Physical Sciences and Mathematics Commons^™

Local Infrasound Observations Of Large Ash Explosions At Augustine Volcano, Alaska, During January 11-28, 2006, Tanja Petersen, Silvio De Angelis, Guy Tytgat, Stephen R. Mcnutt

School of Geosciences Faculty and Staff Publications

We present and interpret acoustic waveforms associated with a sequence of large explosion events that occurred during the initial stages of the 2006 eruption of Augustine Volcano, Alaska. During January 11–28, 2006, 13 large explosion events created ash-rich plumes that reached up to 14 km a.s.l., and generated atmospheric pressure waves that were recorded on scale by a microphone located at a distance of 3.2 km from the active vent. The variety of recorded waveforms included sharp N-shaped waves with durations of a few seconds, impulsive signals followed by complex codas, and extended signals with emergent character and durations up …

An Investigation Into The Antifungal Activities Of N-Thiolated Beta- Lactams Against Selected Candida Species, Marci Culbreath

USF Tampa Graduate Theses and Dissertations

β-lactam antibiotics have long been a reliable course of treatment for bacterial infections. However, with recent increases in resistance and rising populations of immunocompromised patients new β-lactams have been synthesized and tested. The Turos laboratory has recently discovered novel β-lactams that have a mode of action distinct from penicillin and other β-lactam antibiotics as cell lysis is not observed. In the current investigations, these compounds are shown to also have antifungal properties. The rising incidence and prevalence of invasive fungal infections has become an increasing concern. The most common fungal pathogens involved in these infections are species in the genus …

Impacts Of Rainfall Events On Wastewater Treamtent Processes, Erin K. Mcmahan

USF Tampa Graduate Theses and Dissertations

Current research is revealing that stormwater can carry pathogens and that this stormwater is entering wastewater treatment facilities. During periods of intense rainfall, not only can stormwater carry higher amounts of pathogens, but it also increases the flow rate to the wastewater treatment facility. In many instances, the flow rate exceeds the facilities' treatment capacity and can impact treatment performance. The purpose of this study was to identify whether wastewater treatment is impaired during periods of increased rainfall, and to compare current policies that address this issue. The study was conducted using a case study approach to analyze historical precipitation …

Chemo-Enzymatic Route To Synthesis Of Biodegradable Polymers And Glycolipid Analogs, Surbhi Bhatt

USF Tampa Graduate Theses and Dissertations

New catalytic synthetic methods in organic chemistry that satisfy increasingly stringent environmental constraints are in great demand by the pharmaceutical and chemical industries. Studies over last 15 years have revealed that activity of enzymes can be increased in organic solvents rather than their natural aqueous environment. Because of their ease of use, high selectivity and environment friendliness, enzymes are enjoying increasing popularity in today's synthesis world.

Chapter 1 describes chemo-enzymatic synthesis of various glycolipid analogs. A highly regioselective macrolactonization was achieved using lipase from Candida antarctica as a catalyst. It also describes evaluation of lipases from different source and their …

Is There A Northern Lesser Antilles Forearc Block?, A. M. Lopez, S. Stein, Timothy H. Dixon, G. Sella, E. Calais, P. Jansma, J. Weber, P. Lafemina

School of Geosciences Faculty and Staff Publications

A systematic discrepancy exists between slip vectors of thrust fault earthquakes at the Lesser Antilles trench (LAT) and the predicted direction of North American‐Caribbean convergence. A possibility has been that the discrepancy resulted because neither was well constrained. Estimating Caribbean motion has been challenging owing to the limited data along the plate's complex boundaries. Similarly, earlier studies had few slip vectors because interplate thrust events are infrequent. To address these difficulties, we estimate a new Caribbean‐North America Euler vector using recently available GPS data from sites in the presumably stable interior of the Caribbean, and compare the predicted velocities to …

Evaluation Of Geophysical And Thermal Methods For Detecting Submarine Groundwater Discharge (Sgd) In The Suwannee River Estuary, Florida, Matthew Weiss

USF Tampa Graduate Theses and Dissertations

Submarine groundwater discharge (SGD) represents a significant portion of the total discharge from coastal aquifers through diffuse seepage and point source springs, but can be difficult to locate. SGD is important as it can be a source of nutrients to estuaries and other coastal ecosystems. In an effort to evaluate geophysical and thermal methods for detecting SGD on the Florida Gulf coast, a suite of water-borne surveys were run in conjunction with aerial thermal imagery over the lower Suwannee River and estuary in March and September 2005. Thermal imagery exploits temperature differences between discharging groundwater and surface water. Thermal images …

