Physical Sciences and Mathematics Commons^™

Preparation And Characterization Of The Lani0.6Fe0.4O3-δ Cathode For Intermediate Temperature Solid Oxide Fuel Cell, Hang Liu, Bo Huang, Xin-Jian Zhu

Journal of Electrochemistry

The LaNi_0.6Fe_0.4O_3-δ as cathode material for intermediate temperature solid oxide fuel cell was prepared using a combustion synthesis technique. The X-ray diffraction (XRD) pattern showed that the single-phase LaNi_0.6Fe_0.4O_3-δ perovskite could be obtained after heat treatment at 600°C. The TEM and SEM images of the synthesized powders revealed that the grains were 50-100nm. According to the electrochemical impedance spectra (EIS), the polarization resistance of the symmetric cell LaNi_0.6Fe_0.4O_3-δ/ScSZ/LaNi_0.6Fe_0.4O_3-δ sintered at 1050°C was the smallest (0.70Ω·cm², 0.27Ω·cm^{2 …}

Preparation And Application Of Macroporous Ato/Sio2 Electrode In Electrochemical Degradation Of 4-Chlorophenol, Zhang-Lin Chai, Rui-Feng Zhang, Tong-Hu Xiao, Yun-Xiao Liang

Journal of Electrochemistry

The macroporous ATO/SiO₂ materials were prepared through multiple steps of hydrolysis deposition in ethylene glycol and acetonitrile mixed solutions of SnCl₂/SbCl₃ and subsequent calcination at high temperature. The structures of the obtained materials were characterized by means of SEM and XRD. The results showed that the nano-ATO chemically deposited on the SiO₂ support underwent well-controlled aggregation and recrystallization to form a sandwich structure (ATO-SiO₂-ATO). Through four times loading of ATO the volume resistivity and the specific surface area reached 10·cm and 77 m²·g^-1, respectively. The oxygen evolution potential on …

Electrochemical Studies On Surface Inclusion Of Β-Cyclodextrin With Adriamycin, Jian Shi, Qi-Ping Zhang, Nan-Ping Wang

Journal of Electrochemistry

The β-cyclodextrin (β-CD) modified gold electrode (β-CD/Au) was fabricated to study the electrochemical behavior of adriamycin (ADM). The results indicated that the complexing reaction of ADM with β-CD took place at the β-CD/Au surface. At 25 °C, the complexing constant (K) was 9.54×10⁴ L·mol^-1 in pH=7.0. The K values changed regularly with temperature, and the most suitable temperature of the surface inclusion reaction was 30 ℃. The complexing reaction of ADM with β-CD at the β-CD/Au surface could undergo the quasi-reversible electrochemical reaction with the rate constant being 0.0995 s^-1. The cathodic peak current (Ip) of …

Dynamic Modeling And Characteristic Analysis Of Proton Exchange Membrane Fuel Cell, Qiu-Hong Jia, Ming Han, Bin Deng, Cai-Zhi Zhang

Journal of Electrochemistry

In this paper, a dynamic model of PEMFC is developed to estimate the dynamic performance of PEMFC by analyzing in detail the influence factors of voltage of PEMFC including various losses. The partial pressure of hydrogen and oxygen is obtained using the differential form of the ideal-gas equation in this model. The steady-state model is obtained by setting reasonable parameter values. The simulation results and experimental results have good consistency, which shows that the simulation model is correct, reasonable and effective. It analyzed the dynamic response characteristics of the output voltage and the partial pressure of hydrogen in condition of …

Preparation And Capacitance Characteristics Of Nickel Oxide Electrode With Mesh-Like Structure, Hui Xu, Zhen-Jun Peng, Dong-Hong Guo, Jun-Ling Li

Journal of Electrochemistry

The mesh-like structure of NiO electrode was obtained by first preparing the precursors via hydrothermal process using nickel sulfate and carbamide as reactants, sodium hexametaphosphate as a surfactant, and followed by calcination of the precursors at 400 ℃. The structure, morphology and capacitance characteristics of NiO electrode were characterized by XRD, SEM and constant current charge-discharge testing techniques. The effects of hydrothermal temperatures on the electrochemical properties of NiO electrode were investigated. The results showed that the better property of nickel oxide was obtained when the mole ratio of nickel to urea was 1:4 and the hydrothermal temperature was 140℃. …

