Open Access. Powered by Scholars. Published by Universities.®
Physical Sciences and Mathematics Commons™
Open Access. Powered by Scholars. Published by Universities.®
- Discipline
-
- Physics (504)
- Environmental Sciences (482)
- Computer Sciences (348)
- Chemistry (299)
- Engineering (261)
-
- Earth Sciences (239)
- Life Sciences (223)
- Mathematics (215)
- Education (168)
- Social and Behavioral Sciences (166)
- Science and Mathematics Education (130)
- Oceanography and Atmospheric Sciences and Meteorology (120)
- Geology (107)
- Arts and Humanities (106)
- Natural Resources Management and Policy (101)
- Natural Resources and Conservation (90)
- Water Resource Management (88)
- Physical Chemistry (81)
- Astrophysics and Astronomy (78)
- Electrical and Computer Engineering (78)
- History (70)
- Computer Engineering (68)
- Mechanical Engineering (68)
- Soil Science (67)
- United States History (64)
- Law (63)
- Energy Systems (60)
- Other Mechanical Engineering (60)
- History of Science, Technology, and Medicine (59)
- Institution
-
- University of Nebraska - Lincoln (371)
- TÜBİTAK (264)
- Utah State University (94)
- Old Dominion University (85)
- Missouri University of Science and Technology (72)
-
- Chinese Chemical Society | Xiamen University (70)
- University of Northern Iowa (54)
- Claremont Colleges (50)
- Department of Primary Industries and Regional Development, Western Australia (50)
- Portland State University (46)
- Syracuse University (44)
- Singapore Management University (43)
- Dartmouth College (40)
- Purdue University (39)
- University of New Hampshire (39)
- University of Kentucky (38)
- Chulalongkorn University (36)
- New Jersey Institute of Technology (36)
- Air Force Institute of Technology (35)
- California Polytechnic State University, San Luis Obispo (31)
- University of Colorado Law School (30)
- University of South Florida (26)
- Wright State University (26)
- Nova Southeastern University (24)
- Edith Cowan University (23)
- University of Arkansas, Fayetteville (23)
- Western Michigan University (22)
- Brigham Young University (21)
- University of Nevada, Las Vegas (20)
- Washington University in St. Louis (20)
- Keyword
-
- Western Australia (37)
- Groundwater (20)
- United States (18)
- Environmental (16)
- Outdoor education (16)
-
- Algorithms (14)
- Water quality (14)
- Impact (12)
- Management (12)
- Nebraska (12)
- Salinity (12)
- Utah (12)
- Engineering (11)
- Watersheds (11)
- Assessment (10)
- Mathematics (10)
- Resource (10)
- College of Engineering and Computer Science (9)
- Computer Science (9)
- Nevada (9)
- Newsletters (9)
- Science news (9)
- Statement (9)
- Technical writing (9)
- Watershed management (9)
- Western Kentucky University (9)
- Colorado (8)
- Computer science (8)
- Decision (8)
- Environment (8)
- Publication
-
- Turkish Journal of Physics (132)
- Journal of Electrochemistry (70)
- Faculty Publications (65)
- Nebraska Tractor Tests (59)
- Turkish Journal of Chemistry (55)
-
- Research Collection School Of Computing and Information Systems (43)
- Journal of the Iowa Academy of Science: JIAS (42)
- Theses and Dissertations (42)
- Department of Computer Science Technical Reports (39)
- Turkish Journal of Mathematics (38)
- Thai Environment (36)
- Humanistic Mathematics Network Journal (33)
- Theses (33)
- Physics Faculty Research & Creative Works (29)
- Physics Faculty Publications (26)
- Vertebrate Pest Conference Proceedings: 18th (1998) (26)
- All Physics Faculty Publications (24)
- Chemistry Faculty Research & Creative Works (24)
- Dartmouth Scholarship (24)
- Outdoor Recreation: Promise and Peril in the New West (Summer Conference, June 8-10) (23)
- All U.S. Government Documents (Utah Regional Depository) (22)
- Kenneth Bloom Publications (22)
- Dissertations (21)
- Turkish Journal of Earth Sciences (21)
- All Computer Science and Engineering Research (20)
- RISK: Health, Safety & Environment (1990-2002) (20)
- Drought Network News (1994–2001) (19)
- Conservation and Survey Division: Faculty and Staff Publications (18)
- Turkish Journal of Electrical Engineering and Computer Sciences (18)
- United States Department of Agriculture Wildlife Services: Staff Publications (18)
- Publication Type
- File Type
Articles 481 - 510 of 2339
Full-Text Articles in Physical Sciences and Mathematics
Bond System Monitor, Kyung-Koo Jun, Ladislau Bölöni, Ruibing Hao, Dan C. Marinescu
Bond System Monitor, Kyung-Koo Jun, Ladislau Bölöni, Ruibing Hao, Dan C. Marinescu
Department of Computer Science Technical Reports
No abstract provided.
