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Articles 1711 - 1740 of 1823
Full-Text Articles in Chemistry
Preparation And Examination Of Planar Type Solid Oxide Fuel Cells, Yi Jiang, Jingwang Yan, Shizhong Wang, Chunying Yu, Wenzhao Li
Preparation And Examination Of Planar Type Solid Oxide Fuel Cells, Yi Jiang, Jingwang Yan, Shizhong Wang, Chunying Yu, Wenzhao Li
Journal of Electrochemistry
The solid oxide fuel cells of planar type (SOFC) have been developed after successfully preparing La0.8Sr0.2MnO3 cathodes and Ni-YSZ ceramic anodes on YSZ plates and solving the high temperature sealing technical problem. Examination of the single cells fabricated showed that the maximum power output at 950 ℃ for H2 as fuel and air as oxidant reached 0.12 W/cm2. It was found that the large polarization overpotential of the Ni-YSZ anode and the Ohmic losses of the cells were two main factors responsible for the relative low output power density.
The Electrochemical Behavior And Deposited Mechanism Of Zn-Ni Alloy Codeposition, Jixun Wu, Yongqin Liu, Huimin Meng
The Electrochemical Behavior And Deposited Mechanism Of Zn-Ni Alloy Codeposition, Jixun Wu, Yongqin Liu, Huimin Meng
Journal of Electrochemistry
The electrochemical behavior of Zn-Ni alloy codeposition and concomitant hydrogen evolution have been studied in the chloride ammonia solution through the d-c electroplating method. Under the condition of the applied cathodic current density of 2A/dm2 , the AC impedance spectra have been measured. An equivalent circuit has been presented for the impedance study on the alloy codeposition.
Preparation Of Pbo2/Ti Plate Electrode, Zhigang Shao, Baolian Yi, Xinge Zhang, Enjun Zhang
Preparation Of Pbo2/Ti Plate Electrode, Zhigang Shao, Baolian Yi, Xinge Zhang, Enjun Zhang
Journal of Electrochemistry
The perchlorate was made up of a lead dioxide plate elcetrode and an oxygen cathode. By measuring the flow capacity of cell gas in the cell, and by means of CV, SEM, XRD, the performances of the lead dioxide plate electrodes are evaluated. The influence of changes in the concentrations of electroplating solutions (F, HNO3, Bi3+, Ni2+, Fe3+ and surface active agent) is investigated. The results show that the concentrations of Fe3+ in the solutions must be lower 0.01 g/L, and the concentrations of HNO3 in the solutions are about 20 …
Studies Of Electrocatalytic Properties Of Electrode Of Dispersed Pt On Gc Support In Ethylene Glycol Oxidation, Shengpei Chen, Shigang Sun, Zhiyou Zhou, Shuanjing Hong
Studies Of Electrocatalytic Properties Of Electrode Of Dispersed Pt On Gc Support In Ethylene Glycol Oxidation, Shengpei Chen, Shigang Sun, Zhiyou Zhou, Shuanjing Hong
Journal of Electrochemistry
The structures and properties of electrocatalyst of dispersed Plutinum (Pt) on glassy carbon (GC) support under different conditions were studied using cyclic voltammetry, potential step technique, X-ray diffraction (XRD) and scanning Electron microscopy (SEM). The results indicated that after having been treated in high temperature,the dispersed Pt on GC support was recrystallised with preferented orientation, and the grain of Pt microcrystal become large and regular. It was illustrated that the dispersed Pt on GC support after high temperature treatment exhibited better stability and high activity for ethylene glycol oxidation.
Polymer Electrolyte Fuel Cell Powered Vehicles, Naichao Li, Baolian Yi
Polymer Electrolyte Fuel Cell Powered Vehicles, Naichao Li, Baolian Yi
Journal of Electrochemistry
The background, status and commercialization prospect of polymer electrolyte fuel cell vehicles are surveyed in this paper. The technology of this cell and system used in vehicles is discussed.
