Physical Sciences and Mathematics Commons^™

X-Ray Absorption Study Of Ceria Nanorods Promoting The Disproportionation Of Hydrogen Peroxide, Tai-Sing Wu, Yunyun Zhou, Renat F. Sabirianov, Wai-Ning Mei, Yun-Liang Soo, Barry Chin Li Cheung

Barry Chin Li Cheung Publications

A quasi in situ X-ray absorption study demonstrated that the disproportionation of hydrogen peroxide (H₂O₂) promoted by ceria nanorods was associated with a reversible Ce³⁺/Ce⁴⁺ reaction and structural transformations in ceria. The direction of this reversible reaction was postulated to depend on the H2O2 concentration and the fraction of Ce³⁺ species in ceria nanorods.

Oxyhalogen-Sulfur Chemistry: Kinetics And Mechanism Of Oxidation Of N-Acetylthiourea By Aqueous Bromate And Acidified Bromate, Kudzanai Chipiso, Wilbes Mbiya, Thai Tran, Reuben H. Simoyi

Chemistry Faculty Publications and Presentations

The oxidation of N-acetylthiourea (ACTU) by acidic bromate has been studied by observing formation of bromine in excess bromate conditions. The reaction displays an induction period before formation of bromine. The stoichiometry of the reaction was determined to be 4:3: 4BrO 3 – +3(CH 3 CO)NH(NH 2 )C=S+3H 2 O®4Br – +3(CH 3 CO)NH(NH 2 )C=O+3SO 4 2– +6H + (A) with a complete desulfurization of ACTU to its urea analogue. In excess bromate conditions the stoichiometry was 8:5: 8BrO 3 – + 5(CH 3 CO)NH(NH 2 )C=S + H 2 O ® 4Br 2 + 5(CH 3 CO)NH(NH 2 …

Electrochemistry-Coupled To Mass Spectrometry In Simulation Of Metabolic Oxidation Of Methimazole: Identification And Characterization Of Metabolites, Kudzanai Chipiso, Reuben H. Simoyi

Chemistry Faculty Publications and Presentations

Methimazole (MMI), an antithyroid drug, is associated with idiosyncratic toxicity. Reactive metabolites resulting from bioactivation of the drug have been implicated in these adverse drug reactions. Mimicry of enzymatic oxidation of MMI was carried out by electrochemically oxidizing MMI using a coulometric flow-through cell equipped with a porous graphite working electrode. The cell was coupled on-line to electrospray ionization mass spectrometry (EC/ESI-MS). ESI spectra were acquired in both negative and positive modes. In acidic medium, ESI spectral analysis showed that the dimer was the main product, while in neutral and basic media, methimazole sulfenic acid, methimazole sulfinic acid and methimazole …

Numerical Modeling Of Ambient Noise Seismic Interferometry, Simisola M. Arogundade

Dissertations, Master's Theses and Master's Reports

CO₂ sequestration involves storing CO₂ in a deep geological formation and may help to mitigate the increasing emission of carbon. To monitor the migration of injected fluid in the reservoir, seismic observations may be used to observe changes in reflection character. Conventional methods to image the subsurface, using active seismic measurements, with man-made sources, have been applied at a few test sites, and the use of passive measurements, with natural sources, has been considered as a probable cost-efficient method to monitor CO₂ migration and leakage. This numerical modeling study examines the use of seismic interferometry to retrieve …

Identification Of Taenia Metacestodes From Mongolian Mammals Using Multivariate Morphometrics Of The Rostellar Hooks, Danielle M. Tufts, Nyamsuren Batsaikhan, Michael Pitner, Gábor R. Rácz, Altangerel Tsogtsaikhan Dursahinhan, Scott Lyell Gardner

Erforschung biologischer Ressourcen der Mongolei / Exploration into the Biological Resources of Mongolia, ISSN 0440-1298

