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Articles 3211 - 3240 of 3676

Full-Text Articles in Physical Sciences and Mathematics

Transport And Deposition Of Fluid Mud Event Layers Along The Western Louisiana Inner Shelf, Kristina Anne Rotondo Jan 2004

Transport And Deposition Of Fluid Mud Event Layers Along The Western Louisiana Inner Shelf, Kristina Anne Rotondo

LSU Master's Theses

The western Louisiana inner shelf along the Chenier Plain coast has experienced fluid mud deposition in response to increased fine sediment supplied by the Atchafalaya River since ~1950’s. The goal of this project is to assess the characteristics comprising the sedimentary strata and stratigraphic architecture that result from mud deposition on the inner shelf. Recent time-series cores collected from the inner shelf along the Chenier plain coast show the region is subject to transient fluid mud deposition, leading to high long-term accumulation rates. Sediment cores were collected in May 2001, March and May 2002 from the inner shelf landward of …

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Cox Regression Model, Lindsay Sarah Smith Jan 2004

Cox Regression Model, Lindsay Sarah Smith

LSU Master's Theses

Cox, in 1972, came up with the Cox Regression Model to deal handle failure time data. This work presents background information leading up to the Cox's regression model for censored survival data. The marginal and partial likelihood approaches to estimate the parameters in this model are presented in detail. The estimation techniques of the hazard and survivor functions are explained. All of these ideas are illustrated using data from the Veteran’s Administration lung cancer study.

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Validation Of Pet/Ct Dataset For Radiation Treatment Planning, Rajesh Manoharan Jan 2004

Validation Of Pet/Ct Dataset For Radiation Treatment Planning, Rajesh Manoharan

LSU Master's Theses

PET/CT scans are frequently used for radiation treatment planning (RTP). Our work demonstrates a practical approach for validating the PET/CT dataset for RTP. We tested this QA process on a Reveal HD PET/CT scanner. The phantom used is a TGM2 ISIS QA phantom, a 14 cm acrylic cube with a central bore for object inserts. It has four different built-in inserts for electron density verification. 22Na seeds are inserted into the pinholes at the side of the cube. PET/CT images of the phantom with 22Na seeds are acquired and fused in the scanner Syngo fusion software. Registration of the PET/CT …

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An Examination Of The Relationship Between Environmental Science And Law Due To Emerging Micro-Scale Gas Chromatography Technology, Alfred Ruks Politzer Jan 2004

An Examination Of The Relationship Between Environmental Science And Law Due To Emerging Micro-Scale Gas Chromatography Technology, Alfred Ruks Politzer

LSU Master's Theses

The intersection of science and law is very complex. The two disciplines frequently interact due to environmental issues. Expert testimony is most often the method used to introduce scientific data into the legal system. Advances in technology have allowed scientists to increase the preciseness and reliability of data produced. The development of the gas chromatograph and the recent microFAST gas chromatograph has greatly increased the amounts of data available to the legal system. The legal system has relatively recently developed a set of guidelines with which to evaluate scientific evidence and determine whether it should be admitted into trial. Previously …

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Regional-Scale Eutrophication Models: A Bayesian Treed Model Approach, Angelina Freeman Jan 2004

Regional-Scale Eutrophication Models: A Bayesian Treed Model Approach, Angelina Freeman

LSU Master's Theses

Utilizing Bayesian hierarchical techniques, regional-scale eutrophication models were developed for use in the Total Maximum Daily Load (TMDL) process. The Bayesian tree-based (BTREED) approach allows association of multiple environmental stressors with biological responses, and quantification of uncertainty sources in the water quality model. Simple parametric models are often inadequate for describing complex datasets; the BTREED approach partitions the dataset, and describes the localized subsets of data with linear models, thereby providing a comprehensive representation of stressor and response interactions. Nutrient criteria data for lakes, ponds and reservoirs across the United States were obtained from the Environmental Protection Agency (U.S. EPA) …

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Enhanced Flushing With Cyclodextrin For The Remediation Of Creosote Contaminated Soil, Monalisa Dutta Jan 2004

Enhanced Flushing With Cyclodextrin For The Remediation Of Creosote Contaminated Soil, Monalisa Dutta