Dipole-Dipole Interaction Between Rubidium Rydberg Atoms, Emily Altiere, Donald Fahey, Michael Noel, Rachel J. Smith, Thomas J. Carroll

Physics Faculty Research and Scholarship

Ultracold Rydberg atoms in a static electric field can exchange energy via the dipole-dipole interaction. The Stark effect shifts the energy levels of the atoms which tunes the energy exchange into resonance at specific values of the electric field (Forster resonances). We excite rubidium atoms to Rydberg states by focusing either a 480 nm beam from a tunable dye laser or a pair of diode lasers into a magneto-optical trap. The trap lies at the center of a configuration of electrodes. We scan the electric field by controlling the voltage on the electrodes while measuring the fraction of atoms that …

Electrochemical Behaviors Of Hydroquinone On Polypyrrole/Stab-Nammt/Gc Electrode, Rong Li, Jian Xiong, Wei-Qiong Zhu, Yuan-Yuan Han, Jin Xu, Xiao-Ying He

Journal of Electrochemistry

The PPy/STAB-MMT/GC electrode was made using montmorillonite modified by STAB and polypyrrole (PPy). The electrochemical behaviors of hydroquinone on the PPy/STAB-MMT/GC electrode were researched by cyclic voltammetry and square wave stripping voltammetry (SWSV). The results showed that the electrode reaction occurred on the hydroquinone electrode was controlled by diffusion in PBS (pH=6.0). The number of electron transfer was equal to the number of protons (n=m=1) with the effective area of PPy/STAB-MMT/GC electrode Aeff=0.031 cm². Under the optimized conditions, the linear response of peak current in SWSV with the concentration of hydroquinone in a range of 8.0×10^-6~8.0×10 …

Carry And Expand: A New Nomadic Interaction Paradigm, Richard B. Arthur

Theses and Dissertations

People are nomadic; traveling from place to place. As a user travels, he may need access to his digital information, including his data, applications, and settings. A convenient way to supply this access is to have the user carry that digital information in a portable computer such as a laptop or smart phone. As Moore's Law continues to operate, devices such as smart phones can easily perform the computing necessary for a user's work. Unfortunately, the amount of data a human can receive and convey through such devices is limited. To receive more information humans require more screen real estate. …

Brief Introduction Of Organic Electrochemistry, Huan Wang, Jia-Xing Lu

Journal of Electrochemistry

Organic electrochemistry is a very useful tool for organic synthesis, not only because of the selective introduction or removal of electrons from organic molecules, but also for its green process. In this paper, electroorganic synthesis has been introduced from the systems, research methods and technologies to the characterization. Most of organic compounds could be electrochemically oxidized or reduced. Here, taking C=C compounds as an example, several kinds of electrochemical organic synthesis reactions are discussed, such as electrochemical addition, electrocatalytic dimrization, electropolymerization, etc. Electroorganic synthesis has been industrialized since 1960s. In this paper, electrosynthesis of adiponitrile was used as an example …

Unusual Electron Transfer Rate Effects Due To Pyridyl Ring Substituents And Trace Group Viii B Hexacyano Complexes As Added Salts, Faisal Mehmood

Master's Theses

The rates of pseudo-self-exchange electron transfer reactions between [(NH₃)₅Ru^IIL]²⁺ and [(NH₃)₅Ru^IIIL’]³⁺ at reactant concentrations of 1.0 х 10^-4 M (where L, L’ = substituted pyridines) and the reaction between [(NH₃)₅Ru^IIPy]²⁺ and [(NH₃)₅Ru^III3FPy]²⁺ at different reactant concentrations in the presence of various salts added were studied by using the stopped-flow kinetic spectroscopy. Marcus theory rate vs. driving force plots yielded distinct families of lines depending on whether a 3- or 4- …

Efficient Traffic Crash And Snow Complaint Gis System, Anthony B. Ngo

School of Computing: Dissertations, Theses, and Student Research

We describe the design and implementation of a traffic crash and snow complaint GIS system developed for the Lincoln Public Works department. We also describe a novel geocoding algorithm that was used to move data from the older Criminal Justice Information System, which is a relational database, to the new GIS system. In addition, we describe the implementation of several indexing algorithms that enable the system to efficiently answer rectangular range queries and queries about the relative locations of moving objects. Finally, in many applications (on-line analysis or mobile GIS), we need to execute spatial query efficiently (fast and small), …

