Physical Sciences and Mathematics Commons^™

Post Monitoring Of A Cyclodextrin Remediated Chlorinated Solvent Contaminated Aquifer, Rebecca Mary Hinrichs

LSU Master's Theses

Hydroxypropyl-β-cyclodextrin (HPβCD) has been tested successfully in the laboratory and in the field for enhanced flushing of low-polarity contaminants from aquifers. The cyclodextrin molecule forms a toroidal structure, which has a hydrophobic cavity. Within this cavity, organic compounds of appropriate shape and size can form inclusion complexes, which is the basis for the use of cyclodextrin in groundwater remediation. The hydrophilic exterior of the molecule makes cyclodextrin highly water-soluble. The solubility of cyclodextrins can be further enhanced by adding functional groups, such as hydroxypropyl groups, to the cyclodextrin core. The aqueous solubility of HPβCD exceeds 950 g/L. These high solubilities …

Effects Of Spinning-Wing Decoys On Flock Behavior And Hunting Vulnerability Of Local And Migrant Mallards And Other Ducks In Minnesota, Michael L. Szymanski

LSU Master's Theses

Waterfowl managers in Minnesota and other states are concerned that increased kill rates associated with the use of spinning-wing decoys (SWDs) may negatively affect local breeding populations of mallards (Anas platyrhynchos). I conducted 219 experimental hunts to evaluate hunting vulnerability of mallards to SWDs during the 2002 duck-hunting season in Minnesota. Following experimental hunts, I asked volunteer hunters to complete post-hunt questionnaires to document their hunting experience, and their use and opinions of SWDs. Finally, I used stable isotope methodology to determine natal origins of HY mallards killed during experimental hunts. I found that mallard flocks (≥1 duck) were 2.91 …

Pattern-Based Model Transformation: A Metamodel-Based Approach To Model Evolution, Sheena Judson Miller

LSU Doctoral Dissertations

Software systems continue to grow in complexity at a rapid pace, creating systems that are complex to build and evolve. The problems that accompany changes in requirements, system upgrades, and error correction produce a desire for software evolution methods that increase the efficiency and effectiveness of adapting complex software to changes. As software systems evolve, design models must be modified to accommodate the required changes. Techniques that control the changes to models in a systematic manner are a key to model evolution. A process that improves the ability to effectively modify a design, thereby enhancing design qualities, supports the need …

Leaf Litter Processing By Macrodetritivores In Natural And Restored Neotropical Mangrove Forests, Gary Eugene Raulerson

LSU Doctoral Dissertations

Knowledge of mangrove litter dynamics is crucial to an understanding of the energetic links between mangrove ecosystems and nearby estuaries and coastal waters. Previous research into the role played by macrodetritivores in Neotropical mangrove litter processing has been contradictory. This study used leaf tethering to examine the effects of macrodetritivores on initial rates of mangrove litter degradation in South Florida, USA. Leaf litter dynamics experiments were run in both natural and restored mangrove forests to assess functionality of the restoration projects. Although less important than in some other parts of the world (e.g., the Indo-Pacific), macrodetritivores played a significant role …

Address Optimizations For Embedded Processors, Sai Pinnepalli

LSU Doctoral Dissertations

Embedded processors that are common in electronic devices perform a limited set of tasks compared to general-purpose processor systems. They have limited resources which have to be efficiently used. Optimal utilization of program memory needs a reduction in code size which can be achieved by eliminating unnecessary address computations i.e., generate optimal offset assignment that utilizes built-in addressing modes. Single offset assignment (SOA) solutions, used for processors with one address register; start with the access sequence of variables to determine the optimal assignment. This research uses the basic block to commutatively transform statements to alter the access sequence. Edges in …

The Fidelity Of Red Snapper (Lutjanus Campechanus) To Petroleum Platforms And Artificial Reefs In The Northern Gulf Of Mexico, Megan Blythe Peabody

LSU Master's Theses

The habitat value of petroleum platforms for red snapper, Lutjanus campechanus, is poorly understood. However, it is widely recognized by both scientists and fishermen that the presence of platforms in the northern Gulf of Mexico (GOM) has affected the distribution of red snapper by the addition of hard substrate habitat. I evaluated the habitat value of standing and toppled platforms by monitoring the fidelity of red snapper to these structures with acoustic telemetry. In May 2003, 125 red snapper were captured with hook and line at several platforms in a 35-km2 portion of the South Timbalier oil and gas lease …

