Physical Sciences and Mathematics Commons^™

Laboratory Measurements Of Contact Nucleation By Mineral Dusts, Bacteria, And Soluble Salts, Joseph Niehaus

Dissertations, Master's Theses and Master's Reports

We present results from experiments that emulate atmospheric ice nucleation by aerosols. We have refined experimental techniques to improve measurements of ice forming nuclei in the contact mode. Our results show that atmospherically relevant dusts such as kaolinite, feldspar, rhyolitic ash, and Arizona Test Dust have efficiencies in the contact mode that are higher than the immersion mode. Experiments with bacteria show that biological material has the potential to contribute significantly to ice concentrations, but has large variability. By choosing a soluble compound as an ice nucleus, we are able to place bounds on the timescale for contact freezing and …

Petrophysical And Empirical And Theoretical Rock Physics Modeling For The Moki Formation In Two Fields In The Taranaki Basin, New Zealand, Deniz Yener

Dissertations, Master's Theses and Master's Reports

This work consists of conventional petrophysical analysis and sonic response determination from empirical relations, rock physics modelling, and fluid substitution for six wells in the Moki formation of New Zealand’s Taranaki Basin. The project composed of three parts encompassing conventional log analysis, rock-physics modeling using empirical and theoretical approaches, and finally rock-physics modeling for shaley sands using semi-empirical adaptations to Gassmann fluid substitution. Finally, comparisons are made between results for the different wells, based on their depths and mineralogy.

The first part of this study is presented as a petrophysical analysis, including crossplot analysis, conventional 3-mineral identification approach, and determination …

Maia And Mandos: Tools For Integrity Protection On Arbitrary Files, Paul J. Bonamy

Dissertations, Master's Theses and Master's Reports

We present the results of our dissertation research, which focuses on practical means of protecting system data integrity. In particular, we present Maia, a language for describing integrity constraints on arbitrary file types, and Mandos, a Linux Security Module which uses verify-on-close to enforce mandatory integrity guarantees. We also provide details of a Maia-based verifier generator, demonstrate that Maia and Mandos introduce minimal delay in performing their tasks, and include a selection of sample Maia specifications.

Investigation Of The Resistance To Demagnetization In Bulk Rare-Earth Magnets Comprised Of Crystallographically-Aligned, Single-Domain Crystallites With Modified Intergranular Phase, Jie Li

Dissertations, Master's Theses and Master's Reports

The research presented in this dissertation investigates whether an increased coercivity of Neodymium-Iron-Boron (Nd2Fe14B) based bulk magnets at elevated temperature (160°C), which is now only obtainable by substituting ~7wt% dysprosium (Dy) for a portion of neodymium (Nd), can be achieved through specific microstructural modifications with decreased Dy concentrations. The approach is to reduce the size of individual crystallographically-aligned grains in the magnet so that each grain can only support a single magnetic domain and to simultaneously dilute the Nd-Fe inter-granular phase present in conventional magnets with a non-Fe-containing, Nd-rich phase (Nd-Cu alloy) in an attempt to partially magnetically isolate the …

Effect Of Disulfide Bond Scrambling On Protein Stability, Aggregation, And Cytotoxicity, Colina Dutta

Dissertations, Master's Theses and Master's Reports

Proteins are nano-machines that carry out majority of the cellular functions. Thermodynamically they are functional and stable within a very narrow range (1 kcal/mol). External perturbations in the form of pH change, thermal, or oxidative/reducing stress can destabilize the protein resulting in misfolding and aggregation. Prolonged environmental stress can affect the cells adaptive response resulting in loss of ability to refold or recycle proteins. This can lead to accumulation of misfolded or aggregated proteins within the cell. Such accumulation of aggregated proteins have been associated with neurodegenerative disorders such as Amyotrophic Lateral Sclerosis (ALS), Parkinson’s, Huntington’s, and Alzheimer’s disease. There …

Assessing The Impacts Of Climate Change On The Surface Temperature Of Inland Lakes In Michigan, Kaitlin Reinl

