Physical Sciences and Mathematics Commons^™

A New Method For The Preparation Of Alkylnaphthyl Ethers And Sulfides, Edward Ying-Shih Chen

Theses and Dissertations

The reaction of monohalonaphthalenes with metal alkoxides and mercaptides in a solvent mixture of the corresponding alcohol and dimethyl sulfoxide (DMSO) has been studied. These reactions are convenient methods for the preparation of alkylnaphthyl ethers and sulfides. Only direct nucleophilic substitution was observed in the reactions of bromonaphthalenes with sodium methoxide and sodium nbutyl mercaptide. The reaction of fluoronaphthalene with potassium t-butoxide also proceeded by way of direct nucleophilic substitution rather than the 1,2-dehydronaphthalene intermediate as in the reactions of bromonaphthalene with potassium t-butoxide. The use of a base which is weaker than t-butoxide can change the apparent reaction mechanism …

Rhenium Catalyzed Hydrogenation Of Maleic Anhydride And Crotonaldehyde, William Russel Dixon

Theses and Dissertations

The preparation of a number of supported rhenium catalysts is reported. The determination of their activity and selectivity and of optimal reaction parameters for the reduction of maleic anhydride and crotonaldehyde is reported. Optimal time of hydrogenation was chosen as one hour and pressures were chosen as 2000 psig for crotonaldehyde and 3000 psig for maleic anhydride. Quantitative reduction of maleic anhydride to tetrahydrofuran occurred at 275° with charcoal supported rhenium catalysts. Lower temperatures (ca. 200°) produce quantitative amounts of butyrolactone. Unsupported catalysts at low temperatures (100°) selectively reduce crotonaldehyde to crotyl alcohol, but at very low conversion rates. Temperatures …

Toward Hydrogen Bonds Of Predictable Geometry, Robert Shao-Chih Hsu

Theses and Dissertations

A literature review on the geometry of hydrogen bonding showed that the geometry is often de-emphasized or even ignored, probably because of the inherent flexibility of many systems studied. Examination of molecular models suggested the geometrically constrained bicyclo [2, 2, 1] heptane system wherein hydrogen bond distances and angles might be more easily predicted. Dihydroboration-oxidation of norbornadiene was shown to yield exo, exo-2,5-norbornadiol, thus clarifying uncertainties in the literature. 2, 5-Norbornadiol was oxidized to the corresponding dione, heretofore inadequately characterized. Several derivatives of the dione were prepared, and spectral data were accumulated for the dione, its precursor, and its derivatives. …

Synthesis And Metal Coordination Properties Of Some Cyclic Polyethers And Polythioethers, Barry Lant Haymore

Theses and Dissertations

Thermodynamic values for cation-cyclic polyether interactions for several systems are reported and discussed in light of ligand geometry, cation selectivity, solvent effects, structure, stoichiometry and the nature of the coordinate bond. Cyclic polyethers are shown to be remarkably good ligands even in water and to have marked selectivity for d0, d10 and d10 s2 cations. Syntheses of one new cyclic polyether and several new mixed cyclic polyether-thioethers are reported. Cyclic chelates with smaller rings are shown to prefer smaller cations, but this selectivity is masked by the hydration energy of the cation. Except for thiophillic cations such as Hg2+ and …

Enzymatic Synthesis Of Oligoribonucleotides Of Defined Base Sequence, Mark J. Rowe

Theses and Dissertations

The synthetic reaction of ribonuclease T_1 has been studied as to its potential for the synthesis of oligoribonucleotides of defined base sequence. Conditions have been determined for maximum synthesis with respect to percentage incorporation of both guanosine 2',3'-cyclic phosphate (donor), and cytidine (acceptor). With regard to maximum acceptor incorporation, a donor blocked at the 5'-hydroxyl has been used to drive the reaction. It has also been shown that acceptor incorporation decreases as the chain-length increases up to the hexanucleotide. Synthesis of a 3'-blocked substrate for polynucleotide phosphorylase for use in chain termination studies was attempted using adenylate kinase. In this …

Software Simulation Of The D17b Computer, Bruce Chatterton

Theses and Dissertations

A software program has been written which simulates the functions of the Minuteman D17B computer at the register transfer level. The simulation program is written in the FORTRAN Extended language to be used on the Intercom System (teletype) of a CDC 6600 computer system. The simulation program consists of a main program and eight subroutines. A programming language for the D17B simulation was formed which contains numbers and load codes, switches, and miscellaneous commands. Example programs run on the simulated computer have been included to show the types of output available.