Dynamic Monitoring Of Cytotoxicity Using Electric Cell Substrate Impendence Sensing, Alfred Brian Wafula

USF Tampa Graduate Theses and Dissertations

Electric cell-substrate impedance sensing (ECIS) pioneered by Giaever and Keese is suitable for continuous, automatic and real-time cell attachment analysis. ECIS is a novel electrical method to study, in real time, many of the activities of animal cells when grown in tissue culture. These include morphological changes, cell locomotion, and other behaviors directed by the cell's cytoskeleton. One of the most direct ECIS measurements is that of the attachment and spreading behaviors of cells. These measurements allow one to study and quantify the interaction of cultured cells with extracellular matrix (ECM) proteins and other macromolecules continuously and in real time. …

Coastal Processes And Anthropogenic Factors Influencing The Geomorphic Evolution Of Weedon Island, Florida, Jeanne Lambert

USF Tampa Graduate Theses and Dissertations

Weedon Island, a peninsula located on the western inner shoreline of Tampa Bay, Florida, is the location of a collaborative geological and archaeological project that aims to relate the present day geomorphology to natural processes and human occupational activity during the middle to late Holocene. The area is known for extensive archaeological sites, which were originally investigated in the 1920s, although they have received relatively little scientific attention during most of the last century. We hypothesize that activities associated with pre-historic human occupation of Weedon Island at various times during the last ca. 5,000 years influenced the geomorphic evolution of …

A Modular Onboard Processing System For Small Unmanned Vehicles, Richard D. Garcia

USF Tampa Graduate Theses and Dissertations

This work describes the design and implementation of a generic lightweight onboard processing system for miniature Unmanned Vehicles (UVs) that is computationally powerful and highly adaptable. First, several classical approaches to giant scale and full size UV onboard processing systems are described along with their corresponding limitations. Second, a detailed study is presented that describes the key characteristics of an onboard system along with associated limitations. Next, an implementation of a generic onboard system capable of vision processing and servo based control is presented along with detailed hardware specifications and implementation software. Last, experimental data, both laboratory and field, are …

Vashegyite From Gaura Cu Muscă Cave (Locvei Mountains, Romania): A New And Rare Phosphate Occurrence, Bogdan P. Onac, Luminiţa Zaharia, Joe Kearns, Daniel Veres

International Journal of Speleology

This study investigated the occurrence of vashegyite from a guano-rich deposit located in the Gaura cu Muscă Cave, Romania. Analytical methods used include optical microscopy, X-ray powder diffraction (XRD), scanning electron-microscopy (SEM), inductively coupled plasma-atomic emission spectrometry (ICP-AES), thermal investigations and Fourier-transform infrared (FT-IR) analyses. Vashegyite occurs as friable, chalky white, irregular nodules of up to 2.5 cm in diameter, within a 15 cm thick sequence of organic and minerogenic sediments. The chemical structural formula is: (Al_10.91Fe³⁺_0.06Na_0.1Ca_0.02Mg_0.08)_Σ=11.17[(PO₄)_8.78(SiO₄)_0.056]_Σ=8.83(OH) …

Studies Of Condensation/Evaporation Processes In The Glowworm Cave, New Zealand, C. R. De Freitas, A. Schmekal

International Journal of Speleology

The condensation/evaporation process is important in caves, especially in tourist caves where there is carbon dioxide enriched air caused by visitors. The cycle of condensation and evaporation of condensate is believed to enhance condensation corrosion. The problem is condensation is difficult to measure. This study addresses the problem and reports on a method for measuring and modelling condensation rates in a limestone cave. Electronic sensors for measuring condensation and evaporation of the condensate as part of a single continuous process of water vapour flux are tested and used to collect 12 months of data. The study site is the Glowworm …

Strain Accumulation Across The Carrizo Segment Of The San Andreas Fault, California: Impact Of Laterally Varying Crustal Properties, Gina Schmalzle, Timothy H. Dixon, Rocco Malservisi, Rob Govers

School of Geosciences Faculty and Staff Publications

Major strike slip faults juxtapose geologically dissimilar terrain which may vary in mechanical properties, leading to an asymmetric pattern of strain accumulation. We present new GPS data on the Carrizo segment of the San Andreas Fault, separating the Salinian block southwest of the fault from Franciscan terrane northeast of the fault, to better quantify asymmetric strain accumulation. We also present a series of finite element models to investigate the possible role of variable elastic layer thickness and material properties of the upper crust. The geodetic data are well fit with a simple model comprising a weak upper crustal zone 10–25 …

Salt Ingestion Caves, Charles A. Lundquist, William W. Varnedoe Jr.

