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Articles 3571 - 3600 of 3644

Full-Text Articles in Physical Sciences and Mathematics

Nonenzymatic Glucosylation Of Rat Albumin: Studies In Vitro And In Vivo, James F. Day, Robert W. Thornburg, Suzanne R. Thorpe, John W. Baynes Oct 1979

Nonenzymatic Glucosylation Of Rat Albumin: Studies In Vitro And In Vivo, James F. Day, Robert W. Thornburg, Suzanne R. Thorpe, John W. Baynes

Faculty Publications

Incubation of rat serum with D-glucose in vitro resulted in nonenzymatic glucosylation of serum proteins. Analysis of freshly isolated rat albumin by ion exchange chromatography indicated that the glucosylated albumin accounts for 6.7.+-. 0.9% of total albumin in normal rat serum. Glucosylation of rat albumin in vitro was 1st order with respect to glucose and albumin concentrations and occurs primarily (> 90%) at intrachain lysine residues. Kinetic analysis and inhibition of glucosylation by aspirin suggest that 1 reactive lysine residue is the primary site of glucosylation. Less than 5% of the radioactivity from glucosyl-albumin was released as glucose or mannose …

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Spin-Glass-Like Behavior In Very Dilute Pdfe At Very Low Temperatures, Richard A. Webb, G. W. Crabtree, J. J. Vuillemin Sep 1979

Spin-Glass-Like Behavior In Very Dilute Pdfe At Very Low Temperatures, Richard A. Webb, G. W. Crabtree, J. J. Vuillemin

Faculty Publications

Measurements of the electrical resistivity of palladium, residual resistivity ratio ∼22 500, containing 1.7 ppm of Fe have been made from 5.5 K to 1.8 mK. 15 Hz ac susceptibility measurements from 1 K to 1.8 mK together with the resistivity data suggest that a transition into a spin-glass state occurs near 7 mK.

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Enhanced Nonenzymatic Glucosylation Of Human Serum Albumin In Diabetes Mellitus, C. Earl Guthrow, Mary Ann Morris, James F. Day, Suzanne R. Thorpe, John W. Baynes Sep 1979

Enhanced Nonenzymatic Glucosylation Of Human Serum Albumin In Diabetes Mellitus, C. Earl Guthrow, Mary Ann Morris, James F. Day, Suzanne R. Thorpe, John W. Baynes

Faculty Publications

Use of an ion exchange chromatographic method and a colorimetric method with thiobarbituric acid showed that levels of nonenzymatically glucosylated serum albumin were increased in patients with poorly controlled diabetes mellitus compared to controls. The two methods correlated well (r = 0.99) and clearly discriminated between normal and poorly controlled diabetic populations. The levels of glycosylated hemoglobin were also measured in both populations. Several patients apparently in good control based on glycosylated hemoglobin measurements were found to have increased levels of glycosylated albumin. Because albumin has a shorter circulating half-life than does the human erythrocyte, the plasma concentration of glucosylated …

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Heating-Effect Minimization In Dye Lasers, Kenneth Lee Matheson, James M. Thorne Aug 1979

Heating-Effect Minimization In Dye Lasers, Kenneth Lee Matheson, James M. Thorne

Faculty Publications

Optical pumping of dye lasers deposits heat nonuniformly in the active medium. Because the refractive index of a liquid or gas is a function of temperature, gradients are created which refract the laser beam. This effect is sometimes serious enough to quench laser action. In this paper, we evaluate the effects caused by optical pumping with a coaxial flashlamp and suggest ultraviolet absorbers and wavelength shifters as materials for minimizing the problem

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Nonenzymatically Glucosylated Albumin: In Vitro Preparation And Isolation From Normal Human Serum, James F. Day, Suzanne R. Thorpe, John W. Baynes Feb 1979

Nonenzymatically Glucosylated Albumin: In Vitro Preparation And Isolation From Normal Human Serum, James F. Day, Suzanne R. Thorpe, John W. Baynes

Faculty Publications

Incubation of human serum with D-[6-3H]glucose resulted in the gradual accumulation of radioactivity in acid-precipitable material. Upon chromatography on Sephadex G-200, radioactivity was found associated with each of the major molecular weight classes of serum protein. Purified human serum albumin was also glucosylated in vitro upon exposure to D-[6-3H]glucose in phosphate-buffered saline. The glucosylated and unmodified albumins were separated by ion exchange chromatography. The physiological significance of these observations in vitro was confirmed by the isolation and quantitation of glucosylated albumin from normal human serum. Glucosylated albumin represents approximately 6 to 15% of total serum albumin in normal adults. The …

