Physical Sciences and Mathematics Commons^™

Experimental And Numerical Investigation Of The Effect Of Fuel Composition On Flame Stability On A Gas Turbine Combustor, Gilberto Corona

Open Access Theses & Dissertations

Gas turbines are used for power generation and aviation all over the world. Fossil fuels remain the main source of energy for the operation of gas turbines but the recent increase in environmental awareness has influenced government agencies to impose stringent limits on pollutant emissions from power generation plants. Pollutant emissions control is one of the major challenges for gas turbine designers. In this study, experimental methods and computational fluid dynamics (CFD) technologies are used to study the problems that arise when coal derived fuels are used in Gas Turbine Combustors.

Gas turbine designers need both experimental data and combustion …

Prediction Of Ribonucleic Acid Secondary Structures Using A Heuristic Backtracking Search, Christopher Roman Cuellar

Open Access Theses & Dissertations

Ribonucleic acid (RNA) is essential for all forms of life. RNA is made up of a large chain of nucleotide bases: Guanine (G), Uracil (U), Cytosine (C), and Adenine (A). An RNA strand can fold on itself to allow G-C, A-U, and G-U bases to form hydrogen bonds, this is known as a secondary structure. Knowing the secondary structure of an RNA chain is very important because it will allow researchers to better understand its specific functions. RNA will create secondary structures that tend to minimize their free energy. RNA secondary structure prediction is the attempt to predict physical folding …

Influence Of Orography On The Weather Patterns And Water Availability Of A Topographically Complex Chihuahuan Desert Region, Fernanda De La Cerda Camargo

Open Access Theses & Dissertations

Arid and semi-arid ecosystems cover a large extent of the planet's land surface and are highly susceptible to/and dependent on resource availability patterns, especially precipitation. Topography affects large scale weather patterns and redistributes precipitation which creates a variety of microclimates in complex landscapes; how these patterns are modified, however, is still not fully understood. Climate change models for arid and semi-arid ecosystems predict a change towards more extreme precipitation events; understanding the mechanisms involved in redistributing precipitation is crucial for the protection of these areas. Indio Mountains Research Station (IMRS) is located in the northern Chihuahuan Desert and seems to …

A Proposed Epithermal Model For The High Grade District, California, Michael Nicholas Feinstein

Open Access Theses & Dissertations

A historic gold mining district in northeastern California has not been incorporated into the global knowledge base for precious metal vein deposits. This study collected various data types which are important characteristics in the classification and understanding of vein deposits. The High Grade District (HGD) is a gold mining site located in the northeast corner of Modoc County, California, in the Warner Mountains. The Warner Mountains are composed of Tertiary eruptive centers, cropping out between valleys formed through extensional tectonics. Mineralization of the HGD displays abundant silicification, adularia, and gold; these characteristics are sufficient to classify mineralization as low-sulfidation epithermal …

Optimal Control Applied To A Discrete Time Influenza Model, Paula Andrea Gonzalez Parra

Open Access Theses & Dissertations

For the last decades, mathematical epidemiological models have been used to understand the dynamics of infectious diseases and guide public health policy.

In particular, several continuous models have been considered to study influenza outbreaks and their controls policies. However, most epidemiological data is discrete; therefore, a discrete formulation is more convenient to compare collected data with the output of the model. We introduce a discrete time model in order to study optimal control strategies for influenza transmission.

In our model, we divide the population into four classes: susceptible, infectious, treated, and recovered individuals.

In particular, we evaluate the potential effect …

Development Of A Low-Cost Network Of Webcams For Monitoring Plant Phenology In A Chihuahuan Desert Shrubland, Libia Gonzalez

Open Access Theses & Dissertations

Phenology is the study of the timing of natural events such as the schedule of plant life-cycle events like bud burst, flowering, seed set and senescence. Many factors control plant phenological dynamics including climate. As such, phenology has been shown in published literature to be one of the best biological indicators of climate variability and change. Recent advantages in digital photography and digital image processing have opened new opportunities for inexpensive, repeatable and automated capture of plant and landscape phenological dynamics. This technology, however, remains poorly studied in terms of its capacity to depict the development of different plant phenophases, …

Gpu Based Parallel Smoothing Of Seismic Tomography Models, Ivan Gris

Open Access Theses & Dissertations

Three-dimensional models of the velocity structure of the Earth's crust are an important and relevant factor for several types of analyses across disciplines. Crustal velocity models are also commonly used to analyze and search for different materials of interest or to determine and differentiate many aspects of life on Earth during different eras.