International Journal of Speleology

Large vertebrate herbivores, when they find a salt-bearing layer of rock, say in a cliff face, can produce sizable voids where, over generations, they have removed and consumed salty rock. The cavities formed by this natural animal process constitute a unique class of caves that can be called salt ingestion caves. Several examples of such caves are described in various publications. An example in Mississippi U.S.A., Rock House Cave, was visited by the authors in 2000. It seems to have been formed by deer or bison. Perhaps the most spectacular example is Kitum Cave in Kenya. This cave has been …

Identification Of Cave Minerals By Raman Spectroscopy: New Technology For Non-Destructive Analysis, William B. White

International Journal of Speleology

The identification of minerals from caves generally requires that samples be removed from the cave for analysis in the laboratory. The usual tools are X-ray powder diffraction, the optical microscope, and the scanning electron microscope. X-ray diffraction gives a definitive fingerprint by which the mineral can be identified by comparison with a catalog of reference patterns. However, samples must be ground to powder and unstable hydrated minerals may decompose before analysis is complete. Raman spectroscopy also provides a fingerprint useful for mineral identification but with the additional advantage that some a-priori interpretation of the spectra is possible (distinguishing carbonates from …

Thermal Variations In The Hyporheic Zone Of A Karst Stream, Toby Dogwiler, Carol Wicks

International Journal of Speleology

This investigation quantifies how temperatures in the streambed sediments of a karst stream fluctuate in relation to discharge, seasonal, and diurnal temperature variations as the stream passes through a karst window. Furthermore, the linkages between meteorological processes and temperature variation in the hyporheic zone are delineated. Examination of a high-resolution, three dimensional record of temperature variation in a karst stream substrate provides insight into thermal disturbances in the hyporheic zone. Temperatures in the upper portion of the hyporheic zone are strongly linked to air temperatures via the surface water. The variation is considerably less as depth increases. The annual temperature …

Caves And Speleogenesis At Blomstrandsøya, Kongsfjord, W. Spitsbergen, Stein-Erik Lauritzen

International Journal of Speleology

Blomstrandsøya, at Kongsfjord (78° 57’N), Spitsbergen, is within the high arctic, a completely permafrozen zone. The bedrock consists of Paleozoic marbles and has yielded a surprising amount of karst features. Early phases of hydrothermal, possibly Caledonian, speleogenesis and subsequent Devonian karstification with redbed deposits is well documented. 62 active seacaves, and more than 30 relict karst caves were found in the coastal cliffs and in escarpment faces around the island. All caves have very limited extent; they are either quite short, like most of the active sea caves, or they are soon choked by frozen sediments and ground ice after …

The Distribution Of Diatom Flora In Ice Caves Of The Northern Yukon Territory, Canada: Relationship To Air Circulation And Freezing, Bernard Lauriol, Clément Prévost, Denis Lacelle

International Journal of Speleology

In the late 1980’s and early 1990’s, various media in karst environments in the Northern Yukon Territory were examined for their diatom content. Cryogenic cave calcite powders, grus and various ice formations (ice plugs, ice stalagmites and floor ice) were collected from three freezing caves and one slope cave to make an inventory of the diatom content, and to explain the spatial distribution of the diatoms within the caves. The results show that approximately 20% of diatoms in the caves originate from external biotopes and habitats (e.g., river, lake, stream), with the remaining 80% of local origin (i.e., from subaerial …

Dry Creek Long Term Watershed Study: Buffer Zone Performance As Viable Amphibian Habitat, Brooke L. Talley, Thomas Crisman

School of Geosciences Faculty and Staff Publications

As bioindicators, amphibians typically require both terrestrial and aquatic habitats to complete their life cycles. Pre- timber-harvest monitoring (December 2002 through September 2003) of salamander and frog (Hylidae) populations was conducted in four watersheds of Decatur County, GA. Post- timber-harvest monitoring (December 2003 through September 2004) continued in the same watersheds (two reference and two treatment watersheds). Coverboards were used to monitor adult salamanders, larval salamanders were surveyed with dipnet sweeps, and frogs were monitored with vertical PVC pipes. Six salamander species (Desmognathus apalachicolae, Eurycea cirrigera, E. guttolineata, Notophthalmus viridescens, Plethodon grobmani, and Pseudotriton ruber) and five frog species (Hyla …

