Physical Sciences and Mathematics Commons^™

Hydrometeorological Factors Determining The Development Of Water Table Cave Patterns In High Alpine Zones. The Ordesa And Monte Perdido National Park, Ne Spain, Antonio González-Ramón, Jorge Jódar, José M. Samsó, Sergio Martos-Rosillo, Javier Heredia, Ane Zabaleta, Iñaki Antigüedad, Emilio Custodio, Luis J. Lambán

International Journal of Speleology

This study is focussed on the geomorphological characterization and the processes driving the evolution of the highest karst system in Western Europe, which is located in the Ordesa and Monte Perdido National Park (PNOMP), in the central-southern Pyrenees. The karst system does not seem to have a well-developed epikarst. The studied area shows a karst network of polygenic branchwork type in the vadose zone. Additionally, the explored karst conduits in the epiphreatic zone show a water table cave pattern that is different to the looping one, which is the expected cave pattern development for a karst located in a mountain …

Influence Of Some Climatic Elements On Radon Concentration In Saeva Dupka Cave, Bulgaria, Peter Nojarov, Petar Stefanov, Karel Turek

International Journal of Speleology

This study reveals the influence of some climatic elements on radon concentration in Saeva Dupka Cave, Bulgaria. The research is based mainly on statistical methods. Radon concentration in the cave is determined by two main mechanisms. The first one is through penetration of radon from soil and rocks around the cave (present all year round, but has leading role during the warm half of the year). The second one is through thermodynamic exchange of air between inside of the cave and outside atmosphere (cold half of the year). Climatic factors that affect radon concentration in the cave are temperatures (air, …

Biosynthetic Gene Clusters, Microbiomes, And Secondary Metabolites In Cold Water Marine Organisms, Nicole Elizabeth Avalon

USF Tampa Graduate Theses and Dissertations

Microorganisms and invertebrate animals from cold water marine environments, such as in Antarctica and in Ireland’s deep sea, are a rich source of secondary metabolites. In this dissertation, research was centered around secondary metabolism and natural product biosynthesis. The projects include the delineation of biosynthetic gene clusters hypothesized to be responsible for the biosynthesis of the palmerolides, stratification of the microbiome of the Antarctic ascidian Synoicum adareanum, genomic and peptidomic analysis of a host-associated Antarctic Pseudovibrio sp., and isolation and characterization of secondary metabolites from the Irish deep-sea coral Drifa sp.

Palmerolide A, the principle secondary metabolite associated with S. …

Countermeasures Against Various Network Attacks Using Machine Learning Methods, Yi Li

USF Tampa Graduate Theses and Dissertations

With the rapid development of a computer network, our lives are already inseparable from it. Wireless Fidelity (Wi-Fi) is in use everywhere; more and more devices are connected to the Internet, and many companies and individuals tend to store their data and information online. Furthermore, it is now very convenient to communicate with each other through email and text messages. However, widespread networks also provide more attack surfaces for attackers. There are a variety of network attacks aimed at information theft. To better defend against those network attacks, one needs to have a broad knowledge of existing attacks. In this …

System Support Of Concurrent Database Query Processing On A Gpu, Hao Li

USF Tampa Graduate Theses and Dissertations

The unrivaled computing capabilities of modern GPUs meet the demand of processing massive amounts of data seen in many application domains. While traditional HPC systems support applications as standalone entities that occupy the entire GPU, we propose a GPU-based DBMS (G-DBMS) that can run multiple tasks concurrently. To that end, system-level management mechanisms like resource allocation and buffer manager are needed to build such a concurrent database query processing system and fully unleash the GPUs’ computing power. However, CUDA does not provide enough OS-level functionalities to support it. Thus our research is focusing on implementing the optimization of resource allocation …

Development Of Next-Generation, Fast, Accurate, Transferable, And Polarizable Force-Fields For Heterogenous Material Simulations, Adam E. Hogan

USF Tampa Graduate Theses and Dissertations

Theoretical modeling is extremely useful in guiding to experiment; however quantitatively accurate modeling of energy-relevant small molecule sorption at the heterogeneous interfaces present in metal-organic materials (MOMs) is currently challenging. MOMs are an emerging class of materials consisting of inorganic clusters and organic linkers that offer great potential in the areas of gas storage, gas separation, and catalysis due to the possibility of large surface areas, complex heterogeneous surfaces, and rational designability. Efficient chemical separations involving these materials could reduce the US’s total energy consumption by approximately 10 to 15%. In this dissertation, the parameterization of small molecules and metal …