Parasite diversity in and among various species of mammals within Mongolia is still poorly understood. The current paper focusses on a small part of the results of the Mongolian Vertebrate Parasite Project (MVPP), which entailed a broad-scale biodiversity survey of the vertebrates and their parasites of the Gobi and Altai regions of Mongolia. We report on the prevalence and morphological variation of larval cestodes of the family Taeniidae that occurred in small mammals that were collected from 2009-2012 from various locations in southern Mongolia. From these metacestodes, we studied both large and small rostellar hooks and analyzed both size and …

Deep Subsurface Drip Irrigation Using Coal-Bed Sodic Water: Part Ii. Geochemistry, Carleton R. Bern, George N. Breit, Richard W. Healy, John W. Zupancic

United States Geological Survey: Staff Publications

Waters with low salinity and high sodium adsorption ratios (SARs) present a challenge to irrigation because they degrade soil structure and infiltration capacity. In the Powder River Basin of Wyoming, such low salinity (electrical conductivity, EC 2.1 mS cm⁻¹) and high-SAR (54) waters are co-produced with coal-bed methane and some are used for subsurface drip irrigation (SDI). The SDI system studied mixes sulfuric acid with irrigation water and applies water year-round via drip tubing buried 92 cm deep. After six years of irrigation, SAR values between 0 and 30 cm depth (0.5–1.2) are only slightly increased over non-irrigated …

Geochemical Evidence For Seasonal Controls On The Transportation Of Holocene Loess, Matanuska Valley, Southern Alaska, Usa, Daniel R. Muhs, James R. Budahn, Gary Skipp, John P. Mcgeehin

United States Geological Survey: Staff Publications

Loess is a widespread Quaternary deposit in Alaska and loess accretion occurs today in some regions, such as the Matanuska Valley. The source of loess in the Matanuska Valley has been debated for more than seven decades, with the Knik River and the Matanuska River, both to the east, being the leading candidates and the Susitna River, to the west, as a less favorable source. We report here new stratigraphic, mineralogic, and geochemical data that test the competing hypotheses of these river sources. Loess thickness data are consistent with previous studies that show that a source or sources lay to …

Retrospective: Adjusting Contaminant Concentrations In Bird Eggs To Account For Moisture And Lipid Loss During Their Incubation, Barnett A. Rattner, Stanley N. Wiemeyer, Lawrence J. Blus

United States Geological Survey: Staff Publications

By the 1960s, research and monitoring efforts on chlorinated

pesticide residues in tissues of wildlife were well

underway in North America and Europe. Conservationists

and natural resource managers were attempting to resolve

whether pesticide exposure and accumulated residues were

related to population declines in several species of predatory

and scavenging birds (e.g., bald eagle Haliaeetus

leucocephalus, peregrine falcon Falco peregrinus, brown

pelican Pelecanus occidentalis and osprey Pandion haliaetus).

The avian egg was a favored sampling matrix even

before the realization that eggshell thinning was linked to

population declines (Ratcliffe 1967; Hickey and Anderson

1968) and that the …

Bioaccessibility Tests Accurately Estimate Bioavailability Of Lead To Quail, W. Nelson Beyer, Nicholas T. Basta, Rufus L. Chaney, Paula F.P. Henry, David E. Mosby, Barnett A. Rattner, Kirk G. Scheckel, Daniel T. Sprague, John S. Weber

United States Geological Survey: Staff Publications

Hazards of soil-borne lead (Pb) to wild birds may be more accurately quantified if the bioavailability of that Pb is known. To better understand the bioavailability of Pb to birds, the authors measured blood Pb concentrations in Japanese quail (Coturnix japonica) fed diets containing Pb-contaminated soils. Relative bioavailabilities were expressed by comparison with blood Pb concentrations in quail fed a Pb acetate reference diet. Diets containing soil from 5 Pb-contaminated Superfund sites had relative bioavailabilities from 33% to 63%, with a mean of approximately 50%. Treatment of 2 of the soils with phosphorus (P) significantly reduced the bioavailability …

Component Greenhouse Gas Fluxes And Radiative Balance From Two Deltaic Marshes In Louisiana: Pairing Chamber Techniques And Eddy Covariance, Ken W. Krauss, Guerry O. Holm Jr., Brian C. Perez, David E. Mcwhorter, Nicole Cormier, Rebecca F. Moss, Darren J. Johnson, Scott C. Neubauer, Richard C. Raynie