The Effects Of Nutrient Enrichment On The Decomposition Of Belowground Organic Matter In A Sagittaria Lancifolia - Dominated Oligohaline Marsh, Kristen Raye Laursen

LSU Master's Theses

Wetlands improve water quality through sedimentation and the uptake of excess nutrients. As human population increases in the coastal zone, wetlands receive greater nutrient inputs. These additional nutrients may accelerate microbial activity, leading to faster decomposition rates. This decomposition could exceed belowground organic matter production, resulting in a net reduction in soil organic matter accumulation and vertical marsh accretion. The effects of nutrient enrichment on belowground organic matter decomposition in subtropical marshes have received little attention. As such, this research examined the effects of four levels of nitrogen combined with two levels of phosphorus enrichment on belowground decomposition through the …

Parallel Molecular Dynamics Simulations Of Antimicrobial Peptides, Svetlana V. Oard

LSU Master's Theses

Molecular dynamics (MD) simulations of the wheat antimicrobial peptide â-purothionin were carried out in explicit water (~14,000 atoms) using an all-atom model. The structural properties of the peptide as a function of MD simulation, temperature, and presence of the mono- and divalent metal ions were investigated. The accuracy and scalability tests of the code Peach 3.8 for our system were performed on the Intel Xeon-based Linux cluster SuperHelix at Louisiana State University (LSU). The code showed the reliable accuracy and the parallel efficiency of 0.61 for ~14,000 particles on 16 processors. The microcanonical (MC) MD simulation of â-purothionin in water …

State-Level Environmental Risk Perception: An Analysis Of 20 Comparative Risk Reports, Mandy Green

LSU Master's Theses

Research was conducted to identify the states that compiled Comparative Risk Reports and the year in which the study was completed. The information relating to the type of committee that compiled the risk report and the final risk rankings was examined. State Comparative Risk Reports were collected for twenty states and the risk rankings that each state compiled were reviewed to determine which states ranked third generation environmental problems and the ranking that those problems were given. The risk reports compiled by each state were also used to determine which states ranked natural resource based problems and the ranking that …

Mortality Of Pen-Raised White-Tailed Deer (Odocoileus Virginianus) Released On Three Areas In Louisiana, Barret Keith Fortier

LSU Master's Theses

I monitored 60 radio-collared and tagged pen-raised white-tailed deer (Odocoileus virginianus) to ascertain mortality rates on three areas in Louisiana from April 2001 - April 2002. Two of 60 were not used in the analysis because mortality occurred from complications with darting and an affixed radio-collar. Study deer were exposed to legal hunting mortality only if they emigrated from the three study areas. Twenty deer were released to the wild on the Louisiana State University Deer Study Area (LSUDSA) (4,810 ha), where 9 of 20 (45%) suffered mortality. Harvest accounted for 56%, vehicles 22%, and other 22% of the mortality …

The Radon-Gauss Transform, Vochita Mihai

LSU Doctoral Dissertations

Gaussian measure is constructed for any given hyperplane in an infinite dimensional Hilbert space, and this is used to define a generalization of the Radon transform to the infinite dimensional setting, using Gauss measure instead of Lebesgue measure. An inversion formula is obtained and a support theorem proved.

Microelectrophoresis System Utilizing Conductivity Detection Analyzing Biological Molecues, Michelle Galloway

LSU Doctoral Dissertations

Microfabrication technology has proven to be a valuable tool for creating polymer-based devices utilized in chemical and biochemical assays. Although, reducing the size of the device allows for short analysis times and reduces the reagent demand to ultrasmall volumes (< 1 nanoliter), a resulting consequence is the constraint placed on the limits of detection associated with the detector hardware required for readout. To overcome such constraints, laser-induced fluorescence (LIF) is often employed as a detection method as it provides low detection limits, which approach the single molecule level. Unfortunately, most LIF systems do not offer the benefits of miniaturization, with the detector components (i.e. laser, optics, filters) often times requiring a much larger footprint compared to the device. Another readout strategy that has shown promise for these devices is conductivity detection. Detection can be accomplished using either conventional-size or microfabricated electrodes, which can be integrated on the device. Although conductivity has been commonly used to detect inorganic or small organic species, the potential for detection of biological species has received little attention. In this work, an integrated conductivity detector was developed for the analysis of amino acids, peptides, proteins, and oligonucleotides (double-stranded DNA). Using the detector, mass detection sensitivities in the range of 10^-18 - 10^-21 moles were achieved. To increase the throughput of the system a state-of-the-art, multichannel device with a conductivity array detector was devised. This device, which consists of a 16-channel fluidic network and a printed circuit board, is geared toward automating three-processing steps onto a single fluidic platform including purification, preconcentration and detection for downstream parallel processing.

