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Articles 2161 - 2184 of 2184
Full-Text Articles in Physical Sciences and Mathematics
Chemistry And Environmental Implications Of Thio-Red And 2,4,6-Trimercaptotriazine Compounds, Kevin R. Henke
Chemistry And Environmental Implications Of Thio-Red And 2,4,6-Trimercaptotriazine Compounds, Kevin R. Henke
Theses and Dissertations
Many compounds, including Thio-Red® and 2,4,6-trimercaptotriazine, trisodium salt (TMT-55), have been marketed to precipitate mercury and other heavy metals from water, including contaminated ground waters. For the products to be effective, information is needed on the chemistry of the products, how they precipitate metals from aqueous solutions, and the chemistries and stabilities of the precipitates.
CS32-, HS-, and S2- are the dominant sulfur species in Thio-Red®. They precipitate heavy metals from water as sulfides (e.g., HgS, PbS, and ZnS). Thio-Red® also contains traces of poisonous carbon disulfide (CS2). Additional CS2 could form from reactions between dissolved heavy metals and CS32-. …
Knickpoint Analysis Of Streams In North Dakota, South Dakota, And Nebraska, Trent D. Hubbard
Knickpoint Analysis Of Streams In North Dakota, South Dakota, And Nebraska, Trent D. Hubbard
Theses and Dissertations
Analysis of stream profiles, seismic reflection studies, engineering studies, and historical earthquakes indicates uplift in south-central South Dakota and north-central Nebraska over the last 5-10 ma. The purpose of this study was to determine if this uplift could be detected by constructing topographic profiles along, and in close proximity to several streams in this region. The Cannonball River, ND, was used to compare the streams in South Dakota and Nebraska to a stream beyond the affected area.
Data for the profiles were collected from 7 .5 minute topographic maps as well as GPS surveys. Abrupt changes in slope (irregularities) were …
Efficient Implementation Of Image Compression-Postprocessing Algorithm Using A Digital Signal Processor, Nadir Sinaceur
Efficient Implementation Of Image Compression-Postprocessing Algorithm Using A Digital Signal Processor, Nadir Sinaceur
Dissertations and Theses
In this thesis, an attempt has been made to develop a fast way to implement a post-processing algorithm for image compression. All the previous tests for this postprocessing algorithm, which we will present, have been only software based and did not consider the time parameter.
For this purpose a new algorithm is used to compute the 2-D DCT transform. This change made the process a lot faster on a Spare 5 workstation. We have then decided to further increase the speed of the post-processing scheme by implementing it on the ADSP21020 chip.
The results show that such a chip can …
Global Attractors From The Explosion Of Singular Cycles, Carlos Arnoldo Morales, Maria José Pacífico, Enrique Ramiro Pujals
Global Attractors From The Explosion Of Singular Cycles, Carlos Arnoldo Morales, Maria José Pacífico, Enrique Ramiro Pujals
Publications and Research
Abstract:
In this paper we announce recent results on the existence and bifurcations of hyperbolic systems leading to non-hyperbolic global attractors.
Résumé:
Nous présentons dans cette Note des résultats récents concernant l’existence et les bifurcations d’un nouvel attracteur global chaotique.
Soil Information Sheets For The Northern Agricultural Areas, Natural Resources Assessment Group, Agriculture Western Australia, Landcare Western Australia
Soil Information Sheets For The Northern Agricultural Areas, Natural Resources Assessment Group, Agriculture Western Australia, Landcare Western Australia
Agriculture reports
These soil information sheets are produced for farmers in the Northern Wheatbelt. Each sheet summaries information on the particular soil's characteristic properties and associated land use suitability and management. A photograph of a representative profile is provided for each soil. Technical terms are defined in the glossary. Information is presented under the following headings: Soil series and group, occurrence, native vegetation, soil profile description, characteristic soil properties, soil classification (Australian Soil Classification and Northcote Principal Profile Form).
