Open Access. Powered by Scholars. Published by Universities.®
Physical Sciences and Mathematics Commons™
Open Access. Powered by Scholars. Published by Universities.®
- Discipline
- Keyword
-
- Turkey (105)
- 1 (99)
- 2 (82)
- Classification (70)
- Optimization (65)
-
- Deep learning (61)
- Genetic algorithm (61)
- Machine learning (61)
- Synthesis (61)
- Adsorption (53)
- Particle swarm optimization (51)
- Antimicrobial activity (47)
- Geochemistry (47)
- 3 (44)
- Stability (39)
- Artificial neural network (37)
- Phthalocyanine (35)
- Support vector machine (34)
- Feature extraction (32)
- Wireless sensor networks (31)
- Antibacterial activity (29)
- Artificial neural networks (28)
- Feature selection (28)
- Copper (27)
- Cytotoxicity (27)
- Power quality (27)
- Fuzzy logic (26)
- Molecular docking (26)
- Palladium (26)
- Preconcentration (26)
- Publication Year
Articles 151 - 180 of 10311
Full-Text Articles in Physical Sciences and Mathematics
Differentially Private Online Bayesian Estimation With Adaptive Truncation, Sinan Yildirim
Differentially Private Online Bayesian Estimation With Adaptive Truncation, Sinan Yildirim
Turkish Journal of Electrical Engineering and Computer Sciences
In this paper, a novel online and adaptive truncation method is proposed for differentially private Bayesian online estimation of a static parameter regarding a population. A local differential privacy setting is assumed where sensitive information from individuals is collected on an individual level and sequentially. The inferential aim is to estimate, on the fly, a static parameter regarding the population to which those individuals belong. We propose sequential Monte Carlo to perform online Bayesian estimation. When individuals provide sensitive information in response to a query, it is necessary to corrupt it with privacy-preserving noise to ensure the privacy of those …
Extremal Functions For A Singular Super-Critical Trudinger-Moser Inequality, Juan Zhao
Extremal Functions For A Singular Super-Critical Trudinger-Moser Inequality, Juan Zhao
Turkish Journal of Mathematics
In this paper, we deal with a singular super-critical Trudinger-Moser inequality on a unit ball of Rn , n ≥ 3. For any p > 1, we set λp(B) = inf u∈W1,n 0 (B),u̸≡0 ∫ B |∇u|ndx ( ∫ B |u|pdx)n/p as an eigenvalue related to the n-Laplacian. Let S be a set of radially symmetric functions. Precisely, if β ≥ 0 and α < (1 + p nβ)n−1+n/pλp(B) , then there exists a positive constant ϵ0 such that when λ ≤ 1 + ϵ0 , sup u∈W1,n 0 (B)∩S, ∫ B |∇u|ndx−α( ∫ B |u|p|x|pβdx) np ≤1 ∫ B |x|pβ ( eαn(1+ p n β)|u| n n−1 − λ Σm k=0 |αn(1 + p nβ)u n n−1 |k k! ) dx is attained, where αn = nω1/(n−1) n−1 , ωn−1 is the surface area of the unit ball in Rn . The proof is based on the method of blow-up analysis. The case λ = 0 was studied by Yang-Zhu in [38]. de Figueiredo [11] considered the case p = 2, β ≥ 0, and α = 0 in two dimension. The case λ = 0, p = n,−1 < β < 0, and α = 0 was considered by Adimurthi-Sandeep [1]. Our results extend those of the above cases.
On The Invariance Of Hyperstoneanness Under Lattice Isomorphisms, Banu Güntürk
On The Invariance Of Hyperstoneanness Under Lattice Isomorphisms, Banu Güntürk
Turkish Journal of Mathematics
Let X and Y be compact Hausdorff spaces with Y hyperstonean. In this paper, we prove that if C(X,R) and C(Y,R) are lattice isomorphic then these Banach spaces are linearly isometric, and, consequently, X and Y are homeomorphic, which in turn implies that X is also hyperstonean. Actually, we prove more than what is announced in the headline above. This result, in some ways, is a generalization of the well-known Banach-Stone theorem.