LSU Master's Theses

Past practices of applying creosote and coal tar preservatives to wood, such as unlined pits and trenches, have resulted in contamination of the surface and ground water at thousand of sites. The low aqueous solubility, volatility and bioavailability of many these constituents limit their degradation by natural attenuation and standard remediation techniques such as ground water flushing, soil vapor extraction, and bioremediation. While research has shown that cyclodextrin solutions have the ability to enhance the solubility of some of the components of creosote, additional work is needed to evaluate its potential as a remedial agent for these sites. Equilibrium batch …

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Durability Of Pine Strandboard Modified With Low Molecular Weight Phenol Formaldehyde, Matthew Daniel Voitier Jan 2004

Durability Of Pine Strandboard Modified With Low Molecular Weight Phenol Formaldehyde, Matthew Daniel Voitier

LSU Master's Theses

A continuing challenge for wood and wood-based composite building materials has been durability--the power of resisting agents or influences which tend to cause changes, decay, or dissolution; lastingness. In the case of wood-based products, this often requires a resistance to biological degradation and moisture related dimensional instability (particularly in particle and flake or strand boards). Borden Chemical Company has developed a new low molecular weight phenol formaldehyde additive, PD-112, to improve durability in composite wood products. This study investigated PD-112’s contribution to durability in oriented strand board (OSB) through laboratory testing of treated southern pine strandboard panels versus untreated control …

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Stormwater Diversion As A Potential Coastal Wetland Restoration Method, Jennifer Howard Woods Jan 2004

Stormwater Diversion As A Potential Coastal Wetland Restoration Method, Jennifer Howard Woods

LSU Master's Theses

The Barataria-Terrebonne estuary has been eroding at a rate of up to 103.6 km2 yr-1 for several decades. If the current rate of loss is not reduced, an additional 2,550 km2 of coastal wetlands will be lost by the year 2050. Currently, stormwater in Terrebonne Parish is pumped into canals, ultimately discharging into the Gulf of Mexico. An opportunity exists to use this stormwater for wetland restoration; however, the ecological impacts of stormwater diversions on wetlands are unknown. The objectives of this project were to 1) to investigate the seed banks of a degraded marsh to determine if a viable …

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Properties Of Borate-Treated Strandboard Bonded With Pmdi Resin, Yiqiang Zhou Jan 2004

Properties Of Borate-Treated Strandboard Bonded With Pmdi Resin, Yiqiang Zhou

LSU Master's Theses

Random strandboards from mixed southern wood species were manufactured using calcium borate (CB) and zinc borate (ZB) as chemical additives and polymeric methylene diphenylmethane disocyanate (pMDI) as resin. There were four target levels of borate loading and two levels of resin content. Panel properties, including modulus of elasticity (MOE), modulus of rupture (MOR), internal bond (IB) strength, linear expansion (LE), thickness swelling (TS), leachability, and swelling and strength retention properties under cyclic relative humidity, were measured. The influence of borate content, borate type, and resin content on various properties was analyzed. It was found that the addition of borate negatively …

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Seismic Stratigraphic Investigation Of The Ukpokiti Field Channel Complex, Oml 108, Offshore Nigeria, Northwestern Niger Delta, Toby Latwan Stewart Jan 2004

Seismic Stratigraphic Investigation Of The Ukpokiti Field Channel Complex, Oml 108, Offshore Nigeria, Northwestern Niger Delta, Toby Latwan Stewart

LSU Master's Theses

Detailed seismic stratigraphic analyses and mapping show that a well defined Ukpokiti Field Channel complex (late Miocene) found on the up-thrown side of a major back-to-back fault system in the West Niger delta inner-continental shelf probably formed during a single eustatic fall. The channel (>500 msec, 10 km wide) shows several tributaries entering the trunk axis from what was probably a surface of subaerial exposure. Slumping is prominent on the north flank of the trunk channel. No channel unconformity is evident in the down-thrown block. This investigation seeks to resolve the lack of down-dip correlative seismic expression across the …

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Feeding Ecology And Morphometric Analysis Of Paddlefish, Polyodon Spathula, In The Mermentau River, Louisiana, Nicole Adele Smith Jan 2004

Feeding Ecology And Morphometric Analysis Of Paddlefish, Polyodon Spathula, In The Mermentau River, Louisiana, Nicole Adele Smith