Dissertations, Master's Theses and Master's Reports

The aim of this study was to validate and apply a lake model for predicting the susceptibility of small inland lakes in Michigan to changes in thermal regime and increased cyanobacteria growth as a result of future climate conditions. The Freshwater Lake Model was selected, tested for sensitivity to various inputs, and validated through comparison to observed conditions. The sensitivity analysis showed that the lake model was most sensitive to solar radiation, air temperature, and air humidity. Comparison of predicted climate data with observed conditions revealed highly variable climate model error. The lake model validation was conducted using 10 lakes …

Improved Parameter Estimation Of The Log-Logistic Distribution With Applications, Joseph Reath

Dissertations, Master's Theses and Master's Reports

In this report, we work with parameter estimation of the log-logistic distribution. We first consider one of the most common methods encountered in the literature, the maximum likelihood (ML) method. However, it is widely known that the maximum likelihood estimators (MLEs) are usually biased with a finite sample size. This motivates a study of obtaining unbiased or nearly unbiased estimators for this distribution. Specifically, we consider a certain `corrective' approach and Efron's bootstrap resampling method, which both can reduce the biases of the MLEs to the second order of magnitude. As a comparison, we also consider the generalized moments (GM) …

A High Accuracy Minimally Invasive Regularization Technique For Navier-Stokes Equations At High Reynolds Number, Mustafa Aggul

Dissertations, Master's Theses and Master's Reports

A method is presented, that combines the defect and deferred correction approaches to approximate solutions of Navier-Stokes equations at high Reynolds number. The method is of high accuracy in both space and time, and it allows for the usage of legacy codes (a frequent requirement in the simulation of turbulent flows in complex geometries). The two-step method is considered here; in order to obtain a regularization that is second order accurate in space and time, the method computes a low-order accurate, stable and computationally inexpensive approximation (Backward Euler with artificial viscosity) twice. The results are readily extendable to the higher …

Cave Detection Using Seismic Methods At Madison Blue Spring State Park, Madison County, Florida, Charles Breithaupt

Dissertations, Master's Theses and Master's Reports

Locating caves and quantifying their geometries has significant importance in aquifer characterization, sinkhole mitigation, and contaminant transport monitoring. Several geophysical methods have been used for cave detection with limited success, but no reliable solution has been found. New developments in seismic techniques, however, show promising results indicating that cave voids may be more accurately detected.

We evaluated the capability of several seismic techniques to detect caves by collecting new seismic data over a known conduit connected to Madison Blue Spring, in northern Florida. These analyses validated the abilities of diffracted surface waves to detect water-filled caves by viewing these data …

Comparisons Of Seismic Interferometry By Cross Correlation, Deconvolution, And Cross Coherence, Haitao Cao

Dissertations, Master's Theses and Master's Reports

Ambient noise seismic interferometry (ANSI) has been applied widely for geophysical investigations including earthquake tomography, civil engineering and seismic exploration purposes. Comparing this approach with the traditional active seismic survey, the application of ANSI is cost effective, environmentally friendly and easily repeatable. Conventional seismic interferometry by cross correlating wavefields recorded at different receivers has already obtained fruitful results.

Even though the application of seismic interferometry (SI) by cross correlation has been successful, different methods for the processing workflow such as cross coherence and deconvolution have been conducted in an effort to improve the resolution. While these three methods have been …

Defect-Deferred Correction Method For The Two-Domain Convection-Dominated Convection-Diffusion Problem, Dilek Erkmen

Dissertations, Master's Theses and Master's Reports

We present a method for solving a fluid-fluid interaction problem (two convection-dominated convection-diusion problems adjoined by an interface), which is a simplifed version of the atmosphere ocean coupling problem. The method resolves some of the issues that can be crucial to the fluid-fluid interaction problems: it is a partitioned time stepping method, yet it is of high order accuracy in both space and time (the two-step algorithm considered in this report provides second order accuracy); it allows for the usage of the legacy codes (which is a common requirement when resolving flows in complex geometries), yet it can be applied …

Enhancement Of Margrave Deconvolution And Q Estimation In Highly Attenuating Media Using The Modified S-Transform, Adnan Djeffal