Climate Change And Sustainable Development Within The Tourism Sector Of Small Island Developing States: A Case Study For The Bahamas, Arsum Pathak

USF Tampa Graduate Theses and Dissertations

The research literature suggests Small Island Developing States (SIDS) are vulnerable to climate change. Tourism in SIDS is sensitive to climate variations and dependence of the sector on natural resources (beaches, coral reefs) adds to their vulnerability. The purpose of this study is to assess climate impacts and adaptation within the tourism sector of a SIDS – The Bahamas that relies on tourism and faces climate vulnerabilities, as do other SIDS. Given the importance of tourism to their sustainable development by supporting economic growth and employment, this study identifies timely risks and adaptation planning for a tourism-based SIDS economy in …

Plio-Pleistocene Antarctic Ice-Ocean Interactions In The Ross Sea, Catherine Prunella

USF Tampa Graduate Theses and Dissertations

Warm, intermediate-depth Southern Ocean waters are implicated in recent Antarctic ice mass loss. Direct observations of Antarctic Ice Sheet (AIS) retreat are temporally limited, necessitating paleoceanographic records of ocean-ice interactions during past warm climate intervals. Deepsea and ice-proximal sediments record orbitally-paced glacial-interglacial fluctuations in AIS volume during the Plio-Pleistocene (last 5 million years; Ma), but the total contribution of the AIS and the role of ocean heat in these fluctuations remain unresolved. To address the response of Antarctica’s ice sheets to changing ocean temperatures during the Plio-Pleistocene, International Ocean Discovery Program (IODP) Expedition 374 recovered sediments from the Ross Sea …

Modeling Early Life: Ontogenetic Growth And Behavior Affect Population Connectivity In Gulf Of Mexico Marine Fish, Kelly Vasbinder

USF Tampa Graduate Theses and Dissertations

This dissertation is an examination of growth, behavior, and dispersal during the early life stages of marine fishes in the Gulf of Mexico. Understanding movements of early life stages is a key part of managing exploited fish populations. Position in the water column can impact larval dispersal, since it determines those currents to which larvae are exposed. First, I investigated the relationship between length and age in early life stages of marine fishes. I found that demersal fish taxa tend to be represented by exponential models, while pelagic fish tend to be represented by linear models. I suggest this may …

Characterizing Childhood And Diet In Migration Period Hungary, Kirsten A. Verostick

USF Tampa Graduate Theses and Dissertations

This project investigates children, childhood and diet of two different Migration Period (4^th-8^th century AD) populations, the Gepids and the Avars, in the Great Hungarian Plain. The main goal was to assess whether there are differences in treatment of children and differences in breastfeeding and weaning practices in these distinct sites and populations. Secondarily, this research also focused on characterizing diet for the Gepids and the Avars at four different sites from the Migration Period, to understand how the migration and settling into the region and the assimilation of other groups into the two populations affected their …

Conversion From Metal Oxide To Mof Thin Films As A Platform Of Chemical Sensing, Meng Chen

USF Tampa Graduate Theses and Dissertations

Chemical sensor is working as a widely used device which can be applied to the detection of specific chemicals that are existing in the environment especially in gas phase. The detection of combustible and toxic chemicals can be extremely important in the field of both industrial and civil activities. The chemical sensor is commonly operating by utilizing a chemical or physical interaction between the specific chemical compound and the sensing functional unit, to obtain an electronic signal caused by the property change and realize the chemical detection. Traditional chemical gas sensors such as catalytic gas sensor, thermal conductivity gas sensor, …

An Analysis Of Preservice Elementary Teachers’ Professional Noticing Skills In A Mathematics Education Setting, Liza Bondurant, Lisa Poling, Diana Moss

Journal of Practitioner Research

Prospective elementary mathematics teachers (PTs) were asked to analyze 28 videos of cognitive interviews. The purpose of this study was to determine if experiences analyzing videos would lead to improvements in PTs’ professional noticing skills. Using a coding schema that reflected three levels of understanding (periphery, transitional, and accomplished), a frequency table was constructed that allowed PTs’ use and understanding of a noticing framework to be analyzed. Findings indicate that experiences analyzing videos leads to improvements in PTs’ professional noticing skills.