Improved Measurement Of The Pseudoscalar Decay Constant FDS, M. Chada, Kenneth A. Bloom, Cleo Collaboration
Improved Measurement Of The Pseudoscalar Decay Constant FDS, M. Chada, Kenneth A. Bloom, Cleo Collaboration
Kenneth Bloom Publications
We present a new determination of fDs using 5 million e+e- → cc̅ events obtained with the CLEO II detector. Our value is derived from our new measured ratio Γ(Ds+ → μ+ν)/Γ(Ds+ → φ π +) = 0.173±0.023 ±0.035. Using Ɓ(Ds+ → φ π +) = (3.6±0.9)%, we extract fDs = (280±19±28±34) MeV. We compare this result with various model calculations.
Electric Potential In The Classical Hall Effect: An Unusual Boundary-Value Problem, Matthew J. Moelter, James Evans, Greg Elliot, Martin Jackson
Electric Potential In The Classical Hall Effect: An Unusual Boundary-Value Problem, Matthew J. Moelter, James Evans, Greg Elliot, Martin Jackson
Physics
The classical Hall effect presents a surprisingly unusual and challenging problem in electrostatics, with boundary conditions that are not of Dirichlet, Neumann, or of mixed Dirichlet and Neumann type. These unusual boundary conditions create several difficulties not normally encountered in standard problems, and ultimately lead to expansion of the electric potential in a nonorthogonal basis set. We derive the boundary conditions for the potential in a rectangular geometry, construct a solution for the potential, and discuss the relation between this problem and problems of the standard mixed type. We also address a commonly encountered misconception about the current distribution.
On-Road Remote Sensing Of Automobile Emissions In The Chicago Area: Year 1, Peter J. Popp, Gary A. Bishop, Donald H. Stedman
On-Road Remote Sensing Of Automobile Emissions In The Chicago Area: Year 1, Peter J. Popp, Gary A. Bishop, Donald H. Stedman
Fuel Efficiency Automobile Test Publications
No abstract provided.
Architectural Optimization Of Digital Libraries, Aileen O. Biser
Architectural Optimization Of Digital Libraries, Aileen O. Biser
Computer Science Theses & Dissertations
This work investigates performance and scaling issues relevant to large scale distributed digital libraries. Presently, performance and scaling studies focus on specific implementations of production or prototype digital libraries. Although useful information is gained to aid these designers and other researchers with insights to performance and scaling issues, the broader issues relevant to very large scale distributed libraries are not addressed. Specifically, no current studies look at the extreme or worst case possibilities in digital library implementations. A survey of digital library research issues is presented. Scaling and performance issues are mentioned frequently in the digital library literature but are …
The Use Of A Phenology Model And Of Risk Analyses For Planning Buckwheat (Fagopyrum Esculentum) Sowing Dates In Alpine Areas, Johann Baumgärtner, Per Schilperoord, Paolo Basetti, Alberto Baiocchi, Mauro Jermini
The Use Of A Phenology Model And Of Risk Analyses For Planning Buckwheat (Fagopyrum Esculentum) Sowing Dates In Alpine Areas, Johann Baumgärtner, Per Schilperoord, Paolo Basetti, Alberto Baiocchi, Mauro Jermini
All Peer-Reviewed Publications
A published temperature-dependent phenology model constructed for representing buckwheat (Fagopyrum esculentum) development has been calibrated. The model considers the phenophases of sowing to emergence, of emergence to first anthesis, and of first anthesis to physiological maturity. It is used for the strategic planning of buckwheat production in Alpine areas and predicts the latest possible sowing dates in areas of the Swiss cantons of the Grisons and of the Ticino as well as of the Italian province of Sondrio. The area-specific date is calculated by taking into account a probability of 1% for crop failure which occurs when the crop is …