The Stratigraphy And Economic Potential Of Permo-Pennsylvanian Strata In Southwestern North Dakota, Harold C. Ziebarth

Theses and Dissertations

This study of the Fermo-Pennsylvanian Minnelusa Group in North Dakota was designed to clarify the stratigraphy, illustrate association of depositional environments, and to relate the geologic history and economic potential of these strata.

The Minnelusa Group is defined here to include strata above the unconformity on the Madison and Big Snowy Groups and below the Opeche Formation. The Minnelusa Group in North Dakota contains the Tyler, Alaska Bench, Amsden and Broom Creek Formations. The Amsden has been divided into three marker defined lithozones designated, in ascending order, Medora, Dickinson, and Bismarck.

Drill and core samples were examined and described interpretively …

Applied Geology Of The Bismarck-Mandan Area, North Dakota, Gerald H. Groenewold

Theses and Dissertations

The Bismarck-Mandan area includes about 350 square miles located along both sides of' the Missouri River in south-central North Dakota. The area can be divided into two major physiographic divisions: the broad Missouri River floodplain and the nearly flat uplands which are dissected by minor streams. Geologic units in the area include Upper Cretaceous and lower Tertiary sandstone, siltstone, and shale and Quaternary sand, silt, clay, and gravel.

Expansion of residential areas around the cities of Bismarck and Mandan results in conflicts in land-use between agricultural, urban, and resource development. This study consists of detailed geologic maps and a series …

Septic Tank Nutrients In Groundwater Entering Lake Sallie, Minnesota, David Robert Lee

Theses and Dissertations

The nutrient contribution of septic tanks to a lake was evaluated at Lake Sallie, in glacial outwash terrain of northwestern Minnesota. Groundwater entering the lake was collected by covering 0.258 m2 of lake bed with a bottomless cylinder vented to deflated plastic bag. Inflow velocity ranged from 0.01 to 2.5 micrometers per-second along 30% of the lakeshore. Groundwater inflow along an 800 m segment of shore amounted to 4.50 x 105 m3/year, and was uniformly distributed along the shore, but decreased exponentially away from shore.

Effluent from a heavily-used lakeside septic tank fanned out along the surface of the water …

Geology Of Southern Nelson County, North Dakota, Roger J. Reede

Theses and Dissertations

Southern Nelson County occupies 576 square miles in northeastern North Dakota (Twps. 149-152 N., Rgs. 57-62 W.). Its surface is mantled with glacial drift resting unconformably on the Cretaceous Pierre Shale, which is exposed along the Sheyenne River Valley and the Stump Lake Basin. The entire mantle of glacial drift is part of the Coleharbor Formation, which, in southern Nelson County, averages 45 feet thick with a maximum thickness over 200 feet. Drill-hole data and missile site excavations provide good evidence for the existence of multiple drift sheets, including layers of till separated by more than 25 feet of outwash, …

Black Magnetic Spherules From The Glacial And Sea Ice Of Fletcher's Ice Island (T-3), Richard Scattolini

Theses and Dissertations

Black magnetic spherules are particles which can be derived by ablationary processes from cosmic sources. Spherules from both the glacial ice and sea ice of Fletcher's Ice Island (T-3) were studied to determine their size distribution, sedimentation rates, and other parameters. The results were examined and shown to be similar to those of other researchers' work elsewhere.

Calculated sedimentation rates for glacial ice spherules, extrapolated for the entire earth's surface, range from 1.1 x 10⁴ to 1.1 x 10⁵ metric tons per year. Calculated sedimentation rates for sea ice spherules range from 5.0 x 10³ to 1.6 x 10⁵ metric …

Groundwater Of The Spiritwood Lake Area, Stutsman County, North Dakota, Frank J. Schulte

Theses and Dissertations

The Spiritwood Lake study area is in a generally undulating to rolling glacial plain 17 miles north and east of Jamestown, North Dakota. Spiritwood Lake is about 50 feet below the surface of the bedrock plain in a former melt-water channel. In the study area, glacial drift unconformably overlies the Pierre Shale, the youngest pre-Pleistocene sediment. The boundary between the two units is marked by a zone of shattered Pierre Shale. The top of this shattered zone forms a plain of moderate relief which probably was the preglacial surface of the study area.