Electrochemical Behavior Of Superoxide Dismutase On Gold Minigrid With Thin Layer Cell, Xiaqin Wu, Qian Liu, Bin Xu, Xiaoyun Men, Zongrang Zhang
Electrochemical Behavior Of Superoxide Dismutase On Gold Minigrid With Thin Layer Cell, Xiaqin Wu, Qian Liu, Bin Xu, Xiaoyun Men, Zongrang Zhang
Journal of Electrochemistry
The electrochemical behavior of superoxide dismutase (Cu, Zn-SOD) was investigated on gold wire electrode and gold minigrid with thin layer cell by cyclic voltammetry. A quasi reversible redox wave of SOD has obtained on gold minigrid thin layer electrode, but only oxidation peak has observed on gold wire electrode. The electrochemical reaction parameters, such as the formal potential E0′, diffusion coefficient D and standard rate constant k0′ were estimated.
Electrodeposition Of Amorphous Fe-Cr Alloy Coating, Danhong Cheng, Weiyi Xu, Yiqin Qin, Liqun Hua, Zhongyan Zhang
Electrodeposition Of Amorphous Fe-Cr Alloy Coating, Danhong Cheng, Weiyi Xu, Yiqin Qin, Liqun Hua, Zhongyan Zhang
Journal of Electrochemistry
The amorphous Fe-Cr alloy coatings were obtained by controlling the composition of bath operation conditions. It was found that the pH value, the current density and the content of chromium in Fe-Cr alloy coatings effect the amorphous structure of the coatings. The result of anodic polarization shows that the corrosion resistance of the amorphous coatings in acidic media is higher than the corrosion resistance of the crystal ones.
Studies On Electrodeposition Of Rare Earth Metals And Their Alloys In Molten Salts, Qiqin Yang
Studies On Electrodeposition Of Rare Earth Metals And Their Alloys In Molten Salts, Qiqin Yang
Journal of Electrochemistry
The cyclic voltammetry, convolution voltammetry, potentiostatic electrolysis and open circuit potential time curve after electrolysis, current time curve at potential step, potential time curve at current step, X-ray diffraction, EDAX, electron probe microanalysis were used to investigate the electrode processes of the reduction of rare earth ions on inert electrodes and alloying electrodes in molten chlorides and fluorides. The free energies of formation for the intermetallic compounds, the diffusion coefficients of rare earth ions in the melt, the diffusion coefficients of rare earth atoms in the alloy phases were determined. The alloys of rare earth with iron, cobalt, nickel, copper, …
An Analysis On The Microstructure Of Electrodeposited Zro2-Ni Functionally Graded Materials, Chengjun Quan, Xinghua Xiang, Jingchuan Zhu, Zhongda Yin
An Analysis On The Microstructure Of Electrodeposited Zro2-Ni Functionally Graded Materials, Chengjun Quan, Xinghua Xiang, Jingchuan Zhu, Zhongda Yin
Journal of Electrochemistry
The electrodeposited ZrO2-Ni functionally graded coating was fabricated by controlling the ZrO2 concentration in the bath, and the microstructure was analyzed by X-Ray Diffraction (XRD) and Electron Probe Microanalysis (EPMA). The results show that the functionally graded coating has excellent compositional gradient distribution from the substrate to the surface. The content of ZrO2 is up to 14.4 vol% in the surface layer and the coating consists of the t-ZrO2, m-ZrO2 and Ni phases. Owing to the ZrO2 particles pressed by Ni atoms during electrodepositing, t→m transformation has occurred.
Surface Modification Of Molten Carbonate Fuel Cell Anode, Baizeng Fang, Xinyu Liu, Xindong Wang, Shuzhen Duan
Surface Modification Of Molten Carbonate Fuel Cell Anode, Baizeng Fang, Xinyu Liu, Xindong Wang, Shuzhen Duan
Journal of Electrochemistry
In this study, the anode material of molten carbonate fuel cell was modified by the deposition of niobium on nickel surface. The results of polarization experiments reveal that the corrosion resistant properties as well as electrocatalytic activity have been improved greatly.