Seismic tomography techniques, both in two and three dimensions, perform image reconstruction of the crust of the Earth. Seismic tomography algorithms can calculate crustal velocity structure through inversion of traveltimes of seismic waves produced by natural events, such as earthquakes, or controlled source experiments, such as explosions. …

Quality Of Wastewater In The El Paso, Texas Region--Analysis Of Pharmaceuticals And Personal Care Products Using High Performance Liquid Chromatography Tandem Mass Spectrometry, Rodolfo Guerrero Jr.

Open Access Theses & Dissertations

Pharmaceuticals and Personal Care Products (PPCPs), such as household cleaning materials, prescription medication, and personal hygiene products, are pollutants of emerging concern that are found in 80% of our water system. Because of their applications, PPCPs are subsequently being released into wastewater; however, current wastewater treatment facilities are not regulated or designed to remove PPCPs. Therefore, these compounds are discharged into the environment on a continual basis. The effects of PPCPs on human health are not yet well known; however, recent research has found that exposure to these chemicals has some adverse developmental effects on aquatic species at low concentrations …

Monitoring Ecosystem Dynamics In An Arctic Tundra Ecosystem Using Hyperspectral Reflectance And A Robotic Tram System, Santonu Goswami

Open Access Theses & Dissertations

Global change, which includes climate change and the impacts of human disturbance, is altering the provision and sustainability of ecosystem goods and services. These changes have the capacity to initiate cascading affects and complex feedbacks through physical, biological and human subsystems and interactions between them. Understanding the future state of the earth system requires improved knowledge of ecosystem dynamics and long term observations of how these are being impacted by global change. Improving remote sensing methods is essential for such advancement because satellite remote sensing is the only means by which landscape to continental-scale change can be observed.

The Arctic …

The Impact Of Sulfide Mineral Weathering On The Isotopic Signatures Of Fe And Cu In Metal-Rich Streams, Ana Lourdes Gutierrez

Open Access Theses & Dissertations

The oxidative weathering of sulfide minerals, like pyrite, at the Earth's surface controls the formation of acid mine drainage sites as well as the Fe isotope composition of these areas and the main processes taken place. In this study, water and rock samples were collected from acidic drainages (most from abandoned mining sites) from the St. Juan Mountains in Colorado. The water samples were measured in-situ for dissolved oxygen, dissolved Fe(II), pH, and conductivity. Filtered acidified, unfiltered acidified, and Fe-oxide samples were analyzed for their metal concentrations. Ion-exchange chromatography was applied to both water and digested oxide fractions in order …

A Reduced Order Parameter Estimation Technique Using Orthonormal Wavelets, Miguel Hernandez Iv

Open Access Theses & Dissertations

In this work we introduce methods for model order reduction using orthonormal wavelets. Specifically, we propose techniques and algorithms for wavelet-based reduced order parameter estimation using orthonormal wavelets for solving nonlinear least squares problems. Approaches for parameter reduction using the one dimensional and two dimensional wavelet transforms are presented using multiple levels of decomposition.

The performance of wavelet-based reduced order parameter estimation is tested using a suite of orthonormal wavelets on a groundwater hydraulics model provided by the U.S. Army Corps of Engineers. Using the hydraulics model, the goal is to find a least-squares solution of the permeability field given …

Estimating Statistical Characteristics Under Interval Uncertainty And Constraints: Mean, Variance, Covariance, And Correlation, Ali Jalal-Kamali

Open Access Theses & Dissertations

In many practical situations, we have a sample of objects of a given type. When we measure the values of a certain quantity x for these objects, we get a sequence of values x1, . . . , xn. When the sample is large enough, then the arithmetic mean E of the values xi is a good approximation for the average value of this quantity for all the objects from this class. Other expressions provide a good approximation to statistical characteristics such as variance, covariance, and correlation.

The values xi come from measurements, and measurement is never absolutely accurate.

