Physical Sciences and Mathematics Commons^™

Characterization And Discrimination Of Large Caliber Gun Blast And Flash Signatures, Bryan J. Steward

Theses and Dissertations

Two hundred and one firings of three 152 mm howitzer munitions were observed to characterize firing signatures of a large caliber gun. Muzzle blast expansion was observed with high-speed (1600 Hz) optical imagery. The trajectory of the blast front was well approximated by a modified point-blast model described by constant rate of energy deposition. Visible and near-infrared (450 - 850 nm) spectra of secondary combustion were acquired at 0.75 nm spectral resolution and depict strong contaminant emissions including Li, Na, K, Cu, and Ca. The O2 (X-b) absorption band is evident in the blue wing of the potassium D lines …

Electroluminescence Studies On Longwavelength Indium Arsenide Quantum Dot Microcavities Grown On Gallium Arsenide, John C. Ramsey

Theses and Dissertations

A comprehensive study of the electroluminescence of four GaAs/AlGaAs microcavity devices with InAs/GaInAs quantum dot active regions emitting near 1.3 µm was conducted. The four molecular beam epitaxial grown samples with AlAs oxide aperture confinement layers were fabricated, characterized, and optically modeled. Optical power transmission of the samples was modeled using Matlab and compared with measured transmission data. Resonant cavity light emitting diodes (RCLEDs) and three vertical cavity surface emitting laser (VCSEL) samples were fabricated and electro-optically characterized over a range of injection currents and temperatures. Devices achieved continuous wave room temperature lasing at 1.28 µm with an output power …

Kinetics Of The Electrical Discharge Pumped Oxygen-Iodine Laser, Matthew A. Lange

Theses and Dissertations

A systematic study of microwave discharges at 2.45 GHz has been performed through the pressure range of sustainable electric discharges in pure oxygen flows of 2 to 10 Torr. A corresponding study of 13.56 MHz has also been performed at pressures of 2, 4, and 7 Torr. Optical emissions from O2(a 1Δ), O2(b 1Σ), and O-atoms have been measured from the center of a μ-wave discharge. Discharge residence times from 0.1 to 5 ms have been reported. The O2(b 1Σ) emissions, with a spectral resolution of 0.01 nm, have been used to measure the temperature of the gas, which typically …

Socially Responsible Investment In A Changing World, Desheng Wu

Electronic Thesis and Dissertation Repository

Socially responsible investment funds make up a growing segment of the investment world. This work considers the impact of including SRI in an investor portfolio both normally and during crisis times. Regimes are identified using Markov switching models. This study is based on return data of four indices, namely, the MSCI World Index, S&P 500, Eurostoxx 50, and the socially responsible index - Advanced Sustainable Performance Index (ASPI). The approaches used are portfolio optimization, GARCH and Markov switching models. Our work shows that a socially responsible index is a good asset to keep in a portfolio. Our simulation results suggest …

Design And Synthesis Of Cationic Steroid Antimicrobial Compounds, Synthesis Of Glycolipids Recognized By Natural Killer T Cells And Development Of Tlr-1, Tlr-6 Heterodimer Binders And Studies Of Their Immunology Activities, Yanshu Feng

Theses and Dissertations

Cationic steroid antimicrobial agents (CSAs) are a family of bile acid derivatives. These compounds are amphiphilic and mimic endogenous antimicrobial peptides. The antimicrobial activities of CSA-13 have been investigated and due to portent bactericidal activities and low toxicity, a large amount of CSA-13 is demanded for clinic trails and other antimicrobial applications. During our studies, we optimized the synthetic route of CSA-13, so that it can be prepared at the kilogram, even in tons scale. We investigated three routes and one of them is suitable for industry, because only recrystallization is needed in the synthesis. Natural killer T cells (NKT …

Testing The Limits Of Hyperspectral Airborne Remote Sensing By Mapping Eelgrass In Elkhorn Slough, Kelley J. Bostrom

