Physical Sciences and Mathematics Commons^™

Functionalization Of Resorcinarenes And Study Of Antimicrobial Activity, Kirankirti Muppalla

USF Tampa Graduate Theses and Dissertations

Cavitands are very important class of compounds in supramolecular chemistry. These molecules contain rigid enforced cavity,and have attracted considerable attention in supramolecular chemistry as building blocks for the construction of carcerands, hemicarcerands, and other host guests complexes. Nearly 40 years ago, Niederl and Vogel laid foundation for the study of such type of condensation reactions. In our laboratory we are involved in synthesis of resorcinarenes with readily available substrates such as resorcinol and aldehydes to form a cyclic tetramer.

Herein, I present detailed studies about the functionalization of the synthesized tetramers and their antimicrobial activity. Octahydroxy resorcinarenes were synthesized and …

Climatic And Structural Controls On The Geomorphology Of Wadi Sana, Highland Southern Yemen, Joshua Michael Anderson

USF Tampa Graduate Theses and Dissertations

Middle Holocene climate change forced significant environmental response and influenced human activities throughout southern Arabia. Climate models and proxy data indicate that climate along the southern Arabian peninsula changed from a moist phase, spanning the early to middle Holocene, to an arid phase, which persisted for the last ca. 5,000 years. A weakening and southward shift of the Southwest Indian Monsoon System, forced by northern hemisphere insolation variations in the precession band and/or glacial boundary conditions, is suggested as the mechanism for the abrupt shift to more arid conditions. Geoarchaeological evidence suggests that agriculture was more widespread and evolved alongside …

Evanescent Field Absorption Sensing Using Sapphire Fibers, Michael Grossman

USF Tampa Graduate Theses and Dissertations

This thesis explores the application of coiled sapphire multimode optical fibers for evanescent wave chemical sensing in both the visible spectrum and the near infrared. As has been suggested in the literature pertaining to silica fibers, bending converts low-order modes to high order ones, which leads to more evanescent absorption and thus a more sensitive chemical detector. By coiling the fiber many times, it was expected that even greater sensitivity would be attained.

Experiments were performed to investigate the sensor response to different solutions and to characterize this response. In the first of three experiments, the large absorption peak of …

Influence Of Evapotranspiration On Patterns Of Ground-Water Conductivity In Small Basins, Ana Jiménez

USF Tampa Graduate Theses and Dissertations

Ground-water conductivity data were obtained from shallow wells in a 12 km2 stream-basin along a 400 m transect, extending from the divide to the stream. The stream, Pringle Branch, is a second-order perennial stream in Hillsborough County, Florida. The shallow stratigraphy consists of 2-3 m of fine sand over a layer of clayey silt and silty clay. Vegetation cover includes grasses on the upper and middle slope, and riparian woodlands on the foot slope and floodplain. Precipitation is about 1.3 m per year. Shallow ground-water conductivity is about 50 uS/cm at the divide. It increases moderately along the mid slope, …

Geodetic, Teleseismic, And Strong Motion Constraints On Slip From Recent Southern Peru Subduction Zone Earthquakes, M. E. Pritchard, E. O. Norabuena, C. Ji, R. Boroschek, D. Comte, M. Simons, Timothy H. Dixon, P. A. Rosen

School of Geosciences Faculty and Staff Publications

We use seismic and geodetic data both jointly and separately to constrain coseismic slip from the 12 November 1996 M_w 7.7 and 23 June 2001 M_w 8.5 southern Peru subduction zone earthquakes, as well as two large aftershocks following the 2001 earthquake on 26 June and 7 July 2001. We use all available data in our inversions: GPS, interferometric synthetic aperture radar (InSAR) from the ERS-1, ERS-2, JERS, and RADARSAT-1 satellites, and seismic data from teleseismic and strong motion stations. Our two-dimensional slip models derived from only teleseismic body waves from South American subduction zone earthquakes with M …

High Crystallinity Si-Ferrihydrite: An Insight Into Its Neel Temperature And Size Dependence Of Magnetic Properties, Thelma S. Berquo, Subir K. Banerjee, Robert G. Ford, R. Lee Penn, Thomas Pichler

Geology Faculty Publications

Ferrihydrite, an antiferromagnetic iron oxyhydroxide with resulting magnetization due to uncompensated spins, is of great importance for the cycling of many trace metals in the environment. Four ferrihydrite samples prepared with 1.3 to 3.5 wt% of Si at different synthesis temperatures (7.5°C, 22°C, 50°C, and 75°C) were studied by temperature-dependent hysteresis loops, ZFC/FC susceptibility curves, ac susceptibility and Mössbauer spectroscopy. The incorporation of Si into the ferrihydrite during synthesis changed the properties of this mineral. Interestingly, seven sharp lines were observed in the X-ray diffraction pattern of the ferrihydrite samples prepared at 50°C and 75°C. In general, both XRD and …