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Chemical Vapor Deposited Amorphous Silicon For Use In Photothermal Conversion, David D. Allred, D. C. Booth, M. Janai, G. Weiser, B. O. Seraphin Nov 1978

Chemical Vapor Deposited Amorphous Silicon For Use In Photothermal Conversion, David D. Allred, D. C. Booth, M. Janai, G. Weiser, B. O. Seraphin

Faculty Publications

Efficient photothermal conversion requires surfaces of high solar absorptance and low thermal emittance. This can be accomplished by the tandem action of a good infrared reflector overlaid by a film of sufficient solar absorptance that is transparent in the infrared. Crystalline silicon is a suitable candidate for the absorber layer. Its indirect band gap, however, results in a shallow absorption edge that extends to far into the visible. In contrast, the absorption edge of amorphous silicon is steeper and located farther into the infrared, resulting in a larger solar absorptance. We report on the fabrication of amorphous silicon absorbers by …

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Chemical Vapor Deposited Molybdenum Films For Use In Photothermal Conversion, David D. Allred, G. E. Carver, B. O. Seraphin Nov 1978

Chemical Vapor Deposited Molybdenum Films For Use In Photothermal Conversion, David D. Allred, G. E. Carver, B. O. Seraphin

Faculty Publications

High infrared reflectance, coupled with higher solar absorptance, is required for efficient photothermal conversion. Converters can be fabricated by depositing an absorber on a highly reflecting metal. The absorber functions in the visible, yet becomes transparent in the near infrared, allowing the metal to suppress the thermal emittance. Economic considerations demand the use of thin films, rather than bulk materials. The thin film reflector must be capable of withstanding high temperatures of operation. Compatibility of the reflector with the substrate below, and the absorber above, is required for long-time service. Highly reflective silver films suffer reflectance losses by agglomeration, and …

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An Emulsion Dye Laser, Kenneth Lee Matheson, James M. Thorne Nov 1978

An Emulsion Dye Laser, Kenneth Lee Matheson, James M. Thorne

Faculty Publications

A laser dye which is insoluble in water has been dissolved in hexane and emulsified in a water matrix. When pumped with a nitrogen laser, this mixture was observed to lase. The emulsion is superior to a simple hexane solution because the excellent thermo-optical properties of the water matrix help prevent refractive-index gradients from degrading laser performance. This is a useful characteristic for flash-pumped dye lasers, laser-pumped dye lasers, and liquid filters. Another type of solvent system, a critical solution, is also discussed. For certain dyes, a critical solution has even better thermo-optical properties because of its ability to absorb …

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[3H]‑Raffinose, A Novel Radioactive Label For Determining Organ Sites Of Catabolism Of Proteins In The Circulation, Jonathon Van Zile, Lee A. Henderson, John W. Baynes, Suzanne R. Thorpe Sep 1978

[3H]‑Raffinose, A Novel Radioactive Label For Determining Organ Sites Of Catabolism Of Proteins In The Circulation, Jonathon Van Zile, Lee A. Henderson, John W. Baynes, Suzanne R. Thorpe

Faculty Publications

The primary tissue sites of catabolism of plasma proteins with long circulating half-lives are unknown. It has been difficult to identify these sites because plasma proteins are delivered to tissues at relatively slow rates but are rapidly degraded intracellularly within lysosomes. Therefore, a tracer attached to protein is lost from the site of uptake before an amount sufficient for quantitation can accumulate. We hypothesized that sucrose (Glupal-2 /3Fruf) would be a useful label to circumvent this difficulty because of the stability of sucrose in lysosomes; and thus, sucrose should remain in tissue long after the protein to which it was …

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Bayes Estimation Of Reliability For Mixtures Of Life Distributions, William J. Padgett, Chris P. Tsokos Jun 1978

Bayes Estimation Of Reliability For Mixtures Of Life Distributions, William J. Padgett, Chris P. Tsokos

Faculty Publications

No abstract provided.