Dry Creek Long Term Watershed Study: Assessment Of Immediate Response Of Aquatic Macroinvertebrates To Watershed Level Harvesting And Thinning Of Streamside Management Zones, M. W. Griswold, R. T. Winn, Thomas Crisman, W. R. White

School of Geosciences Faculty and Staff Publications

Streamside Management Zones (SMZs) are meant to protect riparian habitat and the stream ecosystem. Benthic macroinvertebrates are recognized bioindicators of water quality in streams, typically occupying multiple trophic levels in these systems and providing food for vertebrates. Thus, it is important to understand the effects of harvest within and adjacent to the SMZ on macroinvertebrate assemblages. Benthic macroinvertebrates were sampled pre- and post-harvest from four firstorder streams draining the Dry Creek watershed in southwestern Georgia. A multi-habitat sampling procedure was used. Macroinvertebrates were identified and compared using biotic indices. Comparisons were made between streams within the pre-harvest period and between …

Unconfined Versus Confined Speleogenetic Settings: Variations Of Solution Porosity, Alexander Klimchouk

International Journal of Speleology

Speleogenesis in confined settings generates cave morphologies that differ much from those formed in unconfined settings. Caves developed in unconfined settings are characterised by broadly dendritic patterns of channels due to highly competing development. In contrast, caves originated under confined conditions tend to form two- or three-dimensional mazes with densely packed conduits. This paper illustrates variations of solution (channel) porosity resulted from speleogenesis in unconfined and confined settings by the analysis of morphometric parameters of typical cave patterns. Two samples of typical cave systems formed in the respective settings are compared. The sample that represents unconfined speleogenesis consists of solely …

Tracer-Test Design For Losing Stream–Aquifer Systems, Malcolm S. Field

International Journal of Speleology

Hydrological tracer testing is an effective way for assessing the significance and extent of leakage through the bed of an influent (losing and sinking) stream. In karstic terranes, leakage from losing and sinking streams typically resurge at downstream springs, but flow may be intercepted by production wells. Although sinking streams that disappear into swallow holes and caves are relatively easy to trace, developing a tracer test design for a losing stream that allows slow percolation through its bed is complicated by the lack of basic knowledge regarding leakage rate, leakage locations along its length, and temporal variability. To overcome these …

Radon In Caves: Clinical Aspects, Stephen A. Craven, Berend J. Smit

International Journal of Speleology

Historical, experimental and clinical evidence is presented to suggest that radon constitutes a relatively small carcinogenic risk for casual visitors to caves. The risk is dependent on radon levels and the smoking of tobacco. Show cave guides, chronically exposed to radon, may be at increased risk for lung cancer due to the effects of radon, especially if they are smokers of tobacco.

Relationships Between Deflector Faults, Collapse Dolines And Collector Channel Formation: Some Examples From Slovenia, France Šušteršič

International Journal of Speleology

In some Slovenian caves collector channels gather sinking underground streams and redirect them for potentially long distances parallel to certain faults. The collector channels formed due to ongoing long-term collapse of cave roofs at the points where passages break through the faults, which function as a kind of screen and are termed deflector faults. The fault trends are marked by collapse within the caves, and by active collapse dolines at the surface.

Spectral Analysis Of Ground Penetrating Radar Response To Thin Sedimentary Layers, Swagata Guha, Sarah E. Kruse, E. E. Wright, U. E. Kruse

Geology Faculty Publications

Ground penetrating radar (GPR) systems utilized in studies of sedimentary deposits generate wavelengths (tens of centimeters) that are commonly much longer than the thickness of bedding (often millimeters to centimeters) within the target strata. Where this is the case, radar profiles represent interference patterns. Simple models of radar response to sequences of thin beds such as those found in coastal deposits show potentially detectable spectral shifts toward higher frequencies in radar returns. Spectral analysis of radar data over barrier beach deposits at Waites Island, South Carolina, shows that returns from packages with heavy mineral laminations are shifted toward higher frequencies …

Nutrient Enrichment Studies Of Natural Phytoplankton Populations In The Lower Hillsborough River Conducted On October 10 - 13, 2005, The City Of Tampa Wastewater Department