Final Draft Seagrass Transect Monitoring And Aerial Photography In Old Tampa Bay (Task D), J. O. R. Johansson, W. M. Avery, K. B. Hennenfent, J. J. Pacowta

Reports

In 2004, the TBEP and partners were again granted funds from the PCEF to conduct additional seagrass and water quality research primarily in the Feather Sound area of the OTB study area. The overall purpose of this work was to formulate a seagrass restoration and preservation management strategy for, specifically, the NW quadrant. The BSG participated in this project, from here on called PCEF II, and performed Task D of this project named “Seagrass Transect Monitoring and Aerial Photography in OTB.” In addition to the tasks originally identified for Task D, late in the project, the BSG also applied an …

Alexander Klimchouk Oral History Interview With Dr. Bogdan Onac, January 23, 2007, A. B. Klimchuk (Interviewee), Bogdan P. Onac (Interviewer)

Environmental Sustainability Oral Histories

Bogdan Onac, Assistant Professor, Department of Geology, at the University of South Florida, interviews Professor Alexander Klimchouk, Ph.D. The interview focuses on Dr. Klimchouk's work with the Ukrainian Academy of Sciences and the Speleological Institute in the Ukraine. Dr. Klimchouk describes how, as a young man growing up in the Soviet Union, he became interested in speleology, caving, and karst science. He continues with detailed discussions of specific caves in Ukraine; the informal society of karst scientists; and the creation of an international karst network. The interview ends with a discussion of Western Ukrainian caves.

Application Of A Karst Environmental Disturbance Index In Hillsborough County., Philip Van Beynen, Nilda Feliciano, Leslie North, Kaya Van Beynen

USF St. Petersburg Campus Faculty Publications

Hillsborough County, Florida, is a karst region that is heavily urbanized, yet no study has been undertaken measuring the degree of human disturbance. Van Beynen and Townsend (2005) created a hierarchical and standardized disturbance index specifically designed for karst environments. To address the problem of determining human disturbance in the county, the above index was successfully applied and it was found that Hillsborough was highly disturbed (disturbance score of 0.69 of 1.0) because of its predominant urban and rural land use. Furthermore, the application of the index allowed for its refinement and the highlighting of environmental aspects in need of …

Light Induced Conversion Of Nitrogen Dioxide Into Nitrous Acid On Submicron Humic Acid Aerosol, K. Stemmler, M. Ndour, Yasin F. Elshorbany, J. Kleffmann, M. Ammann, B. D'Anna, C. George, B. Bohn

USF St. Petersburg Campus Faculty Publications

The interactions of aerosols consisting of humic acids with gaseous nitrogen dioxide (NO2) were investigated under different light conditions in aerosol flow tube experiments at ambient pressure and temperature. The results show that NO2 is converted on the humic acid aerosol into nitrous acid (HONO), which is released from the aerosol and can be detected in the gas phase at the reactor exit. The formation of HONO on the humic acid aerosol is strongly activated by light: In the dark, the HONO-formation was below the detection limit, but it was increasing with the intensity of the irradiation with visible light. …

Temperature Anomalies In The Lower Suwannee River And Tidal Creeks, Florida, 2005, Ellen A. Raabe, Elzbieta Bialkowska-Jelinska

School of Geosciences Student Publications

Temperature anomalies in coastal waters were detected with Thermal Infrared imagery of the Lower Suwannee River (LSR) and nearshore tidal marshes on Florida’s Gulf Coast. Imagery included 1.5-m-resolution day and night Thermal Infrared (TIR) and 0.75-m-resolution Color Infrared (CIR) imagery acquired on 2-3 March 2005. Coincident temperature readings were collected on the ground and used to calibrate the imagery. The Floridan aquifer is at or near the land surface in this area and bears a constant temperature signature of ~ 22 degrees Celsius. This consistent temperature contrasts sharply with ambient temperatures during winter and summer months. Temperature anomalies identified in …

Sedimentation Patterns In A Stabilized Migratory Inlet, Blind Pass, Florida, Ping Wang, David K. Tidwell, Tanya Beck, Nicholas C. Kraus