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Maximal Residue Difference Sets Modulo P, Duncan A. Buell, Kenneth S. Williams May 1978

Maximal Residue Difference Sets Modulo P, Duncan A. Buell, Kenneth S. Williams

Faculty Publications

Let p ≡ 1 (mod 4) be a prime. A residue difference set modulo p is a set S = {ai} of integers ai such that (ai/p) = +1 and ((ai - aj)/p) = +1 for all i and j with i ≠ j, where (n/p) is the Legendre symbol modulo p. Let mp be the cardinality of a maximal such set S. The authors estimate the size of mp.

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Tip-Angle-Dependent Magnetic Relaxation In Superfluid 3he, Richard A. Webb Mar 1978

Tip-Angle-Dependent Magnetic Relaxation In Superfluid 3he, Richard A. Webb

Faculty Publications

Using a pulsed superconducting-quantum-interference-device (SQUID) NMR technique, relaxation of the longitudinal magnetization in superfluid 3He has been measured in magnetic fields of 31, 102, 180, and 306 Oe in the pressure range 16-26 bar. It is observed that in both superfluid phases there is a temperature-dependent, well-defined spin-tipping angle, θc, for which the relaxation of the magnetization changes from an exponential to a nonexponential behavior.

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The Stephen F. Austin Traveling Science Show, James C. Dennis Jan 1978

The Stephen F. Austin Traveling Science Show, James C. Dennis

Faculty Publications

No abstract provided.

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Compact Compacts: Models: A Simple (And Tasty) Model For Electron Clouds, John T. Moore Jan 1978

Compact Compacts: Models: A Simple (And Tasty) Model For Electron Clouds, John T. Moore

Faculty Publications

A simple (and tasty) model for demonstrating the electron cloud concept; and a classroom visualization of ethylene II and II* molecular orbitals.

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Ferromagneticlike Resonance Behavior In Superfluid 3he-B, Richard A. Webb Oct 1977

Ferromagneticlike Resonance Behavior In Superfluid 3he-B, Richard A. Webb

Faculty Publications

Nonlinear cw NMR behavior, similar to that observed on ferromagnets at high rf powers, has been observed in superfluid 3He-B using a superconducting quantum interference device (SQUID) magnetometer in fields of 31, 102, 180, and 308 Oe and at a pressure of 21 bar. It is observed that beyond some threshold value of the transverse H1 field the z component of magnetization anomalously decreases and is followed by a rapid increase back to the normal resonance curve as the frequency of the H1 field is swept through resonance.

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The Use Of Nuclear Reactions And Sims For Quantitative Depth Profiling Of Hydrogen In Amorphous Silicon, David D. Allred, G. J. Clark, C. W. White, B. R. Appleton, C. W. Magee, D. E. Carlson Aug 1977

The Use Of Nuclear Reactions And Sims For Quantitative Depth Profiling Of Hydrogen In Amorphous Silicon, David D. Allred, G. J. Clark, C. W. White, B. R. Appleton, C. W. Magee, D. E. Carlson

Faculty Publications

Depth profiles for hydrogen in amorphous silicon have been determined by the use of resonant nuclear reactions [1H(15N,αγ)12C and 1H(19F,αγ)16O] and by secondary ion mass spectroscopy (SIMS). Independent calibration procedures were used for the two techniques. Measurements were made on the same amorphous silicon film to provide a direct comparison of the two hydrogen analysis techniques. The hydrogen concentration in the bulk of the film was determined to be about 9 at % H. The SIMS results agree with the resonant nuclear reaction results to within 10%, which demonstrates that quantitative hydrogen depth profiles can be obtained by SIMS analysis …

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Fragments Of 1st-Order Logic, I: Universal Horn Logic, George F. Mcnulty Jun 1977

Fragments Of 1st-Order Logic, I: Universal Horn Logic, George F. Mcnulty

Faculty Publications

No abstract provided.