Economic Considerations Of Land-Use And Landcare In The Peel-Harvey Catchment, Roger Attwater
Economic Considerations Of Land-Use And Landcare In The Peel-Harvey Catchment, Roger Attwater
Natural resources published reports
The first section of this paper reviews some spreadsheets of land-use profitability by soil type which were developed in a previous study, "The economic land capability assessment, Waroona to Capel". The second section discusses how externalities can be accounted for by developing a range of complementary approaches which reinforce property rights.
The spreadsheets reviewed were developed as an aid to aggregate land-use planning, and were proposed as a basis for determining transfer payments to reflect the social costs of phosphorus pollution. The spreadsheets were found to lack the flexibility needed to compare alternative management options, and considered inappropriate for dealing …
A Strategy For Monitoring Glaciers, Andrew G. Fountain, Robert M. Krimmel, Dennis C. Trabant
A Strategy For Monitoring Glaciers, Andrew G. Fountain, Robert M. Krimmel, Dennis C. Trabant
Geography Faculty Publications and Presentations
Glaciers are important features in the hydrologic cycle and affect the volume, variability, and water quality of runoff. Assessing and predicting the effect of glaciers on water resources require a monitoring program to provide basic data for this understanding. The monitoring program of the U.S. Geological Survey employs a nested approach whereby an intensively studied glacier is surrounded by less intensively studied glaciers and those monitored solely by remote sensing. Ideally, each glacierized region of the United States would have such a network of glaciers. The intensively studied glacier provides a detailed understanding of the physical processes and their temporal …
An Approach To Display Layout Of Dynamic Windows, Nihar Trivedi
An Approach To Display Layout Of Dynamic Windows, Nihar Trivedi
Theses: Doctorates and Masters
The development of windows based user interface has introduced a new dimension to the field of human computer interaction. Now a user is able to perform multiple tasks at a time, often switching from one task to another. However windows environment also imposes the burden of manual windows management on the user. Several studies have suggested that manual window management is an unproductive chore often resulting in clutter and confusion on the display screen. Therefore we need a automatic windows layout generator to free the user to perform other useful tasks. This thesis introduces SPORDAC {Shadow Propagation for Overlap Removal …
Randomised Shuffle And Applied Misinformation: An Enhanced Model For Contact-Based Smart-Card Serial Data Transfer, Michael Collins
Randomised Shuffle And Applied Misinformation: An Enhanced Model For Contact-Based Smart-Card Serial Data Transfer, Michael Collins
Theses: Doctorates and Masters
Contact-based smart-cards, which comply to the International Standard IS0-7816, communicate with their associated read/write machines via a single bi-directional serial link. This link is easy to monitor with inexpensive equipment and resources, enabling captured data to be removed for later examination. In many contact-based smart-cards the logical abilities are provided by eight-bit microcontroller units (MCU) which are slow at performing effective cryptographic functions. Consequently, for expediency, much data may be transferred in plain-text across the vulnerable communications link, further easing an eavesdropper's task. Practitioners in military communications protect transmitted information by varying a link's carrier frequency in an apparently random …