Geology Faculty Publications

The shoaling rate in Blind Pass entrance channel approximately equals the net southward longshore sediment transport rate. Most of the shoaling occurs along the northern side of the channel. Flow measurements and numerical modeling reveal that the ebb current is approximately twice as strong in the thalweg along the south side as compared to the rest of the channel. In contrast, the flood current is mainly uniform across the inlet and is stronger than the ebb flow over the northern portion. This flow-velocity distribution induced by a nearly 90-deg bend of the channel contributes to the shoaling pattern. Two years …

Data Report: Laboratory Testing Of Longshore Sand Transport By Waves And Currents; Morphology Change Behind Headland Structures, Mark B. Gravens, Ping Wang

Geology Faculty Publications

Data from five series of movable bed laboratory experiments are presented herein. These experiments were conducted in the Largescale Sediment Transport Facility at the U.S. Army Engineer Research and Development Center, Vicksburg, MS. The data collected from these experiments are being used to improve longshore sand transport relationships under the combined influence of waves and currents and the enhancement of predictive numerical models of beach morphology evolution, in particular, with respect to modeling of tombolo development at detached breakwates and T-groins. These data were instrumental in the development and validation of GENESIS-T (Hanson et al. 2006) an enhanced version of …

Jonas Kamlet (1914-1960) Chemist/Entrepreneur, Dean F. Martin, Barbara B. Martin

Chemistry Faculty Publications

Jonas Kamlet, Ph.D., as a chemist, inventor, and a significant entrepreneur who founded Kamlet Laboratories in New York City that became the model of a successful consulting firm. Among his hundreds of patents and inventions were a tablet that could be used to measure glucose in urine, a treated strip that could detect pregnancy, a fodder for ruminants that used newsprint, and biuret (a self-condensation product of urea) that could be used as a non-protein component of fodder. Following his death in an airplane collision on December 16, 1960, his wife and collaborator (and later a resident of Florida) carried …

Petrographic And Geochemical Study On Cave Pearls From Kanaan Cave (Lebanon), Fadi H. Nader

International Journal of Speleology

The Kanaan cave is situated at the coastal zone, north of Beirut City (capital of Lebanon). The cave is located within the upper part of the Jurassic Kesrouane Formation (Liassic to Oxfordian) which consists mainly of micritic limestone. Twenty seven cave pearls were subjected to petrographic (conventional and scanning electron microscopy) and geochemical analyses (major/trace elements and stable isotopes). The cave pearls were found in an agitated splash-pool with low mud content. They are believed to have formed through chemical precipitation of calcite in water over-saturated with calcium. The nucleus and micritic laminae show δ¹⁸O_V-PDB values of …

Kinematics Of The Nicaraguan Forearc From Gps Geodesy, Henry L. Turner, Peter Lafemina, Armando Saballos, Glen S. Mattioli, Pamela E. Jansma, Timothy H. Dixon

School of Geosciences Faculty and Staff Publications

Campaign GPS data from a network in the Nicaraguan forearc show a strong component of arc-parallel motion indicating northwest translation of a nearly rigid forearc sliver. Our measured mean velocity for forearc sites of 15.1 mm yr⁻¹ agrees well with the arc-parallel sliver motion predicted previously by DeMets (2001) derived from closure constraints on oblique convergence between the Cocos and Caribbean plates. The lack of a northeasterly oriented arc-normal component of motion in forearc velocities indicates that there are complexities involved beyond a simple interpretation of sliver motion being driven by oblique convergence. The forearc is reasonably well-fit by …

Observation Of Glacial Isostatic Adjustment In “Stable” North America With Gps, Giovanni F. Sella, Seth Stein, Timothy H. Dixon, Michael Craymer, Thomas S. James, Stephane Mazzotti, Roy K. Dokka

School of Geosciences Faculty and Staff Publications

Motions of three hundred and sixty Global Positioning System (GPS) sites in Canada and the United States yield a detailed image of the vertical and horizontal velocity fields within the nominally stable interior of the North American plate. By far the strongest signal is the effect of glacial isostatic adjustment (GIA) due to ice mass unloading during deglaciation. Vertical velocities show present-day uplift (∼10 mm/yr) near Hudson Bay, the site of thickest ice at the last glacial maximum. The uplift rates generally decrease with distance from Hudson Bay and change to subsidence (1–2 mm/yr) south of the Great Lakes. The …

Climatic Differences And Similarities Between Indian And East Asian Monsoon Regions Of China Over The Last Millennium: A Perspective Based Mainly On Stalagmite Records, Ming Tan