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Measurement Of The Difference Between The Dynamic Nmr And Static Susceptibilites Of Superfluid 3he-B Using An Rf-Biased Superconducting Quantum-Interference Device, Richard A. Webb May 1977

Measurement Of The Difference Between The Dynamic Nmr And Static Susceptibilites Of Superfluid 3he-B Using An Rf-Biased Superconducting Quantum-Interference Device, Richard A. Webb

Faculty Publications

The temperature-dependent susceptiblity of superfluid 3He-B has been measured both statically and via a pulse technique in a field of 309 G using an rf-biased superconducting quantum-interference device (SQUID). In the pressure range 26.5 to 18 bar, the dynamic NMR susceptiblity agrees qualitatively with the theoretical weak-coupling predictions for the Balian-Werthamer state. However, the static susceptiblity, measured using the same rf-biased SQUID and detection system, is significantly smaller thatn the dynamic susceptibility.

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A Random Differential-Equation Approach To Probability Distribution Of Bod And Do In Streams, William J. Padgett, G Schultz, Chris P. Tsokos Mar 1977

A Random Differential-Equation Approach To Probability Distribution Of Bod And Do In Streams, William J. Padgett, G Schultz, Chris P. Tsokos

Faculty Publications

No abstract provided.

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Intermolecular Potential Surfaces From Electron Gas Methods. Ii. Angle And Distance Dependence Of The A’ And A” Ar–No(X^2ii) Interactions, Glen C. Nielson, Gregory A. Parker, Russell T. Pack Feb 1977

Intermolecular Potential Surfaces From Electron Gas Methods. Ii. Angle And Distance Dependence Of The A’ And A” Ar–No(X^2ii) Interactions, Glen C. Nielson, Gregory A. Parker, Russell T. Pack

Faculty Publications

Angle dependent intermolecular potential energy surfaces for the two states (2A’ and 2A”) that arise from the interaction of ground (X^2II) state NO with Ar are calculated using the electron gas model to obtain the short range interactions. The average and difference of the two interaction energies are fit to analytic forms convenient for use in scattering calculations and joined smoothly onto the long range van der Waals potential previously determined. The results, which appear to be of useful accuracy, and the applicability of the electron gas model to such open shell–closed shell interactions are discussed.

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Computer Model Of A Fast Toroidal Plasma Compression, With Application To The Topolotron, H. Mark Nelson, Keith H. Brown, Charles A. Hart Nov 1976

Computer Model Of A Fast Toroidal Plasma Compression, With Application To The Topolotron, H. Mark Nelson, Keith H. Brown, Charles A. Hart

Faculty Publications

The method is developed for a comuputer sequence which models a fast toroidal theta or screw pinch for a highly conducting axially symmetric plasma. The computer sequence takes into account the self-inductances of the plasma and the external conductors which drive the compression as well as the mutual inductance which electromagnetically couples the two. The computer sequence is divided into three phases: a snowplow compression phase, an adiabatic compression phase, and a crowbarred circuit phase. The computer sequence is applied to a topolotron and an example is given of a magnetohydrodynamic equilibrium geometry for which the plasma surface possesses an …

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Effect Of Glycosylation On The In Vivo Circulating Half-Life Of Ribonuclease, John W. Baynes, Finn Wold Oct 1976

Effect Of Glycosylation On The In Vivo Circulating Half-Life Of Ribonuclease, John W. Baynes, Finn Wold

Faculty Publications

The circulating half-lives of the four isozymes of bovine pancreatic ribonuclease (RNases A, B, C, and D) have been determined in normal and in nephrectomized rats. The isozymes differ only in their glycosyl content. While A contains no sugars, B has a simple oligosaccharide (GlcNAc, Man,+), and C and D each have a complex oligosaccharide (GlcNAc, Man,., Gal, Fuc NeuAc%, and GlcNAc, Mans Gal, Fuc NeuAc,, respectively) attached to Asn-34 of the polypeptide chain. All four isozymes were cleared rapidly in normal rats (t,,, = 2 to 3 min), as expected on the basis of the established role of the …

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Application Of Theorems Of Schur And Albert, Thomas L. Markham Sep 1976

Application Of Theorems Of Schur And Albert, Thomas L. Markham

Faculty Publications

No abstract provided.

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Undecidable Properties Of Finite Sets Of Equations, George F. Mcnulty Sep 1976

Undecidable Properties Of Finite Sets Of Equations, George F. Mcnulty

Faculty Publications

No abstract provided.

