Physical Sciences and Mathematics Commons^™

Speciation Of Elements Via A Sequential Extraction Procedure In Municipal Wastewater Biosolids From Three Rural Wwtp In East Texas (Usa), Kefa K. Onchoke

Faculty Publications

In this data article, the bioavailability of elements in municipal wastewater sludge (also known as biosolids) in samples collected from three treatment plants in East Texas, USA was evaluated. Although detailed speciation of the metals were assessed by using inductively coupled plasma optical spectroscopy (ICP-OES), and were discussed in the research article titled “Evaluating bioavailability of elements in municipal wastewater sludge (Biosolids) from three rural wastewater treatment plants in East Texas (USA) by a sequential extraction procedure” [1], this report presents the absolute raw concentrations and fractionations of the 26 metals from the biosolids (Nacogdoches Wastewater Sludge, Lufkin Wastewater Sludge, …

A Molecular Chemodosimeter To Probe “Closed Shell” Ions In Kidney Cells, Rashid Mia

Faculty Publications

Two quinidine-functionalized coumarin molecular probes have been synthesized and have been found to bind metal cations (Cd2+, Co2+, Cu2+, Fe2+, Hg2+, Ni2+, and Zn2+) with high affinity in organic–aqueous media (DMSO–HEPES). The chemodosimeters coordinate with the Zn2+ ions in a two-to-one ratio (molecular probe : Zn2+) with a log β of 10.0 M−2. Upon the addition of the closed-shell metal ions studied, a fluorescence turn-on via an excimer formation is seen at 542 nm due to the quinaldine moiety adopting a syn arrangement when coordinated to the metal Zn2+ ions. Confocal microscopy monitored free Zn2+ ions in the Human Embryonic …

Health Disparity And Covid-19—A Retrospective Analysis, Sanjay Sarkar, Archie Taylor, Pratik Dutta, Bidisha Sengupta, Debarshi Roy

Faculty Publications

Background and Aims

According to the World Health Organization (WHO), more than 75.7 million confirmed cases of coronavirus disease 2019 (COVID-19), a global pandemic caused by severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2), have been reported so far. Researchers are working relentlessly to find effective solutions to this catastrophe, using genomic sequence-based investigation, immunological analysis, and more. The role of health disparity has also emerged as an intriguing factor that made a huge impact on the lives of people.

Methods

We analyzed various factors that triggered the health disparity in the United States of America along with the rate of …

2-Adic Valuations Of Quadratic Sequences, Will Boultinghouse, Jane H. Long, Olena Kozhushkina, Justin Trulen

Faculty Publications

We determine properties of the 2-adic valuation sequences for general quadratic polynomials with integer coefficients directly from the coefficients. These properties include boundedness or unboundedness, periodicity, and valuations at terminating nodes. We completely describe the periodic sequences in the bounded case. Throughout, we frame results in terms of trees and sequences.

Geology And Fossils Of North Central Texas (Fort Worth To Mineral Wells): Texas Academy Of Science February 28 2021, R. Larell Nielson

Faculty Publications

The 2021 Texas Academy of Science Geology field trip will be a virtual field trip that you may run at any time. It will have two parts;Part 1 consists of a video discussion of each stop( https://www.youtube.com/watch?v=EJKSgqtLvw0)and Part 2 consists of this field trip guidebook (for use when visiting each of the locations). The field trip will start at Holiday Park,near Benbrook,southwest of Fort Worth,Texas, and will end at the Mineral Wells Fossil Park, west of Minerals Wells, Texas. T

Transepithelial Anti-Neuroblastoma Response To Kale Among Four Vegetable Juices Using In Vitro Model Co-Culture System, John Piletz, Yuhan Mao, Debarshi Roy, Bilal Qizilbash, Eurielle Nkamssi, Enleyona Weir, Jessica Graham, Mary Emmanuel, Suwaira Iqbal, Kellie Brue, Bidisha Roy Sengupta

Faculty Publications

Juicing vegetables is thought to be an anticancer treatment. Support exists for a rank order of anticancer greens (kale > dandelion > lettuce > spinach) based on degrees of bioavailability of different phytochemicals, also offset by some noxious molecules (i.e., calcium-oxalate). We developed a new in vitro transepithelial anti-neuroblastoma model system. The juices were diluted as predicted once in the small intestine. They were applied to apical Caco-2Bbe1 cells atop dividing SH-SY5Y neuroblastoma cells, and changes in transepithelial electrical resistance (TEER) and cell growth were considered with juice spectroscopies. Studied first in monoculture, kale and dandelion were the most cytostatic juices on SH-SY5Ys, …