Spontaneous Raman Scattering Enhancement With Microcavities And Multipass Resonators For Trace Gas Detection, Juan Sebastian Gomez Velez

USF Tampa Graduate Theses and Dissertations

The continual increase in production and use of chemicals in an ever-growing field of applications naturally brings forth the necessity to accurately and efficiently measure molecular composition. Spontaneous Raman scattering is a reliable technique which can optically identify molecules based on their intrinsic rotational-vibrational energy structure. The Raman emission from a substance can be spectrally analyzed to detect molecular species simultaneously and with isotopic sensitivity using a single laser source. However, even though the process is non-invasive and effective, the rate at which the emission occurs is notoriously low due to a weak scattering cross-section. Therefore, research into the development …

Maternal Social Status, Offspring 2d:4d Ratio And Postnatal Growth, In Macaca Mulatta (Rhesus Macaques), Juan Pablo Arroyo

USF Tampa Graduate Theses and Dissertations

Early life exposure to stressors can disrupt growth and development, resulting in long-term compromised function and increased risk for disease throughout the lifecourse. Maternal exposure to psychosocial stressors (i.e., stressors derived from social status, social inequalities, and social interactions) during pregnancy has been associated with reduced fetal growth, adverse birth outcomes, and increased morbidity for the offspring later in life. Maternal hormonal responses to stress, such as fluctuations in glucocorticoids (e.g., cortisol) and androgens (e.g., testosterone), can result in increased developmental instability, interfere with offspring growth in-utero, and may alter developmental processes of sexual dimorphism. Second digit to fourth digit …

The Utilization Of Shared Energy Storage In Energy Systems: Design, Modeling And Optimization, Rui Dai

USF Tampa Graduate Theses and Dissertations

Energy storage (ES) plays a significant role in modern smart grids and energy systems. With the advances of ES technologies, efficiently applying ES to energy systems has become the bottleneck for achieving the benefits of ES. The traditional approach of utilizing ES is the so-called distributed framework in which there is a separate ES for each individual user. Due to the inherent limits in the distributed framework such as cost inefficiency and space limitations, many studies have promoted to utilize a shared ES in energy systems to further exploit the potentials of ES. However, current studies always focus on maximizing …

Porosity And Permeability Extremes In An Eogenetic Carbonate Platform: Mechanisms For Formation And Implications For Fluid Flow, Charles I. Breithaupt

USF Tampa Graduate Theses and Dissertations

Carbonate rocks contain about a third of the worlds drinking water and host 60-70% of proven hydrocarbon reserves. Effective development and management of these resources relies heavily on geologic concepts used to predict the distribution, and magnitude of porosity and permeability in the aquifer or reservoir. Most geologic concepts used for flow prediction have been developed in telegenic limestones, where fracture networks, bedding plains, and conduits hosted in effectively impermeable bedrock control the movement of fluids, and evolution of porosity. However, a growing body of work has recognized fluid flow within eogenetic limestones is fundamentally different, and that new concepts …

Discrete Models And Algorithms For Analyzing Dna Rearrangements, Jasper Braun

USF Tampa Graduate Theses and Dissertations

In this work, language and tools are introduced, which model many-to-many mappings that comprise DNA rearrangements in nature. Existing theoretical models and data processing methods depend on the premise that DNA segments in the rearrangement precursor are in a clear one-to-one correspondence with their destinations in the recombined product. However, ambiguities in the rearrangement maps obtained from the ciliate species Oxytricha trifallax violate this assumption demonstrating a necessity for the adaptation of theory and practice.

In order to take into account the ambiguities in the rearrangement maps, generalizations of existing recombination models are proposed. Edges in an ordered graph model …

Save Water Drink Wine: Challenges Of Implementing The Ethnography Of The Temecula Valley Wine Industry Into Food-Energy-Water Nexus Decision-Making, Zaida E. Darley

USF Tampa Graduate Theses and Dissertations

This study demonstrates the interrelationships of people, food, energy, and water associated with Temecula Valley’s wine industry and reveals contradictions and biases in how people view these resources, which ultimately shape management and policies. The FEW (Food, Energy, and Water) Nexus is an approach increasingly used by policy- and decision-makers to understand the interrelationship of several resources. However, a FEW Nexus approach often lacks in social aspects that influence environmentally and economically sustainable outcomes, especially in the wine and wine tourism industry. When quantitative and qualitative data are available, the other challenge is which assessment to use. Two assessments often …