Two large valleys can be distinguished in …

Annotated Bibliography Of The Geology Of North Dakota, 1806-1959, Mary Woods Scott

Theses and Dissertations

References to the literature on North Dakota geology published between 1805 and 1960 are listed in this annotated bibliography. Published bibliographies on North American geology, bibliographies on geological subjects important to North Dakota, unpublished lists of references, and references cited in each entry herein were used to compile the bibliography. Each reference is provided with an annotation of its contents. A subject and geographical index and a list of serials cited are included.

Stratigraphy And History Of The Sakakawea Sequence, South-Central North Dakota, William B. Bickley Jr.

Theses and Dissertations

The Sakakawea Sequence (Pleistocene) in North Dakota contains six formations that make up the Coleharbor Group (Pleistocene). The Braddock Formation (Wisconsinan) is mainly glacial sediment. The Emmons Formation (late Wisconsinan) is mainly glacial sediment. The Four Bears Formation (Wisconsinan) is mainly either fluvial or lacustrine sediment. The Coteau Formation (Holocene) is mostly fluvial, colluvial, or slough sediment. The Denbigh Formation (Holocene) is mostly eolian sediment. The Oahe Formation (late Wisconsinan and Holocene) is mostly eolian sediment (loess) The Oahe Formation is divided into three members: the Mallard Island (late Wisconsinan), Aggie Brown (latest Wisconsinan to earliest Holocene), and Riverdale (middle …

The Thermal Decomposition Of 2,2'-Azoisobutane, Mervin Dewain Atwood

Theses and Dissertations

Nitrogen, isobutane, isobutylene and 2,2,3,3-tetramethylbutane are the only products found in the thermal decomposition of 2,2'-azoisobutane. They are the results of the direct free radical dimerization and disproportionation. Ratio of the rate constants of disproportionation to dimerization was found to be 1.9 at 268°C and 4.5% azobutane in helium. This compared with Blackham and Eatough's value of 1.4 at 243°C and 3.6 at 290°C with 4% azobutane in helium. The ratio of the disproportionation to dimerization increased with an increase in temperature. A change in contact time affected the ratio at lower reaction temperatures but had little effect on it …

An Investigation Of Some Free Radicals.|Ni.|Pdecomposition Of Nitrosyl Disulfonate Ion In Polar Non-Aqueous Solvents.|Nii.|Preaction Between 2,2-Diphenyl -1- Picryl Hydrazyl And Nitrosyl Disulfonate Ion Free Radicals, Janan Mary Hayes

Theses and Dissertations

Part I reports the stud y of the decomposition of nitrosyl disulfonate ion in DMSO, acetonitrile, and dichloromethane. A multi-step mechanism involving sulfite ion, sulfite ion radical, and nitrosyl monosulfonate radical as intermediates is proposed. The products of the decomposition are nitrosonium ion, hydroxylamine disulfonate ion, and hydroxylamine trisulfonate ion. A competitive chain reaction was observed when the decomposition occurred in DMSO. The chain reaction was insignificant in carefully dried acetonitrile and dichloromethane. Part II reports the study of the reaction between 2,2-diphenyl-1-picryl hydrazyl (DPPH) and nitrosyl disulfonate ion. Product analysis and kinetic data obtained from stopped-flow procedures suggest that …

Studies Of Pig Brain Thiamin Pyrophosphokinase, James Weldon Peterson

Theses and Dissertations

Pig brain thiamin pyrophosphokinase (TPK) (ATP: thiamin pyrophosphotransferase, EC 2.7.6.2) was purified 260-fold over extracts of brain acetone powder. The purification was followed using a direct, radiometric assay. As determined in an analytical ultracentrifuge and by disc-gel electrophoresis, the most highly purified enzyme preparations were not homogeneous. The purified enzyme has a broad pH optimum extending from 8.3 to 9.3 in phosphate-glycylglycine buffer. It has an isoelectric point at about pH 4.2. For optimal enzymatic activity, the ratio of magnesium to ATP must be 0.6. Any deviation from this ratio causes a rapid drop in enzymatic activity. A study of …

Solid-Liquid Phase Equilibria Studies :|Bi. Several Charge Transfer Systems ; Ii. A Metallic System ; Iii. A Liquid Crystal, Dee Edward Oyler