Often, …

Evidence Of Ancient Rifts Beneath Texas, Keisuke Irie

Open Access Theses & Dissertations

Continental rifts are defined as geological features where Earth's lithosphere is pulled away by surface expansion of the Earth. Their physiographic features include linear rift valleys associated with active volcanism. Many rifts fail to split a continent and ancient rifts that failed to split can be found by using seismic waves to image these ancient structures. Using seismic data collected by EarthScope USArray stations in Texas, teleseismic receiver functions was calculated and utilized surface wave dispersion curves to simultaneously invert for the 2D velocity structure beneath each seismic station. EarthScope is a scientific program funded by NSF that provides geophysical …

An Integrated Geographic Information Systems (Igis) Analysis And Definition Of The Tectonic Framework Of Northern Mexico, Carlos Manuel Martinez

Open Access Theses & Dissertations

Crustal rupture structures reactivated in the course of the tectonic history of northern Mexico are the surface expressions of planes of weakness, in the form of simple or composite rectilinear features or slightly curved, defined as lineaments. Unless otherwise defined as strike-slip faults, lineaments are part of parallel and sub-parallel oblique convergent or oblique divergent tectonic zones cross cutting the Sierra Madre Occidental and northern Mexico, in a NW trend. These shear zones are the response to the oblique subduction of the Farallon plate beneath North America.

Kinematic analysis of five selected sites in northern Mexico, three basins and two …

Principal Differential Analysis With Covariates : A Simulation Study On The Effect Of The Smoothing Parameters, Indika Varuna Mallawaarachchi

Open Access Theses & Dissertations

Principal Differential Analysis deals with functional data. The word functional data refers to a collection of curves that are independent and measured on a dense grid of time points in an interval. These time points can be equally or unequally spaced. A differential equation is believed capable of capturing the features of these n curves.

Ramsay(1996) first introduced Principal Differential Analysis (PDA) as an alternative to the Principal Component Analysis(PCA). PDA finds a linear differential equation that captures features of a collection of curves, in order to have a low dimensional approximation for functional data. PDA is based on the …

Fold-Thrust System Overprinting Syn-Rift Structures On The Margin Of An Inverted Rift Basin: Indio Mountains, West Texas, Seth Joel Page

Open Access Theses & Dissertations

Detailed mapping in the central Indio Mountains in west Texas, reveal a complex stacking of thrust sheets that record inversion of the Mesozoic Chihuahua Trough rift basin. Important newly recognized structural complexities include both folding of older thrust sheets and development of younger, out-of-sequence thrusts that cut across older folds; detachment fold horizons within thrust sheets; and a regional anticlinorium that exposes the Squaw thrust in a structural half-window bounded on the west by the Neogene Indio normal fault. The Chihuahua trough originated as part of the late Mesozoic border rift system and was inverted during Laramide thrusting. Remnants of …

Supramolecular Organization Of Nanoparticles, Brenda M. Porta Linnell

Open Access Theses & Dissertations

The study of supramolecular structures with nano-architectures has become an active area of research in recent years. They have the potential to generate functional materials with applications in medicine and emerging technologies. In this dissertation, the supramolecular organization of gold nanoparticles (AuNP) and other nano-scale structures such as discrete styrene-based polymers was investigated. The synthesis and characterization of metal-mediated AuNPs systems using pendant ligands on the AuNP such as 11-diethylenetriamine-undecane-1-thiol, 11-Mercapto-undecanoic acid [2-(2-amino-ethylamino)-ethyl]-amide, Bis(11-oxo-nicotinic acid, undecine)disulfide, and 11-mercaptoundecanoic acid, and using Cu(II) to mediate the formation of supramolecular AuNP systems with sizes of 200 nm ¡V 3 fÃ?m, are …

An Experimental Study On The Effect Of Particle Geometry On Drag And Flow Behaviors In A Packed Fluidized Bed, Md Mahamudur Rahman

Open Access Theses & Dissertations

Gasification offers a promising solution to producing fuels effectively in the coming years by providing a low-cost energy system, clean environmental performance, and reliability. Feedstock is prepared and fed to a gasifier in either a dry form or as slurry (mixed with water). One application of this technology uses heat, pressure, and steam to convert feedstock into a gaseous mixture, composed primarily of carbon monoxide (CO) and hydrogen (H2), named as syngas. Several technical and commercial issues were identified by the Nation Energy Technology Laboratory (NETL) in 2006 Multiphase workshop. US Department of Energy (DOE) is now focusing on attaining …

Digital Image Processing Based On Sparse Representation And Convex Programming, Carlos Andres Ramirez

Open Access Theses & Dissertations

Sparse representation models have been of central interest in recent years due to important achievements in computational harmonic analysis, such as wavelet transformations, and the most recent sampling theory, compressed sensing. Numerous applications based on sparse models have been studied in the last decade leading to promising results. These applications include areas in seismology, image processing, wireless sensor networks, computed tomography and magnetic resonance imaging just to mention a few.