LSU Master's Theses

Little is known about the morphometrics and the feeding ecology of paddlefish in Louisiana. I examined the morphometrics and feeding ecology of paddlefish from the Mermentau River, Louisiana from March 2002 to February 2003. Paddlefish were examined morphometrically by taking measurements of eye-fork length (EFL), body cavity length (BCL), girth (G), vent girth (VG), mouth vertical (MTB), mouth horizontal (MSS), and mouth gullet bottom (MGB) to determine which parameters would give a better estimate of weight (W). Regression analysis resulted in a morphometric model of the form: logW = 10.10 + 1.52 (logEFL) + 1.21 (logG) + 0.24 (logVG) (r2 …

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Software Architecture: Styles And Representational Schemes, Somo Subro Banerjee Jan 2004

Software Architecture: Styles And Representational Schemes, Somo Subro Banerjee

LSU Master's Theses

Software architecture is being widely used today to describe a very high-level design methodology of large software systems. Software architecture represents the overall structure of a system in an abstract, structured manner. A good architectural representation scheme holds the key to the effectiveness of a software architecture description and usage. In this work we look at architectural styles and architectural representation schemes. We propound the idea that the layered architectural model is a suitable candidate for a generalized architectural style and that it can cater to many different problem domains, other than the message-passing systems it has traditionally been used …

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Quality Assurance Testing Of The Eclox-M In Detecting Terrorism Threats In Louisiana's Public Drinking Water Systems, Jessica Coleman Jan 2004

Quality Assurance Testing Of The Eclox-M In Detecting Terrorism Threats In Louisiana's Public Drinking Water Systems, Jessica Coleman

LSU Master's Theses

A quality assurance testing of the ECLOX-M™, a rapid water quality indicator used in potential terrorist attacks, was evaluated for its adequacy in nine regional Louisiana water systems. The ECLOX-M™ system uses enhanced chemiluminescence to measure toxicity in water by integration of a mixture of luminol (C8H7O3N3), and an oxidant in the presence of a catalyst enzyme - horseradish peroxidase (HRP). Water samples were tested for chemiluminescence, chlorine content, pH, and arsenic and/or nerve agent/pesticide contamination. In addition, three toxic industrial chemical standards were evaluated (mercury, a volatile liquid mixture, and a …

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Evaluation Of Growth, Production And Cold Tolerance Of Four Varieties Of Tilapia, Patricio Enrique Paz Jan 2004

Evaluation Of Growth, Production And Cold Tolerance Of Four Varieties Of Tilapia, Patricio Enrique Paz

LSU Master's Theses

As global tilapia production grows, it is important to characterize varieties available for production and generate data on environmental tolerances. This study generated data on tolerances, adaptabilities and production characteristics of four tilapia varieties. Goals of this study were to: (1) compare growth of four tilapia varieties in two types of recirculating systems, (2) evaluate juvenile growth of seven tilapia varieties in fresh and brackishwater mesocosms, and (3) estimate cold tolerance of juveniles of four tilapia varieties in fresh and brackishwater. Nile tilapia (Oreochromis niloticus), blue tilapia (Oreochromis aureus), Mississippi commercial strain tilapia (MCS), and Florida red tilapia (FRT) were …

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The Syntheses Of Novel Indicators And Materials For Chiral Separation, Rolanda Johnson Jan 2004

The Syntheses Of Novel Indicators And Materials For Chiral Separation, Rolanda Johnson

LSU Doctoral Dissertations

The colorimetric properties of resorcinarene solutions had not been fully investigated since von Baeyer's initial synthesis. We find that the solutions containing resorcinarene macrocycles develop color upon heating or standing. In the presence of saccharides, these solutions exhibit significant color changes which are readily observable by visual inspection. We determined that the solution color is due to macrocycle ring opening and oxidation. The optical responses to saccharides are due to complexation of the sugar with the acyclic chromophores. We have applied these mechanistic insights towards the challenging problems of the visual detection of saccharides and other important biologically analytes. In …

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Investigation Of Structure-Property Relationships Of Heavy-Fermion Materials, Robin Macaluso Jan 2004

Investigation Of Structure-Property Relationships Of Heavy-Fermion Materials, Robin Macaluso