Coral Reef Restoration In The Tropical West Atlantic Amid The Covid-19 Pandemic, Linden Cheek

USF Tampa Graduate Theses and Dissertations

Climate change is increasing threats to coasts, both from storm surge and sea level rise. Healthy coral reefs provide reduction in storm surges, wave energy, coastal flooding and everyday erosion, and are found across a variety of spatial scales. Given the state of coral reefs worldwide, active Coral Reef Restoration (CRR) in emerging as a necessary component of coastal protection. CRR can be classified as a nature-based solutions (NbS) for coastal protection that also provides a multitude of ecosystem-based services to both humans and other life. Nearly all literature on coral restoration efforts assume a steady-state of human-ecological interactions, but …

Laser-Induced Modifications In Two-Dimensional Materials, Tariq Afaneh

USF Tampa Graduate Theses and Dissertations

Atomically thin two-dimensional (2D) materials have attracted a growing interest in the lastdecade from the fundamental point of view as well as their potential applications in functional devices. Due to their high surface-to-volume ratio, the physical properties of 2D materials are very sensitive to the environmental factor such as surrounding media and illumination conditions (e.g. light-mater interaction). In the first part of this dissertation I will present recent advances in developing laser-assisted methods to tune the physical properties of 2D transition metal dichalcogenides (TMDs). We demonstrate laser-assisted chemical modification ultrathin TMDs, locally replacing selenium by sulfur atoms. The photo-conversion process …

A Novel Magnetic Respiratory Sensor For Human Healthcare, Kee Young Hwang

USF Tampa Graduate Theses and Dissertations

Breathing is vital to life. Therefore, the real-time monitoring of a patient’s breathing pattern is crucial to respiratory rehabilitation therapies such as magnetic resonance exams for respiratory-triggered imaging, chronic pulmonary disease treatment, and synchronized functional electrical stimulation. While numerous respiratory devices have been developed, they are often in direct contact with a patient, which can yield inaccurate or limited data. In this study, we developed a novel, non-invasive, and contactless magnetic sensing platform that can precisely monitor a patient’s breathing, movement, or sleep patterns, thus providing efficient monitoring at a clinic or home. A magneto-LC resonance (MLCR) sensor converts the …

On Some Problems On Polynomial Interpolation In Several Variables, Brian Jon Tuesink

USF Tampa Graduate Theses and Dissertations

Polynomial approximation is a long studied process, with a history dating back to the 1700s, At which time Lagrange, Newton and Taylor developed their famed approximation methods. At that time, it was discovered that every Taylor projection (projector) is the pointwise limit of Lagrange projections. This leaves open a rather large and intriguing question, What happens in several variables?

To this end we define a linear idempotent operator to be an ideal projector whenever its kernel is an ideal. No matter the number of variables, Taylor projections and Lagrange projections are always ideal projectors, and it is well known that …

The Development Of Aapeptides, Lulu Wei

USF Tampa Graduate Theses and Dissertations

Non-natural peptide mimics are referred to as peptidomimetics, which contains unnatural backbones that mimic the primary peptide structure. There are a large number of peptidomimetics that have been developed including α-peptides, β-peptides, peptoids, arylamide oligomers, cationic polymers, and other peptidomimetics in the last decades. Compared to conventional peptides, these peptidomimetics have many advantages such as resistance to proteolysis, improved bioavailability, and reduced immunogenicity. However, the development of peptidomimetics is still far below the expectation due to the limitation of the availability of backbones. It is an urgent need to generate a new diverse library for novel drug discovery, design antimicrobial …

Analytical Methods And Critical Analyses Supporting Thermodynamically Consistent Characterizations Of The Marine Co2 System, Jonathan D. Sharp

USF Tampa Graduate Theses and Dissertations

Chemical equilibria describing the unique behavior of gaseous and ionic forms of dissolved carbon dioxide (CO₂) in seawater comprise what is known as the marine CO₂ (or carbonate) system. Observations of the marine CO₂ system with high degrees of accuracy, reproducibility, spatial coverage, and temporal resolution are critical for evaluating natural cycles of carbon within the Earth system, as well as chemical and biological responses to anthropogenic CO₂ emissions.