Dissertations, Master's Theses and Master's Reports

We evaluate the performance of the Margrave deconvolution and spectral ratio methods using the Gabor, S-, and modified S transforms in highly attenuating media, where the quality factor changes with depth dramatically. Our results substantiate that the modified S-transform deconvolution is more robust in terms of generating fewer artifacts and providing better estimates of reflectivities than the Gabor transform. The results also show that using the modified S-transform in the spectral ratio method produces better Q estimates than the S-transform and the Fourier transform that is conventionally used in the spectral ratio method. This improvement in the estimates of reflectivities …

Reservoir Characterization Through Pre-Stack Seismic Analysis And Inversion In The Thrace Basin, Northwest Turkey, Emre Doguturk

Dissertations, Master's Theses and Master's Reports

This study analyzes hydrocarbon reservoirs by using Amplitude-Versus-Offset (AVO) analysis and different inversion methods to investigate hydrocarbon reservoir in the Thrace Basin which is located in northwest Turkey.

A 3D seismic survey containing prestack data was provided by Turkish Petroleum Corporation as true amplitude NMO corrected 3D gathers.

The quality of this land data was poor for AVO applications, and steps were taken to make it useful. Radon filtering proved to be extremely useful for this purpose. Although application of this filter affected the AVO characteristics differently depending on the parameters selected for the filter, relative AVO characteristics remained useful …

Can Seismic Velocity Stacking Errors Result In The Low-Frequency Shadow?, Umit Serhan Inan

Dissertations, Master's Theses and Master's Reports

The low-frequency shadow is the area on reflection seismic data, underneath gas reservoirs, that exhibits anomalously low frequency. This phenomenon has been related to the highly attenuating nature of the gas reservoir, which could explain the low-frequency shadows observed underneath extremely thick reservoirs, but not the ones underneath thin reservoirs. There are several other mechanisms that could be responsible, however detailed analysis of these possible explanations is yet to be found in the literature.

The main focus of this research is to test the possible contribution of stacking of offset seismic data, namely, their mis-stacking, to the generation of the …

Communication Patterns And Strategies In Software Development Communities Of Practice, Shreya Kumar

Dissertations, Master's Theses and Master's Reports

Some of the greatest challenges in the relatively new field of software development lie in the decidedly old technology of communication between humans. Software projects require sophisticated and varied communication skills because software developers work in a world of incomplete, imperfect information where teams evolve rapidly in response to evolving requirements and changing collaborators. While prescriptive models for software process such as Agile suggest ways of doing, in reality these codified practices must adapt to the complexities of a real workplace. Patterns, rather than rules of behavior within software process are more suitable to the varied and mutable nature of …

Single Particle-Inductively Coupled Plasma-Mass Spectrometry Technology Development For Metallic Nanoparticle Characterization In Complex Matrices, Yongbo Dan

Doctoral Dissertations

"As the rapid growing of nanotechnology, the release of engineered nanoparticles (ENPs) into the environment is inevitable. After entering the real environment, ENPs tend to react with different components of the ecosystem (e.g. water, soil, air, plants) and make their characterization difficult. Analyzing ENPs in these complex matrices still remains as a grand challenge. ENPs characterization is normally the first step of risk assessment. Current analytical techniques have shown some limitations in revealing the unique characteristics of ENPs in complex matrices and reliable analytical techniques are in urgent need. Single particle inductively coupled plasma mass spectrometry (SP-ICP-MS) is an emerging …

Modeling Daily Electricity Load Curve Using Cubic Splines And Functional Principal Components, Abdelmonaem Salem Jornaz

Doctoral Dissertations

"Forecasting electricity load is very important to the electric utilities as well as producers of power because accurate predictions can cut down costs by avoiding power shortages or surpluses. Of specific interest is the 24-hour daily electricity load profile, which provides insight into periods of high demand and periods where the use of electricity is at a minimum. Researchers have proposed many approaches to modeling electricity prices, real-time load, and day-ahead demand, with varying success. In this dissertation three new approaches to modeling and forecasting the 24-hour daily electricity load profiles are presented. The application of the proposed methods is …

Spectroscopic And Spectro-Astrometric Analysis Of T Tauri Stars, Logan Ryan Brown