LSU Doctoral Dissertations

This work focuses on how local structural features influence large effective masses, magnetism, and superconductivity that are yet to be understood in heavy-fermion materials. Three sets of structurally-related materials are discussed in light of dimensionality, layering effects, choice of transition metal, coordination, and structural distortions: LnnMIn3n+2 (Ln = La, Ce; n = 1, 2, ‡; M = Co, Rh, Ir), CePdGa6, and Ce2PdGa12, and CeNiSb3. The LnnMIn3n+2 (n = 1, 2, ‡; Ln = La, Ce; M = Rh, Ir) intergrowth homologous series presents a unique opportunity to study structure-property relationships. LnnMIn3n+2 (Ln = La, Ce; n = 1, 2; …

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Class Groups And Norms Of Units, Costel Ionita Jan 2004

Class Groups And Norms Of Units, Costel Ionita

LSU Doctoral Dissertations

Our object of study is relative quadratic extensions of algebraic number fields. In 'Class Number Parity', the authors P.E. Conner and J. Hurrelbrink study in detail the cases of real and CM-extensions. In this paper we generalize some of the results without any assumption on the type of the relative quadratic extension.

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Foreland Basins: Lithospheric Flexure, Plate Strength And Regional Stratigraphy, John Londono Jan 2004

Foreland Basins: Lithospheric Flexure, Plate Strength And Regional Stratigraphy, John Londono

LSU Doctoral Dissertations

Foreland basin subsidence through time is reproduced in this study, as the flexure of an elastic beam in an inviscid fluid under the vertical stress, caused by discrete-distributed loads. Thus, seismostratigraphic data from the Timor Sea peripheral foreland basin, in northwestern Australia, and the Putumayo retroarc foreland basin in the Colombian Andes, are forward modeled, at chronostratigraphic intervals, to assess the evolving geodynamic conditions of the basins. Results show that the accommodation in foreland basins varies as the depositional basement is vertically adjusted according to the regionally isostatic compensation of the lithosphere. Distributed tectonic (thrust belts) and sedimentary loads that …

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Spectroscopic Investigation Of Nitrogenase: Epr And Mcd Studies Of The Femo Cofactor And The P-Cluster, Robyn B. Broach Jan 2004

Spectroscopic Investigation Of Nitrogenase: Epr And Mcd Studies Of The Femo Cofactor And The P-Cluster, Robyn B. Broach

LSU Doctoral Dissertations

Little is known about substrate binding and reduction of nitrogenase. EPR spectroscopy is used here to observe intermediate states generated by different substrates. Two different spin states (S=3/2 and S=1/2) were exhibited for each substrate, which may result from different binding of the substrate to the cofactor (side-on or terminal binding) or the difference of the substrate binding to either Fe or Mo of the cofactor. Parallel studies were performed on a variant MoFe protein, alpha-195Gln, which exhibited different signals from the wild-type suggesting that the substituted amino acid maybe necessary to reach some mechanistic states that the …

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Protein Aggregation Studies: Inhibiting And Encouraging Β-Amyloid Aggregation, Jed Paul Aucoin Jan 2004

Protein Aggregation Studies: Inhibiting And Encouraging Β-Amyloid Aggregation, Jed Paul Aucoin

LSU Doctoral Dissertations

This work demonstrates peptide-based aggregation mediation of fibril forming peptides, notably β-amyloid (1-40), Aβ1-40. To achieve the goals of this work, Aβ1-40 aggregation was governed by ionic strength, temperature, and pH. After controlling and reproducing Aβ1-40 aggregate formation (fibrils), each peptide-based aggregation mediator was evaluated for its ability to self-aggregate and to possess surface-active properties. The incorporation of these mediators in Aβ1-40 solutions changed the surface tension and produced aggregate complexes of mediator and Aβ1-40. Evidence that Aβ1-40 fibril formation may be mediated by disorder-to-order transitions has been observed by layer formation …

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Applications Of The Titanium Catalyzed Cyclocarbonylation Towards Natural Product Syntheses, Jongtae Yang Jan 2004

Applications Of The Titanium Catalyzed Cyclocarbonylation Towards Natural Product Syntheses, Jongtae Yang