Quantification Of Marine Sediment Properties From Planar And Volumetric Pore Geometries, Allen Hagerman Reed

LSU Doctoral Dissertations

Pore geometry and topology are important determinants of sediment physical properties, such as porosity and permeability. They also influence processes that occur in the sediment, such as acoustic propagation, attenuation, and dispersion, single- and multi-phase fluid flow, and hydrodynamic dispersion. This study uses images to evaluate pore geometry and topology of ooid (subspherical particles) and siliclastic (angular quartz) sand that was collected from the marine environment south of Bimni Bahamas and Ft. Walton Beach, FL, respectively. Image analysis techniques and predictive tools enable insight into the relationships among sediment pore geometry, topology, and physical properties for these differently shaped sands. …

Electronic Structural Investigations Of Bi- And Polymetallic Complexes Using Quantum Mechanical Methods, Zakiya Sheni Wilson

LSU Doctoral Dissertations

Understanding the dynamics influencing chemical reactivity is essential for properly exploiting matter into more useful purposes. In that manner, computational chemistry is a tool frequently used to study chemical properties at the most intimate level, i.e. the single molecule.

With this work, we probe the chemistry governing a variety of multi-faceted bi- and polymetallic compounds. To date our research consists of four major projects: bimetallic rhodium-catalyzed hydroformylation and aldehyde-water shift hydrocarboxylation catalysis; a novel linear M-H-M interaction in a bridged bis(dialkylphosphino)methane complex of nickel; and CeBe₁₃, a heavy fermion conductor. Computational investigations on these systems allow us to …

Comparison Of The Efficiency Of Utilization Of Amino Acids From Intact Protein And Amino Acids In Crystalline Form By Channel Catfish, (Ictaluras Punctatus), Amogh Arun Ambardekar

LSU Master's Theses

Two laboratory feeding trials were conducted to quantify differences in the digestibility and absorption of dietary amino acids provided in intact protein or in purified amino acid mixtures. In the first experiment, 36 channel catfish (346 ± 47 g) were force-fed one of six practical feed ingredients (blood meal, corn meal, fish meal, meat and bone meal, soybean meal or wheat middlings), or a mixture of crystalline amino acids designed to duplicate the amino acid composition of each of the practical ingredients. Apparent digestibility coefficients (ADC) were calculated for 15 amino acids in each practical ingredient and in each amino …

Temperature Effects On Spawning And Fingerling Production Of Channel Catfish Ictalurus Punctatus, Patrice Arnold Pawiroredjo

LSU Master's Theses

The goal of this study was to develop several techniques that utilize the use of geothermal water that can contribute to increased profitability for commercial catfish producers. The primary objectives of this study were to: 1) determine the heating requirement using degree-days of channel catfish spawning 2) improve the efficiency of artificial spawning and, 3) evaluate the effectiveness of stocking outdoor ponds and pools with channel catfish fry. The heating requirement for channel catfish spawning was determined to be between 99 and 129 degree days at the peak of spawning. There was no difference in degree-day values between spawns collected …

Investigation Of Accuracy In Quantitation Of 18f-Fdg Concentration Of Pet/Ct, Yuri Ishihara

LSU Master's Theses

The PET/CT scanner has been recognized as a powerful diagnostic imaging modality in oncology and radiation treatment planning. Traditionally, PET has been used for quantitative analysis, and diagnostic interpretations of PET images greatly relied on a nuclear medicine physician’s experience and knowledge. The PET data set represents a positron emitter’s activity concentration as a gray scale in each pixel. The assurance of the quantitative accuracy of the PET data is critical for diagnosis and staging of disease and evaluation of treatment. The standard uptake value (SUV) is a widely employed parameter in clinical settings to distinguish malignant lesions from others. …

Nature And Dynamics Of Late Miocene/Early Pliocene Ice-Sheet Grounding Events On The Pacific Margin Of The Antarctic Pennisula Outer Continental Shelf, David C. Egan

LSU Master's Theses

Package-3 unconformities identified by Bart and Anderson (1995) were mapped to evaluate their glacial unconformity interpretation using a regional grid of single channel seismic data from the Antarctic Peninsula outer continental shelf. Detailed correlations show many crosscutting relationships within Package 3 such that the unconformities and units they bound are not regionally continuous across the margin. Comparison of Package-3 unconformities with the modern bathymetry reveals that cross-shelf trough and bank morphology is absent, which indicates that ice streams probably did not exist on the shelf during Package-3 time. On the continental shelf, only the middle part of Package 3 is …