Doctoral Dissertations

"To understand our own solar origins, we must investigate the composition of the protoplanetary disk from which the solar system formed. To infer this, we study analogs to the early solar system called T Tauri stars. These objects are low-mass, pre-main sequence stars surrounded by circumstellar disks of material from which planets are believed to form. We present high-resolution, near-infrared spectroscopic data for the T Tauri stars DR Tau and AA Tau using NIRSPEC at the Keck II telescope. For DR Tau, a spectro-astrometric analysis was performed, obtaining sub-seeing spatial information on water emission. Alongside a disk model, we constrained …

Unconventional Phase Transitions In Random Systems, Hatem Nuri Barghathi

Doctoral Dissertations

"In this thesis we study the effects of different types of disorder and quasiperiodic modulations on quantum, classical and nonequilibrium phase transitions. After a brief introduction, we examine the effect of topological disorder on phase transitions and explain a host of violations of the Harris and Imry-Ma criteria that predict the fate of disordered phase transitions. We identify a class of random and quasiperiodic lattices in which a topological constraint introduces strong anticorrelations leading to modifications of the Harris and Imry-Ma criteria for such lattices. We investigate whether or not the Imry-Ma criterion, that predicts that random field disorder destroys …

Properties Of Amorphous Transparent Conducting And Semiconducting Oxides From First Principles, Rabi Khanal

Doctoral Dissertations

"Amorphous transparent conducting and semiconducting oxides possess properties superior or comparable to their crystalline counterparts. The structure-property relationship in amorphous oxides is not nearly as well understood as in the case of the crystalline transparent conducting oxides. We have employedab initio molecular dynamics and a liquid quench approach to simulate amorphous oxide structures and performed density functional-based calculations to study the electronic properties of several amorphous conducting and semiconducting oxides with various cation compositions.

The effect of amorphization in oxides was investigated by taking indium oxide as a progenitor of the system. From the thorough study it was confirmed …

Seismic Reflection, Well Log, And Gravity Analysis Of The Thrace Basin, Northwestern Turkey, Murat Kuvanc

Graduate Theses/Dissertations

The Thrace basin is located between the Paleogene the Istranca and Rhdope massifs in the northwestern part of Turkey. Sediments in the Thrace basin accumulated during the early Eocene to the late Miocene, and the basin includes normal and strike-slip faults that were mainly formed in the Miocene. The hydrocarbon potential of the Thrace basin has been investigated by analyzing seismic reflection, well log, and gravity data since the 1930s; the basin has a huge gas reservoir potential and contains the first gas production field in Turkey. To determine the geologic and geophysics features of a portion of the basin …

พอลิเมอร์ผสมของพอลิแล็กทิกแอซิดและเซลลูโลสแอซีเทตจากผักตบชวา, กรองกาญจน์ อมตาริยกุล

Chulalongkorn University Theses and Dissertations (Chula ETD)

เซลลูโลสอะซิเทดถูกสังเคราะห์โดยใช้เซลลูโลสผักตบชวาเป็นวัตถุดิบ ซึ่งส่วนที่ใช้จะเป็นส่วนของก้านขั้นตอนแรกนำเส้นใยผักตบชวาไปกำจัดสิ่งสกปรกก้านแห้งและตามมาด้วยการฟอกสีไฮโปคลอไรเซลลูโลสให้เป็นสีขาวสีขาวแล้ว หลังจากนั้นเตรียมเซลลูโลสเจลโดยใช้โซเดียมไฮดรอกไซด์ / ยูเรีย / น้ำ (7:12:81 โดยน้ำหนัก) จากนั้นนำมาผสม ปริมาณของไวนิลอะซิเตทโดยมีอัตราส่วนต่างกันคือ 3.0, 5.0, 7.0, 9.0, 11.0% โดยน้ำหนักของเซลลูโลส หลังจากนั้นส่วนผสมที่ถูกเก็บไว้ในตู้แช่แข็งเป็นเวลา 6 ชั่วโมงเพื่อให้เกิดปฏิกิริยาแอซิทิเลชันสมบูรณ์ เซลลูโลสอะซิเตทมีความสามารถในการปรับปรุงคุณสมบัติของพอลิแล็กทิกแอซิดโดยการเปลี่ยนเป็นผลึกที่สมบัติเชิงกลและสมบัติทางความร้อน จุดมุ่งหมายของการศึกษาครั้งนี้คือการสังเคราะห์ เซลลูโลสแอซิเทดจากผักตบชวาโดยใช้พอลิไวนิลอะซิเตตสารช่วยเพิมความเข้ากันได้ (Compatiblizer) จากนั้นพอลิแล็กทิกแอซิด / เซลลูโลสอะซิเทดนำไปผสมกันโดยใช้เครื่องอัดรีดเกลียว หลังจากนั้นนำไปวิเคราะผล ดังนี้ วิเคราะห์หมู่ฟังก์ชันโดยใช้ฟูเรียทรานสฟอร์มสเปกโตรสโคปี (FTIR) วิเคราห์ความเป็นผลึกด้วยเครื่องเอกซ์เรย์ดิฟแฟรกโทรมิเตอร์(XRD) และ วิเคราะห์สัณฐานวิทยาด้วยกล้องจุลทรรศน์อิเล็กตรอนแบบส่องกราด(SEM) พบว่าพอลิแล็กทิกแอซิด / เซลลูโลสอะซิเตทโดยความเข้มข้นที่เหมาะสมที่สุดของเซลลูโลสอะซิเตทสำหรับการผสมกับพอลิแล็กทิกแอซิด เป็น 11% โดยน้ำหนักและสัดส่วนของพอลิแล็กทิกแอซิด/เซลลูโลสแอซิเทดคือ 95 : 5

