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Full-Text Articles in Physical Sciences and Mathematics

The Synthesis And Structural Characterization Of Metal Oxide Nanoparticles Having Catalytic Applications, Stacey Janel Smith Jul 2012

The Synthesis And Structural Characterization Of Metal Oxide Nanoparticles Having Catalytic Applications, Stacey Janel Smith

Theses and Dissertations

Nanotechnology is blossoming into one of the premiere technologies of this century, but the key to its progress lies in developing more efficient nanosynthesis methods. Variations in synthetic technique, however, can cause variations in size, structure, and surface characteristics, thereby altering the physical properties and functionality of the particles. Careful structural characterizations are thus essential for understanding the properties and appropriate applications for particles produced by new synthetic techniques.In this work, a new ‘solvent-deficient’ method is presented for the synthesis of an unprecedentedly wide range of metal oxide nanomaterials including at least one metal oxide from each group in Groups …


Subdivision Rules, 3-Manifolds, And Circle Packings, Brian Craig Rushton Mar 2012

Subdivision Rules, 3-Manifolds, And Circle Packings, Brian Craig Rushton

Theses and Dissertations

We study the relationship between subdivision rules, 3-dimensional manifolds, and circle packings. We find explicit subdivision rules for closed right-angled hyperbolic manifolds, a large family of hyperbolic manifolds with boundary, and all 3-manifolds of the E^3,H^2 x R, S^2 x R, SL_2(R), and S^3 geometries (up to finite covers). We define subdivision rules in all dimensions and find explicit subdivision rules for the n-dimensional torus as an example in each dimension. We define a graph and space at infinity for all subdivision rules, and use that to show that all subdivision rules for non-hyperbolic manifolds have mesh not going to …