United States Geological Survey: Staff Publications

Coastal marshes take up atmospheric CO₂ while emitting CO₂, CH₄, and N₂O. This ability to sequester carbon (C) is much greater for wetlands on a per area basis than from most ecosystems, facilitating scientific, political, and economic interest in their value as greenhouse gas sinks. However, the greenhouse gas balance of Gulf of Mexico wetlands is particularly understudied. We describe the net ecosystem exchange (NEE_c) of CO₂ and CH₄ using eddy covariance (EC) in comparison with fluxes of CO₂, CH₄, and N₂O using …

Mapping Marginal Croplands Suitable For Cellulosic Feedstock Crops In The Great Plains, United States, Yingxin Gu, Bruce K. Wylie

United States Geological Survey: Staff Publications

Growing cellulosic feedstock crops (e.g., switchgrass) for biofuel is more environmentally sustainable than cornbased ethanol. Specifically, this practice can reduce soil erosion and water quality impairment from pesticides and fertilizer, improve ecosystem services and sustainability (e.g., serve as carbon sinks), and minimize impacts on global food supplies. The main goal of this study was to identify high-risk marginal croplands that are potentially suitable for growing cellulosic feedstock crops (e.g., switchgrass) in the US Great Plains (GP). Satellitederived growing season Normalized Difference Vegetation Index, a switchgrass biomass productivity map obtained from a previous study, US Geological Survey (USGS) irrigation and crop …

Elevation Dynamics In A Restored Versus A Submerging Salt Marsh In Long Island Sound, Shimon C. Anisfeld, Troy D. Hill, Daonald R. Cahoon

United States Geological Survey: Staff Publications

Accelerated sea-level rise (SLR) poses the threat of salt marsh submergence, especially in marshes that are relatively low-lying. At the same time, restoration efforts are producing new low-lying marshes, many of which are thriving and avoiding submergence. To understand the causes of these different fates, we studied two Long Island Sound marshes: one that is experiencing submergence and mudflat expansion, and one that is undergoing successful restoration. We examined sedimentation using a variety of methods, each of which captures different time periods and different aspects of marsh elevation change: surface-elevation tables, marker horizons, sediment cores, and sediment traps. We also …

Processes Contributing To Resilience Of Coastal Wetlands To Sea-Level Rise, Camille L. Stagg, Ken W. Krauss, Donald R. Cahoon, Nicole Cormier, William H. Conner, Christopher M. Swarzenski

United States Geological Survey: Staff Publications

The objectives of this study were to identify processes that contribute to resilience of coastal wetlands subject to rising sea levels and to determine whether the relative contribution of these processes varies across different wetland community types. We assessed the resilience of wetlands to sea-level rise along a transitional gradient from tidal freshwater forested wetland (TFFW) to marsh by measuring processes controlling wetland elevation. We found that, over 5 years of measurement, TFFWs were resilient, although some marginally, and oligohaline marshes exhibited robust resilience to sea-level rise. We identified fundamental differences in how resilience is maintained across wetland community types, …

A Personal Perspective On Searching For The Ivory-Billed Woodpecker: A 41-Year Quest, Paul W. Sykes Jr.

United States Geological Survey: Staff Publications

I first learned about the Patuxent Wildlife Research Center (Patuxent) in Laurel, MD, while attending high school in the mid-1950s. Patuxent wildlife biologists Brooke Meanley, Chandler (Chan) S. Robbins, and Robert (Bob) E. Stewart, Sr., visited me at my parents’ home in Norfolk, VA. I was the compiler of the Norfolk County Christmas Bird Count (which included the eastern portion of the Virginia sector of the Dismal Swamp). As part of that count, we had for several years been estimating populations of red-winged blackbirds (Agelaius phoeniceus) and common grackles (Quiscalus quiscula) in the millions. Patuxent was …