Theses and Dissertations

Solid-liquid phase equilibria studies were used to investigate possible compound formation in solutions of (i) N,N-dimethylformamide (DMF) and (ii) N,N-dimethylacetamide (DMA) with a series of halogenated hydrocarbons that were selected to give a wide range of acceptor properties. Solid 1:1 intermolecular compounds were identified from solutions of (i) DMF and (ii) DMA with CCl_4, CBrCl_3, and C_6H_5CCl_3. The intermolecular compounds (DMF)_2•CCl_4 and (DMF)_2•CBrCl_3 were also found. The results suggest charge transfer from DMF or DMA to the chlorine atoms of the acceptor molecule as the process for compound formation. Thermal methods were used to determine with high precision the solid-liquid …

A Calorimetric Study Of Metal Ion Cyclic Polyether Interaction :|Bi. Cation Binding Properties Of Macrocyclic Polyethers In Aqueous Solution As A Function Of Temperature ; Ii. Effect Of Solvent Dielectric Constant On The Binding Properties Of Cyclic Polyethers For Na[Superscript +] And K[Superscript +], Dennis Pershing Nelson

Theses and Dissertations

The complexation properties of the two isomers of the cyclic polyether dicyclohexyl-18-crown-6 are examined in aqueous solution for a series of metal ions at various reaction temperatures. The results are discussed in terms of size relationships and salvation characteristics of both polyether and metal ions. ΔCp° values are determined from the temperature dependence of the ΔH° values. A discussion of the errors involved in the determination of ΔH° from the temperature dependence of log K values is also included. Comparisons are made between the results of this study and those of a similar study by H. K. Frensdorff, E. I. …

Eutrophication Of Small Lakes, Lynn T. Kenison

Theses and Dissertations

An estimate was made to determine the amount of nitrate and phosphate entering Utah Lake in 1968. To make this estimate, the flow data for 1968 and the nitrate and phosphate concentrations for 1970 were used. This was done because of the lack of information. The results show that the total nitrate added to Utah Lake in 1968 was 7,638,000 pounds. The total phosphate added was 1,740,200 pounds. Of this amount, 12,4 per cent of the nitrate and 18.0 per cent of the phosphate was released from the lake through the Jordan River. The rest remained in the lake to …

The Roles Of Chlorine Azide In Chemical Lasers, Walter Wood Rice

Theses and Dissertations

ClN_3 was photolyzed in various gas mixtures to transform its chemical energy into laser radiation. Reaction mechanisms, energy distribution in reaction products, and relative reaction rates were deduced from the laser emission. Flash photolysis of ClN_3-H_2 mixtures produced HCl laser emission; however, due to a narrow range of operating conditions and many competing reactions, the laser output was less than that obtained from comparable Cl_2-H_2 mixtures. The rate constants for H + ClN_3 —> HCl* (v=n) + N_3 were determined to be 0.45 ± 0.05 of the corresponding rate constants for H + Cl_2 —> HCl* (v=n) + Cl. Chlorine …

Solid-Liquid Phase Equilibria Of The Potassium-Rubidium And Rubidium-Cesium Alloy Systems, Elisabeth M. Delawarde

Theses and Dissertations

Thermal methods of high precision were used to determine the solid-liquid phase equilibria diagrams for the potassium-rubidium and the rubidium-cesium systems. Both form minima in the liquidus curves occurring at 307.00° K with 0.667 mole fraction rubidium in the potassium-rubidium system and 282.85° K with 0.530 mole fraction cesium in the rubidium-cesium system. In the potassium-rubidium system, the liquidus and solidus points are very close together, giving a very narrow temperature range for the two phase region. The freezing point minimum in the potassium-rubidium system occurs at 0.667 mole fraction rubidium, suggesting the possible formation of a KRb2 intermetallic compound.

Group Sequential Methods For Clinical Trials Applied To The Logistic Regression Model, Joy Duci Mele

Theses and Dissertations

The objectives of this thesis are

1. to provide a comprehensive guide to using Pocock's group sequential method for clinical trials and

2. to show by computer simulations that the group sequential method is appropriate when using the logistic regression model.

In section 1.2, clinical trials are defined with an emphasis on Phase III clinical trials. The primary intent of sections 1.2 and 1.3 is to describe clinical trial characteristics which suggest that interim analyses are desirable. In section 1.4, it is shown that interim analyses should not consist of performing the usual significance tests. Chapter 1, then, describes the …

Attitudes Concerning Birth Control And Abortion As Related To Lds Religiosity Of Brigham Young University Students, Erlend D. Peterson

Theses and Dissertations

This study was an analysis of the relationship between LDS religiosity of college students and their attitudes concerning birth control and abortion.

