Chemistry Commons^™

Influence Of The Nature Of The Medium On The Conformational States Of Macromolecules Of Anionic Polyelectrolytes And Their Flocculating Effect, Mapruza Dzhumamuratova, Amanbay Pirniyazov, Oleg Dormeshkin, Akhmed Reymov, Tleumuratov Kuanish, Saparbay Kalbaev

Karakalpak Scientific Journal

The properties of surfactants of anionic polyelectrolytes are investigated depending on the nature of the medium, conformational states neutralized by organic bases, differing in the length of the hydrocarbon radical. The concept of the role of the state of macromolecules in solution in the indicated processes has been developed. The anionic carboxyl-containing polyelectrolytes synthesized on the basis of methacrylic acid differed not only in the length of the hydrocarbon radical of the organic base - counterion, but also in their branching. The relationship between the state of polyelectrolyte macromolecules in solution and their ability to regulate the properties of natural …

Features Of Heart Activity Of Cattle In The Conditions Of Southern Aral Sea Region, Svetlana Mambetullaeva, Khayratdin Seytkamalov

Karakalpak Scientific Journal

In this article, the results of comparative analysis of electrocardiogram are shown for the cows of different breeds in the Aral Sea region. It is set that the high temperature of the environment and sunny insolation render a negative influence on the functional parameters of the cardiac vascular system of animals. There are facts about the cows of different breeds at the influence of different temperatures that have unidirectional functional changes in the operation of the heart. At the same time, we will mark that these changes are less expressed for the cows of the improved zebu visible cattle, what …

Photoelectric Injection Amplification Of Al–Al2o3–P-Cdte–Mo Structures At Low Bias Voltages, A K. Uteniyazov

Karakalpak Scientific Journal

The results of studies of photoelectric injection enhancement of the Al–Al₂O₃–p-CdTe –Mo structure upon application of low bias voltages. It has been shown that the studied Al-Al₂O₃–p-CdTe-Mo structure under can be represented as a n⁺-p-R_ом structure with a long base. Conducted researches show that Al-Al₂O₃–p-CdTe-Mo structure has unique properties. It has very high photocurrent and photosensitivity at both direct and reverse dias voltage under even small bias voltage (up to 500mV).

Synthesis Of Supramolecular Complex L– (-) – Menthol, Ziyada Djumanova Dr, Lolaxan Ettibaeva, Ugilay Abduraxmonova, Zulfiya Khalmuratova

Karakalpak Scientific Journal

In this article glycyrrhizic acid content with menthol in several various proportions (2:1; 4:1; 9:1), information was given on synthesis and physical and chemical properties of new supermolecular complexes. Received supramolecular complexes concerning 4:1 it was chemically defined and also studied the structure of supramolecular complexes by physical methods on the basis of interaction of organic molecules with electromagnetic radiation, in particular their range IR – of spectroscopy. Our work of the near future will be turned to check its recent supramolecular complexes on the basis of GA: Menthol for growth of a plant and biotic elasticity of tension …

Spectrophotometric Characterization Of The Complexation Of Gossypol Acetic Acid With Cobalt Ion, Ugilay Abdurahmanova, Habibjon Kushiev, Maral Askarova, Dilafruz Allanazarova

Karakalpak Scientific Journal

The authors of the article suggest simple and express method of spectrophotometric determination of cobalt with the help of derivatives of gossypol. Optimal conditions of determining cobalt are found. Under optimal conditions there was created a graded graph, which is more linear in the range for cobalt concentration of 10.0 – 50.0 microgram/25 ml, contents and constants of cobalt complex with gossypol vinegar acid.