Self-Calibrating Method For Measuring Local Multiphotonionization Yields As A Function Of Absolute Intensity, Cornelis J. Uiterwaal, B. Witzel, H. Schröder, K.-L. Kompa
Self-Calibrating Method For Measuring Local Multiphotonionization Yields As A Function Of Absolute Intensity, Cornelis J. Uiterwaal, B. Witzel, H. Schröder, K.-L. Kompa
C.J.G.J. Uiterwaal Publications
We present a self-calibrating method for measuring local multiphoton-ionization yields as a function of absolute intensity. In contrast to the method recently described by Walker et al. [Phys. Rev. A 57, R701 (1998)], our method does not require any assumption on the intensity distribution inside a laser focus, nor does it use any mathematical procedure such as deconvolution that would be based on such an assumption. In this sense, our method is self-calibrating. The proposed method immediately gives ion yields as a function of absolute intensity. Furthermore, it allows the intensity distribution inside the focal volume to be measured with …
Micromagnetics Of Ultrathin Films With Perpendicular Magnetic Anisotropy , Ralph Skomski, H.-P. Oepen, J. Kirschner
Micromagnetics Of Ultrathin Films With Perpendicular Magnetic Anisotropy , Ralph Skomski, H.-P. Oepen, J. Kirschner
Ralph Skomski Publications
Magnetization processes in ultra-thin transition-metal films with perpendicular magnetic anisotropy are investigated. By model calculations it is shown that nucleation in ideal films is incoherent and therefore bulk-like, whereas the truly ultra-thin limit of coherent nucleation is restricted to film patches of small cross-section areas. In ideal mono-layers, the nonzero film thickness leads to bulk-like nucleation if the lateral dimensions of the film exceed about 1 mm. This means that monolayer patches having sub-micrometer diameters cannot be regarded as ultra-thin in a micro-magnetic sense. On the other hand, the critical single-domain diameter of ultra-thin films is larger by one order …
Neutron Diffraction And Mössbauer Spectral Study Of Nd₂Fe₁₆Ti And Its Nitride, Fernande Grandjean, Peter C. Ezekwenna, Gary J. Long, Oran Allan Pringle, P. H. L'Héritier, Mohamed Ellouze, H. P. Luo, William B. Yelon
Neutron Diffraction And Mössbauer Spectral Study Of Nd₂Fe₁₆Ti And Its Nitride, Fernande Grandjean, Peter C. Ezekwenna, Gary J. Long, Oran Allan Pringle, P. H. L'Héritier, Mohamed Ellouze, H. P. Luo, William B. Yelon
Chemistry Faculty Research & Creative Works
The 295 K powder neutron diffraction patterns and the temperature dependence of the Mössbauer spectra of Nd2Fe17-xTix and Nd2Fe17-xTixNx have been measured. A Rietveld refinement of the neutron diffraction patterns yields the Nd2Fe16.32Ti0.68 and Nd2Fe16.32Ti0.68N2.7 stoichiometries for the two compounds and indicates that titanium occupies only the 6c crystallographic site and nitrogen only the 9e site in the rhombohedral Th2Zn17 structure. The insertion of interstitial nitrogen into Nd2Fe16.32Ti0.68 …
Search For Sleptons In E+E- Collisions At Centre-Of-Mass Energies Up To 184 Gev Aleph Collaboration, R. Barate, Manoj Thulasidas
Search For Sleptons In E+E- Collisions At Centre-Of-Mass Energies Up To 184 Gev Aleph Collaboration, R. Barate, Manoj Thulasidas
Research Collection School Of Computing and Information Systems
The data collected by the ALEPH experiment at LEP at centre–of–mass energies around 183 GeV are analysed to search for sleptons, the partners of leptons in supersymmetric theories. The previously published search for acoplanar leptons and missing energy has been updated. New searches have been developed to cover a wider range of slepton signals. These include single electrons, acoplanar leptons accompanied by two photons plus missing energy as well as particles with lifetime. No evidence for the production of any such particles is found. Slepton mass limits are reported within gravity mediated and gauge mediated SUSY breaking scenarios.