Master's Theses

Seagrass ecosystems are a valuable resource, but vulnerable to changing conditions in the coastal ocean. Quantification of seagrass density and distribution from aerial imagery can be applied as a tool in resource management and ecosystem health and stability monitoring. This study investigates analytical methods for mapping eelgrass beds in an optically complex shallow, turbid estuary. Hyperspectral imagery (HSI) of Elkhorn Slough, CA was collected by the Spectroscopic Aerial Mapper with Onboard Navigation (SAMSON) instrument. In-situ data of water column and benthic optical properties and Hydrolight Radiative Transfer model were used to create a spectral library describing the reflectance of Elkhorn …

Collisional Reactivation Of Rift Margin Fracture Zones, Taiwan And The Taconic Allochthon, David C. Mirakian

Master's Theses

Chapter I. Transverse Topographic Development due to the Reactivation of a Partially-Subducted Fracture Zone: The Southwest Hsüehshan Range, Central Taiwan

Abstract — The southwest flank of the Hsüehshan Range is defined by a topographic break which cuts across regionally mapped structures in central Taiwan. The mountain front trends ~345°, slightly oblique to the Sanyi-Puli seismic zone which has been previously interpreted as a reactivated continental margin fracture zone. Structural data collected along the length of the topographic break reveal two populations of cross-cutting faults with distinct fault-zone materials and a series of southwest-plunging folds. Paleostress axes were reconstructed using the …

Multivariate Models And Algorithms For Systems Biology, Lipi Rani Acharya

University of New Orleans Theses and Dissertations

Rapid advances in high-throughput data acquisition technologies, such as microarraysand next-generation sequencing, have enabled the scientists to interrogate the expression levels of tens of thousands of genes simultaneously. However, challenges remain in developingeffective computational methods for analyzing data generated from such platforms. In thisdissertation, we address some of these challenges. We divide our work into two parts. Inthe first part, we present a suite of multivariate approaches for a reliable discovery of geneclusters, often interpreted as pathway components, from molecular profiling data with replicated measurements. We translate our goal into learning an optimal correlation structure from replicated complete and incomplete …

Mineralogy And Geochemistry Of Anorogenic Granitic Miarolitic Pegmatites Associated With The White Mountain Intrusive Suite, New Hampshire, Kristen F. Camp

University of New Orleans Theses and Dissertations

Subvolcanically emplaced granitic, miarolitic pegmatites associated with the White Mountain Igneous Province (WMIP), New Hampshire, were sampled and analyzed using modern analytical techniques including X-ray fluorescence, electron microprobe, scanning electron microscopy, and direct-coupled plasma spectrophotometry. Analytical results suggest that all the sampled miarolitic pegmatites from this study are petrogenetically related to the same intrusive suite, the WMIP. Based on the geochemical data, all the samples formed in an anorogenic tectonic setting and are rift-related. They are classified as NYF-type and plot in the “within plate granite” field on tectonic discrimination diagrams. The majority of the samples are peraluminous, A_{1 …}

Statistical Spectral Parameter Estimation Of Acoustic Signals With Applications To Byzantine Music, Kyriakos Michael Tsiappoutas

University of New Orleans Theses and Dissertations

Digitized acoustical signals of Byzantine music performed by Iakovos Nafpliotis are used to extract the fundamental frequency of each note of the diatonic scale. These empirical results are then contrasted to the theoretical suggestions and previous empirical findings. Several parametric and non-parametric spectral parameter estimation methods are implemented. These include: (1) Phase vocoder method, (2) McAulay-Quatieri method, (3) Levinson-Durbin algorithm,(4) YIN, (5) Quinn & Fernandes Estimator, (6) Pisarenko Frequency Estimator, (7) MUltiple SIgnal Characterization (MUSIC) algorithm, (8) Periodogram method, (9) Quinn & Fernandes Filtered Periodogram, (10) Rife & Vincent Estimator, and (11) the Fourier transform. Algorithm performance was very precise. …