Conserving California Condors In The 1980s, Noel F.R. Snyder

United States Geological Survey: Staff Publications

By the late 1970s, the California condor (Gymnogyps californianus) was in serious trouble, with probably no more than about 30 birds left in existence, all in a mountainous region just north of Los Angeles that is vegetated mainly in chaparral and grasslands. All estimates of population size and trends offered since the early condor studies by Carl Koford in the 1930s and 1940s indicated a continuing decline toward extinction, and it appeared that few years were left before the species would be gone (see Koford, 1953; Wilbur, 1978). Evidently, the conservation steps that had been taken, including the …

Patuxent’S Role In The Development Of The North American Breeding Bird Survey, John R. Sauer

United States Geological Survey: Staff Publications

The North American Breeding Bird Survey (BBS) is a roadside survey of the breeding birds of North America. The BBS provides data from the contiguous United States, Alaska, southern and central Canada, and northern Mexico. Begun in 1966 by Chandler (Chan) S. Robbins at the U.S. Geological Survey (USGS) Patuxent Wildlife Research Center (Patuxent), and now jointly managed by Patuxent, the Canadian Wildlife Service, and the Mexican Commission for the Knowledge and Use of Biodiversity, the survey is conducted primarily in June along more than 5,000 roadside survey routes that are surveyed once each year. Volunteer observers drive the 39.4-kilometer …

Patuxent’S Long-Term Research On Wolves, David L. Mech

United States Geological Survey: Staff Publications

The gray wolf (Canis lupus) was one of the first species placed on the Endangered Species List in 1967. The Endangered Species Act of 1973 legally protected the wolf along with other listed species. Patuxent Wildlife Research Center (Patuxent) in Laurel, MD, began its Endangered Wildlife Program in 1966, and U.S. Fish and Wildlife Service (USFWS) biologist Ray Erickson was assigned to lead it. In 1973, I was transferred to the program from Region 3 of the USFWS, having been employed there since 1969 to study wolves in Minnesota. Endangered Species Act protection of the wolf fostered its …

The Migratory Bird And Habitat Research Laboratory And The Accelerated Research Program, Richard A. Coon

United States Geological Survey: Staff Publications

The Patuxent Wildlife Research Center (Patuxent) housed two important programs that were not supervised through the office of the Director of Patuxent during the 1960s and 1970s. Although they received administrative support from Patuxent, they were supervised from the U.S. Fish and Wildlife Service (USFWS) headquarters in Washington, D.C. One, the Migratory Bird Populations Station (MBPS), was established in 1961; the other, the Migratory Bird and Habitat Research Laboratory (MBHRL), was established in 1972 (Perry, 2004). This chapter briefly discusses MBPS and how some of its functions were transferred to MBHRL when this new laboratory was created.

A Spatio-Temporal Comparison Of Avian Migration Phenology Using Citizen Science Data, Ali Arab, Jason R. Courter, Jessica Zelt

United States Geological Survey: Staff Publications

The effects of climate change have wide-ranging impacts on wildlife species and recent studies indicate that birds’ spring arrival dates are advancing in response to changes in global climates. In this paper, we propose a spatio-temporal approach for comparing avian first arrival data for multiple species. As an example, we analyze spring arrival data for two long-distance migrants (Rubythroated Hummingbird Archilochus colubris; and Purple Martin Progne subis) in eastern North America from 2001–2010 using Citizen Science data. The proposed approach provides researchers with a tool to compare mean arrival dates while accounting for spatial and temporal variability. Our results show …

In-Air Hearing Of A Diving Duck: A Comparison Of Psychoacoustic And Auditory Brainstem Response Thresholds, Sara E. Crowell, Alicia M. Wells-Berlin, Ronald E. Therrien, Sally E. Yannuzzi, Catherine E. Carr

United States Geological Survey: Staff Publications

Auditory sensitivity was measured in a species of diving duck that is not often kept in captivity, the lesser scaup. Behavioral (psychoacoustics) and electrophysiological [the auditory brainstem response (ABR)] methods were used to measure in-air auditory sensitivity, and the resulting audiograms were compared. Both approaches yielded audiograms with similar U-shapes and regions of greatest sensitivity (2000-3000 Hz). However, ABR thresholds were higher than psychoacoustic thresholds at all frequencies. This difference was least at the highest frequency tested using both methods (5700 Hz) and greatest at 1000 Hz, where the ABR threshold was 26.8 dB higher than the behavioral measure of …