Scalar Quark Searches In E+E- Collisions At √S = 181 - 184 Gev, Barate, R.; Et Al., M. Thulasidas
Scalar Quark Searches In E+E- Collisions At √S = 181 - 184 Gev, Barate, R.; Et Al., M. Thulasidas
Research Collection School Of Computing and Information Systems
Searches for scalar top, scalar bottom and degenerate scalar quarks have been performed with data collected with the ALEPH detector at LEP. The data sample consists of 57 pb−1 taken at s = 181–184 GeV. No evidence for scalar top, scalar bottom or degenerate scalar quarks was found in the channels t̃→cχ, t̃→bℓν̃, b̃→bχ, and q̃→qχ. From the channel t̃→cχ a limit of 74 GeV/c2has been set on the scalar top quark mass, independent of the mixing angle. This limit assumes a mass difference between the t̃ and the χ in the range 10–40 GeV/c2. From the channel t̃→bℓν̃ the …
Improvement Of Epa Method 8330: Complete Separation Of Explosives Using A Two Phase Approach, Michael J. Lang
Improvement Of Epa Method 8330: Complete Separation Of Explosives Using A Two Phase Approach, Michael J. Lang
Masters Theses
A wide range of primary and secondary contaminants is found in environmental matrices containing explosive residues. HPLC methodology for the detection of explosive is now standardized in EPA Method 8330, and represents the most common method currently used for explosive analysis. However, co-elution of some of the analytes occurs even using method 8330. As a result, explosive analysis using HPLC have required the use of a confirmation column in an additional analysis step.
In the current work, all of the compounds in the EPA 8330 explosives list were resolved using a single HPLC separation. While the EPA 8330 HPLC conditions …
Join Processing In Web Databases, Sourav S. Bhowmick, Wee-Keong Ng, Ee Peng Lim
Join Processing In Web Databases, Sourav S. Bhowmick, Wee-Keong Ng, Ee Peng Lim
Research Collection School Of Computing and Information Systems
Recently, there has been increasing interests in data models and query languages for unstructured data in the World Wide Web. When web data is harnessed in a web warehouse, new and useful information can be derived through appropriate information manipulation. In our web warehousing project, we introduce a new operator called the web join. Like its relational counterpart, web join combines information from two web tables to yield a new web table. This paper discusses various issues in web join such as join semantics, joinability, and join evaluation.
The Forward-Backward Asymmetry For Charm Quarks At The Z, R. Barate, Manoj Thulasidas
The Forward-Backward Asymmetry For Charm Quarks At The Z, R. Barate, Manoj Thulasidas
Research Collection School Of Computing and Information Systems
From 1.4 million hadronic Z decays collected by the ALEPH detector at LEP, an enriched sample of Z → cc̄ events is extracted by requiring the presence of a high momentum D∗±. The charm quark forward-backward charge asymmetry at the Z pole is measured to be AFB0.c = (8.0 ± 2.4) % corresponding to an effective electroweak mixing angle of sin2θWeff = 0.2302 ± 0.0054.
Information Systems And Economics, Robert J. Kauffman, Frederick J. Riggins
Information Systems And Economics, Robert J. Kauffman, Frederick J. Riggins
Research Collection School Of Computing and Information Systems
Do big dollar expenditures on information systems pay off? Friction-free: is that what we really want markets to be? Is it time for consumers to say goodbye to fixed pricing? The Internet creates an environment in which the cost of buyer-seller interactions is cheaper than ever, and consumers can participate in the price-setting process—revealing their willingness to pay—making it the most efficient one-on-one selling environment anywhere, approaching the efficiency of the financial markets. In fact, such transformation is evident throughout the information economy. We see it in the approximately 1,000% annual network growth rates expected by some Internet service providers’ …
Modelling Medical Decisions In Dynamol: A New General Framework Of Dynamic Decision Analysis, Tze-Yun Leong, Cungen Cao
Modelling Medical Decisions In Dynamol: A New General Framework Of Dynamic Decision Analysis, Tze-Yun Leong, Cungen Cao
Research Collection School Of Computing and Information Systems
Dynamic decision analysis concerns decision problems in which both time and uncertainty are explicitly considered. We present a new dynamic decision analysis framework, called DynamoL, that supports graphical presentation of the decision factors in multiple perspectives. To alleviate the difficulty in assessing conditional probabilities over time in dynamic decision models, DynaMoL incorporates a Bayesian learning system to automatically learn the probabilistic parameters from large medical databases. We describe the DynaMoL modeling and learning architecture through a medical decision problem on the optimal follow-up schedule for patients after curative colorectal cancer surgery. We also show that the modeling experience and results …