Investigating The Thermal Stability And Cation Ordering In Layered Cathode Lixmo2 (X ≤ 1; M = Co, Mn, Ni) Materials For Li-Ion Rechargeable Batteries And Studying The Ferroelectric Properties Of Linbo3 Nanoparticles, Debasish Mohanty

University of New Orleans Theses and Dissertations

In recent years, transition metal oxides have drawn extensive attention because of their wide application in electronic, memory, battery, informatics, and optoelectronics devices. In this dissertation, we have studied two different types of oxide materials which are technologically important: LiMO 2 (M = Co, Mn, Ni), has served as cathode materials in the rechargeable battery, and LiNbO3, has wide application in ferroelectric devices such as electronics, non-volatile memories, and thin film capacitors. LiMO2 was synthesized and characterized to understand the correlation between capacity fading and thermal stability relating to the microstructures. Our results showed that delithiated (charged) LiCoO2, forms a …

Synthesis And Antifungal Evaluation Of Spirostane Saponins, Sunil Upadhyay

University of New Orleans Theses and Dissertations

Methods for the preparation of novel antifungal saponins have been investigated in

order to further explore their medicinal utility and provide the opportunity to synthesize

their derivatives.

Through this work, several partially protected stereoisomers of Cholestane,

Androstane and Spirostane have been prepared which could be used for the synthesis of

various saponin derivatives in order to discover novel saponin based antifungal agent.

Various mono and disaccharide derivatives of these steroids have been synthesized and

evaluated for their antifungal activity against four pathogenic fungal strains. Among the

various derivatives maltose derivatives were found to have the best antifungal activity.

However there …

Synthesis Of Chemical Models Of Hydrolase Enzymes For Intramolecular Catalysis., Cornelius Ndi Ndi

Electronic Theses and Dissertations

Most nuclease enzymes can hydrolyze phosphoester bonds (in DNA and RNA) by using metal ions cofactors that coordinate and activate water molecules in the enzymes' active sites. However, there are some hydrolase enzymes (including nucleases) that can function without the aid of metal ions. 2,6-Di(1H-imidazol-2-yl)phenol, a model compound for hydrolase enzyme, was synthesized by the reaction between ethylenediamine and dimethyl-3-carboxysalicylate, initially resulting in the formation of diimidazoline. The diimidazoline was subsequently aromatized to the diimidazole by dehydrogenation over palladium. The overall reaction yield was low; therefore, other dehydrogenation transformation reactions were tried but all failed to improve the …

Mesoporous Functionalized Materials For Post-Combustion Carbon Dioxide Capture., Kolade Omoniyi Ojo

Electronic Theses and Dissertations

Novel highly functionalized hybrid organic-inorganic materials were synthesized by polycondensation of bis[3-(trimethoxysilyl)propyl]amine in presence of cationic and anionic surfactants. Reaction media strongly affected gelation time. Thus, in basic media gelation occurred immediately while acid increased gelation time. Material structures were studied by IR spectroscopy, porosimetry, XRD, and SAXS methods. In spite of the absence of an inorganic linker, obtained bridged silsesquioxanes had mesoporous structure. A material prepared in the presence of dodecylamine as a template had higher surface area and narrow pore size distribution while the use of sodium dodecylbenzene sulfate resulted in formation of mesopores with wide size ranges. …

Using Electrochemical Method To Study The Interaction Between Dna And A Compound Known To Have Anticancer Property., Alexander Kamasah

Electronic Theses and Dissertations

The interaction of 4-(1'-[8'-(1''-pyrenyl)naphthyl])-2,6-diaminopyridine bis-glycamide bishydrocholride known to have anticancer properties with deoxyribonucleic acid (DNA) had been studied on a modified gold electrode by self-assembled monolayer using cyclic voltammetry. K₄Fe (CN)₆ was used as a probe to obtain electrochemical information on the electrode surface.