Geochemical Characterization Of Base Metals In Stream Water And Sediments In The Caddo Lake Watershed, Cass, Harrison, And Marion Counties, Texas, Melinda S. Faulkner, Melanie L. Ertons, Joseph D. Watkins

Faculty Publications

The Caddo Lake watershed is located in northeastern Texas and encompasses much of Cass, Harrison, and Marion counties. The watershed is drained by major streams and tributaries flowing in an easterly direction over Eocene-aged rocks and sediments of the Wilcox and Claiborne groups, and empty into the western arm of Caddo Lake. Since 1995, Caddo Lake and some of its tributaries have been included on the State of Texas Clean Water Act 303(d) list by the Texas Commission on Environmental Quality (TCEQ) for impairment due to mercury content in edible tissue, depressed dissolved oxygen, base metal concentrations, and low pH …

Geology Of Nacogdoches, Texas: Texas Academy Of Science March 1, 2020, R. Larell Nielson, Mike Read, Mindy Faulkner, Hannah C. Chambers, Jessica O'Neal

Faculty Publications

No abstract provided.

Interpretability Of Api Call Topic Models: An Exploratory Study, Puntitra Glendowne, Dae Glendowne

Faculty Publications

Topic modeling is an unsupervised method for discovering semantically coherent combinations of words, called topics, in unstructured text. However, the human interpretability of topics discovered from non-natural language corpora, specifically Windows API call logs, is unknown. Our objective is to explore the coherence of topics and their ability to represent the themes of API calls from malware analysts’ perspective. Three Latent Dirichlet Allocation (LDA) models were fit to a collection of dynamic API call logs. Topics, or behavioral themes, were manually evaluated by malware analysts. The results were compared to existing automated quality measures. Participants were able to accurately determine …

Data On Gc/Ms Elution Profile, 1h And 13c Nmr Spectra Of 1-, 3-, And 6-Nitrobenzo[A]Pyrenes, Kefa Karimu Onchoke

Faculty Publications

The data presented in this article is related to the research article entitled, “¹³C NMR Chemical Shift Assignments of Nitrated Benzo[a]pyrenes based on Two-dimensional Techniques and DFT/GIAO Calculations”, Kefa K. Onchoke, PeerJ., . The NMR spectral profiles of nitrated benzo[a]pyrenes is presented. Further, the article describes elution profiles of 1-, 3- and 6-NBaP, the acquisition of ¹H and ¹³C NMR data and the J-Coupling constants (which are useful for the assignment of peaks via 2D HMQC and HMBC techniques). The data presented is useful for developing structure-activity relationships for other nitrated polycyclic aromatic hydrocarbons (NPAHs)

Spectroscopic Study On Pseudomonas Aeruginosa Biofilm In The Presence Of The Aptamer-Dna Scaffolded Silver Nanoclusters, Bidisha Sengupta, Prakash Adhikari, Esther Mallet, Ronald Havner, Prabhakar Pradhan

Faculty Publications

We report the effectiveness of silver nanocluster (Ag-NC) against the biofilm of Pseudomonas aeruginosa (PA). Two DNA aptamers specific for PA and part of their sequences were chosen as templates for growing the Ag-NC. While circular dichroism (CD) studies determined the presence of secondary structures, UV/Vis absorption, and fluorescence spectroscopic studies confirmed the formation of the fluorescent Ag-NC on the DNA templates. Furthermore, mesoscopic physics-based partial wave spectroscopy (PWS) was used to analyze the backscattered light signal that can detect the degree of nanoscale mass density/refractive index fluctuations to identify the biofilm formation, comparatively among the different aptamers with respect …

Conformational Polymorphism In Organic Crystals: Structural And Functional Aspects - A Review, Bidisha Sengupta, Pradeep K. Sengupta, Romans Grant1, Matthew Beasley1, Benjamin Mason1, Tanesha Love1, Larissa Barroso9, Mariela Alvarado9, M S. Zaman

Faculty Publications

Polymorphism in organic crystals involves the formation of isomeric molecular identities. It is dependent on the structural arrangement due to inter-atomic interactions, as well as external stimuli, which include temperature, visible and UV radiation. Conformational polymorphism of organic crystalline molecules is often the result of isomerism due to the twisting and turning of angular bonds. The arrangement of the atoms supports different types of bonding mechanisms (which include hydrogen bonding) within the same compound. This, in turn, results in the formation of cis/trans configurational isomers or a proton transfer species (tautomer), having different functional properties. The conformers support the flexibility …