Stabilizing Capability Of Gum Arabic On The Synthesis Of Poly(Styrene-Methylmethacrylate-Acrylic Acid) Latex For The Generation Of Colloidal Crystal Films, Ikhazuagbe Ifijen, Stanley Omorogbe, Muniratu Maliki, Ifeanyi Odiachi, Aireguamen Aigbodion, Esther Ikhuoria

Tanzania Journal of Science

This article describes the generation and characterization of colloidal crystals from particles of gum arabic (GA) and sodium dodecylbenzene sulfate (SDBS) emulsified poly(styrene methylmethacrylate-acrylic acid) (P(St-MMA-AA) latex. The colloidal latex was synthesized using GA and SDBS as the emulsifying agents and then used to generate colloidal crystal films via the vertical deposition technique. Dynamic light scattering analysis placed the average particle diameter, polydispersity and Zeta potential at about 122 nm, 0.014 and –36.20 mV for the as-synthesized GA emulsified terpolymer latex and 213 nm, 0.006, –35.60 mV for the SDBS emulsified terpolymer latex, respectively. Thermo-gravimetric analysis and differential scanning calorimetry …

Fuzzy Synergetic Control Nonlinear Dynamic Objects, Isomiddin Sidikov, Noilakhon Yakubova, Komil Usmanov, Saparbay Kazakhbayev

Karakalpak Scientific Journal

The article deals with the synthesis of effective algorithms for controlling a chemical reactor and developed a fuzzy synergistic controller for a class of indefinite nonlinear dynamic systems. A synergetic control scheme is proposed for solving the control problem for nonlinear systems. Non-linear systems with configurations and parameters that change over time require a completely non-linear model and adaptive control scheme for a practical operating environment. The synthesis of control laws is performed by the method of analytical design of aggregated controllers (ACAR). Fuzzy logic systems are used to evaluate the unknown nonlinear behavior of the system, and a new …

Synthesis, Characterisation And Biological Evaluation Of Tyramine Derived Schiff Base Ligand And Its Transition Metal(Ii) Complexes, Abdul Khader Jailani, N.S.K. Gowthaman, Mookkandi Palsamy Kesavan

Karbala International Journal of Modern Science

In this study, a new tyramine derived Schiff base ligand (L) (L=1,3-phenylene-bis-4-aminoantipyrinyl-4-aminoethylphenol) and its derived transition metal(II) complexes [Cu(L)Cl₂](1), [Ni(L)Cl₂](2), [Co(L)Cl₂] (3) and [Zn(L)Cl₂] (4) have been synthesized and well characterized by the way of different spectroscopic and analytical techniques. Analytical and spectroscopic studies result suggests that metal(II) complexes more probably have octahedral geometry. DNA binding tendency of L and metal(II) complexes 1-4 have been assessed by probing their ability to bind with Calf Thymus DNA (CT-DNA) via electronic absorption and cyclic voltammetry titration methods. The results clearly reveal that the metal(II) …

Evaluation Of Structure And Properties Of Various Sol–Gel Nanocoatings On Biomedical Titanium Surface, Mohsin Talib Mohammed, Sarah Mohammed Hussein

Karbala International Journal of Modern Science

This study deals with the preparation and characterization of different bioceramic nanofilms formed on the surface of new metastable β-titanium (Ti) alloy. The films of pure TiO₂, pure HA, TiO₂/HA bilayer and HA/TiO₂ composite were coated successfully on Ti surface by sol-gel using spray pyrolysis deposition technique. The surface characteristics of coated substrates, such as thickness, topography, morphology, phase transformations and wear behavior, were evaluated and compared to uncoated substrate. The results showed that the sol-gel is a promising technique to create biocoatings on Ti surface with outstanding structure and properties for biomedical applications.

On The Dynamic Behaviour Of Automobile Pulleys Under Cyclic Loading, Haval Kamal Asker, Thaker Saleh Dawood

Karbala International Journal of Modern Science

This paper investigates the dynamic characteristics of pulley systems with different numbers of bolt holes. Models with four, six and eight bolt holes were chosen for the pulley. Three sets of cyclic pressure were applied to the pulley system to resemble the different running revolutions of an engine. The study investigates the effect of the number of holes on the system’s stiffness and natural frequency. Finite element models were used to simulate the obtained deformations, stresses and frequency response function (FRF) for pulley models comprising four, six and eight bolt holes under different cyclic pressures. The results show that the …

Optically Thick Radiating Free Convective Mhd Nanofluid Flow Over An Exponentially Accelerated Plate, D.P. Bhatta, S.R. Mishra, J.K. Dash

Karbala International Journal of Modern Science

The present analysis investigates an unsteady conducting water-based nanofluid embedding with porous medium over an exponentially accelerated vertical plate. The plate is accelerated with moving ramped temperature. However, water is treated as the base fluid with Copper (Cu) and Titanium Oxide (TiO₂) as nanoparticles. Effects of thermal radiation, heat source, and radiation absorption are taken care of in the energy equation which may enhance the heat transfer properties of nanofluid. The crux of the investigation is to find the closed-form solution of nonlinear coupled partial differential equations. Laplace Transform technique is employed to solve these equations. The influence …

A Support Vector Machine-Based Prediction Model For Electrochemical Machining Process, Subham Agarwal Mr., Shruti Sudhakar Dandge Ms., Shankar Chakraborty Prof.