Study Of Electrodepositing Bright Tin Cobalt Zinc Alloy From Weak Acid Solution, Zhengzhong Zuo, Runxiang Hou, Shaochun Xia
Study Of Electrodepositing Bright Tin Cobalt Zinc Alloy From Weak Acid Solution, Zhengzhong Zuo, Runxiang Hou, Shaochun Xia
Journal of Electrochemistry
A new process of electrodeposting bright Tin Cobalt Zinc alloy from weak acid solution is proposed in this paper. The solution compositions and operating conditions are Na3C6H5O7·2H2O 100~150, Na2EDTA·2H2O 20~30, SnCl2·2H2O 15~20, CoSO4·72H2O 25~35, ZnCl2 15~20 g·L-1; stabilizer WDZ-160~100, brightener WDZ-215~20 mL·L-1; pH=4~6, DK=0.5~5.0 A·dm-2, T=5~35 ℃. A bright Sn-Co-Zn deposit having Co about 0.5~3.5% and Zn about 1~10% is produced. The effects of bath compositions on Co or …
Electroluminescence Of Photoelectrochemically Etched N+-Si, Guozheng Li, Chengqian Zhang, Xiumei Yang
Electroluminescence Of Photoelectrochemically Etched N+-Si, Guozheng Li, Chengqian Zhang, Xiumei Yang
Journal of Electrochemistry
Porous silicon with micrometer size pores, which is made on n+-Si by photoelectrochemically etched, has electroluminescent property. Each monochromic intensity and wavelength range of luminescent spectra depend on polarized potential. The intersity and the stability of cathodic electroluminescence is high than those of anodic one. Voltammetric behavior before quenching indicated that the electrochemical reactions of some surface species are involved in except the reduction of S2O82-, which leads to radiative recombination. The energy band diagram based on n+-Si(Eg=1.1 eV)/PS(Eg=1.8 eV) junction is proposed.
Effects Of Curvature On The Electrochemical Behaviors Of Tubular Electrode, Yirong Wu, Zhenghao Wang
Effects Of Curvature On The Electrochemical Behaviors Of Tubular Electrode, Yirong Wu, Zhenghao Wang
Journal of Electrochemistry
The convective diffusion equation of tubular electrode was solved with the implicit finite difference numerical method. Comparing with the electrochemical behaviors of channel electrode, the behaviors of tubular electrode were analysised. The effects of curvature on the electrochemical behaviors of tubular electrode and the limit of applying Levich approximation to tubular electrode were discussed.
Mechanism And Texture Of Ni-Mo Alloy Electrodeposition, Ling Huang, Shukai Xu, Jaoning Tang, Fangzu Yang, Shaomin Zhou
Mechanism And Texture Of Ni-Mo Alloy Electrodeposition, Ling Huang, Shukai Xu, Jaoning Tang, Fangzu Yang, Shaomin Zhou
Journal of Electrochemistry
Ni-Mo alloy deposits with (111) preferred orientation was obtained in a solution of 0.22 mol/L NiSO4·6H2O, 0.06 mol/L Na2MoO4·2H2O and 0.3 mol/L Na3C6H5O7·2H2O in temperature from 25℃ to 50℃, and current densities ranged from 10 mA·cm-2 to 30 mA·cm-2. The electrodeposition of Ni-Mo alloy was studied by cylic voltammetry and potential step experiment. It was shown that Ni-Mo alloy is formed by mechanism involving progressive nucleation followed by three dimensional growth of the metal centres. The complex …
Study On The Preparation, Properties And Applications Of The Polymer/Graphite Composite Electrode, Guohua Chen, Jinrui Xu
Study On The Preparation, Properties And Applications Of The Polymer/Graphite Composite Electrode, Guohua Chen, Jinrui Xu
Journal of Electrochemistry
The graphite AS composite electrodes, which show high electric conductivity, high mechanical strength and operationl stability, were prepared by filling and extruding the AS copolymer with graphite powder. It exhibited a substantial hydrogen overvoltage and small residual current in different electrolytes, as compared with glassy carbon electrode. The electrode was applied to the determination of traces of Pb2+ in mineral water, Ag+ in waste water and In3+, Cu2+, Pb2+, Cd2+ in zinc ore, and showed high stability, reproducibility and selectivity. Owing to the existence of abundant polar functioal groups on the …
Studies On An Iron Heteropolyacid Redox Flow Battery, Peiju Sun, Wansheng You, Zhorgyin Tan
Studies On An Iron Heteropolyacid Redox Flow Battery, Peiju Sun, Wansheng You, Zhorgyin Tan
Journal of Electrochemistry
This paper reports a new Fe-HP redox flow cell. The positive and negative electrodes active materials are phosphomolybdic acid and acidified ferrous sulphate solutions respectively. Two activated porous carbon felt electrodes where the electrochemical reactions take place, are separated by a selective cation exchange membrane. The both couples have a suitable electrochemical reversibility on carbon and graphite electrodes. The active materials of the cell have very high stability. Moreover the cell has no life cycle limiting.