Enabling Method To Design Versatile Biomaterial Systems From Colloidal Building Blocks, Shalini Saxena, L. Andrew Lyon

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Development of materials with fine spatial control over topographical, mechanical, or chemical features has been investigated for a variety of applications. Here we present a method to fabricate an array of polyelectrolyte constructs including two-dimensionally and three-dimensionally patterned assemblies using both compressible and incompressible colloidal building blocks. This method eliminates prior constraints associated with specific chemistries, and can be used to develop modular, multi-component, patterned assemblies. In particular, development of constructs were investigated using microgels, which are colloidally stable hydrogel microparticles, polystyrene (PS) beads, and PS-microgel core-shell building blocks in conjunction with the polycation poly(ethyleneimine) (PEI). The topography, mechanical properties, …

Success Stories And Emerging Themes In Conservation Physiology, Christine L. Madliger, Steven J. Cooke, Erica J. Crespi, Jennifer L. Funk, Kevin R. Hultine, Kathleen E. Hunt, Jason R. Rohr, Brent J. Sinclair, Cory D. Suski, Craig K. R. Willis, Oliver P. Love

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

The potential benefits of physiology for conservation are well established and include greater specificity of management techniques, determination of cause–effect relationships, increased sensitivity of health and disturbance monitoring and greater capacity for predicting future change. While descriptions of the specific avenues in which conservation and physiology can be integrated are readily available and important to the continuing expansion of the discipline of ‘conservation physiology’, to date there has been no assessment of how the field has specifically contributed to conservation success. However, the goal of conservation physiology is to foster conservation solutions and it is therefore important to assess whether …

Physical And Electrochemical Area Determination Of Electrodeposited Ni, Co, And Nico Thin Films, Matthew Gira, Kevin Tkacz, Jennifer R. Hampton

Faculty Publications

The surface area of electrodeposited thin films of Ni, Co, and NiCo was evaluated using electrochemical double-layer capacitance, electrochemical area measurements using the [Ru(NH₃)₆]³⁺/[Ru(NH₃)₆]²⁺ redox couple, and topographic atomic force microscopy (AFM) imaging. These three methods were compared to each other for each composition separately and for the entire set of samples regardless of composition. Double-layer capacitance measurements were found to be positively correlated to the roughness factors determined by AFM topography. Electrochemical area measurements were found to be less correlated with measured roughness factors as well as applicable …

Landmark Based Shape Analysis For Cerebellar Ataxia Classification And Cerebellar Atrophy Pattern Visualization, Zhen Yang, S. Mazdak Abulnaga, Aaron Carass, Bruno Jedynak, Chiadi U. Onyike, Jerry L. Prince, Multiple Additional Authors