Karbala International Journal of Modern Science

Manufacturing of quality products is one of the core measures to address competitiveness in industries. Hence, it is always necessary to accomplish quality prediction at early stages of a manufacturing process to attain high quality products at the minimum possible cost. To achieve this goal, the past researchers have developed and investigated the applications of different intelligent techniques for their effective deployment at various stages of manufacturing processes. In this paper, support vector machine (SVM), a supervised learning system based on a novel artificial intelligence paradigm, is employed for prediction of three responses, like material removal rate, surface roughness and …

Influence Of Carbon Fibres On Strain Sensing And Structural Properties Of Rc Beams Without Stirrups, Arvind Kumar Cholker, Manzoor Ahmad Tantray

Karbala International Journal of Modern Science

In present study, effect of micro carbon fibres on strain sensing property and structural behavior of the reinforced concrete (RC) beams in absence of stirrups was experimentally investigated. A total of three RC beams of dimensions, 125 mm width, 350 mm height and 1500 mm long were manufactured without stirrups. All the three beams had different longitudinal reinforcement ratios (0.9%, 1.43% and 1.03 %) and uniform strength of concrete of 36.5 MPa. All the beams had carbon fibre based concrete (CFBC) at top and bottom surface in mid span for a length of 350mm and depth of 78 mm. All …

Approximating Fixed Points In Modular Spaces, Salwa Salman Abed, Meena Fouad Abduljabbar

Karbala International Journal of Modern Science

A generic two theorems for the two step iterative sequence of multivalued mappings are proved in a complete convex real modular space, and then cite some corollaries that are special cases of these theorems.

Editorial Board

Karbala International Journal of Modern Science

No abstract provided.

Table Of Contents

Journal of the South Carolina Academy of Science

No abstract provided.

Preliminary Investigation Of The Effects Of Sex And Electrical Venom Extraction On Venom Composition In The Southern Devil Scorpion, Vaejovis Carolinianus, Chase Czaykowsky

Capstone Research Projects

No abstract provided.

Antibacterial Properties Of Novel Amphiphiles, Ariana Simeone

Masters Theses, 2020-current

Hospital acquired infections, particularly antibiotic resistant infections, are a growing concern due to their infection and mortality rate, as well as their growing economic burden, and it has been estimated that by the year 2050 the associated mortality rate will be around 10 million deaths per year. A solution to this is better means of prevention, and amphiphiles, compounds with at least one hydrophilic head group and at least one hydrophobic tail, are promising candidates for stopping the spread of infectious bacteria. Novel amphiphiles with two bipyridinium head groups, separated by a hydrophobic carbon spacer of varying lengths, and each …

Toxicity Analysis Of 2’-Deoxyguanosine-N2-6-Aminopyrene And 2’-Deoxyguanosine-N2-8-Aminopyrene In Escherichia Coli, Emily Janeiro

Honors Scholar Theses

Cancer is a disease that stems from genomic errors that are not corrected properly by cellular repair mechanisms. Errors are more likely to form when organisms are subjected to DNA damage by mutagenic compounds. 1-Nitropyrene, a nitrated polycyclic aromatic hydrocarbon (nitro-PAH), has been shown to be a potent mutagen that causes cancer. Nitro-PAHs can arise from diesel exhaust products in the environment. Out of all nitro-PAHs, 1-nitropyrene is found in largest quantities in the environment. This poses a great need to study its effects biochemically in order to address its toxicity in DNA. Other nitropyrene derivatives, including 1,6-dinitropyrene and 1,8-dinitropyrene, …