In this work, we propose to extend such applications in the area of image processing, particularly for the image segmentation problem, and examine algorithms involved in sparse modeling from both …

Gemini Metallo-Surfactants: Chemical And Physical Properties, Erich Ivan Valenzuela

Open Access Theses & Dissertations

Gemini surfactants are amphiphilic molecules that consist of two surfactant molecules chemically joined together by a spacer group. These molecules tend to self‐assemble into vesicles at much lower concentrations than traditional surfactants and have found many applications in catalysis, adsorption applications, drug‐delivery, nanoscale technology, and biotechnology. In this thesis, the synthesis, characterization and physical properties of a new type of Gemini surfactant derived from dinuclear Cu(II) metal complexes is presented. We call these molecules Gemini Metal‐Organic Surfactants (GMOs).

Three newly developed new GMOs (compounds 1‐3) are composed of Cu(II) ions ligated to a lipid‐functionalized triamine group and the metals are …

X-Ray Diffraction Studies Of Room And Intermediate Tempertaure Phases Of Phosphate Based Solid Acids, Kiran Vajrapu

Open Access Theses & Dissertations

In this work, the MH2PO4-type solid acids (where M= Cs, K, Rb) structure and properties are studied and their contribution towards fuel cell industry is understood. Some research groups have shown that, CsH2PO4 (CDP) and RbH2PO4 (RDP) shows sudden, several order of magnitude jumps in their proton conductivity at certain high temperatures.(31, 32) This so called superprotonic behavior of these compounds makes them a fuel cell electrolyte at elevated temperatures. (33) Most of the research groups working on two possible causes to get the reliable information for the high proton conductivity: polymorphic phase transition (Botez et al.,) and thermal dehydration …

Evaluating Suspended Dust Particulate Matter From Anthropogenically - Altered Lands, Roberto Velarde

Open Access Theses & Dissertations

Substantial dust loads are transported from drylands including the Saharan, Asian, and Chihuahuan Desert deposits by localized to planetary-scale processes to nearby and distal sites. These dusts may carry harmful constituents. To evaluate dust movement patterns and characteristics relative to carried constituents, three studies are presented comprising (A) Localized displacement of uranium and progeny radionuclides from high-grade uranium ore storage piles at Peña Blanca, Chihuahua, Mexico; (B) Long-distance transport of plutonium via Saharan and Asian aeolian pathways; and (C) Dust movement patterns in military maneuvering and non-maneuvering areas at White Sands Missile Range (WSMR), New Mexico. Study (A) evaluated surface …

Distributional Properties Of Inversions And Segmentation Algorithms For Rna Sequences, Sameera Dhananjaya Viswakula

Open Access Theses & Dissertations

Ribonucleic acid (RNA) is a long single stranded molecule made up of four types of nucleotide bases: Adenine (A), Cytosine(C), Guanine (G) and Uracil (U). It folds back on itself and forms C-G and A-U complementary base pairs. The set of such hydrogen-bonded pairs in an RNA molecule is called its secondary structure. Knowing the secondary structure of RNA is useful for understanding its biological function. Prediction of RNA secondary structure from the nucleotide sequence has been an important bioinformatics problem for over two decades.