A bare gold (Au) electrode was modified with cysteamine and our results showed no change in the limiting steady state current as compared to the bare Au electrode. There was a reduction in the steady state current after the modification of the gold electrode with DNA. Immobilization of the DNA modified gold electrode …

A Study Of The Effects Of Titanium Dioxide Nanoparticles On The Fluorescent Intensity Of Fluorescent Compounds In The Presence Of Known Quenchers., Vivian Dzigbodi Koka

Electronic Theses and Dissertations

Titanium Dioxide is a naturally occurring oxide of titanium. It has a wide range of uses in commercial products for providing whiteness and opacity. It has photocatalytic properties and can also be used to produce electricity in its nanoparticles form. This research is focused on investigating the effect of titanium dioxide nanoparticles in analysis of compounds using luminescence-based techniques. Quenching, which is one of the basic problems of fluorescent measurements, was studied in the presence of molecular oxygen and methyl iodide. The rutile phase of titanium dioxide nanoparticles was synthesized by the acid hydrolysis of titanium isobutoxide at low temperatures …

Understanding Uplift Of The Ethiopian Plateau From Longitudinal Profile Analysis Of The Blue Nile Drainage System, Prabhat Chandra Neupane

University of New Orleans Theses and Dissertations

The Ethiopian Plateau is one of the few tectonically-active regions on Earth that is situated in continental rift zones. About 1.6 km deep gorge of the Nile was carved by the Blue Nile River on the Ethiopian Plateau, as the plateau has been experiencing continuous uplift and exhumation in the Cenozoic. Here, we used quantitative analysis of longitudinal rive-profile forms and parameters (knickpoint and normalized steepness-index k_sn) of the Blue Nile tributaries to tease out regional tectonic signals.

244 knickpoints were examined in the tributaries, majority (>80%) of which are unassociated with lithology or geological structures. Knickpoint …

Development Of A Methodology For Dormitory Energy Load Estimation And Analysis, John Michael Real

Masters Theses, 2010-2019

In recent years interest in reducing energy consumption at the building levels has been increasing, especially in the higher education sector. Many examples exist of higher education institutions reducing their environmental impact through energy consumption reductions, however the majority of these are anecdotal examples and it is difficult to replicate these initiatives at other institutions, either due to resource constraints, financial constraints, or a lack of reproducible methodology. This issue is further compounded by the fact that a generalized methodology does not exist for the purposes of estimating building energy loads, especially in dormitories in the absence of expensive and …

Synthesis And Biological Evaluation Of Aeruginosin Based Compounds And Self-Assembly Of Glucosamine Based Compounds, Navneet Goyal

University of New Orleans Theses and Dissertations

Aeruginosins are a family of marine natural products containing mostly non-proteogenic amino acids. These compounds contain a common 2-carboxy-6-hydroxy-octaindole (Choi) rigid bicyclic structure. Many aeruginosins are inhibitors for enzymes involved in the blood coagulation cascade, such as thrombin and Factor VIIa. In order to understand the structure activity relationship (SAR) of the aeruginosins and to discover novel anticoagulants with potentially improved inhibitory and pharmacokinetic properties, in the first part of my thesis I have discussed, synthesis of a series of novel analogs of aeruginosin 298-A, in which the Choi will be replaced with L-proline and oxygenated Choi analogs, and the …

Android Memory Capture And Applications For Security And Privacy, Joseph T. Sylve

University of New Orleans Theses and Dissertations

The Android operating system is quickly becoming the most popular platform for mobiledevices. As Android’s use increases, so does the need for both forensic and privacy toolsdesigned for the platform. This thesis presents the first methodology and toolset for acquiringfull physical memory images from Android devices, a proposed methodology for forensicallysecuring both volatile and non-volatile storage, and details of a vulnerability discovered by theauthor that allows the bypass of the Android security model and enables applications to acquirearbitrary permissions.