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Behavior Of A Manganin Coil At Elevated Temperatures And Pressures, Jonathan D. Weiss, Daniel L. Decker, H. B. Vanfleet Sep 1976

Behavior Of A Manganin Coil At Elevated Temperatures And Pressures, Jonathan D. Weiss, Daniel L. Decker, H. B. Vanfleet

Faculty Publications

We have determined the temperature dependence in the first-order pressure coefficient of a manganin coil to be dBetaB/dT= (4.2±0.8) ×10^-7 (kbar degrees C)^-1 in the equation R (T,P) =R (T,0)(1+BetaP+GammaP2), where R (T,P) is the coil resistance at temperature T and pressure P. The measurements were performed by simultaneously measuring the coil resistance and temperature at the transitions of mercury and bismuth, which were observed by differential thermal analysis.

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Esr Study Of Free Radicals In Irradiated Single Crystals Of Potassium Hydroxylamine Disulfonate, B. J. Wilson, Robert W. Holmberg Aug 1976

Esr Study Of Free Radicals In Irradiated Single Crystals Of Potassium Hydroxylamine Disulfonate, B. J. Wilson, Robert W. Holmberg

Faculty Publications

Two free radicals formed when single crystals of potassium hydroxylamine disulfonate are irradiated with gamma rays at 77degrees K were studied by ESR. The ESR spectra result from a predominant center (radical A) exhibiting large 14N and 1H hyperfine splittings and from lesser amounts of Fremy's radical [O-dotN(SO3)2-2]. The g and hyperfine tensors of these radicals have been evaluated and are discussed. Radical A, whose identity remains in doubt, may be regarded as the precursor to Fremy's radical; on warming its lines decay and those of Fremy's radical are formed. Lines from radical A decrease in strength and those of …

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Van Der Waals Interactions Of Ii-State Linear Molecules With Atoms. C6 For No(X 2Π) Interactions, Glen C. Nielson, Gregory A. Parker, Russell T. Pack Mar 1976

Van Der Waals Interactions Of Ii-State Linear Molecules With Atoms. C6 For No(X 2Π) Interactions, Glen C. Nielson, Gregory A. Parker, Russell T. Pack

Faculty Publications

Formulas are derived for the van der Waals Cn coefficients for the interaction of a diatomic molecule in a II electronic state with an S-state atom. Two triatomic states arise from the degenerate IIstate. The average of the two energies has the usual Legendre polynomial (PL) angular dependence, but the difference in energies of the two states is shown to have associated Legendre polynomial (PML with M=2) angular dependence. Procedures for including spin orbit coupling are included, and the extension to interactions of Delta- and Phi-state molecules is discussed. Values of the spherical part of the C6 coefficients for the …

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Van Der Waals Interactions Of Carbon Monoxide, Gregory A. Parker, Russell T. Pack Mar 1976

Van Der Waals Interactions Of Carbon Monoxide, Gregory A. Parker, Russell T. Pack

Faculty Publications

Pade approximant methods and experimental frequency dependent polarizabilities are used to calculate reliable van der Waals C6 coefficients for the interaction of CO with He, Ne, Ar, Kr, Xe, H, Li, Na, K, Rb, Cs, H2, N2, O2, CO2, and CO. Error bounds are given for the C6 coefficients and for the CO oscillator strength sums.

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Comment On ''Inelastic Scattering In Atom-Diatomic Molecule Collisions. I. Rotational Transitions In The Sudden Approximation'', Russell T. Pack Feb 1976

Comment On ''Inelastic Scattering In Atom-Diatomic Molecule Collisions. I. Rotational Transitions In The Sudden Approximation'', Russell T. Pack

Faculty Publications

It is argued that conflicting approximations in a recent paper [J. R. Stallcop, J. Chem. Phys. 61, 5085 (1974)] render the resulting theory invalid.

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Relaxation Of The Wall-Pinned Magnetization Ringing Mode In Superfluid 3he-B, Richard A. Webb, R. E. Sager, J. C. Wheatley Oct 1975

Relaxation Of The Wall-Pinned Magnetization Ringing Mode In Superfluid 3he-B, Richard A. Webb, R. E. Sager, J. C. Wheatley

Faculty Publications

Observations of the wall-pinned mode in 3He-B allow new magnetic relaxation phenomena to be studied. Excepting the quantitative value of the zero-time ringing frequency, comparison of experiment with theory is satisfactory, including a linear dependence of the square of the ringing period on time and a square-root singularity near Tc in the relaxation parameter.

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