Invariant Symplectic Forms On Number Fields, Ahmad Rafiqi, Ayberk Zeyti̇n
Invariant Symplectic Forms On Number Fields, Ahmad Rafiqi, Ayberk Zeyti̇n
Turkish Journal of Mathematics
We show that a number field of the form Q(λ) admits a symplectic form which is invariant under multiplication by λ if and only if the minimal polynomial of λ is palindromic of even degree. In particular, if λ is an algebraic integer, it is forced to be a unit. In the case when the minimal polynomial of λ is palindromic of degree 2d, we show that there is a d-dimensional space of invariant symplectic forms on Q(λ) .
Globally Generated Vector Bundles On The Del Pezzo Threefold Of Degree 6 With Picard Number 2, Takuya Nemoto
Globally Generated Vector Bundles On The Del Pezzo Threefold Of Degree 6 With Picard Number 2, Takuya Nemoto
Turkish Journal of Mathematics
We classify globally generated vector bundles on a general hyperplane section of P2 × P2 embedded by the Segre embedding, considering small first Chern classes c1 = (1, 1) and c1 = (2, 1).
On Strong Solvability Of One Nonlocal Boundary Value Problem For Laplace Equation In Rectangle, Telman Gasymov, Baharchin Akhmadli, Ümi̇t Ildiz
On Strong Solvability Of One Nonlocal Boundary Value Problem For Laplace Equation In Rectangle, Telman Gasymov, Baharchin Akhmadli, Ümi̇t Ildiz
Turkish Journal of Mathematics
One nonlocal boundary value problem for the Laplace equation in a bounded domain is considered in this work. The concept of a strong solution to this problem is introduced. The correct solvability of this problem in the Sobolev spaces generated by the weighted mixed norm is proved by the Fourier method. In a classic statement, this problem has been
On The Qualitative Analysis Of Nonlinear Q-Fractional Delay Descriptor Systems, Abdullah Yi̇ği̇t
On The Qualitative Analysis Of Nonlinear Q-Fractional Delay Descriptor Systems, Abdullah Yi̇ği̇t
Turkish Journal of Mathematics
In this manuscript, we obtain some sufficient conditions for a nonlinear q fractional integro singular system with constant delays to be asymptotically admissible and a nonlinear q fractional non-singular system to be asymptotically stable. We use Lyapunov-Krasovskii functionals and some inequalities to obtain these conditions. At the same time, we present some numerical examples that confirm the sufficient conditions we obtained theoretically, with their annotated solutions and graphs.
Some Estimates On The Spin−Submanifolds, Serhan Eker
Some Estimates On The Spin−Submanifolds, Serhan Eker
Turkish Journal of Mathematics
In this paper, an optimal lower bound is given for the Submanifold Dirac operator in terms of the trace of an Energy−Momentum tensor, scalar curvature and mean curvature. In the equality case, it is proven that the submanifold is Einstein if the normal bundle is flat. Key words: Spin geometry, eigenvalues,
On Lyapunov-Type Inequalities For Five Different Types Of Higher Order Boundary Value Problems, Mustafa Fahri̇ Aktaş, Bariş Berkay Erçikti
On Lyapunov-Type Inequalities For Five Different Types Of Higher Order Boundary Value Problems, Mustafa Fahri̇ Aktaş, Bariş Berkay Erçikti
Turkish Journal of Mathematics
In this paper, we establish the uniqueness and existence of the classical solution to higher-order boundary value problems. Then, we give a new Lyapunov-type inequalities for higher order boundary value problems. Our study is based on Green’s functions corresponding to the five different types of two-point boundary value problems. In addition, some applications of the obtained inequalities are given.