Electrochemical Properties Of Tungstogermanate And Electrocatalysis Of H2O2 On Gew11Co/P-Opd/Gc Electrode, Li-Li Zhu, Jian-Ying Qu, Jue Wang, Hao-Yue Feng

Journal of Electrochemistry

The electrochemical properties of Co-substituted trimeric tungstogermanate containing Keggin fragments were studied. Cyclic voltammograms revealed two couples of reversible redox peaks on glassy carbon (GC) electrode in acid solutions. They corresponded to two-electron reductions accompanying by the additions of four protons and three protons, respectively, both were controlled by adsorption. The differences in the peak potentials of 2-electron-4-proton and 2-electron-3-proton reactions were 31 mV and 35 mV, respectively..Furthermore, the tungstogermanate (GeW11Co) modified GC electrode with functionalization by poly(o-phenylenediamine) (P-oPD) was prepared readily by electropolymerization. The GeW11Co/P-oPD/GC electrode could electrocatalyze the reduction of hydrogen peroxide, which showed good stability and quick …

Preparation And Application Of Nano-Nio As Anode In Lithium-Ion Batteries, Cheng-Dong Bai, Jia-Jia Chen, Qi Zhang, Ming-Sen Zheng, Quan-Feng Dong

Journal of Electrochemistry

In this work, the nano-NiO material was prepared by hydrothermal method. The surface morphologies and electrochemical properties of nano-NiO material were investigated. The special nano-NiO material with porous surface assembling honeycombs(100-200nm) was obtained by using surface active agents. The discharge capacity of nano-NiO electrode up to 2385.7 mAh/g was achieved at current density of 0.1A/g in the first circle,while 1100mAh/g could be maintained after 100 circles. At current density of 2.0A/g, the discharge capacity of 600 mAh/g was obtained. And when the current density was reduced to 0.1A/g, the discharge capacity was restored to 1050 mAh/g. The nano-NiO electrode exhibited …

A Brief Review Of Research Progress In The Development Of Engineering Models For Lithium Ion Batteries, Da-Wei Wang, Dong-Jiang Li, Jun Li, Yong Yang

Journal of Electrochemistry

Lithium ion battery has become an important and popular electrochemical device for energy storage.Suitable evaluation and understanding of electrochemical performance and state of charge play a key role in the applications of lithium ion batteries.Construction and utilization of engineering modeling for lithium ion batteries is an effective way to fulfill this target.In this paper,engineering models of lithium ion batteries based on electrochemical reaction,ionic diffusion and migration are introduced.The emphasis is placed on the development of engineering models by the introduction of side reaction,phase transition,stress and energy.The applications of engineering models in such simulations as charge-discharge,concentration distribution,current distribution,state of charge,stress and …

Superhydrophilic/Superhydrophobic Surface Constructions On Titanium And Their Effects On Anti-Bacterial Properties, Guo-Wei Wang, Qiao-Ling Huang, Ren Hu, Chang-Jian Lin, Hao Wang, Li-Hai Zhang, Pei-Fu Tang

Journal of Electrochemistry

The microbial infection of biomaterials often causes clinic problems and sometimes even leads to the prosthesis failure. It is, therefore, important to prevent the biomaterials from bacterial contamination. This can be done by using anti-bacteria drugs. However, this method causes physiological burdens to the patients and does not always work. To stop the contamination from the just beginning is believed to be a better choice. The first step for infection is the attachment of bacteria on the material. In this work, the thin TiO₂ nanotubes array films were constructed with totally different wettabilities showing either superhydrophobic or superhydrophilic. The …

Indirect Electrochemical Reduction And Cotton Dyeing Process In Fe(Ⅲ)-Oxalate-Calcium Gluconate System, Qing-Zhi Wang, Wei Wang

Journal of Electrochemistry

The electrochemical behavior and possible reaction mechanism in Fe(Ⅲ)-oxalate-calcium gluconate system were studied by cyclic voltammetry. The results showed that Fe(Ⅱ)-gluconate was the final reductant. The reduction time, the working voltage and the cathode area influenced the current efficiency. The high current efficiency of 89% for the indirect electrochemical reduction of Vat Scarlet R could be achieved with reduction time of 10 min, working voltage of 4 V and cathode area of 40 cm² in Fe(Ⅲ)-oxalate-calcium gluconate system.

