Design …

Electrochemistry At Work: Bouncing Batteries, Bryant Corbin, James Daniel, Jade Riddle

Fall Showcase for Research and Creative Inquiry

No abstract provided.