Estimating The Population Of Greater And Lesser Scaup During Winter In Off-Shore Louisiana, Sean David Kinney

LSU Master's Theses

I analyzed data from an experimental aerial transect survey, using stratified random sampling, to estimate wintering populations of greater scaup (Aythya marila) and lesser scaup (Aythya affinis) (hereafter scaup) in off-shore waters along the coast of Louisiana during winters 2000-2002. My objectives were to evaluate anecdotal reports of large numbers of scaup in off-shore waters of Louisiana during winter, and to develop estimates and confidence intervals for numbers of scaup in this area. My analysis yielded estimates of 815,700, 420,600, and 791,000 scaup in off-shore Louisiana for years 2000-2002, respectively. Confidence intervals were 1,087,000 to 545,000, 594,300 to 247,000, and …

Physical, Chemical, And Mechanical Properties Of Bamboo And Its Utilization Potential For Fiberboard Manufacturing, Xiaobo Li

LSU Master's Theses

This study investigated the chemical, physical, and mechanical properties of the bamboo species Phyllostachys pubescens and its utilization potential to manufacture medium density fiberboard (MDF). The result showed holocellulose and alpha-cellulose content increased from the base to the top portion. There was no significant variation in Klason lignin content or ash content from the base to the top portion of the bamboo. The outer layer had the highest holocellulose, alpha cellulose, and Klason lignin contents and the lowest extractive and ash contents. The epidermis had the highest extractive and ash contents and the lowest holocellulose and alpha-cellulose content. Specific gravity …

Determining Epigenetic Instability In Normal And Diseased Human Vulva, Kirk Hutchinson

LSU Master's Theses

Epigenetics is defined as the study of heritable changes of DNA. One such component of epigenetic regulation is DNA methylation in humans. In neoplastic cells epigenetic controls are often dysregulated, especially in the promoter region of CpG islands. Global hypomethylation along with region specific hypermethylation of CpG islands in the promoter region of tumor suppressor is often indicative of neoplastic cells. In cancer, CpG island cytosine hypermethylation has been observed in more than fifty genes, including known tumor suppressor and DNA repair genes. Squamous cell carcinoma (SCC), lichen sclerosis (LS), and adjacent normal tissues were obtained by radical vulvectomies of …

Individual And Landscape-Level Effects Of Selective Herbicides, Mowing, And Prescribed Fire On Habitat Quality For Northern Bobwhite (Colinus Virginianus), Charles Lynn Kitts

LSU Master's Theses

Northern bobwhite (Colinus virginianus) populations have been declining throughout their range during the past 30 years primarily because of a result of loss of early successional habitat. Specifically, intensive silviculture practices and reduction in the use of prescribed fire has led to this loss. I studied effects of management practices (selective herbicides, mowing, and prescribed fire) on male and covey distribution, and brood-rearing habitats on Jackson-Bienville Wildlife Management Area (JBWMA). Specifically, I used calling surveys to assess landscape characteristics associated bobwhite distribution. I also measured vegetation and arthropod response, using imprinted bobwhite chicks, pitfalls, and sweep nets, to different habitat …

Overlap Zones, Growth Faults, And Sedimentation: Using High Resolution Gravity Data, Livingston Parish, La, Carrie Alison Cazes

LSU Master's Theses

In south Louisiana, parallel to the coast of the Gulf of Mexico, are belts of east-to-west trending, listric-normal faults with associated contemporaneous sedimentation and fault movement. The Tepetate-Baton Rouge Fault system in south-central Louisiana contains individual fault segments which are arcuate and overlap each other in map view, as seen on LiDAR data. Gravity survey data, with a sample spacing of 20 to 50 m, was collected across normal fault scarps. Structural ramps may form in the area between overlapping normal fault segments creating an east-to-west gradient. This gradient change may divert streams and provide areas for coarse-grained sediments to …

Query Of Image Content Using Wavelets And Gibbs-Markov Random Fields, Imtiaz Hossain

LSU Master's Theses

The central theme of this thesis is the application of Wavelets and Random Processes to content-based image query (on texture patterns, in particular). Given a query image, a content-based search extracts a certain representative measure (or signature) from the query image and likewise for all the target images in the search archive. A good representative measure is one that provides us with the ability to differentiate easily between different patterns. A distance measure is computed between the query properties and the properties of each of the target images. The lowest distance measure gives us the best target match for the …