Genesis Of Efficient Reservoirs In Mixed Sedimentary Setting: A Case Study Of Benxi Formation In The Gaoqiao Area, Ordos Basin, Shu Liu, Jinbu Li, Fengbo Jin, Haifeng Liu, Meng Wang, Yulin Cheng, Yulin Cheng, Xiaohong Zhong, Hao Lu
Genesis Of Efficient Reservoirs In Mixed Sedimentary Setting: A Case Study Of Benxi Formation In The Gaoqiao Area, Ordos Basin, Shu Liu, Jinbu Li, Fengbo Jin, Haifeng Liu, Meng Wang, Yulin Cheng, Yulin Cheng, Xiaohong Zhong, Hao Lu
Turkish Journal of Earth Sciences
The Benxi-Taiyuan Formation in the southern region of the Ordos Basin represents a typical mixed sedimentary system, which has witnessed recent breakthroughs in the exploration of tight sandstone gas within the Benxi Formation. However, the development patterns of reservoirs in this mixed sedimentary area remain unclear, influenced by the sedimentary model and the distribution scale of sedimentary sandstone bodies. This study investigates the paleogeomorphology, sedimentary model, sandstone body type, petrological characteristics, and pore structure of the Benxi Formation. Field profiles, drilling core observations, microscopic section analysis, scanning electron microscopy (SEM), high-pressure mercury injection (HPMI), and physical property analysis are employed. …
An Experimental Investigation On The Discrete Poisson’S Upward Continuation Of Anomalous Gravity Field Data, Mehmet Si̇mav, Bi̇hter Erol, Muhammet Aki̇f Gülender, Serdar Erol
An Experimental Investigation On The Discrete Poisson’S Upward Continuation Of Anomalous Gravity Field Data, Mehmet Si̇mav, Bi̇hter Erol, Muhammet Aki̇f Gülender, Serdar Erol
Turkish Journal of Earth Sciences
The Poisson upward continuation of gravity field functionals, typically given on the Earth’s irregular topography with limited spatial extent, necessitates some proper treatments due to the theoretical requirements. This study reviews the Poisson theory and investigates a more rigorous methodology for the numerical solution of the spherical integral equation by addressing many issues such as spherical-Earth model implementation, far-zone effect, Poisson kernel modification, and suitable ground data reduction scheme. We first explore the far-zone effect and search for an optimal near-zone spherical cap radius above which the truncation error is negligible. We then compare different variants of remove-restore technique with …
Microfacies, Geometry And Growth Phases Of Microbial Mound In Gucheng Area, Southeastern Tarim Basin, China, Xu Chen, Iftikhar Satti, Yuwen Dong
Microfacies, Geometry And Growth Phases Of Microbial Mound In Gucheng Area, Southeastern Tarim Basin, China, Xu Chen, Iftikhar Satti, Yuwen Dong
Turkish Journal of Earth Sciences
Microbial mound is favorable carbonate reservoir for petroleum exploration, especially for the deep tight reservoirs in the Tarim petroliferous basin. Due to lack of effective research methods, it is difficult to analyze its unique sedimentary structure and evolution process. In this study, based on cores, thin-sections, logging, 3D seismic data and geochemical test data, the petrographic texture, microfacies, geometry and growth phases of microbial mound in Gucheng area, Southeastern Tarim Basin were investigated, which can be used to reconstruct dynamic evolution of the microbial mounds and discuss the controlling factors. The major results are as follows: (1) Gucheng area is …
Mineralogical And Geochemical Characteristics Of The Upper Cretaceous And Lower Paleocene Parts Of The Germav Formation: Southeastern Türkiye, Sema Teti̇ker
Turkish Journal of Earth Sciences