One component of the CO₂ system is the carbonate ion (CO²−₃), a dissolved ion that is produced when carbonic acid (H …

Multimodal Data Fusion And Attack Detection In Recommender Systems, Mehmet Aktukmak

USF Tampa Graduate Theses and Dissertations

The commercial platforms that use recommender systems can collect relevant information to produce useful recommendations to the platform users. However, these sources usually contain missing values, imbalanced and heterogeneous data, and noisy observations. Such characteristics render the process of exploiting the information nontrivial, as one should carefully address them during the data fusion process. In addition to the degenerative characteristics, some entries can be fake, i.e., they can be the outcomes of malicious intents to manipulate the system. These entries should be eliminated before incorporation to any recommendation task. Detecting such malicious attacks quickly and accurately and then mitigating them …

Digital Identity: A Human-Centered Risk Awareness Study, Toufic N. Chebib

USF Tampa Graduate Theses and Dissertations

Cybersecurity threats and compromises have been at the epicenter of media attention; their risk and effect on people’s digital identity is something not to be taken lightly. Though cyber threats have affected a great number of people in all age groups, this study focuses on 55 to 75-year-olds, as this age group is close to retirement or already retired. Therefore, a notable compromise impacting their digital identity can have a major impact on their life.

To help guide this study, the following research question was formulated, “What are the risk perceptions of individuals, between the ages of 55 and 75 …

Unifying Security Policy Enforcement: Theory And Practice, Shamaria Engram

USF Tampa Graduate Theses and Dissertations

Security policies stipulate restrictions on the behaviors of systems to prevent themfrom behaving in harmful ways. One way to ensure that systems satisfy the constraints of a security policy is through the use of security enforcement mechanisms. To understand the fundamental limitations of such mechanisms, formal methods are employed to prove properties and reason about their behaviors. The particular formalism employed, however, typically depends on the time at which a mechanism operates.

Mechanisms operating before a program's execution are static mechanisms, and mechanisms operating during a program's execution are dynamic mechanisms. Static mechanisms are fundamentally limited in the types of …

Multifunctional Metal-Organic Frameworks (Mofs) For Applications In Sustainability, Gaurav Verma

USF Tampa Graduate Theses and Dissertations

Climate change, affordable and clean energy, and responsible consumption and production are some of the important goals to be achieved for sustainable development. The current technologies used to address these challenges are energy and resource intensive. Furthermore, there are various limitations related to cost, storage, scalability and safety.Adsorbent materials are seen as a promising alternative remediation system due to their low energy consumption and minimal chemical waste production. However, most of the traditional adsorbents, such as activated carbon and zeolites lack the structural tunability to have long-term effectiveness and their use is limited. As discussed in Chapter 1, metal organic-frameworks …

Sustainable Non-Noble Metal Based Catalysts For High Performance Oxygen Electrocatalysis, Swetha Ramani

USF Tampa Graduate Theses and Dissertations

Current energy crisis has dramatically shifted the focus of technological advancements towards clean and renewable forms of energy. Continued dependence and utilization of fossil fuels has created global awareness on harmful greenhouse gas emissions and climate change. A need for sustainable technology has gained a lot of significance in the recent years. This has led to the development of devices and technologies that rely on environmentally friendly electrochemical conversion and storage of energy. One such advancement that generates electrical energy from chemical reactions is known as fuel cell technology. While fuel cells have demonstrated potential in replacing the conventional technologies …

The Use Of Spanish Moss As A Biological Indicator To Examine Relationships Between Metal Air Pollution, Vegetation Cover, And Environmental Equity In Tampa, Florida, Yousif Abdullah

USF Tampa Graduate Theses and Dissertations

Studies of inequality in exposure to less common air pollutants, like metals, are often limited by the costs of high spatial resolution measurements. Spanish moss (Tillandsia usneoides) is a promising bioindicator for measuring air pollution due to its lower cost, enabling capture of time-average environmental concentrations at high spatial resolution. This study had three major aims. First, I aimed to use Spanish moss as a bioindicator to characterize ambient concentrations of selected metals (Ti, Cr, Mn, Co, Ni, Cd, Hg, Pb, As, and Sb) in Tampa, Florida. My second goal was to determine the impact of vegetation cover on metals …