Amino Acid Specific Stable Nitrogen Isotope Values In Avian Tissues: Insights From Captive American Kestrels And Wild Herring Gulls, C.E. Hebert, B.N. Popp, K.J. Fernie, C. Ka’Apu-Lyons, B.A. Rattner, N. Wallsgrove

United States Geological Survey: Staff Publications

Through laboratory and field studies, the utility of amino acid compound-specific nitrogen isotope analysis (AA-CSIA) in avian studies is investigated. Captive American kestrels (Falco sparverius) were fed an isotopically characterized diet and patterns in δ15N values of amino acids (AAs) were compared to those in their tissues (muscle and red blood cells) and food. Based upon nitrogen isotope discrimination between diet and kestrel tissues, AAs could mostly be categorized as source AAs (retaining baseline δ15N values) and trophic AAs (showing 15N enrichment). Trophic discrimination factors based upon the source (phenylalanine, Phe) and trophic (glutamic acid, Glu) AAs were 4.1 (muscle) …

Phosphorus Retention In A Lowland Neotropical Stream Following An Eight-Year Enrichment Experiment, Gaston E. Small, Marcelo Ardón, John H. Duff, Alan P. Jackman, Alonso Ramírez, Frank J. Triska, Catherine M. Pringle

United States Geological Survey: Staff Publications

Human alteration of the global P cycle has led to widespread P loading in freshwater ecosystems. Much research has been devoted to the capacity of wetlands and lakes to serve as long-term sinks for P inputs from the watershed, but we know much less about the potential of headwater streams to serve in this role. We assessed storage and retention of P in biotic and abiotic compartments after an 8-y experimental P addition to a 1st-order stream in a Neotropical wet forest. Sediment P extractions indicated that nearly all P storage was in the form of Fe- and Al-bound P …

Pranked By Audubon: Constantine S. Rafinesque’S Description Of John James Audubon’S Imaginary Kentucky Mammals, Neal Woodman

United States Geological Survey: Staff Publications

The North American naturalist Constantine S. Rafinesque spent much of the year 1818 engaged in a solo journey down the Ohio River Valley to explore parts of what was then the western United States. Along the way, he visited a number of fellow naturalists, and he spent more than a week at the Henderson, Kentucky, home of artist and ornithologist John James Audubon. During the succeeding two years, Rafinesque published descriptions of new species that resulted from his expedition, including eleven species of fishes that eventually proved to have been invented by Audubon as a prank on the credulous naturalist. …

Cryptography With Right-Angled Artin Groups, Ramon Flores, Delaram Kahrobaei

Publications and Research

In this paper we propose right-angled Artin groups as a platform for secret sharing schemes based on the efficiency (linear time) of the word problem. Inspired by previous work of Grigoriev-Shpilrain in the context of graphs, we define two new problems: Subgroup Isomorphism Problem and Group Homomorphism Problem. Based on them, we also propose two new authentication schemes. For right-angled Artin groups, the Group Homomorphism and Graph Homomorphism problems are equivalent, and the later is known to be NP-complete. In the case of the Subgroup Isomorphism problem, we bring some results due to Bridson who shows there are right-angled Artin …

Ferroelectric Polymer Nanopillar Arrays On Flexible Substrates By Reverse Nanoimprint Lithography, Jingfeng Song, Haidong Lu, Keith Foreman, Shumin Li, Li Tan, Shireen Adenwalla, Alexei Gruverman, Stephen Ducharme

Stephen Ducharme Publications

With the increasing interest in deploying ferroelectric polymer in flexible electronics and electromechanics, high-throughput and low-cost fabrication of 3D ferroelectric polymer nanostructures on flexible substrates can be a significant basis for future research and applications. Here, we report that large arrays of ferroelectric polymer nanopillars can be prepared directly on soft, flexible substrates by using low-cost polydimethylsiloxane (PDMS) soft-mold reverse nanoimprint lithography at 135 °C and at pressures as low as 3 bar. The nanopillar arrays were highly uniform over large areas of at least 200 × 200 μm and had good crystallinity with nearly optimum (110) orientation. Furthermore, the …