The mineralogical and chemical characteristics of Upper Cretaceous-Lower Paleocene claystone sediment samples taken from Mardin and Batman, located in southeastern Türkiye, were analyzed in the present study. The clay mineral paragenesis in the Upper Cretaceous units consisted of chlorite-smectite (C-S) and illite, whereas the Lower Paleocene unit consisted of chlorite-vermiculite (CV) and vermiculite minerals. Analyses conducted on clay samples indicated high levels of Al, Mg, Fe, Cr, V, Ni, and Zr. Low levels of alkali and alkaline earth elements (Mg, Na, Ca, K) in the clay-rich sediments suggest relatively high-grade weathering in the source area. The mineralogical compositions, major elemental …
Dinsar Analysis And Geophysical Modeling Of 2022 November 23 Gölyaka-Düzce Earthquake, Şükrü Onur Karaca, Gülteki̇n Erten, Batuğhan Yikmaz, Seli̇m Özalp
Dinsar Analysis And Geophysical Modeling Of 2022 November 23 Gölyaka-Düzce Earthquake, Şükrü Onur Karaca, Gülteki̇n Erten, Batuğhan Yikmaz, Seli̇m Özalp
Turkish Journal of Earth Sciences
Numerous significant earthquakes have occurred along the North Anatolian Fault Zone (NAFZ), Türkiye’s most important fault zone. An earthquake with magnitude of Mw 6.0 occurred near the Gölyaka District of Düzce Province at 04:08 local time on November 23, 2022. According to the moment tensor solutions published by national and international seismology centers, the earthquake occurred at the northeast end of the Karadere segment within the NAFZ and was caused by a right-lateral strike-slip fault in the NW-SE direction. In this study, the differential interferometric synthetic aperture radar (InSAR) method was employed to analyze the deformation. Four Sentinel-1A complex datasets …
Evaluating The Neotectonic Activities Of The Eastern Makran At The Northern Edge Of The Triple Junction In Southwest Pakistan, Waseem Khan, Ke Zhang, Hao Liang
Evaluating The Neotectonic Activities Of The Eastern Makran At The Northern Edge Of The Triple Junction In Southwest Pakistan, Waseem Khan, Ke Zhang, Hao Liang
Turkish Journal of Earth Sciences
A number of five GIS-based indices, such as stream slope (Ss), surface roughness (Sr), asymmetric factor (Af), hypsometry integral (Hi), and stream-length gradient (SL), were summarised to examine the intensity of the index of tectonic activity (IAT) in 43 subbasins of Hingol Basin at the northern edge of the triple junction in southwest Pakistan. In addition, tectonic influences were identified by knickpoints spatial distribution and field surveys. The majority of the indices are consistent and display roughly the same classifications. The uncertain results have a less substantial impact on the obtained results in most of the 43 subbasins. Using these …
Landslide Susceptibility Assessment Of The Asi Watershed, Southern Türkiye, Senem Teki̇n, Adolfo Quesada Román, Tolga Çan
Landslide Susceptibility Assessment Of The Asi Watershed, Southern Türkiye, Senem Teki̇n, Adolfo Quesada Román, Tolga Çan
Turkish Journal of Earth Sciences
Landslides constitute recurrent natural hazards worldwide with greater socioeconomic impacts in low-income places. Landslide susceptibility studies are carried out to determine the potential for landslides to occur in a region, to predict possible risks in the future and to integrate this information into sustainable planning and management strategies. Slip-type landslides occur in limited areas of less than 1% of the Asi watershed in Southern Türkiye. Therefore, meaningful estimations cannot be made with classical statistical models. So, using the maximum entropy approach (MaxEnt), a technique for estimating based on a small number of observations, a landslide susceptibility assessment was constructed. The …