A Meta-Analysis Of Randomness In Human Behavioral Research, Summer Ann Armstrong

LSU Master's Theses

This work analyzes the concept of randomness in binary sequences from three different perspectives: mathematically, statistically, and psychologically and examines the research on human perception of randomness and the question of whether or not humans can simulate random behavior. Generally, research shows that human subjects have great difficulty producing random sequences, even when they are instructed and motivated. We survey some of the literature and present some leading theoretical proposals. Finally, we present some basic statistical tests that can be used to evaluate randomness in a given binary sequence.

Migmatization Of Archean Aluminous Metasediments From The Eastern Beartooth Mountains, Montana, U.S.A., Andrew T. Maas

LSU Master's Theses

Geothermobarometry, mineral compositions and textures, and thermodynamic models suggest biotite dehydration melting occurred in the peraluminous rocks of the eastern Beartooth Mountains. These Archean metapelitic migmatites are metatexites and diatexites, and have typical metamorphic assemblages of Qtz + Pl + Kfs + Bt + Sil +/- Grt +/- Crd. The subsequent in situ crystallization of the magma derived from the biotite dehydration created migmatitic leucosomes in the rocks. These leucosomes are primarily composed of quartz, plagioclase and potassium feldspar. Water derived from the dehydration of biotite was dissolved in the melted phase. Crystallization of the magma reintroduced this water to …

A Comparison Of A High-Resolution Survey And A Three-Dimensional Seismic Survey In A Feature-Rich Region Of The Green Canyon Area, Gulf Of Mexico, Bruce Miles Samuel

LSU Master's Theses

Recent advances in Autonomous Underwater Vehicle (AUV) technology have revolutionized the positioning and accuracy of high-resolution deep sea mapping tools. Geologic hazard and engineering surveys by AUV’s are producing high-resolution data sets of a quality that has never before been seen. Three-dimensional (3D) seismic data, though traditionally used for only deep subsurface mapping of large areas, is now being reprocessed at a higher resolution and utilized in well site investigations and geologic hazard assessments. This study makes a comparison between a 3D seismic survey and an AUV high-resolution survey in order to determine the strengths and weaknesses of both of …

Freshwater And Nutrient Inputs To A Mississippi River Deltaic Estuary With River Re-Introduction, Emily Christina Grace Hyfield

LSU Master's Theses

In this study, I quantified freshwater and nutrient inputs in the Breton Sound estuary which is receiving freshwater reintroduction in an effort to restore deteriorating wetlands. Almost all wetlands of the Mississippi deltaic plain are isolated from riverine input due to flood control levees along the Mississippi River. This has altered water and nutrient budgets and is a primary cause of the massive wetland loss in the delta. Maintenance of the delta depends on a healthy, functioning ecosystem which includes riverine input. The Breton Sound estuary is located southeast of New Orleans and until recently was hydrologically isolated from direct …

Characteristics Of Hurricane Lili's Intensity Changes, Adele Marie Babin

LSU Master's Theses

Rapid intensity changes of Hurricane Lili in the Gulf of Mexico (GOM) were studied in three distinct ways: climatology, satellite remote sensing, and surface meteorological and oceanographic measurements. Each research methodology provided insight about Hurricane Lili's intensity behavior. A climatology of rapid and explosive intensifications of hurricanes was developed using minimum central pressure observations for the Atlantic tropical cyclone record. Results showed these events were frequent, especially in the GOM. The majority of intensification events occurred ≤ 24 h before landfall, with a third to one-half ≤ 12 h. Lili emerged anomalous as the only hurricane to weaken at a …

Assessing Landscape-Level Impacts Of Red Imported Fire Ants On Native Faunal Communities In Pine-Dominated Forests, Keri Elizabeth Landry

LSU Master's Theses

Since the accidental introduction of red imported fire ants (Solenopsis invicta Buren, RIFA) into Mobile, Alabama in the 1930’s, the invasion of this species into other areas across the southeast has increased drastically. RIFA have been implicated in the disruption of ecosystems and decreases in biodiversity. Most research on effects of RIFA on vertebrates and invertebrates have focused on small spatial scales and single species. I examined established populations of RIFA in relation to native ground-dwelling arthropods and small mammal communities in longleaf-pine and pine-hardwood forests. I evaluated the efficacy of using Amdro® to control RIFA and determined the effect …