Reports

The Bay Study Group (BSG) conducted nutrient enrichment studies (bioassays) on natural phytoplankton population samples collected at four locations in the Lower Hillsborough River on October 10, 2005. Test site HR1 was located approximately 320m upriver of the Rowlett Park Blvd. bridge (Lat: 28o 01.368’N; Lon: 82o 25.914’W), test site HR2 was located approximately 200m upriver of the Nebraska Ave. bridge (Lat: 28o 01.174’N; Lon: 82o 26.960’W), test site HR3 was located approximately 280m downriver of the Florida Ave. bridge (Lat: 28o 01.257’N; Lon: 82o 27.740’W), and test site HR4 was located approximately 20m upriver of the Sligh Ave. bridge …

Systematic Revision Of The Genus Eupleura H. And A. Adams, 1853 (Gastropoda: Muricidae) In The Neogene To Recent Of Tropical America, Gregory S. Herbert

School of Geosciences Faculty and Staff Publications

The systematics of the Neogene to Recent genus Eupleura of tropical America are revised, with descriptions of four new species: Eupleura engerrabunda, from the Late Miocene of Mexico (Atlantic); Eupleura gravidentata, from the Plio-Pleistocene of Colombia (Atlantic); Eupleura paroudia, from the Early or middle Pliocene of Mexico (Atlantic); and Eupleura vokesorum, from the Pliocene of Costa Rica (Pacific) and Ecuador and the Recent tropical eastern Pacific. Two recent taxa, Eupleura plicata and Eupleura limata, are also resurrected, increasing the standing diversity of Eupleura in the eastern Pacific to seven species. Eupleura limata, however, may …

Geodetic Gps Measurements In South Iceland: Strain Accumulation And Partitioning In A Propagating Ridge System, P. C. Lafemina, Timothy H. Dixon, R. Malservisi, T. Arnadottir, E. Sturkell, F. Sigmundsson, P. Einarsson

School of Geosciences Faculty and Staff Publications

GPS observations in south Iceland between 1994 and 2003 are compared with two-dimensional elastic half-space and viscoelastic coupling models for two parallel rift zones, representing the Western and Eastern volcanic zones (WVZ, EVZ). GPS data from the Hreppar block, between the WVZ and EVZ, fit a rigid block model within uncertainties. Spreading rates across the WVZ increase from 2.6 ± 0.9 mm/yr in the northeast to 7.0 ± 0.4 mm/yr in the southwest. Conversely, spreading rates in the EVZ decrease from 19.0 ± 2.0 mm/yr in the northeast to 11.0 ± 0.8 mm/yr in the southwest, the direction of ridge …

Data Summary From The Tampa Bay Interagency Seagrass Monitoring Program Through Year 2004, Walt Avery, Roger Johansson

Reports

Results regarding seagrass species abundance, distribution, and zonation over time are presented for the 1997-2004 period in Hillsborough Bay (HB, Figures 16-27) and the 1998-2004 period for Old Tampa Bay (OTB, Figures 3-14), Middle Tampa Bay (MTB, Figures 29-41), Lower Tampa Bay, including Terra Ceia Bay (LTB, Figures 43-57), and Boca Ciega Bay (BCB, Figures 59-69). For each transect, results are presented in a graphic format illustrating annual species composition, abundance, and distribution. Seagrass abundance is presented as percent coverage within a square meter using the Braun Blanquet coverage class system.

The 7 May 2001 Induced Seismic Event In The Ekofisk Oil Field, North Sea, L. Ottemöller, H. H. Nielsen, K. Atakan, Jochen Braunmiller, J. Havskov

School of Geosciences Faculty and Staff Publications

A moderate size seismic event on 7 May 2001 was strongly felt on platforms in the Ekofisk oil field, in the southern North Sea, but did not cause damage to platforms or wells. We combined near- and far-field observations to develop a consistent source model and to determine whether the event was induced. Seismic data placed the epicenter inside the Ekofisk field and suggested a shallow source depth based on spectral and moment tensor analysis. GPS data from the Ekofisk platforms displayed permanent vertical and horizontal movement due to the event. A topographic bulge in the sea bottom, revealed by …

Modeling Tephra Sedimentation From A Ruapehu Weak Plume Eruption, Costanza Bonadonna, J. C. Phillips, B. F. Houghton

Geology Faculty Publications

We present a two-dimensional model for sedimentation of well-mixed weak plumes, accounting for lateral spreading of the cloud, downwind advection, increase of volumetric flux in the rising stage, and particle transport during fallout. The 17 June 1996 subplinian eruption of Ruapehu produced a bent-over plume that rose to a height of 8.5 km in a wind field with an average velocity of 24 m s⁻¹ and generated a narrow deposit on land extending up to 200 km from vent. The sedimentation from the Ruapehu plume was dominated by coarse ash, with all the blocks and most of the lapilli …