The Influence Of Strategies Used To Communicate Sustainable Corporate Responsibility On Reputation Of A Major Airport, Benno D. Hoffmann

Walden Dissertations and Doctoral Studies

Self-presentation of a corporation as a citizen committed to sustainable corporate responsibility can, according to scholarly findings, help the organization improve its reputation among key stakeholders. The purpose of this case study was to explore the success of one major airport in aligning communication strategies to improve its reputation. The research question involved how effectively a major German airport communicated its commitment to sustainable corporate responsibility to its key stakeholders during 2005--2009. Of particular interest was how key stakeholders perceived the airport's stance towards the impacts of aircraft noise. Corporate documents, newspaper articles, and semistructured interviews comprised the data. Data …

Security Applications Of Formal Language Theory, Len Sassaman, Meredith L. Patterson, Sergey Bratus, Michael E. Locasto, Anna Shubina

Computer Science Technical Reports

We present an approach to improving the security of complex, composed systems based on formal language theory, and show how this approach leads to advances in input validation, security modeling, attack surface reduction, and ultimately, software design and programming methodology. We cite examples based on real-world security flaws in common protocols representing different classes of protocol complexity. We also introduce a formalization of an exploit development technique, the parse tree differential attack, made possible by our conception of the role of formal grammars in security. These insights make possible future advances in software auditing techniques applicable to static and dynamic …

Temperature Dependence Of Sio2 Electron-Induced Luminescence, Amberly Evans Jensen, Gregory Wilson, Jr Dennison

Presentations

No abstract provided.

Scaling Of Losses With Size And Wavelength In Nanoplasmonics And Metamaterials, Jacob B. Khurgin, Greg Sun

Physics Faculty Publications

We show that, for the resonant metal-dielectric structures with sub-wavelength confinement of light in all three dimensions, the loss cannot be reduced considerably below the loss of the metal itself unless one operates in the far IR and THz regions of the spectrum or below. Such high losses cannot be compensated by introducing gain due to Purcell-induced shortening of recombination times. The only way low loss optical meta-materials can be engineered is with, as yet unknown, low loss materials with negative permittivity.

Stratigraphic Record Of Holocene Coseismic Subsidence, Padang, West Sumatra, Tina Dura, Charles M. Rubin, Harvey M. Kelsey, Benjamin P. Horton, Andrea Hawkes, Christopher H. Vane, Mudrik Daryono, Candace Grand Pre, Tyler Landinsky, Sarah Bradley

All Faculty Scholarship for the College of the Sciences

Stratigraphic evidence is found for two coseismic subsidence events that underlie a floodplain 20 km south of Padang, West Sumatra along the Mentawai segment (0.5°S–0.3°S) of the Sunda subduction zone. Each earthquake is marked by a sharp soil‐mud contact that represents a sudden change from mangrove to tidal flat. The earthquakes occurred about 4000 and 3000 cal years B.P. based on radiocarbon ages of detrital plant fragments and seeds. The absence of younger paleoseismic evidence suggests that late Holocene relative sea level fall left the floodplain too high for an earthquake to lower it into the intertidal zone. Our results …

A Foveated System For Wilderness Search And Rescue In Manned Aircraft, Carson D. Fenimore

Theses and Dissertations

Wilderness search and rescue can be assisted by video searchers in manned aircraft. The video searcher's primary task is to find clues on the ground. Due to altitude, it may be difficult to resolve details on the ground with a standard video camera. As the video streams at a constant frame rate, the searcher may become distracted by other tasks. While handling these tasks the searcher may miss important clues or spend extra time flying over the search area; either outcome decreases both the effectiveness of the video searcher and the chances of successfully finding missing persons. We develop an …

De Sitter Gravity From Lattice Gauge Theory, Simon Catterall, Daniel Ferrante, Arwen Nicholson

Physics - All Scholarship

We investigate a lattice model for Euclidean quantum gravity based on discretization of the Palatini formulation of General Relativity. Using Monte Carlo simulation we show that while a naive approach fails to lead to a vacuum state consistent with the emergence of classical spacetime, this problem may be evaded if the lattice action is supplemented by an appropriate counter term. In this new model we find regions of the parameter space which admit a ground state which can be interpreted as (Euclidean) de Sitter space.