Volume 12, Haleigh James, Hannah Meyls, Hope Irvin, Megan E. Hlavaty, Samara L. Gall, Austin J. Funk, Karyn Keane, Sarah Ghali, Antonio Harvey, Andrew Jones, Rachel Hazelwood, Madison Schmitz, Marija Venta, Haley Tebo, Jeremiah Gilmer, Bridget Dunn, Benjamin Sullivan, Mckenzie Johnson

Incite: The Journal of Undergraduate Scholarship

Introduction, Dr. Roger A. Byrne, Dean

From the Editor, Dr. Larissa "Kat" Tracy

From the Designers, Rachel English, Rachel Hanson

Immortality in the Mortal World: Otherworldly Intervention in "Lanval" and "The Wife of Bath's Tale" by Haleigh James

Analysis of Phenolic Compounds in Moroccan Olive Oils by HPLC by Hannah Meyls

Art by Hope Irvin

The Effects of Cell Phone Use on Gameplay Enjoyment and Frustration by Megan E. Hlavaty, Samara L. Gall, and Austin J. Funk

Care, No Matter What: Planned Parenthood's Use of Organizational Rhetoric to Expand its Reputation by Karyn Keane

Analysis of Petroleum Products for …

An Experiential Report On The Thayer Method Of Teaching Across College-Level Chemistry, Biology, Math, And Physics Courses, Kevin P. O'Halloran, Sairam Tangirala, Fengjie Sun, Leonard E. Anagho, Gerald Agbegha, Clay Runck, David Roth, Amy H. Erickson

Georgia Journal of Science

The Thayer method of instruction is a little-known active learning technique that dates back to 1817 at the U.S. Military Academy. This study describes the implementation and statistical evaluation of an adaptation of the Thayer method in a variety of college science and math courses. All courses had five characteristics in common: (i) students were given a daily reading schedule and instructed to prepare before class, (ii) each class started with a question and answer session, (iii) class time minimized the use of lecture, (iv) class time maximized the use of active learning, and (v) students were frequently quizzed. A …

Senior Project: An Investigative Study Into The Bacterial Contamination Of Little Black Creek, Margaret I. Brenneman

Honors Projects

An investigation of Escherichia coli concentrations in a west Michigan stream was conducted to determine sources of fecal contamination that impact water quality. Little Black Creek (LBC) is located in Muskegon County and discharges into Lake Michigan at the P.J. Hoffmaster Campground Beach. Often referred to as an “indicator bacteria,” water contaminated with E. coli has a high probability to contain other enteric pathogens as well. Beach water testing in 2020 using Colilert-18 methods revealed E. coli levels of 579 cfu/100mL in the creek discharge area that exceeded total body contact criteria of 300 cfu/100mL. A follow-up study of the …

Current And Future Applications Of 3d Printing Using Custom-Made Materials, Bridger T. Irons

Honors Thesis

The use of 3D printers has increased exponentially from its inception in the 1980s. Recently, the ability to design and create detailed objects has drawn the attention of many who wish to capitalize on this highly customizable process. With much of the focus in this industry being placed on finding new printable materials, many are overlooking the possibility of modifying existing materials. The aim of our research was to modify the materials already being used by 3D printers to alter their properties and explore future possible applications. We examined the addition of graphene powder, carbon microfibers, and other nanoparticles to …

Study Of Deformation Parameters (Β2, Δ) For 18,20,22,24,26,28ne Isotopes In Sdpf Shell, Ahmed H. Ali, Maha Taha Idrees

Karbala International Journal of Modern Science

The quadrupole deformation is basic to study the shape transitions; it is possible to predict many important properties of even-even nuclei as a function of the deformation parameter. The deformations of nuclei are important for understanding their shapes prolate or oblate. The quadrupole deformation parameters were calculated by the transition probability B (E2) for ^{18, 20, 22, 24, 26,28}Ne isotopes, were adopted different interactions three. The calculations are performed with the Bohr-Mottelson (B-M) effective charges, which represent the effect of the core-polarizations. Also, the deformation parameters were calculated for different nuclei and adopted two methods of calculation: from reduced …

Investigation Of Glucose Oxidation At Gold Nanoparticles Deposited At Carbon Nanotubes Modified Glassy Carbon Electrode By Theoretical And Experimental Methods., Farhat Saira, Humaira Razzaq, Misbah Mumtaz, Safeer Ahmad, Muhammad Aftab Rafiq, Azra Yaqub, Nabiha Dilshad, Ayesha Ihsan, Muhammad Masood Ul Hasan

