Physical Sciences and Mathematics Commons^™

Ground-State Characterizations Of Systems Predicted To Exhibit L11 Or L13 Crystal Structures, Lance J. Nelson, Gus L. W. Hart, Stefano Curtarolo

Faculty Publications

Despite their geometric simplicity, the crystal structures L11 (CuPt) and L13 (CdPt3) do not appear as ground states experimentally, except in Cu-Pt. We investigate the possibility that these phases are ground states in other binary intermetallic systems, but overlooked experimentally. Via the synergy between high-throughput and cluster-expansion computational methods, we conduct a thorough search for systems that may exhibit these phases and calculate order-disorder transition temperatures when they are predicted. High-throughput calculations predict L11 ground states in the systems Ag-Pd, Ag-Pt, Cu-Pt, Pd-Pt, Li-Pd, Li-Pt and L13 ground states in the systems Cd-Pt, Cu-Pt, Pd-Pt, Li-Pd, Li-Pt. Cluster expansions confirm …

Dynamics Of The Solvent Exchange Reaction Of Weakly Bound Organic Solvents To Group 6 Transition Metal Carbonyls And The Molybdenum Hexacarbonyl Mediated Pauson-Khand Reaction, Richard J. Gates

Theses and Dissertations

Many organometallic reactions are solvent-dependent, suggesting solvent molecules interact with reaction intermediates. Studies of the solvent exchange reaction of group 6 transition metal carbonyls with moderately binding ligands have provided insight into these interactions, however, studies of the mechanism for this reaction with weakly binding ligands have not been performed. Experiments were conducted on the nanosecond time scale in methylcyclohexane over the temperature range of 4 to 44 °C using Step Scan FTIR (SS FTIR) spectroscopy with weakly binding ligands benzene and mesitylene. Upon photolysis of the metal hexacarbonyls, the kinetically favored product (M(CO)5(solv)), decays following pseudo-first-order kinetics to the …

Stable Ordered Structures Of Binary Technetium Alloys From First Principles, Gus L. W. Hart, Ohad Levy, Junkai Xue, Shidong Wang, Stefano Curtarolo

Faculty Publications

Technetium, element 43, is the only radioactive transition metal. It occurs naturally on earth in only trace amounts. Experimental investigation of its possible compounds is thus inherently difficult and limited. Half of the Tc-transition-metal systems (14 out of 28) are reported to be phase separating or lack experimental data. Using high-throughput first-principles calculations, we present a comprehensive investigation of the binary alloys of technetium with the transition metals. The calculations predict stable, ordered structures in nine of these 14 binary systems. They also predict additional compounds in all nine known compound-forming systems and in two of the five systems reported …

Computer Aided Geometric Design, Thomas W. Sederberg

Faculty Publications

This semester is the twenty-fourth time I have taught a course at Brigham Young University titled, "Computer Aided Geometric Design." When I first taught such a course in 1983, the field was young enough that no textbook covered everything that I wanted to teach, and so these notes evolved. The field now has matured to the point that several semesters worth of valuable material could be compiled. These notes, admittedly biased towards my own interests, reflect my personal preferences as to which of that material is most beneficial to students in an introductory course. I welcome anyone who has an …

Variable Object Research: Methods And Processes, Dan Broadbent

Faculty Publications

Some objects in the sky vary over time in terms of how much of their energy reaches the earth. Studying how the energy varies, and identifying any periodicities, will give clues as to what is actually happening at the source.

The purpose of this paper is to document the current methods involved in gathering and processing data, specifically on the variable object Markarian 501. The intent is that this will provide a foundation for later work to automate the process.

A Synthetic Document Image Dataset For Developing And Evaluating Historical Document Processing Methods, Daniel Walker, William Lund, Eric Ringger

Faculty Publications

Document images accompanied by OCR output text and ground truth transcriptions are useful for developing and evaluating document recognition and processing methods, especially for historical document images. Additionally, research into improving the performance of such methods often requires further annotation of training and test data (e.g., topical document labels). However, transcribing and labeling historical documents is expensive. As a result, existing real-world document image datasets with such accompanying resources are rare and often relatively small. We introduce synthetic document image datasets of varying levels of noise that have been created from standard (English) text corpora using an existing document degradation …

"Ultracold" Neutral Plasmas At Room Temperature, N. Heilmann, J. B. Peatross, Scott D. Bergeson

Faculty Publications

We report a measurement of the electron temperature in a plasma generated by a high-intensity laser focused into a jet of neon. The 15 eV electron temperature is determined using an analytic solution of the plasma equations assuming local thermodynamic equilibrium, initially developed for ultracold neutral plasmas. We show that this analysis method accurately reproduces more sophisticated plasma simulations in our temperature and density range. While our plasma temperatures are far outside the typical "ultracold" regime, the ion temperature is determined by the plasma density through disorder-induced heating just as in ultracold neutral plasma experiments. Based on our results, we …