Electrochemical Synthesis And Characterization Of Ba-Pb-O And Bi-Pb-O Oxides, Min Xie, Liangzhong Zhao, Cuiying Xu, Jinbiao Zhang
Electrochemical Synthesis And Characterization Of Ba-Pb-O And Bi-Pb-O Oxides, Min Xie, Liangzhong Zhao, Cuiying Xu, Jinbiao Zhang
Journal of Electrochemistry
Pb-based oxides Ba-Pb-O and Bi-Pb-O were synthesized from aqueous solutions by using electrochemical method. The resulting Ba-Pb-O and Bi-Pb-O were characterized using XPS, EDX and XRD. The results show that perovskite BaPb0.9O3 can be electrodeposited on the anode only from strong alkaline solution. In acid aqueous solution, conducting BiPb2Oz oxide is fromed on the anode. In these oxides the nominal valence of lead is +4.
Electrochemical Studies Of Spinel Limn2O4 Rechargeable Lithium Battery, Li Feng, Yuqin Chang, Lie Wu, Hong Li, Yibin San, Tianhong Lu
Electrochemical Studies Of Spinel Limn2O4 Rechargeable Lithium Battery, Li Feng, Yuqin Chang, Lie Wu, Hong Li, Yibin San, Tianhong Lu
Journal of Electrochemistry
The spinel Li intercalation compound LiMn2O4 was prepared and studied using ac impedance and cyclic voltammogram techniques. It was first discussed that the impedance behaviors of LiMn2O4 electrode varied as lithium ion was intercalated in or out the electrode with the help of fractal theory. The Li reversible behaviors in LiMn2O4 electrode were shown by the cyclic voltammogram results.
Problems Of The Study Of Anodic Films On Pb In Sulfuric Acid Solution (Ⅲ), Houtian Liu, Qunzhou Wang, Weifang Zhou, Wenbin Cai
Problems Of The Study Of Anodic Films On Pb In Sulfuric Acid Solution (Ⅲ), Houtian Liu, Qunzhou Wang, Weifang Zhou, Wenbin Cai
Journal of Electrochemistry
The interstitial liquid among the particles in anodic Pb(Ⅱ) films could be the major passage for ion transportation. This is discussed with the mechanism of the cathodic reduction of anodic PbSO4 film and the effect of Sb on the growth of anodic Pb(Ⅱ) oxides film.
Electrochemical Behaviors Of Isoalloxazine Confined In Montomorillonite Olay Modified Electrode, Zhibin Wu, Yuan Lin, Daodao Zhang, Haoqin Wu
Electrochemical Behaviors Of Isoalloxazine Confined In Montomorillonite Olay Modified Electrode, Zhibin Wu, Yuan Lin, Daodao Zhang, Haoqin Wu
Journal of Electrochemistry
A cyclic voltametric investigation of stability and redox properties of isoalloxazne on cetytrimethyammonium bromide (CTAB) modified montomorillonite clay platinium electrode in aqueous solution has been performed. pH dependent film concentrations and apparent diffusion coefficents were measured. The mechanism of the charge transport process with in the clay film were discussed.
Studies On The Cathodic Current Efficiency In The Electrodeposition Ni-Psz Gradient Coating, Jun Li, Dianlong Wang, Li Chen, Xinguo Hu
Studies On The Cathodic Current Efficiency In The Electrodeposition Ni-Psz Gradient Coating, Jun Li, Dianlong Wang, Li Chen, Xinguo Hu
Journal of Electrochemistry
The cathodic current efficiency and the electrochemical behavior in electrodeposition Ni-PSZ gradient coating were investigated by various electrochemical techniques and scanning electron microscope. The results showed that the Ni-PSZ composite coatings can accelerate evolution of hydrogen with the increase of PSZ content. The overpotential of nickel reduction will be increased and that of hydrogen reaction will be reduced in the presence of PSZ particles in electrolyte. The effect of PSZ particles on nickel electrodeposition was preferentially to catalyze the formation of H ads . These all contributed to the lower current efficiency.