Karbala International Journal of Modern Science

In the current research work, AuNPs-CNTs nanocomposite was synthesized chemically and decoration of AuNPs on the surface of MWCNTs was confirmed by UV-Vis, SEM and XPS analysis. Synthesized nanocomposite was utilized for its application towards non-enzymatic glucose sensing by modifying glassy carbon electrode with nanocomposite employing electrochemical techniques. In addition, theoretical calculations were performed by Density Functional Theory (DFT), employing B3YLP with basis set 6- 311+G(d,p) in gaseous phase and LANL2DZ basis set. Both theoretical and experimental results predicted Au-CNTs composite as a better candidate for glucose oxidation as compared to CNTs and AuNPs alone, owing to the synergistic effect …

A Study To Explore The Ldlr Gene Polymorphisms Contribute To Atorvastatin Response In A Sample Of Iraqi Population With Atherosclerotic Coronary Artery Disease, Shaimaa Y. Abdulfattah, Salwa J. Abdullah, Hilal B. Alsaffar

Karbala International Journal of Modern Science

Genetic factors will determine the higher variability, which found in response to lipid reduction treatment (statins). However, due to ethnicity the frequency and effect of single nucleotide polymorphisms (SNPs) may differ. The main aim of lipid lowering medical treatment is to eventually prevent the endogenous production of cholesterol through inhibition of HMG-CoA reductase, The resulting decrease in hepatocyte cholesterol concentration triggers up-regulation of low-density lipoprotein (LDL)-receptor expression by inducing sterol regulatory element-binding protein (SREBP) 2 cleavage, as SREBP-2 activates LDL receptor transcription. The aim of this study was to evaluate the effects of low density lipoprotein receptor (LDL-R) …

Using Freak Descriptor To Classify Plasma Influence In Mice Sperm, Ekhlas Falih, Alaa Noori Mazhar

Karbala International Journal of Modern Science

Numerous classification mechanisms anticipate the class's instances to be carried out as the features' vectors, namely the points in a feature's space. It is oftentimes a chance to make an informative exemplification of an image's feature vector for classification problems in computer vision like utilizing global descriptors for the texture description or shape description. The proposed methodology is to classify the sperm image in mice that has been affected through plasma and this methodology consists of three stages. The points of interest could be elicited from sperm plasma images in the first stage by utilizing Adaptive and Generic Corner detector …

Editorial Board

Karbala International Journal of Modern Science

No abstract provided.

Semester-Long Course-Based Research Project In Second-Semester Organic Chemistry: Synthesizing Potential Lead Compounds For The Treatment Of A Neglected Tropical Disease, Kerry L. Barnett, Kevin M. Shea, Catherine Mcgeough, Kristine Trotta, Steven A. Williams, Minh Ly, Kathryn Aloisio

Chemistry: Faculty Publications

A semester-long research project for second-semester organic chemistry lab sections was developed. Student projects were based on preliminary data from faculty research that suggested the natural product neurolenin B to be a treatment for lymphatic filariasis. Students isolated neurolenins from the Central American plant Neurolaena lobata and proposed syntheses of previously unknown analogues using reactions learned in first- and second-semester organic chemistry. Using literature-based procedures, students ran reactions on neurolenins and analyzed their results by TLC and NMR spectroscopy. The semester culminated with a public poster session and final report using the Organic Letters template. Students in a total of …

Hydrophilic Porphyrins Based Chemosensors For First Transition Series Metal Ions [Chemistry], Sunaina Singh

Open Educational Resources

General Chemistry is a two-semester course (General Chemistry I, SCC 201 and General Chemistry II, SCC 202) required for majors in Biology and Environmental Sciences.

This lab experiment, aligned to LaGuardia Community College’s Inquiry and Problem Solving Core Competency and Written Communication Ability was designed for General Chemistry I (SCC 201 Honors) course. Honors courses in LaGuardia emphasize critical thinking, analytical writing, and introduce students to research. This lab experiment provides an opportunity for students to engage in hands-on laboratory work, to develop laboratory skills, and to conduct research in the classroom by using two water soluble porphyrins to detect …