International Journal of Speleology

Cave sediments, especially stalagmites, have been providing absolute dated climate records that can extend from the present to over 500,000 years ago. Based on the reconstructed temperature time series, a comprehensive overview of the climatic differences and similarities between the Indian and the East Asian Monsoon regions of China over the last millennium is presented. Evidence from accurately dated and high-resolution records including stalagmites, ice cores and tree rings show that there was a “Medieval Warm Period” (around 1000 to 1400 AD) in north and east China where climate is dominated by the East Asian monsoon; whilst no such interval …

The Impact Of Host Rock Geochemistry On Bacterial Community Structure In Oligotrophic Cave Environments, Hazel A. Barton, Nicholas M. Taylor, Michael P. Kreate, Austin C. Springer, Stuart A. Oehrle, Janet L. Bertog

International Journal of Speleology

Despite extremely starved conditions, caves contain surprisingly diverse microbial communities. Our research is geared toward understanding what ecosystems drivers are responsible for this high diversity. To asses the effect of rock fabric and mineralogy, we carried out a comparative geomicrobiology study within Carlsbad Cavern, New Mexico, USA. Samples were collected from two different geologic locations within the cave: WF1 in the Massive Member of the Capitan Formation and sF88 in the calcareous siltstones of the Yates Formation. We examined the organic content at each location using liquid chromatography mass spectroscopy and analyzed microbial community structure using molecular phylogenetic analyses. In …

The Polygenetic Caves Of Cuatro Ciénegas (Coahuila, Mexico): Morphology And Speleogenesis, Leonardo Piccini, Paolo Forti, Italo Giulivo, Marco Mecchia

International Journal of Speleology

The Cuatro Ciénegas area is renown worldwide for its thermal springs, which feed a unique ecosystem consisting of many pools, lakes and marshes. The pools also represent a very important water resource in a region characterized by scarce rainfalls. Field investigation has emphasized the role of karst in the hydrogeology of the area. Only few and restricted forms of surface karst are represented; caves are mainly relics of old speleogenetic phases of thermal and bathyphreatic water flow.

Acadian Biospeleology: Composition And Ecology Of Cave Fauna Of Nova Scotia And Southern New Brunswick, Canada, Max Moseley

International Journal of Speleology

The vertebrate and invertebrate fauna, environment and habitats of caves and disused mines in Nova Scotia and southern New Brunswick are provisionally catalogued and described, based on field collections made over many years. The area was glaciated and the subterranean fauna consists of non-troglobites all of which have arrived and colonised the caves during or following final recession of the Pleistocene glaciers. The statistical composition of the fauna at the higher taxonomic level is similar to that in Ontario, but is less species rich and there are some notable ecological and other differences. Porcupine dung accumulations are an important habitat …

Bomb-Spike Dating Of A Mummified Baboon In Ludwig Cave, Namibia, Greg Hodgins, George A. Brook, Eugene Marais

International Journal of Speleology

In 1982 a mummified adult female baboon was discovered on a ledge in Ludwig Cave in Namibia. A toe bone was removed for dating in July 1995. AMS radiocarbon dating of bone collagen, tendon, and skin indicates a post-modern age. Application of the atomic bomb-spike calibration curve suggests death in late 1977 and an age at death of around 19 years. Baboons roost in the cave and the mummified female, along with a mummified juvenile male discovered in 2002 and three rotting corpses discovered in 1995, were probably chased by other baboons or by leopards down a ca. 6 m …

Eogenetic Karst, Glacioeustatic Cave Pools And Anchialine Environments On Mallorca Island: A Discussion Of Coastal Speleogenesis, Angel Ginés, Joaquín Ginés

International Journal of Speleology

Coastal karst is characterized by special geomorphologic and hydrodynamic conditions as well as by peculiar sedimentary, geochemical, and biospeleological environments. Generally, the more distinctive karstic features produced near the coastline are strongly influenced by sea-level changes, which generate a broad set of interactions between littoral processes and karst development. The glacioeustatic rises and falls of sea level affected the littoral karst in different ways, namely: vertical and horizontal shifts in the shoreline position, changes in elevation of the local water table, and vertical displacements of the halocline. Most eogenetic karsts have been subjected over long time spans to repeated changes …

Speleothems As Indicators Of Wet And Dry Periods, Ian John Fairchild, Emily Anne Mcmillan

International Journal of Speleology

Calcareous speleothems provide a record of dripwater composition which in turn is a function of climatic conditions. The historical focus of speleothem palaeoclimate studies has been on the derivation of palaeotemperatures through oxygen isotope studies. However, it is now realized that water availability is a more generally important control on their characteristics. Growth rate and growth morphology in principle should give rise to recognizable changes at low flow. However, accidental plumbing effects during aquifer evolution, can also lead to variations in water supply and it is not easy to distinguish these effects. In areas where there is a strong amount …