Investigation Of Earthquake Sequence And Stress Transfer In The Eastern Anatolia Fault Zone By Coulomb Stress Analysis, Hamdi̇ Alkan, Aydin Büyüksaraç, Özcan Bektaş
Investigation Of Earthquake Sequence And Stress Transfer In The Eastern Anatolia Fault Zone By Coulomb Stress Analysis, Hamdi̇ Alkan, Aydin Büyüksaraç, Özcan Bektaş
Turkish Journal of Earth Sciences
A devastating earthquake with a magnitude of (Mw = 7.7) occurred on February 06, 2023, in the Pazarcık segment of the Eastern Anatolian Fault Zone, which has not shown major earthquake activity for a long time. On the same day, another earthquake with a magnitude of (Mw = 7.6) occurred in Ekinözü-Elbistan (Kahramanmaraş) in the northwest. Three more earthquakes with magnitudes of Mw = 6.6, Mw = 5.9, and ML = 5.7 occurred on the same day, and significant damage, loss of life, and property occurred in 11 provinces and districts. A sixth earthquake occurred with Mw = 6.4 magnitude …
Preliminary Results Of The Great Kahramanmaraş 6 February 2023 Earthquakes (Mw 7.7 And 7.6) And 20 February 2023 Antakya Earthquake (Mw 6.4), Eastern Türkiye, Şule Gürboğa, Önder Kayadi̇bi̇, Hafi̇ze Akilli, Serap Arikan, Sevi̇lay Tan
Preliminary Results Of The Great Kahramanmaraş 6 February 2023 Earthquakes (Mw 7.7 And 7.6) And 20 February 2023 Antakya Earthquake (Mw 6.4), Eastern Türkiye, Şule Gürboğa, Önder Kayadi̇bi̇, Hafi̇ze Akilli, Serap Arikan, Sevi̇lay Tan
Turkish Journal of Earth Sciences
The first MW 7.7 and second MW 7.6 Kahramanmaraş earthquakes were the strongest tectonic events in Eastern Türkiye since the MW 7.9 Erzincan earthquake in 1939. The first and second events occurred on the Pazarcık and Çardak segments of the East Anatolian Fault System, respectively. A subsequent significant earthquake of MW 6.4 occurred in the Antakya fault zone. We summarize preliminary earthquake data and share our previous field observations to better understand the mechanism and provide scientific consequences for future investigations and layout planning. After combining the field observations, kinematic analysis of fault surfaces, investigations of orthophotos, characteristics of mainshocks, …
Surface Rupture During The 6th Of February 2023 Mw 7.6 Elbistan-Ekinözü (Kahramanmaraş) Earthquake: Implications For Fault Rupture Dynamics Along The Northern Branch Of East Anatolian Fault Zone, Mustafa Softa, Fi̇kret Koçbulut, Eli̇f Akgün, Ercan Aksoy, Hasan Sözbi̇li̇r, Orhan Tatar, Volkan Karabacak, Çağlar Özkaymak, Mehmet Utku, Özkan Cevdet Özdağ, Recep Çakir, Ahmet Demi̇r, Gökhan Arslan
Surface Rupture During The 6th Of February 2023 Mw 7.6 Elbistan-Ekinözü (Kahramanmaraş) Earthquake: Implications For Fault Rupture Dynamics Along The Northern Branch Of East Anatolian Fault Zone, Mustafa Softa, Fi̇kret Koçbulut, Eli̇f Akgün, Ercan Aksoy, Hasan Sözbi̇li̇r, Orhan Tatar, Volkan Karabacak, Çağlar Özkaymak, Mehmet Utku, Özkan Cevdet Özdağ, Recep Çakir, Ahmet Demi̇r, Gökhan Arslan
Turkish Journal of Earth Sciences
On the 6th of February 2023, Mw 7.7 Pazarcık (Kahramanmaraş) and Mw 7.6 Ekinözü (Kahramanmaraş) earthquakes that occurred in Türkiye are devastating earthquake series that filled the existing seismic gaps on East Anatolian Fault Zone on the same day. The first Mw 7.7 earthquake caught most people in their sleep and 9 h later, a second one was triggered, ending up with more than 50k death toll, widespread damage to buildings, and massive landslides. This study presents the surface rupture geometry and coseismic displacement characteristics determined with field observations immediately after February 6, 2023, Ekinözü (Kahramanmaraş, Türkiye) earthquake (Mw 7.6). …