Water Flow Through Temperate Glaciers, Andrew G. Fountain, Joseph S. Walder
Water Flow Through Temperate Glaciers, Andrew G. Fountain, Joseph S. Walder
Geography Faculty Publications and Presentations
Understanding water movement through a glacier is fundamental to several critical issues in glaciology, including glacier dynamics, glacier-induced floods, and the prediction of runoff from glacierized drainage basins. To this end we have synthesized a conceptual model of water movement through a temperate glacier from the surface to the outlet stream. Processes that regulate the rate and distribution of water input at the glacier surface and that regulate water movement from the surface to the bed play important but commonly neglected roles in glacier hydrology. Where a glacier is covered by a layer of porous, permeable firn (the accumulation zone), …
Radiocarbon From Nuclear Testing Applied To Age Validation Of Black Drum, Pogonias Cromis, Steven E. Campana, Cynthia M. Jones
Radiocarbon From Nuclear Testing Applied To Age Validation Of Black Drum, Pogonias Cromis, Steven E. Campana, Cynthia M. Jones
OES Faculty Publications
Radiocarbon ((14)C) in the world's oceans increased sharply between 1950 and 1970 as a result of the atmospheric testing of nuclear weapons. Through comparison with the (14)C time series reconstructed from atmospheric measurements and marine carbonates, Kalish, in 1993, used the (14)C concentration measured in fish otolith cores as a means of confirming the annulus-based age estimates for some South Pacific fish species. Here we report the pre-and postbomb (14)C chronology of North Atlantic adult black drum (Pogonias cronis), assumed to be between 15 and 42 yr of age on the basis of otolith annulus counts. According to …
Enantiomeric Separation Of Unusual Secondary Aromatic Amino Acids, A. Péter, G. Török, G. Tóth, W. Van Den Nest, G. Laus, D. Tourwé, Daniel W. Armstrong
Enantiomeric Separation Of Unusual Secondary Aromatic Amino Acids, A. Péter, G. Török, G. Tóth, W. Van Den Nest, G. Laus, D. Tourwé, Daniel W. Armstrong
Chemistry Faculty Research & Creative Works
High-performance liquid chromatographic and gas chromatographic methods were developed for the separation of unusual secondary aromatic amino acids. Amino acids containing 1,2,3,4-tetrahydroisoquinoline, 1,2,3,4-tetrahydronorharmane-1-carboxylic acid and 1,2,3,4-tetrahydro-3-carboxy-2-carboline moieties were synthetized in racemic or chiral forms. The high-performance liquid chromatography was carried out either on a teicoplanin-containing chiral stationary phase or on an achiral C18 column. In the latter case the diastereomers of the amino acids formed by precolumn derivatization with the chiral reagents 2,3,3,6-tetra-O-acetyl-β-D-glucopyranosyl isothiocyanate or 1-fluoro-2,4-dinitrophenyl-5-L-alanine amide were separated. The gas chromatographic analyses were based on separation on a Chirasil-L-Val column.
Disorder-Induced Topological Defects In A D=2 Elastic Medium At Zero Temperature, Alan Middleton
Disorder-Induced Topological Defects In A D=2 Elastic Medium At Zero Temperature, Alan Middleton
Physics - All Scholarship
The density and correlations of topological defects are investigated numerically in a model of a d=2 elastic medium subject to a periodic quenched random potential. The computed density of defects decreases approximately exponentially with the defect core energy. Comparing the defect-free ground state with the ground state with defects, it is found that the difference is described by string-like excitations, bounded by defect pairs, which have a fractal dimension of 1.250(3). At zero temperature, the disorder-induced defects screen the interaction of introduced vortex pairs.
Cold Relativistic Wavebreaking, J.K. Kim, Donald P. Umstadter
Cold Relativistic Wavebreaking, J.K. Kim, Donald P. Umstadter
Donald Umstadter Publications
The two-dimensional wave-breaking of relativistic plasma waves driven by a ultrashort high-power lasers, is described within a framework of cold 2-D fluid theory. It is shown that the transverse nonlinearity of the plasma wave results in temporally increasing transverse plasma oscillation in the wake of the laser pulse, inevitably inducing wave-breaking below the 1-D threshold. A condition for wavebreaking is obtained and evaluated. A preformed density channel is found to partially cancel the effect and increase the length of wakefield that survives before wavebreaking occurs.