The Zeus Leading Proton Spectrometer And Its Use In The Measurement Of Elastic Ρ0 Photoproduction At Hera, M. Derrick, D. Krakauer, S. Magill, D. Mikunas, B. Musgrave, J. R. Okrasiński, J. Repond, R. Stanek, R. L. Talaga, H. Zhang, Margarita C. K. Mattingly, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, P. Bruni, G. Cara Romeo, G. Castellini, M. Chiarini, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, I. Gialas, P. Giusti, G. Iacobucci, G. Laurenti
The Zeus Leading Proton Spectrometer And Its Use In The Measurement Of Elastic Ρ0 Photoproduction At Hera, M. Derrick, D. Krakauer, S. Magill, D. Mikunas, B. Musgrave, J. R. Okrasiński, J. Repond, R. Stanek, R. L. Talaga, H. Zhang, Margarita C. K. Mattingly, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, P. Bruni, G. Cara Romeo, G. Castellini, M. Chiarini, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, I. Gialas, P. Giusti, G. Iacobucci, G. Laurenti
Faculty Publications
The differential cross section dσ/dt for elastic ρ0 photoproduction, γp → ρ0ρ (ρ0 → π+π-), has been measured in ep interactions at HERA. The squared four-momentum exchanged at the proton vertex, t, has been determined directly by measuring the momentum of the scattered proton using the ZEUS Leading Proton Spectrometer (LPS), a large scale system of silicon micro-strip detectors operating close to the HERA proton beam. The LPS allows the measurement of the momentum of high energy protons scattered at small angles with accuracies of 0.4% for the longitudinal momentum and 5 MeV for the transverse momentum. Photoproduction of ρ0 …
Measurement Of Inelastic J/Ψ Photoproduction At Hera, J. Breitweg, M. Derrick, D. Krakauer, S. Magill, D. Mikunas, B. Musgrave, J. Repond, R. Stanek, R. L. Talaga, R. Yoshida, H. Zhang, Margarita C. K. Mattingly, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, G. Castellini, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, I. Gialas, P. Giusti, G. Iacobucci, G. Laurenti
Measurement Of Inelastic J/Ψ Photoproduction At Hera, J. Breitweg, M. Derrick, D. Krakauer, S. Magill, D. Mikunas, B. Musgrave, J. Repond, R. Stanek, R. L. Talaga, R. Yoshida, H. Zhang, Margarita C. K. Mattingly, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, G. Castellini, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, I. Gialas, P. Giusti, G. Iacobucci, G. Laurenti
Faculty Publications
No abstract provided.
Measurement Of Elastic J/Ψ Photoproduction St Hera, J. Breitweg, M. Derrick, D. Krakauer, S. Magill, D. Mikunas, B. Musgrave, J. Repond, R. Stanek, R. L. Talaga, R. Yoshida, H. Zhang, Margarita C. K. Mattingly, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, G. Castellini, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, I. Gialas, P. Giusti, G. Iacobucci, G. Laurenti
Measurement Of Elastic J/Ψ Photoproduction St Hera, J. Breitweg, M. Derrick, D. Krakauer, S. Magill, D. Mikunas, B. Musgrave, J. Repond, R. Stanek, R. L. Talaga, R. Yoshida, H. Zhang, Margarita C. K. Mattingly, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, G. Castellini, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, I. Gialas, P. Giusti, G. Iacobucci, G. Laurenti
Faculty Publications
The reaction γ p → J/ψ p has been studied in ep interactions using the ZEUS detector at HERA. The cross section for elastic J/ψ photoproduction has been measured as a function of the photon-proton centre of mass energy W in the range 40 < W < 140 GeV at a median photon virtuality Q2 of 5 × 10-5 GeV2. The photoproduction cross section, σγp→J/ψp, is observed to rise steeply with W. A fit to the data presented in this paper to determine the parameter δ in the form σγp→J/ψp α Wδ yields the value δ = 0.92±0.14±0.10. The differential cross section dσ/d|t| is presented over the range |t| < 1.0 GeV2 where t is the square of the four-momentum exchanged at the proton vertex. dσ/d|t| falls exponentially with a slope parameter of 4.6 ± 0.4-0.6+0.4 GeV-2. The measured decay angular distributions are consistent with s-channel helicity conservation. © Springer-Verlag 1997.