Synthesis And Applications Of Luminescent Quantum Dots In Bioassays, Venkata Ramana Kethineedi

University of New Orleans Theses and Dissertations

Luminescent quantum dot (QD) based probes have gained significance in the last decade for optical imaging of cells, tissues and in bioassays as alternatives to conventional organic fluorophores. The main objective of my PhD dissertation was to develop luminescent quantum dot based bioassays for real time monitoring of enzyme activity and simultaneous detection of several biomarkers. The quantum dot based bioassays developed will be potential tools in identification and diagnosis of several ailments that interfere with normal living conditions of human beings.

In Chapter 2 new liposome encapsulated quantum dot based fluorescence resonance energy transfer (FRET) probes have been fabricated …

Development Of A Novel Electron-Transfer Secondary Reaction Matrix, Characterization Of The Site–Specificity Of Novel Bilin-Lyase, And Fundulus Grandis Protein Expression Investigation Using Mass Spectrometry, Mohamed N. Boutaghou

University of New Orleans Theses and Dissertations

Reported in this dissertation are the results of investigations performed at the New Orleans Center for Mass Spectrometry at the University of New Orleans. The projects that are detailed in the coming pages take on a variety of subjects, but a common thread is that each employs matrix-assisted laser desorption/ionization (MALDI) mass spectrometry to solve a problem. Fundamental aspects of MALDI in-plume ionization are implicated in the introduction of a newly developed electron-transfer secondary ionization matrix. The remaining projects are related to the ever expanding field of proteomics. Mass spectrometry was used to investigate the site specificity of a newly …

A Dynamical Study Of The Evolution Of Pressure Waves Propagating Through A Semi-Infinite Region Of Homogeneous Gas Combustion Subject To A Time-Harmonic Signal At The Boundary, John Eslick

University of New Orleans Theses and Dissertations

In this dissertation, the evolution of a pressure wave driven by a harmonic signal on the boundary during gas combustion is studied. The problem is modeled by a nonlinear, hyperbolic partial differential equation. Steady-state behavior is investigated using the perturbation method to ensure that enough time has passed for any transient effects to have dissipated. The zeroth, first and second-order perturbation solutions are obtained and their moduli are plotted against frequency. It is seen that the first and second-order corrections have unique maxima that shift to the right as the frequency decreases and to the left as the frequency increases. …

Self-Assemblies Driven By The Hydrophobic Effect, Haiying Gan

University of New Orleans Theses and Dissertations

Water is a simple molecule but is an essential part of life. One key aspect of the properties of water is the hydrophobic effect, and whilst there is an appreciation of this phenomenon at the macro-scale (raindrops falling off leaves) and the micro-scale (the structure of cellular systems), a complete understanding at the molecular level still eludes science. Addressing this issue, our studies involve synthetic supramolecular compounds that assemble in water via the hydrophobic effect.

First of all, a novel water-soluble deep-cavity cavitand was synthesized. It possesses four endo methyl groups on top rim of the cavitand, eight water-solubilizing carboxylic …

Exchange Flows In An Urban Water Body: Bayou St. John Responses To The Removal Of Flood Control Structures, Future Water Elevation Control, And Water Quality, Robin L. Schroeder

University of New Orleans Theses and Dissertations

Bayou St. John, an urban water body extending south from Lake Pontchartrain, has two anthropogenic structures that regulate flow from the Lake . The City of New Orleans has plans to remove the inner control structure to improve water quality. Field and numerical methods used in this study show removing this structure increased water elevations throughout the Bayou but resulted in lower water elevation signal amplitudes that caused a lower tidal flow exchange from north to south. Bulk Richardson numbers showed mixing was inversely related to flow and the Bayou generally remains stratified. Resuspension of contaminated sediment could negatively impact …

Fabrication Of Chemically Modified Nanometer-Sized Gold Electrodes And Their Application In Electrocatalysis At Pt Nanoparticles., Jude Lakbub