Study On Properties Of Magnesium Alloy Electrode With Anodized Film, Yi Chi, Ping Yang, Xiufeng Lin
Study On Properties Of Magnesium Alloy Electrode With Anodized Film, Yi Chi, Ping Yang, Xiufeng Lin
Journal of Electrochemistry
The corrosion resistance of Mg alloy electrode with anodized film in atmosphere is bigger than that of the Mg alloy electrode with chromate film. The corrosion resisance and voltage delay of such electrode with anodized film in NaCl solution changed with anodizing comdition. The effects of composition, morphology and thickness of the anodized film on the peoperty of Mg alloy electrode are discussed.
Surface Modifications Of Carbon Materials Used As Anode Of Lithium Ion Battery Ⅱ. The Carbon Material With Core Shell Structure And Its Positive Effect On Cell Performance Of Graphite Anode, Shuhua Ma, Hanju Guo, Ji Li, Hongze Liang, Xiabin Jing, Fosong Wang
Surface Modifications Of Carbon Materials Used As Anode Of Lithium Ion Battery Ⅱ. The Carbon Material With Core Shell Structure And Its Positive Effect On Cell Performance Of Graphite Anode, Shuhua Ma, Hanju Guo, Ji Li, Hongze Liang, Xiabin Jing, Fosong Wang
Journal of Electrochemistry
The carbon powders and film electrode with core shell structure were prepared by carbonization in gas state with using refined coal as shell material and Artificial Graphite and Mesocarbon Microbeads (2 800 ℃) graphite as core material. Galvanostatic charge/discharge measurement showed that both steady charge/discharge capacity and first charge/discharge efficiency were improved. Cyclic voltammetry indicated that the peak at about 0.7 V vs. Li+/Li characteristic of decomposition of electrolyte got weakened, and a more compact film was formed. X-ray diffraction measurement suggested the existence of amorphous carbon shell on the carbon powders and carbon film.
A Study On The Electrodeposition Of Palladium And It's Nucleation, Fangzu Yang, Shukai Xu, Shibing Yao, Bingyi Chen, Xueqing Zheng, Xiaohui Zhong, Shaomin Zhou
A Study On The Electrodeposition Of Palladium And It's Nucleation, Fangzu Yang, Shukai Xu, Shibing Yao, Bingyi Chen, Xueqing Zheng, Xiaohui Zhong, Shaomin Zhou
Journal of Electrochemistry
The electrodeposition and nucleation of palladium are studied in the system of potassium citrate and ammonium oxalate. The results show that, with the additives of XP-4 and XP-7 prepared in our laboratory, a full bright palladium electrodeposits will be obtained in the wide ranges of the cathode current densities 0.5~3.5 A/dm2 and temperature 40~60 ℃; the qualities of the thick deposits will be effectively improved by means of pulse current plating. Cyclic voltammograms results show that the division of peaks between anodic and cathodic on the electrode process of palladium will be up to 1.05 V, which shows the …
Studies Of Electrochemical Behaviors Of Cytochrome C On Pretreated Gold Electrode, Jin Luo, Lingling Wu, Shaohua Huang, Zhonghua Lin
Studies Of Electrochemical Behaviors Of Cytochrome C On Pretreated Gold Electrode, Jin Luo, Lingling Wu, Shaohua Huang, Zhonghua Lin
Journal of Electrochemistry
The quasi reversible responses of both adsorbed and bulk cytochrome c at the pretreated gold electrode are observed. The adsorption behaviors and reaction kinetics have been studied using in situ FTIR spectroscopy, UV/Vis reflection spectroscopy, voltammetry, AC impedance and potential step methods. The results show that the cytochrome c can irreversibly adsorb on the gold surface in a complete monolayer and the adsorbed layer can mediate the redox reaction of the cytochrome c in the solution in the absence of promoter.