A Comparison Of The Trojan Y Chromosome Strategy To Harvesting Models For Eradication Of Non-Native Species, Jingjing Lyu, Pamela J. Schofield, Kristen M. Reaver, Matthew Beauregard, Rana D. Parshad

Faculty Publications

The Trojan Y Chromosome Strategy (TYC) is a promising eradication method for biological control of non-native species. The strategy works by manipulating the sex ratio of a population through the introduction of supermales that guarantee male offspring. In the current manuscript, we compare the TYC method with a pure harvesting strategy. We also analyze a hybrid harvesting model that mirrors the TYC strategy. The dynamic analysis leads to results on stability of solutions and bifurcations of the model. Several conclusions about the different strategies are established via optimal control methods. In particular, the results affirm that either a pure harvesting …

Large And Small Data Blow-Up Solutions In The Trojan Y Chromosome Model, Rana D. Parshad, Matthew Beauregard, Eric M. Takyi, Thomas Griffin, Landrey Bobo

Faculty Publications

The Trojan Y Chromosome Strategy (TYC) is an extremely well investigated biological control method for controlling invasive populations with an XX-XY sex determinism. In [35, 36] various dynamical properties of the system are analyzed, including well posedness, boundedness of solutions, and conditions for extinction or recovery. These results are derived under the assumption of positive solutions. In the current manuscript, we show that if the introduction rate of trojan fish is zero, under certain large data assumptions, negative solutions are possible for the male population, which in turn can lead to finite time blow-up in the female and male populations. …

Quenching Estimates For A Non-Newtonian Filtration Equation With Singular Boundary Conditions, Matthew Beauregard, Burhan Selcuk

Faculty Publications

In this paper, the quenching behavior of the non-Newtonian filtration equation (φ(u))t = (|ux| r−2 ux)x with singular boundary conditions, ux (0, t) = u −p (0, t), ux (a, t) = (1 − u(a, t))−q is investigated. Various conditions on the initial condition are shown to guarantee quenching at either the left or right boundary. Theoretical quenching rates and lower bounds to the quenching time are determined when φ(u) = u and r = 2. Numerical experiments are provided to illustrate and provide additional validation of the theoretical estimates to the quenching rates and times.

Structural Control Of Mesic Vegetation Communities Within The Owl And Bear Creek Watersheds, Fort Hood Military Installation, Texas, Melinda S. Faulkner, Matthew Mcbroom, Kenneth W. Farrish, Kevin Stafford

Faculty Publications

The Fort Hood Military Installation is a karst landscape, dominated by Lower Cretaceous carbonates of the Trinity and Fredericksburg groups. The study area is the northeastern peninsula known as the Owl Mountain Province, utilized by the U.S. Army for troop maneuvers and training. The geomorphic evolution of the province has been controlled by the structural development of incised canyons in the Owl and Bear creek watersheds, following the deformational trend of the Balcones/Ouachita fault system and the transverse Belton High-Central Texas Reef Trend. These trends control cave development in the subsurface, karst manifestations at the surface, joints in outcrop, stream …

Sensitivity Analysis Of Computations Of The Vapor-Liquid Equilibria Of Methane + Methanol Or Glycols At Gas Hydrate Formation Conditions, Christopher E. Ozigagu, Anthony J. Duben

Faculty Publications

The Soave-Redlich-Kwong (SRK-EOS) and Peng-Robinson (PR-EOS) equations of state are used often to describe the behavior of pure substances and mixtures despite difficulties in handling substances, like water, with high polarity and hydrogen bonding. They were employed in studying the binary vapor-liquid equilibria (VLE) of methane + methanol, monoethylene glycol (MEG), and triethylene glycol (TEG). These liquids are used to inhibit the formation of gas hydrates. The investigation focused on the conditions at which methane-water clathrates can form 283.89 K to 323.56 K and 5.01 MPa to 18.48 MPa. The pressure of methane in methanol is overestimated by a factor …

A Variable Nonlinear Splitting Algorithm For Reaction Diffusion Systems With Self- And Cross-Diffusion, Matthew Beauregard, Joshua L. Padgett

Faculty Publications

Self- and cross-diffusion are important nonlinear spatial derivative terms that are included into biological models of predator-prey interactions. Self-diffusion models overcrowding effects, while cross-diffusion incorporates the response of one species in light of the concentration of another. In this paper, a novel nonlinear operator splitting method is presented that directly incorporates both self- and cross-diffusion into a computational efficient design. The numerical analysis guarantees the accuracy and demonstrates appropriate criteria for stability. Numerical experiments display its efficiency and accuracy