Study Of Photon Dissociation In Diffractive Photoproduction At Hera, J. Breitweg, M. Derrick, D. Krakauer, S. Magill, D. Mikunas, B. Musgrave, J. Repond, R. Stanek, R. L. Talaga, R. Yoshida, H. Zhang, Margarita C. K. Mattingly, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, G. Castellini, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, I. Gialas, P. Giusti, G. Iacobucci, G. Laurenti
Study Of Photon Dissociation In Diffractive Photoproduction At Hera, J. Breitweg, M. Derrick, D. Krakauer, S. Magill, D. Mikunas, B. Musgrave, J. Repond, R. Stanek, R. L. Talaga, R. Yoshida, H. Zhang, Margarita C. K. Mattingly, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, G. Castellini, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, I. Gialas, P. Giusti, G. Iacobucci, G. Laurenti
Faculty Publications
Diffractive dissociation of quasi-real photons at a photon-proton centre of mass energy of W ≈ 200 GeV is studied with the ZEUS detector at HERA. The process under consideration is γp → XN, where X is the diffractively dissociated photon system of mass MX and N is either a proton or a nucleonic system with mass MN < 2 GeV. The cross section for this process in the interval 3 < MX < 24 GeV relative to the total photoproduction cross section was measured to be σDpartial/σtot = 6.2 ± 0.2(stat) ± 1.4(syst)%. After extrapolating this result to the mass interval of mφ2 < MX2 < 0.05W2 and correcting it for proton dissociation, the fraction of the total cross section attributed to single diffractive photon dissociation, γp → Xp, is found to be σSD/σtot = 13.3 ± 0.5(stat) ± 3.6(syst)%. The mass spectrum of the dissociated photon system in the interval 8 < MX < 24 GeV can be described by the triple pomeron (IP IP IP) diagram with an effective pomeron intercept of αIP(0) = 1.12 ± 0.04(stat) ± 0.08(syst). The cross section for photon dissociation in the range 3 < MX < 8 GeV is significantly higher than that expected from the triple pomeron amplitude describing the region 8 < MX < 24 GeV. Assuming that this discrepancy is due to a pomeron-pomeron-reggeon (IP IP IR) term, its contribution to the diffractive cross section in the interval 3 < MX < 24 GeV is estimated to be fIP IP IR = 26 ± 3(stat) ± 12(syst)%. © Springer-Verlag 1997.
Search For Lepton Flavor Violation In Ep Collisions At 300 Gev Center Of Mass Energy, M. Derrick, D. Krakauer, S. Magill, D. Mikunas, B. Musgrave, J. R. Okrasiński, J. Repond, R. Stanek, R. L. Talaga, H. Zhang, Margarita C. K. Mattingly, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, P. Bruni, G. Cara Romeo, G. Castellini, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, I. Gialas, P. Giusti, G. Iacobucci, G. Laurenti, G. Levi
Search For Lepton Flavor Violation In Ep Collisions At 300 Gev Center Of Mass Energy, M. Derrick, D. Krakauer, S. Magill, D. Mikunas, B. Musgrave, J. R. Okrasiński, J. Repond, R. Stanek, R. L. Talaga, H. Zhang, Margarita C. K. Mattingly, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, P. Bruni, G. Cara Romeo, G. Castellini, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, I. Gialas, P. Giusti, G. Iacobucci, G. Laurenti, G. Levi
Faculty Publications
Using the ZEUS detector at the HERA electron-proton collider, we have searched for lepton flavor violation in ep collisions at a center-of-mass energy (√s) of 300 GeV. Events of the type e + p → ℓ + X with a final-state lepton of high transverse momentum, ℓ = μ or τ, were sought. No evidence was found for lepton flavor violation in the combined 1993 and 1994 data samples, for which the integrated luminosities were 0.84 pb-1 for e-p collisions and 2.94 pb-1 for e+p collisions. Limits on coupling vs. mass are provided for leptoquarks and R-parity violating squarks. For …
Comparison Of Zeus Data With Standard Model Predictions For E+P → E+X Scattering At High X And Q2, J. Breitweg, M. Derrick, D. Krakauer, S. Magill, D. Mikunas, B. Musgrave, J. Repond, R. Stanek, R. L. Talaga, R. Yoshida, H. Zhang, Margarita C. K. Mattingly, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, G. Castellini, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, I. Gialas, P. Giusti, G. Iacobucci, G. Laurenti