Electronic Theses and Dissertations

Hydrogen evolution via proton reduction occurs at a high rate at the surface of Pt than at Au electrodes. Using cyclic voltammetry, chemically modified nanometer-sized Au electrodes, prepared by the Laser-Assisted Puller Method, were employed to examine current amplification by electrocalysis at Pt nanoparticles adsorbed on the modified Au electrode surfaces. The electrodes were modified with Self-Assembled Monolayers (SAMs) of cysteamine and soaked in Pt colloid solutions overnight. Monitoring the decrements of the characteristic steady-state catalytic current for proton reduction indicated that aggregates of Pt nanoparticles are adsorbed on the cysteamine monolayers and desorb from them particle by particle. The …

Determination Of Select Metal Ions In Commercially Available Conventional And Organic Baby Foods., Neva S. Winters

Electronic Theses and Dissertations

The goal of this study is to determine whether or not there is an appreciable difference between concentrations of various metal ions present in conventionally grown and processed and organically grown and processed baby foods. Two prominent, commercially available brands were chosen to undergo comparative studies between both their own conventional and organic varieties of second stage green beans and carrots. Samples were tested for cadmium, calcium, iron, lead, nickel, and zinc. Two containers of each variety of baby food were sampled in triplicate, with purchases of foods being made in separate areas to ensure that each set came from …

Modified Organoclay Containing Chelating Ligand For Adsorption Of Heavy Metals In Solution., Mary Akuyea Addy

Electronic Theses and Dissertations

Presence of a chelating ligand in the clay structure significantly improves its ability to immobilize heavy metals from contaminated sludge or wastewater. Two-step modification procedure comprising sequential pillaring and grafting of chelating agent to the modified clay is involved.

Montmorillonite and kaolin were chosen as typical examples of expandable and non-expandable clays, correspondingly. Modifications with silica and ferric oxide were targeted on development of mesoporous structure. Laboratory tests of the organoclay efficiency for purification of wastewater were conducted with the most promising sample, i.e. organoclay with the highest specific loading of chelating agent. Experiments were conducted with model wastewater containing …

Synthesis Of Resveratrol Ester Derivatives Using Selective Enzymatic Hydrolysis., Marian Osei-Mensah

Electronic Theses and Dissertations

Resveratrol, a naturally derived stilbene, is an interesting compound mostly talked about recently because for its anti-cancer properties. Unfortunately it has some shortcomings due to its low bioavailability and low solubility in water. For this reason, my research is to overcome resveratrol's drawbacks by improving its bioavailability and hydrophilicity. My research is focused on syntheses of novel derivatives of resveratrol such as 3, 5-di-O-isobutyroyl resveratrol and 3, 5-di-O-hexanoyl resveratrol using lipase catalyzed hydrolysis. Therefore, the tri-acylated resveratrols 3, 5, 4'-tri-O-isobutyroyl resveratrol and 3, 5,4'-tri-O-hexanoyl resveratrol were first synthesized.

3,5,4'-tri-O-isobutyroyl resveratrol and 3,5,4'-tri-O-hexanoyl resveratrol were then hydrolyzed using lipase (C. …

Survey Of Flavonoids And Their Distribution In Different Kinds Of Onions Using High Performance Liquid Chromatography And Gas Chromatography Mass Spectrometry., Archana Racharla

Electronic Theses and Dissertations

This research is done to determine the distribution of flavonoids in diverse varieties of onions (commercial and wild onions). Reflux extraction method was done on dried onions and the abstracts were analyzed subsequently by high performance liquid chromatography (HPLC) and gas chromatography-mass spectrometry (GCMS). Statistical calculations were done to see if there are significant differences in the varieties of onions studied from the chromatographic profiles obtained. The chromatograms obtained were patterned using visual observations, scatter plot study, correlation co-efficient, and ANOVA to evaluate the significant difference of the distribution of flavonoids in varieties of onions. The organic white onions seem …