The work in this thesis is motivated by the need to improve the secondary structure …

Principles Of Thomas Pynchon's Literary Realities, Ira Anthony Walker

Open Access Theses & Dissertations

Thomas Pynchon's literature is unique in subject and style. Postmodern by definition, Pynchon illustrates physics as a societal metaphor; Guy Debord's text The Society of the Spectacle suggests that these societal, literary, metaphors constitute and/or lead to a Spectacle. Through the analysis of an unpublished text: Minstrel Island, an early written short story: "Entropy," and a short novel: The Crying of Lot 49 the reader is capable of seeing a developing theme of physics as metaphor constituting multiple Spectacles. The narrative devices offered by Thomas Pynchon become Spectacular in nature and reflect the characteristics and environment of the tumultuous 1960s …

Development Of An Expert System To Aid In The Selection Of Sustainability Design Engineering Methods, Pedro Renato Acosta

Open Access Theses & Dissertations

The objective of this thesis is to present the development of an expert system to aid designers in the selection of design methods, in particular for sustainability methods. When practicing engineers need help in their design process, they look for design methods and tools; this is a challenge especially for inexperienced engineers in the sustainability area. Engineers, due to time constrains, will only utilize one or few methods during their professional life. The origin of this situation can be traced to engineering education, where it is typical that an instructor prefers one or few methods in particular, and even when …

Magnetic-Field Induced Stability In Two-Flavor Color Superconductivity, Churna B. Bhandari

Open Access Theses & Dissertations

It has long been understood that the ground state of a superdense quark system, a Fermi liquid of weakly interacting quarks, is unstable with respect to the formation of diquark condensates. This nonperturbative phenomenon is essentially equivalent to the Cooper instability of conventional BCS superconductivity. As the quark pairs have nonzero color charge, this kind of superconductivity breaks the SU(3) color gauge symmetry, thus it is called color superconductivity. A peculiar feature of spin-zero color superconductivity is the lack of Meissner effect for a combination of the regular electromagnetic field and one of the gluon fields. This combination behaves as …

Development And Testing Of An Unmanned Aircraft System For Environmental Science, Jerald James Brady

Open Access Theses & Dissertations

For some environmental science applications, Unmanned Aircraft Systems (UASs) are increasingly recognized for their capacity to collect remotely sensed data in a safer, more efficient and effective manner than is permitted with manned aircraft and satellite remote sensing platforms. To date, however, technological, human, and other challenges have constrained adoption of UASs in the environmental sciences. This study developed and tested a new UAS for an archetypical environmental science research group (stakeholder) composed of non-UAS experts. Specifically, this thesis: 1) Assessed the research and operational needs of the stakeholder to determine the optimum UAS platform; 2) Developed an Unmanned Aerial …

Decentralized Fault Tolerant Caching With Memcached, Bivas Das

Open Access Theses & Dissertations

Recent changes in web trends not only have increased popularity of web services, but also have vastly increased usage. Popular techniques, such as web-caching, used by content and service providers to provide faster content delivery at user end, is not enough to keep up, due to diversity and dynamic nature of web-contents.

Emerging ideas to cache on the server side, for faster content generation and delivery, is currently in use by popular web-service providers. One example of such caching system is Memcached. However, memcached, a distributed high performance caching system, is ineective in dynamic organization of itself and scaling when …

Analysis Of Endocrine Disrupting Compounds In Wastewater Treatment Plants: A Perspective Of Trans-Boundary Waterborne Pollution, Roberto De La Torre

Open Access Theses & Dissertations

Recent decades have brought an increasing concern of potential adverse human and ecological health effects resulting from Endocrine Disruptor Compounds (EDCs). In particular from new emerging compounds such as natural estrogens (e.g., 17©¬-estradiol, estrone), synthetic estrogens (e.g., 17Â¥á-ethynylestradiol), bisphenol A (BPA), nonylphenol ethoxylates (NPEOS), and nonylphenol (NP). These chemicals which are also known as organic wastewater contaminants are released directly to the environment after passing through wastewater treatment plants (WWTPs), which often are not designed to remove them from the effluent. The occurrence of the aforementioned compounds in surface water is becoming of increasing concern worldwide, and has led to …

Incorporating Sustainability Into Urban Infrastructures: The Tension Between Bio-Cultural Aspects And Environmental Considerations, Shane Epting

Open Access Theses & Dissertations

The following arguments focus on how to think about sustainability as it relates to technology and the non-human world within an anthropocentric framework. We end up with a picture showing that humankind needs to change the ways in which we look at anthropocentric concerns. Secondly, the discussion that leads up to the final picture details the urgency that guides the thinking behind the implementation of sustainability. Because, as the West learns to live in an entirely new sense that is consistent with holding humankind's desire for existence as a permanent situation, one finds that this notion must be paramount for …