Comparison Of Zeus Data With Standard Model Predictions For E+P → E+X Scattering At High X And Q2, J. Breitweg, M. Derrick, D. Krakauer, S. Magill, D. Mikunas, B. Musgrave, J. Repond, R. Stanek, R. L. Talaga, R. Yoshida, H. Zhang, Margarita C. K. Mattingly, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, G. Castellini, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, I. Gialas, P. Giusti, G. Iacobucci, G. Laurenti
Faculty Publications
Using the ZEUS detector at HERA, we have studied the reaction e+p → e+X for Q2 > 5000 GeV2 with a 20.1 pb-1 data sample collected during the years 1994 to 1996. For Q2 below 15000 GeV2, the data are in good agreement with Standard Model expectations. For Q2 > 35000 GeV2, two events are observed while 0.145 ± 0.013 events are expected. A statistical analysis of a large ensemble of simulated Standard Model experiments indicates that with probability 6.0%, an excess at least as unlikely as that observed would occur above some Q2 cut. For x > 0.55 and y > 0.25, four …
An Assessment Of The Prevalence Of Trichomonas Sp. In The Domestic Pigeon (Columba Livia) Population, In The Emirates Of Abu Dhabi And Dubai, Theresa Caroline Bailey
An Assessment Of The Prevalence Of Trichomonas Sp. In The Domestic Pigeon (Columba Livia) Population, In The Emirates Of Abu Dhabi And Dubai, Theresa Caroline Bailey
Theses
A survey of 250 captive (animal market) and free-flying (trapped at a sheep farm) pigeons was conducted to assess the prevalence of Trichomonas sp. in the domestic pigeon (Columba livia) population, in the United Arab Emirates (UAE). Oropharyngeal swabs demonstrated that 52% of all pigeons were found with Trichomonas sp. in their oropharynx, of which 60%, 68% and 35% of pigeons were Trichomonas sp. positive in the AI Ain and Abu Dhabi animal markets and AI Ain sheep farm respectively. Captive birds had a significantly higher infection rate than the free-flying pigeons. Inspection of the oropharynx of live pigeons positive …
Effect Of Oil Pollution On Juvenile And Adult Rabbitfish (Siganus Canaliculatus), Mohammed Abdul Rahim Hassan Al Zarouni
Effect Of Oil Pollution On Juvenile And Adult Rabbitfish (Siganus Canaliculatus), Mohammed Abdul Rahim Hassan Al Zarouni
Theses
The possible toxic effect of crude oil and dispersant on the reproduction and performance of common marine fish in the United Arab Emirates coasts were investigated. Adult female and juvenile rabbitfish (Siganus canaliculatus) were exposed to different concentration of Sharjah light crude oil (0, 4, 6 ml crude oil/l) in the presence or absence of 0.3 mI/l Nalfleet dispersant (Maxi-Clean 2) dissolved in sea water. Juvenile fish were exposed to treatments for 3, 6, 9 or 15 days and adult female were treated for 18 days. At the end of each experimental period histopathological changes in the skin, gills, liver …
Semantic Analysis Of The Postscript Page Description Language, Ben Knuth
Semantic Analysis Of The Postscript Page Description Language, Ben Knuth
Honors Theses, 1963-2015
The Postscript page description language is a functional programming language. Central to the effective use of the language are the functional properties of delayed evaluation and referential transparency. Postscript performs all of its operations via distinct, multiple stacks which stores function binding lists, function parameters, and function code. By way of these stacks, Postscript creates dynamic computational states which leads identical expressions to evaluate to different results. This hints towards the polymorphic quality of an object-oriented language, even though it contradicts the functional precept of manifest interfaces thereby introducing a nonorthogonality. One other streak of object-orientation that shows up in …
Where The Guesswork Ends And The Accrual Begins: Environmental Remediation Liabilities And Their Effects On The Managerial Decision-Making Process, Corie Sue Dumdie
Where The Guesswork Ends And The Accrual Begins: Environmental Remediation Liabilities And Their Effects On The Managerial Decision-Making Process, Corie Sue Dumdie
Honors Theses, 1963-2015