Octary Codewords With Power Envelopes Of 3∗2M, Katherine M. Nieswand, Kara N. Wagner
Octary Codewords With Power Envelopes Of 3∗2M, Katherine M. Nieswand, Kara N. Wagner
Department of Math & Statistics Technical Report Series
This paper examines codewords of length 2m in Z8 with envelope power maxima of 3 ∗ 2m. Using the general form for Golay pairs as a base, a general form is derived for the set of coset leaders that generate these codewords. From this general form it will be proven that there exists at least one element in the coset that achieves a power of 3 ∗ 2m for each m-even and m-odd case.
40th Rocky Mountain Conference On Analytical Chemistry
40th Rocky Mountain Conference On Analytical Chemistry
Rocky Mountain Conference on Magnetic Resonance
Final program, abstracts, and information about the 40th annual meeting of the Rocky Mountain Conference on Analytical Chemistry, co-sponsored by the Colorado Section of the American Chemical Society and the Rocky Mountain Section of the Society for Applied Spectroscopy. Held in Denver, Colorado, July 25 - August 1, 1998.
Role Of The Maillard Reaction In Aging Of Tissue Proteins: Advanced Glycation End Product-Dependent Increase In Imidazolium Cross-Links In Human Lens Proteins, Elisabeth Brinkmann Frye, Thorsten P. Degenhardt, Suzanne R. Thorpe, John W. Baynes
Role Of The Maillard Reaction In Aging Of Tissue Proteins: Advanced Glycation End Product-Dependent Increase In Imidazolium Cross-Links In Human Lens Proteins, Elisabeth Brinkmann Frye, Thorsten P. Degenhardt, Suzanne R. Thorpe, John W. Baynes
Faculty Publications
Dicarbonyl compounds such as glyoxal and methylglyoxal are reactive dicarbonyl intermediates in the nonenzymatic browning and cross-linking of proteins during the Maillard reaction. We describe here the quantification of glyoxal and methylglyoxal-derived imidazolium cross-links in tissue proteins. The imidazolium salt cross-links, glyoxal-lysine dimer (GOLD) and methylglyoxal-lysine dimer (MOLD), were measured by liquid chromatography/mass spectrometry and were present in lens protein at concentrations of 0. 02-0.2 and 0.1-0.8 mmol/mol of lysine, respectively. The lens concentrations of GOLD and MOLD correlated significantly with one another and also increased with lens age. GOLD and MOLD were present at significantly higher concentrations than the …
Asymptotic Norming Properties And Related Themes., Sudeshna Basu Dr.
Asymptotic Norming Properties And Related Themes., Sudeshna Basu Dr.
Doctoral Theses
In the first part of this chapter, we explain the main theme of this thesis. The second part consists of some of the notions and results used in subsequent discussions.It is a very familiar fact that a point outside a (bounded) closed convex set in a Banach space can be separated from the latter by a hyperplane. One can ask whether the separation can be effected by disjoint balls. This is a typical example of a ball separation property, study of which has become important in Banach space theory. In this thesis, we study several such properties along with some …
Statistics Of Active Galactic Nuclei In Rich Clusters Revisited, M. Way, R. Flores, H. Quintana
Statistics Of Active Galactic Nuclei In Rich Clusters Revisited, M. Way, R. Flores, H. Quintana
Physics Faculty Works
Using the spectrophotometry of a large sample of galaxies in 19 Abell clusters, we have selected 42 candidate active galactic nuclei (AGNs) using the criteria used by Dressler and coworkers in their analysis of the statistics of 22 AGNs in 14 rich cluster fields, which are based on the equivalent width of [O II] 3727 Å, Hβ, and [O III] 5007 Å emission. We have then discriminated AGNs from H II region-like galaxies (hereafter H II galaxies) in the manner developed by Veilleux & Osterbrock using the additional information provided by Hα and [N II] 6583 Å or Hα and …
Synthesis And Characterization Of Large Stereoregular Organosiloxane Cycles, O. I. Schchegolikhina, V. A. Igonin, Yulia A. Molodtsova, Yu. A. Pozdniakova, Alexandr A. Zhdanov, T. V. Strelkova, Sergey V. Lindeman
Synthesis And Characterization Of Large Stereoregular Organosiloxane Cycles, O. I. Schchegolikhina, V. A. Igonin, Yulia A. Molodtsova, Yu. A. Pozdniakova, Alexandr A. Zhdanov, T. V. Strelkova, Sergey V. Lindeman
Chemistry Faculty Research and Publications
The large stereoregular phenyltrimethylsiloxysiloxane macrocycles of general formula [PhSi(OSiMe3)O]n (n=6 and 12) have been selectively obtained with high yields by trimethylsilylation of cage-like oligophenylmetallasiloxanes (OPMS) which we described earlier. The compounds 3 (n=6) and 4 (n=12) have been characterized by NMR-spectroscopy method and by single crystal X-ray analysis. This investigation showed unambiguously that the siloxane macrocycles keep their size and configuration (the same as in the initial OPMS) during the trimethylsilylation. Thus a synthetic route for obtaining large stereoregular siloxane macrocycles has been developed.