Effectiveness Of Plant Species For Removing Atmospheric Ammonia, Marife B. Anunciado, Sheryll B. Jerez, Hans Williams, Joey Bray, Dean W. Coble, Rena Saito

Faculty Publications

Six plant species of Yaupon, Eastern red cedar, American holly, Arizona cypress, Arborvitae and Roughleaf dogwood were utilized to determine their effectiveness in the removal of atmospheric ammonia. All species were exposed to three ammonia levels (1, 5 and 10 ppm) in an environmental chamber. Foliar ammonia content was quantified using an enzymatic technique. The effects of exposure to ammonia on the physiological responses (e.g. photosynthetic activity, stomatal conductance, and transpiration rate) of plants in ambient condition were also determined using an open design photosynthetic gas exchange system. Foliar ammonia content was significantly different among the six plant species (p<0.0001) with Eastern red cedar exhibiting the highest content. The physiological responses differed significantly depending on the plant species and the ammonia treatment level. The photosynthetic response of plants to the presence of ammonia was mixed. At low exposure level, all species except Arborvitae had decreased photosynthetic activity, reducing by as much as 44.5% for Yaupon. At the highest concentration, however, Yaupon’s photosynthetic activity improved by about 10%. Exposure to ammonia caused increased stomatal conductance and transpiration rate on American holly and Arizona cypress, making them more susceptible to water loss.

Case–Control Research Study Of Auto-Brewery Syndrome, Barbara Jean Cordell, Anup Kanodia, Gregory K. Miller

Faculty Publications

Background: Auto-brewery syndrome (ABS), also known as Gut Fermentation Syndrome and Endogenous Ethanol Fermentation, is afflicting people worldwide, but little is known about ABS patients’ demographics, health history, lifestyle factors, and diet.

Method: We conducted a broad-based case–control survey study on 52 patients known to have a diagnosis of ABS and their household members. The research compares the symptomatic group (N ¼ 28) to the asymptomatic group (N ¼ 18) regarding lifestyle and health, diet, and medical history.

Results: With a response rate of 88% and using rank-sum tests, the data demonstrate that patients with ABS have …

Recovering A Random Variable From Conditional Expectations Using Reconstruction Algorithms For The Gauss Radon Transform, Jeremy Becnel, Daniel Riser-Espinoza

Faculty Publications

The Radon transform maps a function on n-dimensional Euclidean space onto its integral over a hyperplane. The fields of modern computerized tomography and medical imaging are fundamentally based on the Radon transform and the computer implementation of the inversion, or reconstruction, techniques of the Radon transform. In this work we use the Radon transform with a Gaussian measure to recover random variables from their conditional expectations. We derive reconstruction algorithms for random variables of unbounded support from samples of conditional expectations and discuss the error inherent in each algorithm.

A Limiting Process To Invert The Gauss-Radon Transform, Jeremy Becnel

Faculty Publications

In this work we extend the finite dimensional Radon transform [23] to the Gaussian measure. We develop an inversion formula for this GaussRadon transform by way of Fourier inversion formula. We then proceed to extend these results to the infinite dimensional setting.

A Student Led Investigation Of The Landscape Dynamics Of Campus Recycling, Brandon Mcbride, Cheryl L. Scott, David L. Kulhavy, I-Kuai Hung, Daniel Unger

Faculty Publications

Two senior undergraduate students within the environmental science division at Stephen F. Austin State University (SFASU) quantitatively diagnosed the environmental, ecological, and socioeconomic dynamics involved in plastic recycling. This study incorporated actively collecting recycled plastic bottles on campus to produce an enumerated analysis of recycling on campus; and to gain an understanding of the socioeconomics of recycling via an anonymous survey used to determine the recycling knowledgebase of natural resource students at SFASU. Undergraduate students, via their incorporation into a campus wide environmental site assessment of recycling plastic bottles, were able to apply their classroom knowledge to a real-world environmental …

Move It Or Lose It: Interspecific Variation In Risk Response Of Pond-Breeding Anurans, Philip Matich, Christopher M. Schalk

Faculty Publications

Changes in behavior are often the proximate response of animals to human disturbance, with variability in tolerance levels leading some species to exhibit striking shifts in life history, fitness, and/or survival. Thus, elucidating the effects of disturbance on animal behavior, and how this varies among taxonomically similar species with inherently different behaviors and life histories is of value for management and conservation. We evaluated the risk response of three anuran species—southern leopard frog (Lithobates sphenocephalus), Blanchard’s cricket frog (Acris blanchardi), and green tree frog (Hyla cinerea)—to determine how differences in microhabitat use (arboreal vs …