Response Of Water Resources To The Kahramanmaraş Earthquakes (Mw 7.7 And Mw 7.6) That Occurred On February 6, 2023, On The East Anatolian Fault Zone (Türkiye), Celaletti̇n Şi̇mşek, Görkem Akinci, Okan Fistikoğlu, Kerem Canli, Hasan Sözbi̇li̇r, Azi̇ze Ayol, Efem Bi̇lgi̇ç
Response Of Water Resources To The Kahramanmaraş Earthquakes (Mw 7.7 And Mw 7.6) That Occurred On February 6, 2023, On The East Anatolian Fault Zone (Türkiye), Celaletti̇n Şi̇mşek, Görkem Akinci, Okan Fistikoğlu, Kerem Canli, Hasan Sözbi̇li̇r, Azi̇ze Ayol, Efem Bi̇lgi̇ç
Turkish Journal of Earth Sciences
On February 6, 2023, two destructive earthquakes of 7.7 MW and 7.6 MW occurred in Pazarcık (Kahramanmaraş) and Elbistan (Kahramanmaraş) at 04:17 and 13:24 hours, respectively. These earthquakes caused a surface rupture with a total length of 450 km in the region with an average displacement of 3 m between the Arabian and Anatolian plates. This study was conducted to investigate the physical deformation of the aquifer system and the current water quality characteristics in the affected region utilizing field observations and on-site analysis of water sources and tap water. The study revealed significant physical changes in the karstic springs …
Tepehan Rockslide: A Large-Scale Earthquake-Induced Geological Structure Formed By Mw:7.8 Kahramanmaraş (Pazarcık) Earthquake, Türkiye, Ökmen Sümer
Turkish Journal of Earth Sciences
Three devastating and powerful earthquakes hit the southeastern and eastern parts of Turkey and the northestern part of Syria in February of 2023, causing many earthquake-induced slope movements. One of these major mass movements is called the “Tepehan Rockslide”, which was formed by the first Mw: 7.8 earthquake on February 6th, 2023 at Pazarcık (Kahramanmaraş) located in the Altınözü district of Hatay province. The rockslide involved the movement of Middle Miocene basement rocks that consist of clayey limestone, marl, and fine-grained clastic sedimentary rocks. The morphogenetic evaluation of the structure reveals that the Tepehan Rockslide is a very rapidly developed …
Soil Liquefaction And Subsidence Disaster In İskenderun Related To The 6 February 2023 Pazarcık (Mw: 7.7) And 20 February Defne (Mw: 6.4) Earthquakes, Türkiye, Hüseyi̇n Öztürk, Craig A. Davis, İbrahi̇m Kuşku, Süleyman Dalğiç, Cem Kasapçi, Muharrem Alper Şengül
Soil Liquefaction And Subsidence Disaster In İskenderun Related To The 6 February 2023 Pazarcık (Mw: 7.7) And 20 February Defne (Mw: 6.4) Earthquakes, Türkiye, Hüseyi̇n Öztürk, Craig A. Davis, İbrahi̇m Kuşku, Süleyman Dalğiç, Cem Kasapçi, Muharrem Alper Şengül
Turkish Journal of Earth Sciences
The Mw 7.7 Pazarcık earthquake on February 06, 2023, struck southern Türkiye, causing typical liquefaction along the shores of İskenderun Bay. This liquefaction was characterized by lateral spreading, subsidence, and flooding. Subsidence-triggered sand ejecta, water flows, and opening cracks were identified in areas spanning approximately 2 km in length and 300 m in width. Based on coastal references such as lighthouses or harbor platforms, settlements of 0.8 m and lateral spreading of 0.4% were recorded along the coastal zone following the Pazarcık earthquake. According to camera recordings, liquefaction-related water and silty sand outflows occurred 29 min after the earthquake. The …
Lithography-Free Highly Sensitive Detection Of Glucose Based On Colloidal Spheres, Habibe Durmaz
Lithography-Free Highly Sensitive Detection Of Glucose Based On Colloidal Spheres, Habibe Durmaz
Turkish Journal of Physics