Does Gender Bias Influence Awards Given By Societies?, Mary Anne Holmes, Pranoti Asher, John Farrington, Rana Fine, Margaret S. Leinen, Phoebe Leboy

Department of Earth and Atmospheric Sciences: Faculty Publications

AGU is a participant in a U.S. National Science Foundation (NSF)–funded project called Advancing Ways of Awarding Recognition in Disciplinary Societies (AWARDS), which seeks to examine whether gender bias affects selection of recipients of society awards. AGU is interested in learning why there is a higher proportion of female recipients of service and education awards over the past 2 decades. Combined with a lower rate of receipt of research awards, these results suggest that implicit (subconscious) bias in favor of male candidates still influences awardee selection.

Six other professional societies (American Chemical Society, American Mathematical Society, American Society of Anesthesiologists, …

Orbital Separation Amplification In Fragile Binaries With Evolved Components, K. B. Johnston, Terry D. Oswalt

Publications

The secular stellar mass-loss causes an amplification of the orbital separation in fragile, common proper motion, binary systems with separations of the order of 1000 A.U. In these systems, companions evolve as two independent coeval stars as they experience negligible mutual tidal interactions or mass transfer. We present models for how post-main sequence mass-loss statistically distorts the frequency distribution of separations in fragile binaries. These models demonstrate the expected increase in orbital seapration resulting from stellar mass-loss, as well as a perturbation of associated orbital parameters. Comparisons between our models and observations resulting from the Luyten survey of wide visual …

The Stellar-Activity–Rotation Relationship And The Evolution Of Stellar Dynamos, Nicholas J. Wright, Jeremy J. Drake, Eric E. Mamajek, Gregory W. Henry

Information Systems and Engineering Management Research Publications

We present a sample of 824 solar and late-type stars with X-ray luminosities and rotation periods. This is used to study the relationship between rotation and stellar activity and derive a new estimate of the convective turnover time. From an unbiased subset of this sample the power-law slope of the unsaturated regime, LX/Lbol∝Roβ, is fit as β = −2.70 ± 0.13. This is inconsistent with the canonical β = −2 slope to a confidence of 5σ, and argues for an additional term in the dynamo number equation. From a simple scaling analysis this implies ΔΩ/Ω∝Ω0.7, i.e., the differential rotation of …

Green Worlds And Ecosemiotics, Paul Siewers

Faculty Conference Papers and Presentations

"Overlay landscapes" in Early Insular literatures, and how they connect early medieval cosmology with current-day ecosemiotics..

Transition From Static To Dynamic Macroscopic Friction In The Framework Of The Frenkel-Kontorova Model, Naum I. Gershenzon, Gust Bambakidis

Physics Faculty Publications

A new generation of experiments on dry macroscopic friction has revealed that the transition from static to dynamic friction is essentially a spatially and temporally non-uniform process, initiated by a rupture-like detachment front. We show the suitability of the Frenkel-Kontorova model for describing this transition. The model predicts the existence of two types of detachment fronts, explaining both the variability and abrupt change of velocity observed in experiments. The quantitative relation obtained between the velocity of the detachment front and the ratio of shear to normal stress is consistent with experiments. The model provides a functional dependence between slip velocity …

The Effect Of Oxidation And Support On Tio2(110)-Supported Pdn (N=1-7) Clusters, S. Vincent Ong

Theses and Dissertations

First principles theoretical studies based on a gradient-corrected density functional approach have been carried out on the atomic and electronic properties and oxidation of Pdn (n=1-7) clusters supported on the TiO2(110) surface. The studies are aimed to address some of the fundamental issues related to the properties of supported Pdn clusters used as catalysts in oxidation reactions. Of those issues are the following: What are the atomic structures of Pdn clusters on the TiO2 surface? Upon oxidation, do O atoms from a dissociated O2 molecule spill over onto the underlying TiO2 sup- port? How strongly does spillover oxygen bind? What …

Circular And Near-Circular Polarization States Of Evanescent Monochromatic Light Fields In Total Internal Reflection, R. M. A Azzam

Electrical Engineering Faculty Publications

Conditions for the production of near-circular polarization states of the evanescent field present in the rarer medium in total internal reflection of incident monochromatic p-polarized light at a dielectric-dielectric planar interface are determined. Such conditions are satisfied if high-index (>3.2) transparent prism materials (e.g., GaP and Ge) are used at angles of incidence well above the critical angle but sufficiently below grazing incidence. Furthermore, elliptical polarization of incident light with nonzero p and s components can be tailored to cause circular polarization of the resultant tangential electric field in the plane of the interface or circular polarization of the …