Correlates Of Snake Entanglement In Erosion Control Blankets, Sarah E. Ebert, Kasey L. Jobe, Christopher M. Schalk, Daniel Saenz, Cory K. Adams, Christopher E. Comer

Faculty Publications

In road construction projects across the United States, erosion control methods (e.g., erosion control blankets [ECBs]), are mandated to stimulate seedbed regeneration and prevent soil loss. Previous reports have suggested that snakes are vulnerable to entanglement in ECBs. We conducted a literature review, field surveys, and an entanglement experiment to examine what factors increase a snake’s risk of ECB entanglement. Our literature review produced reports of 175 reptiles entangled in mesh products, 89.1% of which were snakes, with 43.6% of snake entanglements occurring in erosion control products. During our field surveys, we found 10 entangled snakes (n = 2 alive; …

Data On Ion Composition And X-Ray Diffraction Patterns Of Biosolids From Wastewater Treatment Plants In Lufkin And Nacogdoches, Texas, Usa, Kefa Karimu Onchoke, Christopher M. Franclemont, Paul W. Weatherford

Faculty Publications

The data presented in this article is related to the research article entitled, “Structural Characterization and Evaluation of Municipal Wastewater Sludge (Biosolids) from two Rural Wastewater Treatment Plants in East Texas, USA”, Onchoke, KK, Franclemont, C.M., Spectrochim. Acta A, In press[1]. The XRD profiles and composition of biosolids from wastewater treatment plant is presented. This study describes the composition of XRD crystalline phase patterns of the wastewater sludge. After the removal of the Ka2 peaks the d-spacing and hkl values were determined. In addition, the ion chromatographic profile of the seven anions (NO₃^-, NO_{2 …}

Unconfined Hypogene Evaporite Karst: West Texas And Southeastern New Mexico, Usa, Kevin W. Stafford, Jon T. Ehrhart, Adam F. Majzoub, Jessica M. Shields, Wesley A. Brown

Faculty Publications

Diverse karst phenomena occur throughout the Gypsum Plain where the Castile Formation crops out over ~1800 km² in West Texas and southeastern New Mexico. Hypergene karst is extensive and widespread, while traditional hypogene karst manifestations (both caves and intrastratal dissolution) occur in high frequency in the western outcrop region where surface denudation has been the greatest so as to induce surficial breaching. Unconfined hypogene karst occurrences have been recently identified, including two general variations: 1) artesian-like discharge features; and 2) venting structures. Artesian-like discharge features arise at surficially-breached hypogene caves and through high permeability regions on the margins of …

Site Factors Influence On Herbaceous Understory Diversity In East Texas Pinus Palustris Savannas, Brooke Mccalip, Brian Oswald, Kathryn R. Kidd, Yuhi Weng, Kenneth Farrish Phd

Faculty Publications

Longleaf pine (Pinus palustris) savannas were once dominant across the southeastern U.S., including East Texas and parts of western and central Louisiana. The diverse understory associated with these historical savannas may occasionally be seen today, but not often in longleaf pine ecosystems. This project aimed to define east Texas site characteristics that are necessary to support these ecosystems with a dense and diverse herbaceous understory with little to no midstory cover. Fifty-nine plots across three study sites were established to evaluate the influence of overstory cover, basal area, aspect, elevation, and slope on the number of plant genera present. Forest …

Accuracy Of Unmanned Aerial System (Drone) Height Measurements, Daniel Unger, I-Kuai Hung, David Kulhavy, Yanli Zhang, Kai Busch-Peterson

Faculty Publications

Vertical height estimates of earth surface features using an Unmanned Aerial System (UAS) are important in natural resource management quantitative assessments. An important research question concerns both the accuracy and precision of vertical height estimates acquired with a UAS and to determine if it is necessary to land a UAS between individual height measurements or if GPS derived height versus barometric pressure derived height while using a DJI Phantom 3 would affect height accuracy and precision. To examine this question, height along a telescopic height pole on the campus of Stephen F. Austin State University (SFASU) were estimated at 2, …

Oysters And Mammoths: Fossils In Central Texas–Texas Academy Of Science 2017, Chris Barker, R. Larell Nielson

Faculty Publications

Texas Academy of Science, 2017 Field Trip

This year's Texas Academy of Science Geology Field Trip takes you to two very different fossil sites in central Texas. Stop 1 is along a quiet road in the Hill Country where you can collect abundant invertebrate fossils from the Lower Cretaceous Comanche Peak Limestone and Walnut Clay. The second stop of the trip is at one of the newest units of America's park service: the Waco Mammoth National Monument. At this site you will see a spectacular fossil discovery that is now one of the main mammoth sites in North America. And …