Diabetes has emerged as a global health crisis, with a substantial increase in prevalence and associated healthcare costs. The urgency for early diagnosis to prevent complications has fueled research into advanced biosensing technologies. Plasmonic sensors, leveraging localized surface plasmon resonance (LSPR), have gained prominence for their sensitivity. This study explores a metamaterial-based sensor platform comprising nanospheres fabricated through colloidal lithography. A comprehensive numerical and experimental analysis of the designed metamaterial-based perfect absorber is presented, focusing on the spectral response at the resonance frequency of 525 nm. Finite-difference time-domain (FDTD) simulations reveal the field and charge distributions, enabling a systematic exploration …
Optimum Pyrolysis Conditions To Prepare The Most Crystalline Boron Carbide Powder From Boric Acid–Mannitol Complex Ester, Abdullah Devri̇m Pekdemi̇r, Müşerref Önal, Yüksel Sarikaya
Optimum Pyrolysis Conditions To Prepare The Most Crystalline Boron Carbide Powder From Boric Acid–Mannitol Complex Ester, Abdullah Devri̇m Pekdemi̇r, Müşerref Önal, Yüksel Sarikaya
Turkish Journal of Chemistry
A weak acidic complex ester (CE) in solid form was prepared by a condensation reaction between very weak boric acid (BA: H3BO3) and (D)-mannitol (MA: C6H14O6) by the molar ratio of BA/MA = 2. A boron carbide (B4C) precursor was obtained from heating of the CE at 400 °C for 4 h. The precursor was pyrolyzed under argon flow in the interval of 1300–1550 °C for 4 h and at 1400 °C for 1–4 h, respectively. The materials were examined using several techniques such as X-ray diffraction analysis, thermal analysis, scanning electron microscopy, particle size distribution, and nitrogen adsorption/desorption. The …
Sustainable Graphitic Carbon From Biomass To Be Suitable For Technological Devices, Gökçen Akgül
Sustainable Graphitic Carbon From Biomass To Be Suitable For Technological Devices, Gökçen Akgül
Turkish Journal of Chemistry
Technological devices are mostly manufactured by conductive and semiconductive materials. As advancement in the last decades, carbon nanomaterials have been explored in electrical/electronic technology due to their unique performances for manufacturing developing, and prudential miniaturized and flexible electrical/electronic devices. In the era of sustainable and clean carbon technology; renewable, alternative, biodegradable, and eco-friendly new carbon resources are required. Biomass could be the answer to offer inspiring carbon allotropes from nature to be suitable for developing electrical/electronic devices. In this article, deriving of the technological carbonaceous material from biomass, studies although they are very limited in the literature on obtaining the …
Comparison Of Metal-Carbenoid Reactions Of Β-2-Five-Membered Heteroaryl Substituted Α,Β-Unsaturated Ketones, Kumsal Eroğlu, Olcay Anaç, Füsun Şeyma Kişkan
Comparison Of Metal-Carbenoid Reactions Of Β-2-Five-Membered Heteroaryl Substituted Α,Β-Unsaturated Ketones, Kumsal Eroğlu, Olcay Anaç, Füsun Şeyma Kişkan
Turkish Journal of Chemistry
In this study, β-2-heteroaryl substituted (N-methyl 2-pyrrolyl, 2-thiophenyl, 2-furyl) α,β-unsaturated ketones were reacted with two α-diazo carbonyl compounds that had different characteristics (dimethyl diazo malonate and 1-diazo-1-phenyl-propane-2-one) in the presence of both copper and rhodium catalysts. In the case of reactions with N-methyl 2-pyrrolyl α,β-unsaturated ketones, the major product was the insertion derivative. However, in the reactions of 2-thiophenyl and 2-furyl α,β-unsaturated ketones with dimethyl diazomalonate (acceptor-acceptor disubstituted), only dihydrofuran products were formed over carbonyl ylides. When 2-thiophenyl and 2-furyl α,β-unsaturated ketones were reacted with 1-diazo-1-phenyl-propane-2-one (donor-acceptor disubstituted), 1-phenylpropane-1,2-dione was obtained under our reaction conditions.