Selective Determination Of Methylmercury By Flow-Injection Fast-Scan Voltammetry, Rebecca Lai, Eva Huang, Feimeng Zhou, David O. Wipf
Selective Determination Of Methylmercury By Flow-Injection Fast-Scan Voltammetry, Rebecca Lai, Eva Huang, Feimeng Zhou, David O. Wipf
Rebecca Lai Publications
A simple flow-injection system, suitable for solution flow rates at microliters-per-minute, has been combined with fast-scan voltammetry for selective determination of methylmercury. A thin Hg film was formed at a Pt microelectrode prior to the measurement. Detection of methylmercury is carried out by measuring the oxidation of methylmercury radicals that have been generated at the Hg microelectrode. At slow scan rates, the electrogenerated methylmercury radicals undergo a follow-up dimerization reaction to form dimethyldimercury (ErCi2 mechanism). At fast scan rates, it was found that methylmercury radicals can be quantitatively reoxidized (reversible electron-transfer). Optimization of the experimental conditions …
Spiral Morphology-Dependent Resonances In An Optical Fiber: Effects Of Fiber Tilt And Focused Gaussian Beam Illumination, Andrew W. Poon, Richard K. Chang, James A. Lock
Spiral Morphology-Dependent Resonances In An Optical Fiber: Effects Of Fiber Tilt And Focused Gaussian Beam Illumination, Andrew W. Poon, Richard K. Chang, James A. Lock
Physics Faculty Publications
Spiral morphology-dependent resonances have been observed in a tilted optical fiber. The polarization-preserving and the cross-polarized elastic-scattering spectra for plane-wave illumination show that the wavelengths of the resonances are blueshifted quadratically as the fiber tilt angle increases. When a focused Gaussian beam illuminates the fiber at its edge, the resonances are blueshifted and broadened as the detector is offset from the scattering plane with the maximum scattering intensity. The blueshift with focused beam illumination is also a consequence of the spiral resonances. (C) 1998 Optical Society of America.
2-Phenyl-3-(5,6,7,7a-Tetrahydro-1h,3h-Pyrrolo[1,2-C]Oxazol-3-Ylidene)-1-Propene-1,1-Dicarbonitrile And 4-(4-Methoxyphenyl)-2,6-Bis(Methylthio)Pyridine-3-Carbonitrile, M. George, S. Das, C.V. Ashokan, N.P. Rath, M.V. George
2-Phenyl-3-(5,6,7,7a-Tetrahydro-1h,3h-Pyrrolo[1,2-C]Oxazol-3-Ylidene)-1-Propene-1,1-Dicarbonitrile And 4-(4-Methoxyphenyl)-2,6-Bis(Methylthio)Pyridine-3-Carbonitrile, M. George, S. Das, C.V. Ashokan, N.P. Rath, M.V. George
Chemistry & Biochemistry Faculty Works
The reaction of 3-aryl-2-cyano-5,5-bis(methylthio)penta-2,4-dienenitrile, (1), with (L)-(-)-2-hydroxymethylpyrrolidine, (2), gave two types of product, the normal substitution product, (3), and a pyridine derivative, (4). The structures of two representative examples, 2-phenyl-3-(5,6,7,7a-tetrahydro1H,3H-pyrrolo[1,2-c]oxazol-3-ylidene)-1-propene-1,1-dicarbonitrile, (3a), as its hemibenzene solvate, C17H14N3O.0.5C6H6, and 4-(4-methoxyphenyl)-2,6-bis(methylthio)pyridine-3-carbonitrile, (4b), C15H14N2OS2, have been unambiguously established by X-ray crystallographic analysis. The molecular packing of (4b) involves loosly held dimers with S1...S1' distances of 3.424 (1) Å.