LSU Doctoral Dissertations

Recently an efficient methodology, a hetero Pauson-Khand reaction, based on titanium-catalyzed cyclocarbonylation of tethered enals for the general preparation of ¥ã-butyrolactone rings, which are typically embedded in polycyclic systems of many natural products was reported. To demonstrate this new strategy, the total syntheses of the natural products asteriscanolide and ginkgolide were investigated. The first part of this work is dedicated to synthetic efforts toward the total synthesis of asteriscanolide. Approaches highlighted by the [2,3]-Wittig rearrangement, the thermal silyloxy-Cope rearrangement, and a titanium-catalyzed cyclocarbonylation, which is the pivotal step to afford the ¥ã-butyrolactone ring. This study firmly established the utility of …

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A Distributed Quadtree Dictionary Approach To Multi-Resolution Visualization Of Scattered Neutron Data, Rion Dooley Jan 2004

A Distributed Quadtree Dictionary Approach To Multi-Resolution Visualization Of Scattered Neutron Data, Rion Dooley

LSU Doctoral Dissertations

Grid computing is described as dependable, seamless, pervasive access to resources and services, whereas mobile computing allows the movement of people from place to place while staying connected to resources at each location. Mobile grid computing is a new computing paradigm, which joins these two technologies by enabling access to the collection of resources within a user's virtual organization while still maintaining the freedom of mobile computing through a service paradigm. A major problem in virtual organization is needs mismatch, in which one resources requests a service from another resources it is unable to fulfill, since virtual organizations are necessarily …

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Synthesis, Characterization And Study Of Novel Reagents For The Detection Of Saccharides And Amino Acids, Nadia Nadette St. Luce Jan 2004

Synthesis, Characterization And Study Of Novel Reagents For The Detection Of Saccharides And Amino Acids, Nadia Nadette St. Luce

LSU Doctoral Dissertations

The design of synthetic receptors for the recognition and sensing of saccharides and amino acids is currently a major challenge. This is due to inherent structural similarity and a lack of chromophoric or fluorophoric properties of these compounds. The synthesis and study of novel detection agents for bioactive molecules as well as mechanistic studies are presented herein. The elucidation of the mechanism by which tetraarylboronic acid resorcinarene interact with sugar molecules and promote a solution color change is explored. This vast collaborative study, reveals that DMSO solutions of boronic acid functionalized resorcinarene macrocycles afford visual color changes upon heating or …

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Attachment Of Oligonucleotide Probes To Polymer Biochips And Its Application For The Detection Of Point Mutations, Yun Wang Jan 2004

Attachment Of Oligonucleotide Probes To Polymer Biochips And Its Application For The Detection Of Point Mutations, Yun Wang

LSU Doctoral Dissertations

This dissertation is on the fabrication of polymer-based microfluidic arrays for the detection of genetic mutations. Poly(methyl methacrylate) was chosen as one of the polymer substrate materials due to its low background noise, low adsorption of biomolecules, and low assembly temperature. The surface modification of polymer substrates for covalent attachment of oligonucleotide probes, the construction of fluidic channels/arrays, and hybridization kinetics will be covered. As an example of the application, point mutation detection using immobilized arrays constructed in microfluidic devices will be demonstrated. The PMMA surface was derivatized with N-lithioethylenediamine solution to introduce amine groups, which were utilized for the …

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Synthesis And Antibacterial Assessment Of Water-Soluble Hydrophobic Chitosan Derivatives Bearing Quaternary Ammonium Functionality, Mrunal R. Thatte Jan 2004

Synthesis And Antibacterial Assessment Of Water-Soluble Hydrophobic Chitosan Derivatives Bearing Quaternary Ammonium Functionality, Mrunal R. Thatte

LSU Doctoral Dissertations

Chitosan is a naturally occurring, bio-degradable, non-toxic, non-allergenic bio-polysaccharide derived from chitin, found in abundance in nature. Studies aimed at deriving newer applications of chitosan are hence of interest. Among these, one of the focuses of investigations is aimed at excellent antimicrobial activity demonstrated by chitosan. In this context, certain quaternary ammonium derivatives of chitosan have been shown in the past to be highly effective antibacterial materials. In the present study, substituted chitosan derivatives were synthesized and further quaternized using Quat-188 to produce water soluble derivatives at neutral pH. The antibacterial assessments of the quaternized derivatives of substituted chitosan were …

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New Insights Into The Binding Site Formation And The Performance Of Molecularly Imprinted Polymers, Hyunjung Kim Jan 2004

New Insights Into The Binding Site Formation And The Performance Of Molecularly Imprinted Polymers, Hyunjung Kim