Synthesis And Singlet Oxygen Generation Of Boron- 2-(4,5-Dibromo-1h-Imidazole-2-Yl)-3,5-Dipyrazolopyridine Complex For Antimicrobial Photodynamic Therapy, Zeynep Ekmekçi̇, Seda Karaoğlu
Synthesis And Singlet Oxygen Generation Of Boron- 2-(4,5-Dibromo-1h-Imidazole-2-Yl)-3,5-Dipyrazolopyridine Complex For Antimicrobial Photodynamic Therapy, Zeynep Ekmekçi̇, Seda Karaoğlu
Turkish Journal of Chemistry
In this study, the pyridine side of a boron 2-(2'-pyridyl) imidazole (BOPIM) core, which has very few derivatives synthesized in the literature and can show fluorescence properties in solid form, was derivatized with 1-methylpyrazole, predicted to have activity against fungi or bacteria according to the literature. Additionally, its imidazole side was brominated to increase the efficiency of singlet oxygen production by increasing the intersystem crossing. The photophysical properties of the new synthesized BOPIM derivative were investigated in general organic solvents with different polarities. While the wavelength of the maximum absorbance was determined as 406 nm in CH2Cl2 and THF, the …
Removal Of Toxic Cr(Vi) From Aqueous Medium With Effective Magnetic Carbon-Based Nanocomposites, Ferda Ci̇van Çavuşoğlu, Gülsüm Özçeli̇k, Şahi̇ka Sena Bayazi̇t
Removal Of Toxic Cr(Vi) From Aqueous Medium With Effective Magnetic Carbon-Based Nanocomposites, Ferda Ci̇van Çavuşoğlu, Gülsüm Özçeli̇k, Şahi̇ka Sena Bayazi̇t
Turkish Journal of Chemistry
Cr(VI), which has toxic effects, is a heavy metal and it must be removed from the environment due to the various damages it causes. In this study, the removal of Cr(VI) pollutants from aqueous solutions with Fe3O4-based materials using a batch adsorption technique was investigated. Magnetically modified graphene nanoplatelet (GNP)-based nanocomposites were prepared and their structures were characterized by FTIR, XRD, SEM, BET, and TGA techniques. The effects of various physicochemical parameters such as adsorbent dose, contact time, initial Cr(VI) solution concentration, pH, and the presence of coexisting ions (NaCl) on the adsorption process were investigated. Accordingly, the optimum conditions …
Production Of Gelatin Fibrous Mats Using Different Nanofiber Production Methods For Medical Applications And Comparison Of Their Properties, Melike Güngör, Kevser Sağlamkol, Zeynep Yağmur Baydemi̇r, Ali̇ Kiliç
Production Of Gelatin Fibrous Mats Using Different Nanofiber Production Methods For Medical Applications And Comparison Of Their Properties, Melike Güngör, Kevser Sağlamkol, Zeynep Yağmur Baydemi̇r, Ali̇ Kiliç
Turkish Journal of Chemistry
In the literature, there are studies on medical applications using different nanofiber production methods with natural polymers. However, each system has different fiber-forming capabilities. For this reason, in this study, we investigated the production of nanofibers from a biodegradable natural polymer, gelatin, using four separate nanofiber production methods, namely electrospinning (ES), electroblowing (EB), solution blowing (SB), and centrifugal spinning (CS). Our aim was to determine the most suitable fibrous web structure for medical applications and contribute to science in this respect. It was observed that the thinnest fibers (386 nm) and the heaviest mats (15.975 g m–2) were produced by …