Environmental remediation is not new, but accounting for the costs of such a process is. In 1996, the first authoritative literature on accounting for the costs of cleaning up environmental degradation were established, and they gave insight into the accounting treatment for environmental remediation liabilities (ERLs). The aim of the thesis is to explain the new accrual methods for ERLs and show their importance as they have influenced many managerial philosophies. The thesis also examines some of the weaknesses of ERLs and illustrates possible changes for the future. The most important aspect of ERLs is that they have helped management …
A Comparison Of The Kinetics Of Fatty-Acid Metabolism In Smokers And Nonsmokers, Patricia A. Valusek
A Comparison Of The Kinetics Of Fatty-Acid Metabolism In Smokers And Nonsmokers, Patricia A. Valusek
Honors Theses, 1963-2015
For many years, the United States government has required labels on all cigarette packages warning against the many ill effects associated with smoking. One of the major factors contributing to the unhealthy aspects of smoking is its profound impact on nutrient levels within the body. Free radicals found in both the gas and tar phases of cigarette smoke may pose a significant threat to the fatty-acid levels in the body. One method of assessing this threat is to examine the fatty-acid synthesis rates of smokers and nonsmokers. An assumption was made that a destruction of fatty-acids will be displayed as …
Simulation Of Living Processes Utilizing Concurrency And Object-Oriented Programming, Aaron Ziegler
Simulation Of Living Processes Utilizing Concurrency And Object-Oriented Programming, Aaron Ziegler
Honors Theses, 1963-2015
What does it mean to be alive? Is it possible to create artificial life-forms that are truly alive? Can a computer program be alive? To answer these questions, I first explore the history of artificial life, beginning with John von Neumann, who designed algorithms possessing lifelike capabilities, and moving on to other famous attempts, such as Horton Conway's 'Game of Life', and Thomas Ray's remarkable 'Tierra' project.
Also included is a discussion on the merits of Object-Oriented programming for simulating, and ultimately synthesizing life on a computer. concurrency is defined, and its value for stimulating and synthesizing life is made …
Preparation And Reactivity Of Acyclic (Pentadienyl)Iron(1+) Cations: Applications To Organic Synthesis, William A. Donaldson
Preparation And Reactivity Of Acyclic (Pentadienyl)Iron(1+) Cations: Applications To Organic Synthesis, William A. Donaldson
Chemistry Faculty Research and Publications
No abstract provided.
Hexakis(Dimethylformamide)Bis(Hexaphenylcyclohexasiloxanehexaolato)Hexacopper(Ii) Dimethylformamide Solvate, Sergey V. Lindeman, Olga I. Shchegolikhina, Yulia A. Molodtsova, Alexandr A. Zhdanov
Hexakis(Dimethylformamide)Bis(Hexaphenylcyclohexasiloxanehexaolato)Hexacopper(Ii) Dimethylformamide Solvate, Sergey V. Lindeman, Olga I. Shchegolikhina, Yulia A. Molodtsova, Alexandr A. Zhdanov
Chemistry Faculty Research and Publications
The sandwich-like title complex, hexakis(dimethylformamide)-1O,2O,3O,4O,5O,6O-bis[2,4,6,8,10,12-hexaphenylsiloxane-2,4,6,8,10,12-hexaolato(6-)-1:22O1,2:32O2,3:42O3,- 4:52O4,5:62O5,1:62O6]hexacopper(II) tetrakis(dimethylformamide) solvate, [Cu6(C3H7NO)6{(C6H5)6O12Si6}2].4C3H7NO, is comprised of two regular crown-shaped macrocyclic hexadentate organosiloxanolate ligands chelating a flat Cu6 hexagon, as in the ethanol-solvated analogue investigated previously. The title complex has a more distorted shape …
N-Methylbenzothiazole-2(3H)-Selone, C8H7Nsse, Steinar Husebye, Sergey V. Lindeman, Martin D. Rudd
N-Methylbenzothiazole-2(3H)-Selone, C8H7Nsse, Steinar Husebye, Sergey V. Lindeman, Martin D. Rudd
Chemistry Faculty Research and Publications
The crystal structure of N-methyl1,3-benzothiazole-2(3H)-selone, (mbts) has been studied to estimate the changes in the molecular geometry of the mbts ligand upon coordination. Hypervalent complexes of mbts with TeII and II have been studied by us previously. A significant elongation of the Se=C bond [from 1.817 (7) in mbts to 1.85-1.88 Å in the complexes] was found, but there were no significant changes in the other geometric parameters of the ligand. The only other bond-length decrease of note was for SeC-NMe [from 1.35 (1) in mbts to 1.32-1.34 Å in the complexes]. Thus, only the …