Electrochemical Studies Of Cyanocobalamin On Silver Electrode, Zhai Jin, Yang Pin, Donghong Zheng, Junwei Zheng, Tianhong Lu
Electrochemical Studies Of Cyanocobalamin On Silver Electrode, Zhai Jin, Yang Pin, Donghong Zheng, Junwei Zheng, Tianhong Lu
Journal of Electrochemistry
The electrochemical characteristics of cyanocobalamin were separately studied on smooth and roughed silver electrode. It was found that the reduction of cyanocobalamin is two one electron steps on roughed silver but one two electron step on smooth electrode. The reason is due to the ability of absorption of the surface of electrode.
The Preparation Of Heteropoly Compound Polypyrrole Film Modified Electrode And Its Electrochemical Properties, Weiqing Wang, Xiumei Zhang, Long Cheng, Baifeng Liu, Shaojun Dong
The Preparation Of Heteropoly Compound Polypyrrole Film Modified Electrode And Its Electrochemical Properties, Weiqing Wang, Xiumei Zhang, Long Cheng, Baifeng Liu, Shaojun Dong
Journal of Electrochemistry
Electronically conducting polypyrrole doped with heteropolyanions K10H3[Nd(SiMo7W4)2]·xH2O(denoted as [Nd(SiMo7W4)2]13-) was synthesized by electrochemical polymerization. This modified electrode maintains the electrochemical and electrocatalytic properties of heteropolyanion, with having good stability and electrocatalytic activity on the reduction of nitric oxide in acidic aqueous solution.
Surface Modifications Of Carbon Materials Used As Anode Of Lithium Ion Battery Ⅰ. Influences Of Oxidation And Reduction Pretreatment On Anode Performance, Shuhua Ma, Hanju Guo, Ji Li, Hongze Liang, Xiabin Jing, Fosong Wang
Surface Modifications Of Carbon Materials Used As Anode Of Lithium Ion Battery Ⅰ. Influences Of Oxidation And Reduction Pretreatment On Anode Performance, Shuhua Ma, Hanju Guo, Ji Li, Hongze Liang, Xiabin Jing, Fosong Wang
Journal of Electrochemistry
The influences of the trace oxygen containing functional groups on surface of carbon material on cell performance of carbon anode for lithium ion batteries were studied by means of the pretreament in various oxidant/reductant systems. The results showed that the rich oxygen containing functional groups impaired the cell performance of carbon material anode, and the reduction of these groups in quantity and oxidation degree can increase charge/discharge capacity and improve first charge/discharge efficiency. The reason was also discussed in the light of effects of surface organic groups on decomposition reactivity of electrolyte and formation process of surface passivating film.
The Current Distribution On The Anode Surface Of The Seale Oval Tubular Lead Acid Battery, Renao Gu, Jianlin Yao, Zhengfa Deng, Ru Sun, Liren Wu, Zhongsi Jiang, Wangen Miao
The Current Distribution On The Anode Surface Of The Seale Oval Tubular Lead Acid Battery, Renao Gu, Jianlin Yao, Zhengfa Deng, Ru Sun, Liren Wu, Zhongsi Jiang, Wangen Miao
Journal of Electrochemistry
The current distribution on anode surface of sealed lead acid batter under different discharge current and degree was studied by chemical analytical method for the first time. We can conclude that the current distribution is not even. The current density on the edge of the electrode surface and the electrode terminal are bigger than other areas, that is, there are edge effect and terminal effect, and these effect are more obvious when the discharge current is 100 A and degree is 100%.
High Active Platinum Plated Titanium Electrode, Xiufeng Xiao, Zeshan Zhu, Yanzhen Chen, Wenyun Hu
High Active Platinum Plated Titanium Electrode, Xiufeng Xiao, Zeshan Zhu, Yanzhen Chen, Wenyun Hu
Journal of Electrochemistry
To prepare the adherent and high active platinum plated titanium electrode, ultrasonic agitation technology and the best conditions of electrodeposition were adopted. Ultrasonic agitation technology can be improved the cohesion between coatings and substrate. The activity of electrode has related to the double layer capacity of electrode, which was due to the electrode rugosity.