The respondents in this research were LDS college students attending Brigham Young University Fall Semester 1970. Goodman and Kruskal's gamma and a difference of means test were used to measure association and difference to determine the statistical significance of the responses as related to religiosity and attitudes concerning birth control and abortion.

The results of the study showed that (1) there was a positive relationship between conservative attitudes toward birth control and abortion and one's degree of measured …

An Easy Access Interactive Statistical System For Use And Training In Biometry, Amos Addison Slaymaker Jr.

Theses and Dissertations

One of the most important tools of the applied statistician is the digital computer. It is natural, therefore, for the instructor in applied statistics to want his students to become familiar with the use of computers. If his students are going to get actual experience in using a computer for statistical analysis, he often has only two alternatives. The students can be required to write their own statistical programs or they can use programs already available through a computer facility.

If the course is to be taught such that each student is responsible for his own programs, the instructor must …

The Petroleum Geology Of The Midale Subinterval In North Central North Dakota, Kent A. Johnson

Theses and Dissertations

The Mississippian Midale subinterval is the basal unit of the Ratcliffe interval of the Madison Group. The Midale subinterval, an important petroleum producing unit in North Dakota, is a dolomitized limestone which is approximately 40 feet thick. A detailed study of 17 oil fields in north central North Dakota was conducted to determine the petroleum geology of the Midale subinterval. The study was done with the use of 563 mechanical well logs and core samples from 10 wells.

The anhydrite and dolomite units of the Rival subinterval, which underlie the Midale, and the Ratcliffe interval, which over lies the Midale, …

Origin And Distribution Of Selenium In The Upper Cretaceous Niobrara And Pierre Formations, Northeastern North Dakota, Robert M. Novak

Theses and Dissertations

High concentrations of selenium, often as much as 28 ppm, have been found in the bentonitic zones near the contact of the Niobrara and Pierre Formations of Cretaceous age in northeastern North Dakota. A 64-foot section in the Pembina Hills area reveals that the highest selenium content occurs in shale and marlstone beds adjacent to the bentonite beds which, themselves, contain comparatively little selenium. Higher concentrations of selenium were found in the brown shale than in the black, with a small variation in color making a big difference in selenium content.

The selenium content of the shale and marlstone drops …

Erosion And Sedimentation In Lake Ashtabula, Southeastern North Dakota, Darryll T. Pederson

Theses and Dissertations

Erosion along the shore of Lake Ashtabula and nearshore and offshore sedimentation were studied from May 1969 to December 1970. The lake, located in the southeastern part of North Dakota, was formed when the Baldhill Dam stopped the flow of the Sheyenne River in 1950. Maximum depth of the lake is 45 feet in the inundated river channel immediately above the dam. The lake is 27 miles long and ranges in width from 1/3 to 1/2 mile.

Shoreline erosion, measured at stations located at 100-foot intervals around the margins of the lake, was found to be a major source of …

Quantitative Geomorphology And Hydrology Of The Cass River Basin, New Zealand, Frank J. Schulte

Theses and Dissertations

The Cass River drainage basin is in the Southern Alps in the central part of the South Island of New Zealand. The Alps are composed of complexly folded greywacke which is still actively rising. The basin has been modified by several glacial advances during Pleistocene time.

The Cass basin has a temperate climate characterized by a steep precipitation gradient. Its vegetation includes plants of the forest grassland, shrubland, swamp, rock, and river-bed associations.

The Cass basin may be divided into four geomorphic areas: bedrock areas, high-angle fans, moderate-angle fans, and a low-angle fan. The bedrock areas consist of fractured greywacke; …

Geology Of Mclean County, North Dakota, John P. Bluemle

Theses and Dissertations

McLean County, in west-central North Dakota on the east side of the Williston Basin, is covered by 8,500 to 13,000 feet of Paleozoic, Mesozoic, and Cenozoic rocks, which dip to the west at low angles. The Tertiary Tongue River and Sentinel Butte Formations are widely exposed in McLean County, and the Tertiary Cannonball Formation is exposed in a few places. Glacial drift, assigned to a new formation, the Coleharbor Formation, occurs throughout the county and reaches a maximum thickness of at least 400 feet in certain preglacial valleys.

The eastern part of McLean County, part of the Missouri Coteau, is …