Sails: A New Gypsum Speleothem From Naica, Chihuahua, Mexico, Tullio Bernabei, Paolo Forti, Roberto Villasuso

International Journal of Speleology

The caves of Naica (Chihuahua, Mexico) are perhaps the most famous mine caves of the world due to the presence of gigantic gypsum crystals. Nevertheless, very little research has been carried out on this karst area until now. A multidisciplinary investigation started in 2006 with the aim not only to define the genesis and the age of the Naica gypsum crystals, but also on other scientific aspects of these caves. This paper describes a completely new type of gypsum speleothem: the “sails”, observed only inside the Cueva de las Velas, one of the caves of the Naica system. This speleothem …

Seasonal Variations Of Co2 And 222Rn In A Mediterranean Sinkhole - Spring (Causse D’Aumelas, Se France), Christelle Batiot-Guilhe, Jean-Luc Seidel, Hervé Jourde, Olivier Hébrard, Vincent Bailly-Comte

International Journal of Speleology

Carbon dioxide and ²²²Rn monitoring of the atmosphere of a Mediterranean sink hole - spring (SE France) during two hydrological cycles (from September 2004 to September 2006) showed seasonal variations with very high concentrations during summer (greater than 6% and 20 000 Bq/m³, respectively). Gas dynamics in caves often show seasonal variations. Meteorological parameters (barometric pressure and temperature mainly), cave geometry and fracture networks control exchanges between the cavity and outside atmosphere. Carbon dioxide and ²²²Rn may have different sources (atmosphere, soil, bedrock, deep gas diffusion, in situ oxidation of organic matter and, in some caves, …

A Taxonomic Survey Of Lamp Flora (Algae And Cyanobacteria) In Electrically Lit Passages Within Mammoth Cave National Park, Kentucky, Thomas Smith, Rick Olson

International Journal of Speleology

A taxonomic survey of the lamp flora from electrically lit passages in Mammoth Cave, Mammoth Cave National Park, identified 28 species. Overall, cyanobacteria were dominant represented by 14 species (50% of the total), green algae had eight species (29%), and six diatoms species (21%) were present. There was not a correlation between species diversity and temperature, but there is a general trend of increasing diversity with warmer temperatures. There were two algal or cyanobacterial species identified in this study that overlapped with previous studies. There is a lack of continuity between previous studies only having one species identified in more …

Tectonic Control Of Subsidence And Southward Displacement Of Southeast Louisiana With Respect To Stable North America, Roy K. Dokka, Giovanni F. Sella, Timothy H. Dixon

School of Geosciences Faculty and Staff Publications

GPS data collected between 1995 and 2006 suggest that southeast Louisiana, including New Orleans and the larger Mississippi Delta, are both subsiding vertically and moving southward with respect to stable North America. Both motions are likely related due to their common tectonic setting. Subsidence in the New Orleans area occurs in part because it is located in the hanging wall of a large listric normal fault system that forms the northern boundary of a 7–10 km thick allochthon that is detached from stable North America. Southward motion of this allochthon relative to stable North America occurs at 2.2 ± 0.6 …

Data Summary From The Tampa Bay Interagency Seagrass Monitoring Program Through Year 2005, Walt Avery, Roger Johansson

Reports

Results regarding seagrass species abundance, distribution, and zonation over time are presented for the 1997-2005 period in Hillsborough Bay (HB, Figures 17-27) and the 1998-2005 period for Old Tampa Bay (OTB, Figures 3-14), Middle Tampa Bay (MTB, Figures 29-41), Lower Tampa Bay, including Terra Ceia Bay (LTB, Figures 43-57), and Boca Ciega Bay (BCB, Figures 59-69). For each transect, results are presented in a graphic format illustrating annual species composition, abundance, and distribution. Seagrass abundance is presented as percent coverage within a square meter using the Braun Blanquet coverage class system.

Sinkhole Structure Imaging In Covered Karst Terrain, Sarah E. Kruse, M. Grasmueck, Matthew Weiss, D. Viggiano

Geology Faculty Publications

Ground penetrating radar (GPR) and resistivity techniques have been widely used to map the locations of sinkholes in covered karst terrain. To determine whether a sinkhole is a likely preferential conduit for groundwater flow, however, requires higher-resolution imaging than that used in conventional sinkhole mapping surveys. Field observations combined with simulated surveys for a 15-m diameter 3-m deep sinkhole in west-central Florida are used to assess the resolution of GPR and resistivity surveys targeting the semiconfining unit that floors the sinkhole depression. 2D resistivity surveys clearly show the central depression as well as resistivity contrasts between the cover sediments within …