LSU Doctoral Dissertations

Molecularly imprinted polymers (MIPs) are finding important applications in the field of separation science, catalysis, sensor, and immunoassays. To optimize the performance of the MIPs, it is essential to understand the underlying mechanism of the process. This research focuses on understanding binding site formation and performance, and improvement of the MIPs. Chapter 1 introduces the concept of the MIPs, and binding isotherm and affinity distribution of heterogeneous binding sites in the MIPs. Chapter 2 describes fundamental studies conducted to understand the binding site formation of the MIPs. The number of binding sites (N) and the number average association constant (Kn) …

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Modeling Longleaf Pine (Pinus Palustris Mill) Wood Properties Using Near Infrared Spectroscopy, Brian Kipling Via Jan 2004

Modeling Longleaf Pine (Pinus Palustris Mill) Wood Properties Using Near Infrared Spectroscopy, Brian Kipling Via

LSU Doctoral Dissertations

This research demonstrated model development for important wood properties using near infrared spectroscopy (NIR); it considered the effect of outside sources of error, and the ability of NIR to measure fiber morphology. Strength, stiffness, and density were successfully modeled from wood samples taken throughout 10 longleaf (Pinus palustris Mill) trees. Principal components and multiple linear regression were compared for performance in prediction of density, strength, and stiffness. I found both modeling techniques to yield similar prediction accuracies. However, I found that density could be estimated through Beer-Lambert’s law since the absorbance at all wavelengths increased with density. Also, 5 of …

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Application Of Disturbance Theory To Assess Impacts Associated With A Three-Dimensional Seismic Survey In A Freshwater Marsh In Southwest Louisiana, Aaron Stuard Bass Jan 2004

Application Of Disturbance Theory To Assess Impacts Associated With A Three-Dimensional Seismic Survey In A Freshwater Marsh In Southwest Louisiana, Aaron Stuard Bass

LSU Doctoral Dissertations

This study examined various practical and theoretical aspects of disturbance in a coastal wetland marsh in southern Louisiana. A literature review approached disturbance ecology from both practical and theoretical perspectives and assessed its applicability to developing broad predictive models. However, specific knowledge of environmental variables, competitive relationships, and the interactive effects of multiple disturbances are required for meaningful usage of these models. The Lacassine National Wildlife Refuge (LNWR) proved to be an ideal laboratory to test various aspects of ecological disturbance theory. I found that the primary disturbances affecting the LNWR have been hurricanes, droughts, water-level manipulations, prescribed burning, oil …

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On Qualitative Properties And Convergence Of Time-Discretization Methods For Semigroups, Mihaly Kovacs Jan 2004

On Qualitative Properties And Convergence Of Time-Discretization Methods For Semigroups, Mihaly Kovacs

LSU Doctoral Dissertations

In this dissertation we use functional calculus methods to investigate convergence and qualitative properties of time-discretization methods for strongly continuous semigroups. Stability, convergence, and preservation of contractivity (or norm-bound) of the semigroup under time-discretization is investigated in a Banach space setting. Preservation of positivity, concavity and other qualitative shape properties which can be described via positivity are treated in a Banach lattice framework. The use of the Hille-Phillips (H-P) functional calculus instead of the Dunford-Taylor functional calculus allows us to extend fundamental qualitative results concerning time-discretization methods and simplify their proofs, including results on multi-step schemes and variable step-sizes. We …

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Short-Term Evolution Of A Marsh Island System And The Importance Of Cold Front Forcing, Terrebonne Bay, Louisiana, Dana Ann Watzke Jan 2004

Short-Term Evolution Of A Marsh Island System And The Importance Of Cold Front Forcing, Terrebonne Bay, Louisiana, Dana Ann Watzke

LSU Master's Theses

Short-term, wave induced erosion along bay beaches in the northern Gulf of Mexico has been linked to the postfrontal phase of cold front passages. Not until recently has consideration been given to the importance of wave erosion on marshes fringing large bays during the entire cold front event. Two WAVCIS (Wave-Current-Surge-Information System) stations were established on the north and south flank of a small marsh island in Terrebonne Bay, Louisiana, to measure and elucidate the hydrodynamic response to these events. Data from WAVCIS stations, which includes wind speed and direction, air temperature, significant wave height and water level, were collected …

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