Mathematics and Statistics Faculty Publications and Presentations

Cerebellar dysfunction can lead to a wide range of movement disorders. Studying the cerebellar atrophy pattern associated with different cerebellar disease types can potentially help in diagnosis, prognosis, and treatment planning. In this paper, we present a landmark based shape analysis pipeline to classify healthy control and different ataxia types and to visualize the characteristic cerebellar atrophy patterns associated with different types. A highly informative feature representation of the cerebellar structure is constructed by extracting dense homologous landmarks on the boundary surfaces of cerebellar sub-structures. A diagnosis group classifier based on this representation is built using partial least square dimension …

Investigating Alaskan Methane And Carbon Dioxide Fluxes Using Measurements From The Carve Tower, Anna Karion, Colm Sweeney Colm Sweeney, John B. Miller John B. Miller, Arlyn E. Andrews, Roisin Commane, Steven Dinardo, John M. Henderson, Jacob Lindaas, John C. Lin, Kristina Luus, Tim Newberger, Pieter Tans Pieter Tans, Steven C. Wofsy, Sonja Wolter, Charles E. Miller

Articles

Northern high-latitude carbon sources and sinks, including those resulting from degrading permafrost, are thought to be sensitive to the rapidly warming climate. Because the near-surface atmosphere integrates surface fluxes over large ( ∼ 500–1000 km) scales, atmospheric monitoring of carbon dioxide (CO2) and methane (CH4) mole fractions in the daytime mixed layer is a promising method for detecting change in the carbon cycle throughout boreal Alaska. Here we use CO2 and CH4 measurements from a NOAA tower 17 km north of Fairbanks, AK, established as part of NASA's Carbon in Arctic Reservoirs Vulnerability Experiment (CARVE), to investigate regional fluxes of …

Variation In Summer Nitrogen And Phosphorus Uptake Among Siberian Headwater Streams, John D. Schade, Erin C. Seybold, Travis Drake, Seth Spawn, William V. Sobczak, Karen E. Frey, Robert M. Holmes, Nikita Zimov

Geography

Arctic streams are likely to receive increased inputs of dissolved nutrients and organic matter from thawing permafrost as climate warms. Documenting how Arctic streams process inorganic nutrients is necessary to understand mechanisms that regulate watershed fluxes of permafrost-derived materials to downstream ecosystems. We report on summer nitrogen (N) and phosphorus (P) uptake in streams draining upland soils from the Pleistocene, and lowland floodplain soils from the Holocene, in Siberia's Kolyma River watershed. Uptake of N and P differed between upland and floodplain streams, suggesting topographic variation in nutrient limitation. In floodplain streams, P uptake rate and uptake velocity were higher …

Regional Effects Of Streptozotocin-Induced Diabetes On Shortening And Calcium Transport In Epicardial And Endocardial Myocytes From Rat Left Ventricle, Manal M.A. Smaill, Muhammad A. Qureshi, Anatoliy Shmygol, Murat Oz, Jaipaul Singh, Vadym Sydorenko, Alya Arabi, Frank C. Howarth, Lina Al Kury

All Works

© 2016 The Authors. In the heart, the left ventricle pumps blood at higher pressure than the right ventricle. Within the left ventricle, the electromechanical properties of ventricular cardiac myocytes vary transmurally and this may be related to the gradients of stress and strain experienced in vivo across the ventricular wall. Diabetes is also associated with alterations in hemodynamic function. The aim of this study was to investigate shortening and Ca2+ transport in epicardial (EPI) and endocardial (ENDO) left ventricular myocytes in the streptozotocin (STZ)-induced diabetic rat. Shortening, intracellular Ca2+ and L-type Ca2+ current (ICa,L) were measured by video detection, …

Combining Weights Of Evidence Analysis With Feature Extraction - A Case Study From The Hauraki Goldfield, New Zealand, Leonardo Feltrin, João Gabriel Motta, Feras Al-Obeidat, Farhi Marir, Martina Bertelli

All Works

© 2016 The Authors. In this contribution we combine different image processing and pattern recognition methodologies to map the probability of discovering epithermal mineral deposits in the northern part of the Coromandel peninsula, in New Zealand. The objective of this work is to propose a case-study where the substitution of structural geology GIS themes (commonly developed by humans) with products derived by image processing, computer-based, semi-automatic edge detection analyses, is carried out to reduce subjective input in the prospectivity analysis. Semi-automated lineament extraction results introduced in the mineral favourability statistical modelling can more easily reveal unexpected potentially mineralised target domains, …