2d Cocrystallization From H‑Bonded Organic Ferroelectrics, Donna A. Kunkel, James Hooper, Benjamin Bradley, Lisa Schlueter, Tom Rasmussen, Paulo Costa, Sunit Beniwal, Stephen Ducharme, Eva Zurek, Axel Enders

Stephen Ducharme Publications

The synthesis of 2D H-bonded cocrystals from the room-temperature ferroelectric organics croconic acid (CA) and 3-hydroxyphenalenone (3-HPLN) is demonstrated through self-assembly on a substrate under ultrahigh vacuum. 2D cocrystal polymorphs of varied stoichiometry were identified with scanning tunneling microscopy, and one of the observed structural building blocks consists of two CA and two 3-HPLN molecules. Computational analysis with density functional theory confirmed that the experimental (CA)₂(3-HPLN)₂ tetramers are lower in energy than single-component structures due to the ability of the tetramers to pack efficiently in two dimensions, the promotion of favorable electrostatic interactions between tetramers, and the …

Fabrication Of Diisopropylammonium Bromide Aligned Microcrystals With In-Plane Uniaxial Polarization, Shashi Poddar, Haidong Lu, Jingfeng Song, Om Goit, Shah Valloppilly, Alexei Gruverman, Stephen Ducharme

Stephen Ducharme Publications

Textured arrays of ferroelectric microcrystals of diisopropylammonium bromide were grown from solution at room temperature onto silicon substrates and studied by means of x-ray diffraction, atomic force microscopy, electron microscopy, and piezoresponse force microscopy. The needle-shaped crystals had dimensions of approximately 50 μm × 5 μm in the plane and were approximately 200 nm thick, where the dimensions and arrangement were influenced by growth conditions. The observations suggest an Ostwald ripening mechanism of the microcrystal growth. The crystals had the structure of the ferroelectric phase, where the polarization axis was in-plane and parallel to the long axis of …

Leveraging Federal Land Plans Into Landscape Conservation, Robert L. Fischman

Articles by Maurer Faculty

Professor Fischman’s article suggests several ways in which a mandated unit-level (e.g. an individual national forest) plan can better contribute to goals of a larger region (e.g. the Willamette River watershed) and of federal agencies (e.g. mandates to maintain ecological integrity). The scientific literature is largely in agreement that achieving ecological integrity, adaptive management, and climate change resiliency all require large-scale coordination across property boundaries and jurisdictions. The author takes these widely accepted findings as a starting point and shows how public agencies can implement effective practices. The article attempts to integrate traditional regulatory analysis with actual planning practices as …

Ogeechee Riverkeeper Oral Histories, Zach S. Henderson Library Special Collections

Finding Aids

This collection consists of oral history interviews of people who grew up living on the Ogeechee River and its watershed. The interviews were conducted from 2016-2017 for Phase I of the Ogeechee Project, but the topics span a broad range of time - including family lore and artifacts from Native American settlement and the Colonial Period through today. Materials include photographs and written documents with audio recordings making the bulk of the collection. Materials were originally collected by c.a.s.e. Consulting Services for the Ogeechee Riverkeeper organization.

Find this collection in the University Libraries' catalog.

Evidence For Simultaneous Production Of J/Ψ And ϒ Mesons, V. M. Abazov, Kenneth A. Bloom, Daniel R. Claes, Kayle Devaughan, Aaron Dominguez, Ioannis Katsanos, Sudhir Malik, Gregory Snow, D0 Collaboration

Kenneth Bloom Publications

We report evidence for the simultaneous production of J/ψ and ϒ mesons in 8.1 fb⁻¹ of data collected at √s = 1.96 TeV by the D0 experiment at the Fermilab p¯p Tevatron Collider. Events with these characteristics are expected to be produced predominantly by gluon-gluon interactions. In this analysis, we extract the effective cross section characterizing the initial parton spatial distribution, σ_eff = 2.2 ± 0.7(stat) ± 0.9(syst) mb.